We construct a holographic p-wave superconductor with excited states in the 4D Einstein–Gauss–Bonnet gravity using the Maxwell complex vector field model. In the probe limit, we observe that, the higher curvature correction or the higher excited state can hinder the vector condensate to be formed in the full parameter space, which is different from the holographic s-wave superconductor. Regardless of the choice of the vector mass by selecting the value of m2L2 or m2Leff2, we note that the critical chemical potential becomes evenly spaced for the number of nodes and that the difference of the critical chemical potential between the consecutive states depends on the curvature correction. Moreover, we find that the higher curvature correction or the higher excited state will alter the universal relation of the gap frequency, and the pole and delta function of the conductivity for the excited states can be broadened into the peaks with the finite width as the curvature correction increases.