Maximum Surface Area Research Articles

Deposition of Fine-Pitch Indium Bumps on Single Die

Photolithographic lift-off at wafer level is a wellestablished method for depositing indium bumps onto pixels of electronic components such as sensors and application-specific integrated circuits (ASIC). These indium bumps form interconnects between pixels of the components during flip-chip bonding to make devices such as radiation detectors. Such components are not always available on wafer-scale, and single dies need to be processed in small-scale production, R&D, or for Cd(Zn)Te detector material. Photolithography on single dies is ineffective due to the edge-bead of photoresist that compromises perfect indium deposition onto pixels near the periphery of the die. To utilize the maximum surface area of a die, a rigid mask with apertures (shadow mask) is an adequate substitute for the photoresist. Different mask designs and production techniques for fine-pitch indium bump arrays are investigated by testing electroformed stencils or micromachined silicon (Si) membranes as shadow masks. For the indium deposition, the sensor and ASIC dies are clamped into custom-made jigs that include shadow masks. Alternatively, dies can be adhered to shadow masks with soluble adhesive. The apertures of a mask are aligned to the pixel array of the detector component. Bump arrays with 250μm- and 100μm-pitch were demonstrated with electroformed stencils. For smaller pitch (55μm) and bump diameter of ~20μm, specialized masks from Si membranes are tested. Components with successfully deposited indium bump arrays were subsequently flip-chip bonded at room temperature without reflowing the indium. A bond yield of at least 99.9% pixels for such flip-chip bonded radiation detector was shown using the read-out signal from exposure with a flat field X-ray radiation of an Am-241 sealed source.

Synthesis, self-aggregation, thermal stability and cytotoxicity trends of alkyloxypropoxycyclohexane based pyridinium ionic liquids

New ether-functionalized pyridinium ionic liquids (ILs) has been synthesized by simple methodology and described by different spectroscopic techniques. Presence of two positional isomers has been confirmed with the help of NMR spectroscopy. The critical micelle concentration and other surface parameters of these ILs were deduced by conductivity, surface tension and fluorescence method. A collection of useful physical parameters i.e. critical micelle concentration (cmc), surface tension accomplished at cmc (γcmc), effectiveness of diminution in surface tension (Πcmc), maximum surface excess concentration (Ʈmax) and minimum surface area per molecule (Amin) at the air–water interface were also estimated. The average size of aggregates formed by investigated pyridinium ILs have been well examined by dynamic light scattering (DLS) experiments. The thermal degradation analysis of the present ILs has also been suggested that these ILs possessed thermal stability ranges from 200 °C to 240 °C. The investigated ILs have also been tested by MTT assay (3-(4, 5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazolium bromide) on the C6 glioma cell line and found to revealed very low cytotoxicity in the concentration range required for biomedical applications. Such a low cytotoxicity of present ILs opens several new applications in the many biological purposes like drug and gene delivery agents. The physical study of investigated ILs indicate that the presence of ether functionality and varying hydrophobic chain length significantly altered the physicochemical properties of these pyridinium ILs than related to earlier synthesized N-(cyclohexanoxycarbonylmethyl) and 3-Cyclohexyloxy-2-Hydroxypropyl Pyridinium and Imidazolium surface active ILs.

Preparation of hollow carbon nanospheres from oxidation of spent tyre oil‐derived carbon black in air

AbstractHollow carbon nanospheres (HCNS) were prepared from carbon black (CB) derived from spent tyre pyrolysis oil. The pristine CB produced by partial oxidation of the pyrolysis oil in a drop tube furnace was subsequently oxidised in air in a fixed bed reactor to yield HCNS. The effect of oxidation temperature (300 to 700°C) and time (1 to 8 h) on the burn‐off (Bt) of the sample over the duration (t) of oxidation and average reaction rate (Rt) was assessed. The BET surface area and pore volume and the nanostructure of the HCNS samples obtained were characterised using N2 adsorption–desorption and high‐resolution transmission electron microscope (HRTEM) techniques, respectively. Higher temperature and longer oxidation time led to higher Bt. As Bt increased, the BET surface area and pore volume initially increased linearly due to the removal of the amorphous core and then decreased because of the collapse of the shell of the carbon nanostructure. At Bt of ~56%, the maximum BET surface area and pore volume of the HCNS were 383.2 m2 g−1 and 0.39 cm3 g−1, respectively, compared to ~19.5 m2 g−1 and 0.033 cm3 g−1 of the pristine CB. The HRTEM images indicate that the change in BET surface area corresponds to the formation of the HCNS, as the core of the CB particle was preferentially consumed to create a hollow structure. The formation of HCNS follows an internal oxidation model, which is characterised by rapid core consumption and relatively slow shell consumption.

The role of baseline 2-[18 F]-FDG-PET/CT metrics and radiomics features in predicting primary gastric lymphoma diagnosis.

Diffuse Large B-Cell Lymphomas (DLCBL) and mucosa-associated lymphoid tissue (MALT) are the two most common primary gastric lymphomas (PGLs), but have strongly different features. DLBCL is more aggressive, is frequently diagnosed at an advanced stage and has a poorer prognosis. The aim of this retrospective study was to explore the role of fluorine-18-fluorodeoxyglucose positron emission tomography/computed tomography (2-[18 F]-FDG-PET/CT) and radiomics features (RFs) in predicting the final diagnosis of patients with PGLs. Ninety-one patients with newly diagnosed PGLs who underwent pre-treatment 2-[18 F]-FDG-PET/CT were included. PET images were qualitatively and semi-quantitatively analyzed by deriving maximum standardized uptake value body weight (SUVbw), maximum standardized uptake value lean body mass (SUVlbm), maximum standardized uptake value body surface area (SUVbsa), lesion to liver SUVmax ratio (L-L SUV R), lesion to blood-pool SUVmax ratio (L-BP SUV R), metabolic tumor volume (gMTV) and total lesion glycolysis of gastric lesion (gTLG), total MTV (tMTV), TLG, and first-order RFs (histogram-related and shape related). Receiver-operating characteristic (ROC) curve analyses were performed to determine the differential diagnostic values of PET parameters. The final diagnosis was DLBCL in 54 (59%) cases and MALT in 37 cases (41%). PGLs showed FDG avidity in 83 cases (90%), 54/54 of DLBCL and 29/37 of MALT. All PET/CT metabolic features, such as stage of disease and tumor size, were significantly higher in DLBCL than MALT; while the presence of H. Pylori infection was more common in MALT. At univariate analysis, all PET/CT metrics were significantly higher in DLBCL than MALT lymphomas, while among RFs only Shape volume_vx and Shape sphericity showed a significant difference between the two groups. In conclusion we demonstrated that 2-[18 F]-FDG-PET/CT parameters can potentially discriminate between DLBCL and MALT lymphomas with high accuracy. Among first-order RFs, only Shape volume_vx and Shape sphericity helped in the differential diagnosis.

Tetraethylenepentamine-modified Cu2(OH)PO4 for efficient CO2 capture

This study focused on creating tetraethylenepentamine (TEPA) modified copper hydroxyl phosphate (Cu2(OH)PO4) adsorbents via physical impregnation. The TEPA-modified Cu2(OH)PO4 adsorbents were analyzed for structure and characteristics through SEM, XPS, TGA, N2 adsorption–desorption studies. The effects of different parameters (TEPA contents, temperatures, flow rates and CO2 concentrations) and cyclic stability were evaluated. Kinetics, thermodynamics and density functional theory (DFT) calculations were employed to understand the impact of TEPA modification on Cu2(OH)PO4 for CO2 adsorption. Experimental results showed that a 50 wt% loading yielded optimal results, with a maximum surface area of 65.12 m2/g, a pore volume of 0.29 cm3/g, and a maximum adsorption capacity of 6.54 mmol/g. The amine efficiency is extraordinary which reached 67 %. The best performance occurred at 60 °C, 30 ml/min gas flow, and 15 vol% CO2 concentration. The pseudo-second-order kinetic model better described the CO2 adsorption process. The adsorption process was found to be exothermic at 20–60 °C and endothermic at 60–80 °C, suggesting physical–chemical co-adsorption and chemical adsorption, respectively. The adsorption activation energy is 34.322 kJ/mol. The DFT shows the adsorption energy ranged from −0.565 eV to −5.584 eV, indicating coexistence of physical and chemical adsorption. The d-band theoretical calculation shows that TEPA doping is beneficial to the adsorption of CO2 by Cu2(OH)PO4. Minimal structural modification of the adsorbate was observed, with bond lengths changing by less than 1 %. The density of states (DOS) curve shifted toward lower-energy states after adsorption, suggesting a more stable structural configuration post-adsorption. We have proved that TEPA-Cu2(OH)PO4 has good adsorption for CO2 and is an efficient green adsorption material.

On the mechanical properties of dual-scale microlattice of starfish ossicles: A computational study

While engineering cellular solids, either stochastic foams or architected lattices, are usually made of polycrystalline or amorphous materials, echinoderms (e.g., sea urchins, starfish, and brittle stars) build their microporous skeletal elements with single-crystalline calcite. This class of biomineralized cellular solid, known as stereom, also exhibits a vast diversity in pore morphology, ranging from random open-cell foams to fully periodic lattices. In particular, the skeletal elements (also known as ossicles) of some starfish species are composed of a diamond-triply periodic minimal surface (diamond-TPMS) microlattice. In addition, the crystallographic symmetries at both atomic (calcite) and lattice (diamond-TPMS) levels are precisely aligned. Here we investigate the mechanical performance of this unique dual-scale microlattice and discuss the synergistic effects of atomic- and lattice-scale crystallographic coalignment. Our computational and theoretical analysis suggests that the mechanical isotropy of ossicles is enhanced due to the property compensation between the atomic-level and lattice-level architectures. Moreover, the observed 50 vol% relative density in the diamond-TPMS microlattice of ossicles may be a result of achieving overall mechanical isotropy, minimal surface curvature, and maximized surface area. We believe the methodology introduced here will be useful for understanding the mechanical behavior of natural crystalline cellular solids such as echinoderms’ stereom and designing dual-scale lattice materials.

Thermal energy management using supersonically sprayed copper pyramids decorated with zinc oxide nanowires for surface cooling

Miniaturized microelectronics or small modular reactors (SMRs) simultaneously undergo an increase in heat flux and a decrease in size with the enhancement of device functionalities. Therefore, efficient convection cooling is required to prevent the malfunctioning of electronic devices or small nuclear reactors. Herein, mesh-patterned copper pyramids were fabricated via supersonic spraying for surface cooling applications. Zinc oxide nanowires (ZnO NWs) were patterned on top of the copper pyramids to produce a highly efficient cooling system for a high-heat-flux surface by increasing the overall surface area of the pyramids. In addition, ZnO NW decoration imparted superhydrophilicity to the surface with firm anchoring and spreading of impacting spray liquid drops until complete evaporation. The effects of macroscale pyramid mesh resolution and introduction of ZnO NWs on the spray cooling efficiency were quantified and compared. Herein, the pyramids with coarse resolution and ZnO NWs yielded the highest heat flux during the drop impact heat transfer process and the lowest surface temperature under air and spray cooling conditions owing to the maximized surface area. The use of the pyramids and introduction of ZnO NWs increased the Leidenfrost temperature from 140 to 190 °C, thereby expanding the range of the evaporation cooling regime.

Effect of asphalt component distribution characteristics in layered porous carbon on performance of supercapacitors

Petroleum asphalt, characterized by its rich aromatic hydrocarbon structures and high carbonization yield, emerges as an ideal precursor for generating porous carbons intended for supercapacitors (SCs). Despite asphalt's classification into four distinct components, the intricate composition due to its diverse sources still presents an unresolved challenge when it comes to elucidating the predominant structural characteristics underlying porous carbons. In the present investigation, we adopted potassium bicarbonate (KHCO3) as a templating agent, and the potassium-containing compounds were thermally polymerized with carbon-based free radicals to facilitate the synthesis of porous carbon materials through carbonization process. We observed that the fabricated porous carbon with a substantial content of heavy fraction (68.5 wt. %) demonstrated the maximal pore volume (1.02 cm3 g−1) and specific surface area (SSA) of 1229 m2 g−1, yielding in the power density of 625 W kg−1 at the energy density of 17.88 W h kg−1 used 1 M tetraethylammonium tetrafluoroborate in acetonitrile (TEATFB/AN). Notably, we corroborated the reliability of the entire process through a rigorous scaling-up experiment to 10 g, demonstrating entirely consistent performance. Our research introduces a novel avenue for strategically selecting petroleum asphalt precursors, with the overarching objective of producing cost-effective carbon materials endowed with commendable performance attributes.

Feasibility of monitoring floodplain on-farm water storages by integrating airborne and satellite LiDAR altimetry with optical remote sensing

Small water storages (≤ 500 ha surface area) enhance water supply for agricultural, human and livestock consumption. Their oftentimes large numbers and wide geographic spread, plus inaccurate or absent in situ metering, make their inclusion in water resource management difficult. This research assessed the capabilities of satellite optical remote sensing and LiDAR altimetry to characterise small water storages used for irrigation, so they can be included in water resources assessments. Landsat and Sentinel-2 water maps were integrated with airborne and satellite LiDAR altimetry to assess: (i) locations; (ii) elevation-area-volume relations; (iii) dates of construction/decommissioning; (iv) actual evaporation losses; and (v) storage volume changes of floodplain on-farm water storages (FoFWS) used primarily for cotton irrigation in the semi-arid Barwon-Darling region (142,173 km2), Australia. These remotely sensed characteristics would enable the representation of FoFWS in river system models and in regional water management plans, thus enhancing socioeconomic and environmental outcomes. Results from Landsat water maps showcased the growth in FoFWS surface area. In January 1988 there were 17 FoFWS with a total maximum surface area of 101.89 ha. By December 2021, the then 105 FoFWS maximum surface area was 5587.68 ha; a 55-times increase. For the first time in a regional context, mean annual (2000/01–2020/21) standing water evaporation losses were estimated for all FoFWS. These accounted to 52.47 MCM/year, which is a substantial ∼27% of the estimated long-term mean regional irrigation diversion limit (189 MCM/year). Elevation measurements from satellite LiDAR altimetry data, specifically GEDI and ICESat-2, were evaluated to assess if water volumes in FoFWS can be estimated through elevation-area-volume relations from a 1 m digital elevation model derived from airborne LiDAR data. Although GEDI's spatially variable footprint and ICESat-2's 91-day repeat cycle render them insufficient to monitor changes in water volumes in FoFWS, both satellite LiDAR altimeters provided accurate water level observations, with root mean squared differences (RMSD) of 0.38 m for GEDI and 0.12 m for ICESat-2, when compared to in situ water level measurements. ICESat-2's 0.7 m along-track sampling interval also detected changes of FoFWS structural features, such as increases in wall heights in recent years. This study demonstrated the value of integrating high-resolution airborne LiDAR data with satellite altimetry (LiDAR and/or radar interferometry), along with satellite optical water maps and rates of actual evaporation, to monitor FoFWS and other similar individually small yet collectively large reservoirs. Where similar data are available globally, then accurate information about small and dispersed water storages across poorly metered irrigated agricultural landscapes can be retrieved. Doing so will improve water resource management in the Barwon-Darling region, and in similar semi-arid and arid areas globally where irrigated agriculture is present.

Anti-inflammatory effect of high flux dialyzer surface area 2.6m2 in high flux hemodialysis and hemodiafiltration

Dialysis therapy has remarkably evolved through the innovation in dialyzers and hemodialysis modalities, enhancing patients’ quality of life. The efficacy of dialysis can be determined by measuring the reduction ratio (RR) of middle molecules such as Interleukin-6 (IL-6) and Procalcitonin. In our study, we tested a high-flux dialyzer, BIOPURE (Biorema) 260 HF, with a surface area (SA) of 2.6 m2, in terms of IL-6 and Procalcitonin removal while performing high-flux hemodialysis (HF-HD) and post-dilution online hemodiafiltration (OL-HDF). This crossover study comprised 25 patients who received a session of HF-HD using the BIOPURE (Biorema) 260 H, followed by a session of post-dilution OL-HDF. A washout period of 2 weeks was instilled between the two sessions, during which the patients received HF-HD using high-flux dialyzers (maximum SA 2.0 m2). All patients’ pre/post dialysis concentrations of IL-6 and procalcitonin were measured. The dialyzer used in this study resulted in a significant IL-6 RR of 44.92±5.11% (p<0.001) with HDF and 32.48±5.72% (p<0.001) with HF-HD; and a procalcitonin RR of 50.32±3.94% (p<0.001) with HDF and 41.80±4.32% (p<0.001) with HF-HD. In conclusion, the dialyzer BIOPURE (Biorema) 260 HF (SA 2.6 m2) is efficient in eliminating IL-6 and procalcitonin, especially with OL-HDF compared to HF-HD, with acceptable albumin loss in the dialysate.

INCREASE IN LEAF SURFACE AND PHOTOSYNTHETIC ACTIVITY OF SOYBEAN PLANTS DEPENDS ON SOWING RATE AND ROW WIDTH

An essential condition for obtaining high soybean yields is the presence of an optimal leaf surface area. An important condition for obtaining the optimal leaf area in plants is the formation of a certain density of plants per unit area. It is known that the optimal area of the leaf surface, for which a high yield of soybean seeds is formed, is considered to be an area within the range of 40–50 thousand m2/ha. The purpose of the research was the determined dependence of the formation of the leaf surface area and the photosynthetic activity of soybean plants under the influence of the sowing rate and the width of the rows. The research was conducted during 2021–2023 at the experimental field of the VSP "Zalischytskyi Vocational College named after E. Khraplyvyh NUBiP of Ukraine". The following methods were used in the research process: field, laboratory, mathematical and statistical using generally recognized methods and methodical recommendations. The experiment was conducted on dark gray podsolized soil. The experiment was based on a three-factor scheme, where Diadema Podillia and Mentor varieties were factor A, and row width was factor B (15 cm – control, 30 cm and 45 cm); factor C is the sowing rate (500 thousand/ha - control, 600 and 700 thousand pieces of similar seeds per 1 ha. The predecessor is winter wheat. The conducted studies showed that the maximum leaf surface area was the Mentor variety - it reached 37,7-44,7 thousand/m2/ha during the seeding period. In the variety Diadema Podillia, the area of the leaf surface grew more slowly and reached the maximum size – 36,3-43,0 thousand m2/ha during the seeding period. The largest assimilation surface of soybean plants was formed at seed sowing rates of 500-600 thousand/ha in the Mentor variety, and in the Diadema Podillia variety at seed sowing rates of 600-700 thousand/ha. and for row widths of 30 and 45 cm in both varieties. It was established that the photosynthetic potential of Diadema Podillia soybean during the period of germination - full maturity was within the range of 1,95-2,21 million m2 days/ha, in the Mentor variety – 2,16-2,56 million m2 days/ha.

Peanut Oil Cake Biomass‐Derived Hierarchical Porous Carbon by Dual Step Activation as Potential Electrodes for Fabrication of Prototype Symmetric Supercapacitor Device

Peanut oil cake biomass is a major by‐product of oil industry and can be a suitable precursor for the production of biomass‐based porous carbon. Herein, dual‐stage activation, physical activation at 400°C, and chemical activation using KOH between 600 and 900°C are adopted to prepare hierarchical porous carbons (HPCs) from peanut oil cake biomass for use as electrode material in electrochemical supercapacitors. The textural and structural properties of the HPC were evaluated by N2‐adsorption/desorption, X‐ray diffraction, Raman, FT‐IR spectroscopy, and scanning electron microscopy. The prepared HPC inherited sufficient micropores and mesopores distribution with a maximum BET surface area of 640 m2/g. The electrochemical properties of the HPC electrodes were evaluated by cyclic voltammetry, galvanostatic charge–discharge, and electrochemical impedance spectroscopic analysis. Among different HPC electrodes prepared, the carbon prepared at 800°C (HPC‐P8) electrode material exhibited a high specific capacitance of 187 F/g at 0.5 A/g in 1M Na2SO4 electrolyte in three‐electrode systems. Symmetric supercapacitors were also fabricated using HPC‐P8//HPC‐P8 as positive and negative electrodes using 1M Na2SO4 electrolyte, in a two‐electrode cell configuration via split cell method. Maximum specific capacitance of 30 F/g was achieved with superior cycle stability of 93.8% capacitance retention over 5,000 cycles for the symmetric device. The device operated at a wide potential window (0–2.0 V) resulted in appreciable specific energy and power density of 15.89 Wh/kg and 493 W/kg, respectively. HPC‐P8 had an ion diffusion coefficient of 7.79 × 10−8 cm2/s which is higher than the other prepared carbon samples. The symmetric device showed relatively high charge storage capacity and cyclic stability without any material degradation. The fabricated prototype portable supercapacitor module was tested for red LED glow with maximum intensity brightness up to 4 min. Thus, the present study reveals that HPC derived from peanut oil cake biomass can behave as a promising electrode material for supercapacitor applications.

Nicop Anchored Porous Ti3C2tx Support with 3D Interconnected Structure for Advanced Hydrogen Evolution Reaction Electrocatalysts

MXene have gained much attention as promising electrocatalysts for noble metal-free hydrogen evolutrion reaction (HER) electrocatalysts owing to their high electrical conductivity, hydrophilic surfaces, abundant functional groups, and rational design for hybridization with other materials. In this study, a novel porous monolayered-Ti3C2TX@NiCoP (P-Ti3C2Tx@NiCoP) nanostructure was developed with 3D interconnected structure to significantly improve charge transfer capability and electrocatalytic activity. A strategic approach of modifying pristine Ti3C2Tx monolayers and combining them with other active cocatalysts. Specifically, the H2O2-utilized oxidation and HF etching process formed a highly microporous structure with a maximized surface area of monolayered MXenes as the support. A subsequent solvothermal process followed by phosphidation enabled successful anchoring of highly HER-active NiCoP nanoclusters onto abundantly exposed terminal edges of the P-Ti3C2Tx support. The structural porosity of the P-Ti3C2Tx nanoflakes played an important role in creating additional room for embedding catalytically active species while stably imparting high electrical conductivity to accelerate charge transfer to NiCoP nanoclusters. Moreover, inspired by the pH dependent change of structural arrangement of the Ti3C2Tx, we successfully induced 3D-interconnetecd structure by modulating surface electrostatic forces among Ti3C2Tx monolayers. Of note, the 3D-interconnected structure would shift charge transfer behavior from intermolecular to intramolecular aspects and this would contribute to enhanced charge transfer kinetics. With structural modification of support material and effective hybridization of active species, P-Ti3C2Tx@NiCoP showed highly enhanced HER activity with significantly lower overpoential of 115 and 101 mV at a current density of -10 mA cm-2 in 0.5 M H2SO4 and 1.0 M KOH, respectively, along with showing long-term stability over 60 h. As such, our approach of designing structurally modified-Ti3C2Tx and hybridization with other electrocatalytically active species would function as a solid platform for implementing Ti3C2Tx-based hetero-nanostructures to achieve state-of-the-art performance in next-generation energy conversion applications.

Low-Cost Plant-Based Metal and Metal Oxide Nanoparticle Synthesis and Their Use in Optical and Electrochemical (Bio)Sensors.

Technological progress has led to the development of analytical tools that promise a huge socio-economic impact on our daily lives and an improved quality of life for all. The use of plant extract synthesized nanoparticles in the development and fabrication of optical or electrochemical (bio)sensors presents major advantages. Besides their low-cost fabrication and scalability, these nanoparticles may have a dual role, serving as a transducer component and as a recognition element, the latter requiring their functionalization with specific components. Different approaches, such as surface modification techniques to facilitate precise biomolecule attachment, thereby augmenting recognition capabilities, or fine tuning functional groups on nanoparticle surfaces are preferred for ensuring stable biomolecule conjugation while preserving bioactivity. Size optimization, maximizing surface area, and tailored nanoparticle shapes increase the potential for robust interactions and enhance the transduction. This article specifically aims to illustrate the adaptability and effectiveness of these biosensing platforms in identifying precise biological targets along with their far-reaching implications across various domains, spanning healthcare diagnostics, environmental monitoring, and diverse bioanalytical fields. By exploring these applications, the article highlights the significance of prioritizing the use of natural resources for nanoparticle synthesis. This emphasis aligns with the worldwide goal of envisioning sustainable and customized biosensing solutions, emphasizing heightened sensitivity and selectivity.

Influence of fungicides usage on the growth, development and yield of potatoes

The article assesses the effect of protective preparations of chemical and biological origin in the treatment of potato tubers and plants during the growing season in the climatic conditions of the Republic of Mari El. The results of the action of fungicides on the formation of potato yields are presented and the effect of the studied preparations on the leaf surface area during the growing season, as well as the effect of chemical preparations in the fight against diseases in the treatment of tubers before planting and plants during the growing season. The use of the fungicide Celest Top and the treatment of plants during vegetation with chemicals increased the leaf surface area during the flowering phase to 40 thousand m2/ ha. In this variant, thanks to chemical fungicides, there were the highest indicators of germination density, phytometric indicators of resistance to the most common diseases, which made it possible to increase and maintain the maximum leaf surface area, thanks to which the yield of potato tuber increased by 4.2%. The purpose of the study is to study the influence of various disease protection systems on potato yield in the conditions of the Republic of Mari El.

Production of Porous Biochar from Cow Dung Using Microwave Process.

To valorize livestock manure, the present study investigated the production of biochar from cow dung (CD) by microwave pyrolysis. The pore properties and chemical characteristics of CD and CD-based biochar products were found to correlate with the process parameters like microwave power (300-1000 W) and residence time (5-20 min). The findings indicated that CD is an excellent biomass based on the richness of lignocellulosic constituents from the results of proximate analysis and thermogravimetric analysis (TGA). Higher calorific values were obtained at mild microwave conditions, giving the maximal enhancement factor 139% in comparison with the calorific value of CD (18.97 MJ/kg). Also, it can be concluded that the biochar product obtained at 800 W for a holding time of 5 min had the maximal BET surface area of 127 m2/g and total pore volume of 0.104 cm3/g, which were microporous and mesoporous in the nitrogen adsorption-desorption adsorption analysis. On the other hand, the CD-based biochar contained oxygen-containing functional groups and inorganic minerals based on the spectroscopic analyses by Fourier-transform infrared spectroscopy (FTIR) and energy-dispersive X-ray spectroscopy (EDS), thus featuring to be prone to hydrophilicity in aqueous solutions.

Facile synthesis of mesoporous active carbon from the valorisation of biomass waste and assessment of sequester efficiency of arsenic (As) from water

In this study, Phoenix dactylifera frond active carbons (PDFACs) were prepared using a low-cost biomass source through zinc chloride (ZnCl2) activation for the efficient elimination at batch scale, of the environmentally hazardous component arsenic (As) from polluted water. The influence of different factors including activation temperature, impregnation ratio, and impregnation time on the pore volumes, surface areas, and carbon yields of PDFACs were investigated. The PDF, PDF charcoal (PDFC) and PDFACs were characterized through thermogravimetric analysis (TGA), BET surface area (N2 adsorption-desorption), pore size distributions (PSD), SEM, FTIR, Energy-dispersive X-ray spectroscopy (EDX), and Transmission electron microscopy (TEM) analysis demonstrated successful modification in porosity and surface morphology. The maximum BET surface area of 1677 m2/g (1666 m2/g mesopore, 11 m2/g micropore surface area) and 0.665 cm3/g total pore volume were achieved at optimum synthesis condition of 4:5 impregnation ratio, 400 °C activation temperature, and 24 h soaking time. The impregnating ratio, impregnation time and activating temperature were found to have an inverse relationship with the yield of PDFACs. The impact of pH, sorbent dosage, As(V) concentration, contact time, temperature and agitation speed were inspected in batch experiments for As(V) adsorption efficiency by PDFAC. A maximum extraction efficiency 97% of As(V) was attained at optimal working conditions of 1.5 g dosage of PDFAC, initial concentration of As(V) 10 mg L−1, 120 min contact time, pH 6.0 and agitation speed 200 rpm at temperature 25 °C. The adsorption kinetic data fit the pseudo second order kinetic model well and the sorption data fit both Langmuir and Freundlich equations with little deviation in the r2 values. Research indicated that PDFAC derived from biomass wastes by ZnCl2 activation was found to be promising and feasible material for the elimination of As(V) from the aquatic environment.

Development of Activated Carbon Textiles Produced from Jute and Cotton Wastes for Electromagnetic Shielding Applications

Increasing amounts of waste resulting from over-consumption carry substantial risks for human and environmental health, and disposing of this waste requires enormous amounts of energy. As a result, waste-to-wealth and circular economy approaches have gained attention in both academia and the commercial sector in recent years. Accordingly, this study aims to develop electromagnetic shielding materials by converting non-conductive waste textiles into conductive value-added product and porous fabrics by carbonizing the structure itself rather than by adding any conductive particles. To this end, the novel contribution of the present study is that waste textiles were converted into activated carbon in a shorter time and without compromising the integrity of the fibrous network via microwave pyrolysis without inert gas. Sulfuric acid was used as a dehydration and activation agent, suppressing the release of volatile organic substances and eliminating greenhouse gas emissions. This approach also increased product yield and reduced energy consumption and sample shrinkage. The structures of the activated carbon textile showed EMI shielding within 20–30 dB (99.9% attenuation) in the 1–6 GHz frequency range. The maximum SSE/t value of 950.71 dB·cm2·g−1 was obtained with the microwave post-treated activated carbon textile. Micropores were dominant characteristics of these materials, and pore diameters increased with increased acid concentration. The maximum surface area of 383.92 m2/g was obtained with 8% acid. Ultrasound treatment reduced water-energy consumption and cost. Only 5 min of microwave post-treatment increased textile conductivity and thermal stability and contributed positively to electromagnetic shielding.

Effect of Post-Washing on Textural Characteristics of Carbon Materials Derived from Pineapple Peel Biomass.

Porous carbon materials have been widely used to remove pollutants from the liquid-phase streams. However, their limited pore properties could be a major problem. In this work, the effects of post-washing methods (i.e., water washing and acid washing) on the textural characteristics of the resulting biochar and activated carbon products from pineapple peel biomass were investigated in the carbonization and CO2 activation processes. The experiments were set at an elevated temperature (i.e., 800 °C) holding for 30 min. It was found that the enhancement in pore property reached about a 50% increase rate, increasing from 569.56 m2/g for the crude activated carbon to the maximal BET surface area of 843.09 m2/g for the resulting activated carbon by water washing. The resulting activated carbon materials featured the microporous structures but also were characteristic of the mesoporous solids. By contrast, the enhancement in the increase rate by about 150% was found in the resulting biochar products. However, there seemed to be no significant variations in pore property with post-washing methods. Using the energy dispersive X-ray spectroscopy (EDS) and the Fourier Transform infrared spectroscopy (FTIR) analyses, it showed some oxygen-containing functional groups or complexes, potentially posing the hydrophilic characters on the surface of the resulting carbon materials.

Anti-PF4/Heparin Monoclonal Antibodies Induce Thrombus Formation in an Ex Vivo Endothelialized Microfluidic System

Introduction: Heparin-induced thrombocytopenia (HIT) is a serious adverse reaction to heparin. Antibodies against platelet factor 4 (PF4) or a heparin/PF4 complex have been reported to activate platelets, neutrophils and possibly endothelial cells, resulting in thrombocytopenia, hypercoagulability and thromboembolic complications. While the impact of anti-PF4/heparin antibodies on platelet, neutrophil and monocyte activation has been extensively studied, the role of endothelial cells in HIT-associated thrombosis remains underexplored. In particular, the interactions between HIT-induced procoagulancy and endothelial cells under dynamic conditions is not completely analyzed. In this report, we investigated how HIT antibodies induce thrombosis in an endothelialized microfluidic system. Methods: Fibrinogen microfluidic channels were coated with confluent monolayer of human umbilical vein endothelial cells (HUVECs). Cells were primed with low-dose TNF-α to induce a sub-thrombotic endothelial activation, prior to perfusion of whole blood. Recalcified unstimulated or Thrombin Receptor Activator Peptide 6 (TRAP-6) activated whole blood was perfused at a venous flow rate. HIT-thrombosis model was established and tested with monoclonal anti-PF4/heparin antibodies in whole blood. In brief, whole blood was pre-incubated with unfractionated heparin (UFH, 0.2 IU/mL and 100 IU/mL). Next, anti-PF4/heparin antibodies were introduced to the whole blood mixture and incubated for 30 minutes. Whole blood was recalcified and perfused over resting or primed endothelial cells at a venous shear stress. Thrombus formation was recorded over time. Results: The endothelialized microfluidic model successfully captures sub-thrombotic conditions under venous shear. Activated platelets induced a procoagulant shift and three-dimensional thrombi. We applied our thrombosis model to investigate thrombus formation induced by a HIT mimicking monoclonal antibody. We show that the heparin-dependent platelet activation predicts the thrombotic response in the microfluidic system: HIT antibodies in absence of heparin did not exert a pro-thrombotic effect on activated endothelial cells. Co-incubation with 0.2 IU/mL UFH induced thrombosis, embolization of thrombus material and channel occlusion only when endothelial cells were primed with TNF-α. The pro-thrombotic effect of HIT antibodies was fully reversed at the super-therapeutic dose of 100 IU/mL UFH. Conclusions: HIT antibodies induce thrombosis and embolization in a system emulating physiological environment. For the first time, we present a comprehensive thrombosis model that incorporates the established thrombogenicity of HIT-mimicking antibodies. We show that our thrombosis model incorporates both endothelial- and blood-based control of thrombosis. Primed endothelial cells and antibody-induced procoagulancy trigger thrombosis in a concerted fashion, allowing investigation of the underlying mechanisms and possible preclinical evaluation of potential inhibitors of HIT-thrombosis. Figure 1, upper panel: Maximal thrombus surface area coverage of TNF-α primed endothelial cells, perfused with unstimulated, TRAP-6 activated or HIT-like IgG/heparin challenged whole blood. HIT-like IgG did not increase thrombus formation in absence of heparin. Addition of low-dose heparin exerted a strong pro-thrombotic effect, that was fully reversible with a super-therapeutic concentration of heparin. Lower panel: representative images of thrombi formed by HIT-like IgG in absence and under low or high-dose heparin. Platelets: green, Calcein-AM. Scale bar: 200 µm.