The need for reliable real-time information on voltage stability margins of electrical power systems is an increasingly relevant concern within the current trend of electrification and deployment of power electronics-based devices. This paper conducts the assessment and comparison of four Voltage Stability Indices (VSIs) proposed for this application and based exclusively on synchronized phasor measurements. The robustness and accuracy of each method in identifying the point of maximum power transfer are evaluated as the correlation between load characteristics and consistent estimation of voltage stability margins is explored. In addition, the likelihood inherent to each VSI formulation of triggering false alarms under certain system dynamics is addressed in detail. The comparative analyses are derived from dynamic simulation data of a 3-bus test system, the IEEE 9-bus network and the IEEE 39-bus network, all modelled in the open-source Python-based power system simulator DynPSSimPy. Case studies cover placement of monitoring device, different load types, line disconnection events and presence of measurement noise. The results presented serve as a reference point for the development and/or enhancement of VSIs suitable for real-time applications, highlighting their most significant advantages and drawbacks and providing insights on potential trade-offs that need to be considered when employing such approaches within control center settings.