Maximum Degree Of Polarization Research Articles

Silicon-based perovskite plasmonic diode with highly polarized emission

Abstract Here, we propose and develop a silicon (Si)-based perovskite plasmon-emitting diode (PED) with controlled linear polarization in this study. Such polarization originates from the efficient excitation of surface plasmons by excitons in the active layer of the device and the efficient outcoupling by a wedged boundary of a metal electrode. Furthermore, a p-type Si substrate serves as an anode of the diode, and a hole blocking layer of SiO2 is introduced in the PEDOT:PSS/Si heterojunction for carrier injection balance. Pure green emission light has been achieved from devices with varied thicknesses of the emitting layer, and the maximum degree of polarization is measured to be 0.79. The field distribution and polarization of the PED were simulated and measured. Such a low-cost Si-based plasmonic diode provides a promising way to realize simpler and more compact multiple-functional light sources, which are extensively demanded for optoelectronic integration.

Multiwavelength Polarization Observations of Mrk 501

Mrk 501 is a prototypical high-synchrotron-peaked blazar and serves as one of the primary targets for the Imaging X-ray Polarimetry Explorer (IXPE). In this study, we report X-ray polarization measurements of Mrk 501 based on six IXPE observations. The detection of X-ray polarization at a confidence level exceeding 99% is achieved in four out of the six observations conducted across the entire energy range (2–8 keV) of IXPE. The maximum polarization degree (ΠX) is measured to be 15.8% ± 2.8%, accompanied by a polarization angle (ψ X) of 98.°0 ± 5.°1 at a confidence level of 5.6σ. During the remaining two observations, only an upper limit of ΠX < 12% could be derived at the 99% confidence level. No temporal variability in polarization is observed throughout all six IXPE observations for Mrk 501. A discernible trend of energy-dependent variation in the polarization degree is detected in optical spectropolarimetry; however, no analogous indication is observed in ΠX. The chromatic behavior of Π and the consistent values of ψ across different frequencies from X-ray to radio bands, along with the agreement between ψ and jet position angle, strongly support the interpretation of the energy-stratified model with shock-accelerated particles in the jet of Mrk 501. Additionally, the possibility of the presence of a global helical magnetic field in the jet of Mrk 501 is discussed.

Linearly Polarized Broadband Emission and Multiwavelength Lasing in Solution-Processed Quantum Dots.

A miniature laser with linear polarization is a long sought-after component of photonic integrated circuits. In particular, for multiwavelength polarization lasers, it supports simultaneous access to multiple, widely varying laser wavelengths in a small spatial region, which is of great significance for advancing applications such as optical computing, optical storage, and optical sensing. However, there is a trade-off between the size of small-scale lasers and laser performance, and multiwavelength co-gain of laser media and multicavity micromachining in the process of laser miniaturization remain as significant challenges. Herein, room-temperature linearly polarized multiwavelength lasers in the visible and near-infrared wavelength ranges are demonstrated, by fabricating random cavities scattered with silica in an Er-doped Cs2Ag0.4Na0.6In0.98Bi0.02Cl6 double-perovskite quantum dots gain membrane. By regulating the local symmetry and enabling effective energy transfer in nanocrystals, multiwavelength lasers with ultralow thresholds are achieved at room temperature. The maximum degree of polarization reaches 0.89. With their advantages in terms of miniaturization, ultralow power consumption, and adaptability for integration, these lasers offer a prospective light source for future photonic integrated circuits aimed at high-capacity optical applications.

Foreground Dust Properties toward the Cluster NGC 7380

Using starlight polarization, we present the properties of foreground dust toward cluster NGC 7380 embedded in H ii region Sh 2-142. Observations of starlight polarization are carried out in four filters using an imaging polarimeter equipped with a 104 cm ARIES telescope. Polarization vectors of stars are aligned along the Galactic magnetic field. Toward the east and southeast regions, the dust structure appears much denser than in other regions (inferred from extinction contours and a color composite image) and is also reflected in polarization distribution. We find that the polarization degree and extinction tend to increase with distance and indication for the presence of a dust layer at a distance of around 1.2 kpc. We have identified eight potential candidates exhibiting intrinsic polarization by employing three distinct criteria to distinguish between stars of intrinsic polarization and interstellar polarized stars. For interstellar polarized stars, we find that the maximum polarization degree increases with the color excess and has a strong scatter, with the mean value of 1.71% ± 0.57%. The peak wavelength spans 0.40–0.88 μm, with a mean value of 0.56 ± 0.07 μm, suggesting similar grain sizes in the region to those in the average diffuse interstellar medium. The polarization efficiency is also found to decrease with visual extinction as Pmax/AV∝AV−0.61 . Our observational results are found to be consistent with the predictions by the radiative torque alignment theory.

Simulating skylight polarization patterns using the backward Markov Chain Monte Carlo method

Skylight polarization patterns provide valuable information for atmospheric measurements, polarized remote sensing and navigation applications. However, efficiently and accurately modeling polarized radiative transfer in atmospheric scattering remains challenging. We propose a backward Markov chain Monte Carlo (B-MCMC) method to simulate skylight polarization patterns by constructing a Markov chain in parameter space to track photons from the sensor to the top-of-atmosphere (TOA). The results show that the B-MCMC model significantly improves the computational efficiency by a factor of 8-10 while retaining the computational accuracy compared with Monte Carlo simulations. The experiments show that in cloudy skies, the skylight polarization pattern is generally weakened, in the field of skylight polarization detection and application, long wavelengths should be used in clear weather and blue-violet light should be used in cloudy weather, which corresponds to a larger degree of polarization (DOP) and facilitates the acquisition of polarization information. Finally, the aerosol optical depth (AOD) has an important effect on the skylight polarization, as the AOD increases, the DOP decreases, and the decreasing trend will be more and more obvious, when the AOD is above 0.3, the maximum DOP will not exceed 0.5, which is verified by the division of focal plane (DOFP) polarization measurement device.

Impact of aerosols on the polarization patterns of full-sky background radiation.

Regarding aerosol particle-laded turbid atmospheres, full-sky background radiation polarization patterns can be adversely affected, an important factor limiting their effective near-ground observation and acquisition. We established a multiple-scattering polarization computational model and measurement system and conducted the following three tasks. (a) We thoroughly analyzed the impact of aerosol scattering characteristics on polarization distributions, calculating the degree of polarization (DOP) and angle of polarization (AOP) patterns for a more comprehensive set of atmospheric aerosol compositions and aerosol optical depth (AOD) values than calculated in previous studies. (b) We assessed the uniqueness of the DOP and AOP patterns as a function of AOD. (c) By employing a new polarized radiation acquisition system for measurements, we demonstrated that our computational models are more representative of the DOP and AOP patterns under actual atmospheric conditions. We found that under a clear sky without clouds, the impact of the AOD on the DOP was detectable. With increasing AOD, the DOP decreased, and the decreasing trend became increasingly obvious. When the AOD was above 0.3, the maximum DOP did not exceed 0.5. The AOP pattern did not change notably and remained stable, except for the contraction point at the sun position under an AOD of 2.

Alignment and rotational disruption of dust grains in the Galactic Centre revealed by polarized dust emission

ABSTRACT We study the alignment and rotational disruption of dust grains at the centre of our Galaxy using polarized thermal dust emission observed by SOFIA/HAWC+ and JCMT/SCUPOL at 53, 216, and 850 µm. We analysed the relationship between the observed polarization degree with total emission intensity, dust temperature, gas column density, and polarization angle dispersion. Polarization degree from this region follows the predictions of the RAdiative Torque (RAT) alignment theory, except at high temperatures and long wavelengths where we found evidence for the rotational disruption of grains as predicted by the RAdiative Torque Disruption mechanism. The grain alignment and disruption sizes were found to be around 0.1 and 1 µm, respectively. The maximum polarization degree observed was around p ∼ 13 per cent at 216 µm and comes from a region of high dust temperature, low column density, and ordered magnetic field. Magnetically enhanced RAT alignment (MRAT) was found to be important for grain alignment due to the presence of a strong magnetic field and can induce perfect alignment even when grains contain small iron clusters. We estimated the mass fraction of aligned grains using a parametric model for the fraction of the grains at high-J attractors and found it to correlate weakly with the observed polarization degree. We observe a change in the polarization ratio, from p216µm/p850µm &amp;lt; 1 to p216µm/p850µm &amp;gt; 1 at Td ≳ 35 K, which suggests a change in the grain model from a composite to a separate population of carbon and silicate grains as implied by previous numerical modelling.

First-Principles Study of Structural, Electronic, Magnetic and Half-Metallic Properties of Mn2ZrX (X = As, Bi) Full Heusler Alloys

In this paper, the structural, electronic, magnetic, and half-metallic properties of full-Heusler alloys Mn2ZrX ([Formula: see text], Bi) in the Hg2CuTi-type structure have been studied by using the first-principles-based density functional theory (DFT) with the full-potential linearized augmented plane-wave (FP-LAPW) method. Mn2ZrX ([Formula: see text], Bi) compounds are found to be half-metallic ferrimagnets. The calculated total magnetic moments of the Mn2ZrX ([Formula: see text], Bi) alloys are estimated at 01[Formula: see text][Formula: see text] according to the Slater–Pauling rule of [Formula: see text] ([Formula: see text]–24) [Formula: see text]. It was discovered that Mn2ZrAs and Mn2ZrBi maintained their half-metallicity for a lattice constant interval of 5.72 to 6.26 Å and 6.33 to 6.62 Å, respectively, and present a maximum degree of spin polarization at the Fermi level. In addition, the predicted formation energy and elastic parameters show that these materials are mechanically stable. All of these results indicate that these new Mn2-based heusler alloys are able to be the candidates for spintronic applications.

Refractive index impacts on polarized signals from a homogeneous Rayleigh scattering medium exposed to oblique irradiation

Refractive index mismatched boundaries commonly occur in many polarimetric observations However, the refractive index effect on the polarization signals from a scattering medium has been rarely investigated and poorly understood. Thus, the polarization signals from a scattering medium with mismatched boundaries are expected to be accurately captured to investigate refractive index effects. In this work, the polarized radiative transfer in a homogeneous Rayleigh scattering slab medium with a refractive index bigger than its surrounding is numerically solved. By fixing the refractive index of the background and the composition of the scatterers in the scattering medium, we studied the refractive index impacts on the polarization signals by varying the refractive index of the Rayleigh scattering medium. Results show that for the media with different refractive indices, the reflected and transmitted radiation intensity is found to diminish monotonically, while the maximum degree of polarization (DoP) decreases at first and then increases versus the refractive index. The refractive-index-dependent polarization signals presented in this work are expected to have guiding implications for target probing, such as water detection from the atmosphere.

Scattering properties of protoplanetary dust analogs with microwave analogy: Aggregates of fractal dimensions from 1.5 to 2.8

Context. The growth of dust grains in protoplanetary disks is not understood in detail. Several studies have proposed the presence of aggregates and irregular grains to overcome the physical barriers in grain growth models. In order to understand the scattering properties of these aggregates, laboratory measurements of light scattering and microwave scattering have been developed over the last 50 years. Aims. We aim to measure the scattering properties of different protoplanetary analog aggregates with fractal dimensions of 1.5, 1.7, 2.0, 2.5, and 2.8. Methods. We used the microwave scattering technique (microwave analogy) for the measurements. The analog particles were virtually generated and fabricated by 3D printing with a controlled size (scaling factor), geometry, and refractive index. The seven analogs were measured at wavelengths ranging from 16.7 mm to 100 mm, leading to aggregate size parameters ranging from Xagg = 1 to Xagg = 20. The results were compared to finite element method calculations of the same analogs for cross-validation. Results. The phase function and the degree of linear polarization were deduced from the scattered field measurements of the different aggregates. These scattering properties are compared and discussed as a function of the fractal dimension. Conclusions. The scattering properties of aggregates with different fractal dimensions are different. Three different realizations of aggregates with the same fractal dimension but different monomer configurations yield the same phase functions. We verified that the maximum degree of linear polarization is higher for porous aggregates than for compact aggregates. Furthermore, the maximum polarization occurs at larger scattering angles for high fractal dimensions, while the half width at half maximum of the phase functions present larger values for small fractal dimensions.

The Polarized Emission of AGN at Millimeter Wavelengths as Seen by POLAMI

We review results from the POLAMI program, which monitors the polarization properties of 36 blazars at the IRAM 30 m telescope. We found that the variability of the degree of linear polarization is faster and of higher amplitude at 1 mm than at 3 mm and that the linear polarization is also more variable than the total flux. The linear polarization angle is highly variable in all sources with excursions &gt; 180°; and for the case of the polarization angle, also the 1 mm variations appear to be faster than those at 3 mm. These results are fully compatible with recent multi-zone turbulent jet models, and they definitively rule out the popular single-zone models for blazars. They also further confirm that the short-wavelength (inner) emitting regions have better ordered magnetic fields than the long-wavelength ones (further downstream). Moreover, the POLAMI program has shown statistical evidence that, for most of the monitored sources, circular polarization emission is displayed the majority of the time. The circular polarization detection rate and the maximum degree of circular polarization found are comparable with previous surveys at much longer wavelengths, thus, opening a new window for circular polarization and jet composition studies in the mm range. The process generating circular polarization must not be strongly wavelength-dependent. The widespread presence of circular polarization in the POLAMI sample is likely due to Faraday conversion of the linearly polarized synchrotron radiation in the helical magnetic field of the jets. The peculiar behavior of circular polarization in 3C 66A, which we consider a hallmark of circular polarization generation by Faraday conversion in helical fields, is discussed.

Interstellar Extinction and Polarization of Stars in the Open Cluster NGC 6709

We present BVRI polarimetric measurements of 23 stars in the direction of the open cluster NGC 6709. Fifteen stars display wavelength-dependence of polarization which is typically due to selective extinction in the interstellar medium and could be fitted to the Serkwoski equation. Based on these stars, we obtained an average maximum degree of polarization of 0.722 ± 0.022% and an average wavelength at a maximum polarization of 0.615 ± 0.011 μm. The observed low polarization may be due to the alignment of grains along a more longitudinally-directed magnetic field in this region which would cause the aspect ratio of the grains to be reduced. This would have the observational consequence of decreased polarization as well as shifting toward longer wavelengths. Using the expression proposed by Whittet & van Breda we calculated the ratio of total-to-selective extinction as , higher than the nominal value of 3.1 for the general ISM. The remaining eight sample stars display an unusual wavelength-dependence that is similar to some Be stars. However, there are only two Be stars currently listed in this cluster, yet, based on our data, they both present reliable fits within the Serkowski equation. The overall alignment of the V-band polarization vectors implies polarization by selective extinction due to foreground dust. Using the Planck 353 GHz channel we find there is an agreement between polarization by emission and selective extinction. Since the optical polarization traces a magnetic field, this suggests that the magnetic field in this region is inclined to the Galactic plane, with an overall average Galactic position angle of 104 ± 12 (st. dev.) degrees.

Polarimetric investigation of selected cloud compositions in exoplanetary atmospheres

Aims. We investigated the impact of selected cloud condensates in exoplanetary atmospheres on the polarization of scattered stellar radiation. Methods. We considered a selection of 25 cloud condensates that are expected to be present in extrasolar planetary atmospheres. Using the three-dimensional Monte Carlo radiative transfer code POLARIS and assuming Mie scattering theory, we calculated and studied the net polarization of scattered radiation as a function of planetary phase angle at optical to near-infrared wavelengths (0.3 μm to 1 μm). Results. In addition to the well-known characteristics in the state of polarization, such as the rainbow determined by the real part of the refractive index, the behavior of the underlying imaginary part of the refractive index causes an increase or decrease in the degree of polarization and a change of sign in the polarization at a characteristic wavelength. In contrast to Al2O3 and MgFeSiO4, clouds composed of SiO, MnS, Na2S, or ZnS produce a rapidly decreasing degree of polarization with increasing wavelength in the context of an exoplanetary atmosphere. Furthermore, the sign of the polarization changes at a wavelength of about 0.5 μm to 0.6 μm, depending on the specific cloud condensate. The resulting net polarization is mainly positive for cloud compositions with large imaginary parts of the refractive index, such as Fe, FeS, and FeO. In addition, for Fe and FeS clouds, the maximum degree of polarization at long wavelengths is shifted to larger phase angles than for FeO. Conclusions. We found that most of these cloud condensates, such as chlorides, sulfides, or silicates, are distinguishable from each other due to their unique wavelength-dependent complex refractive index. In particular, an increase or decrease of the net polarization as a function of wavelength and a change of sign in the polarization at specific wavelengths are important features for characterizing cloud compositions in exoplanetary atmospheres.

Asteroid (3200) Phaethon: results of polarimetric, photometric, and spectral observations

ABSTRACT We present results of polarimetric, photometric, and spectral observations of the near-Earth asteroid (3200) Phaethon carried out at the 6-m BTA telescope of the Special Astrophysical Observatory and the 2.6-m and 1.25-m telescopes of the Crimean Astrophysical Observatory over a wide range of phase angles during its close approach to the Earth at the end of 2017 (α = 19°–135°) and in 2020 at α = 52.2°. Using our and other available in literature data, we found that the maximum degree of linear polarization of Phaethon in the V band is Pmax = (45 ± 1) per cent at the phase angle αmax = 124.0° ± 0.4°, whereas the inversion angle αinv = 21.4° ± 1.2° and polarimetric slope is h = (0.326 ± 0.027) per cent per degree. Using the dependence ‘polarimetric slope – albedo,’ we have found the geometric albedo of asteroid Phaethon to be pv = 0.060 ± 0.005. This value falls into the lower range of albedo values for asteroids determined by different methods. The mean colour indices U–B = 0.207 m ± 0.053 m and B–V = 0.639 m ± 0.054 m of the asteroid are derived at heliocentric and geocentric distances 1.077 au and 0.102 au, respectively, and phase angle α = 23.78°. The absolute magnitude of Phaethon is V(1,1,0) = 14.505 m ± 0.059 m. The effective diameter of Phaethon is estimated from obtained absolute magnitude and geometrical albedo, it is equal to 6.8 ± 0.3 km. The best fit to the observed polarimetric data was obtained with the Sh-matrix model of conjugated random Gaussian particles composed of Mg-rich silicate (90 per cent) and amorphous carbon (10 per cent).

Diffraction characteristics of radiated tilted fiber grating and its spectrometer application.

We have numerically and experimentally presented the diffraction characteristics of radiated tilted fiber grating (RTFG) in terms of the spectrum, bandwidth, degree of polarization, angular dispersion, and temperature crosstalk. The theoretical and experimental results have shown that the polarization property, bandwidth, and dispersion of RTFG highly depended on the tilt angle of RTFG, and the RTFG has ultra-low temperature crosstalk. We have simulated the transmission spectrum of the RTFG with different tilt angles (25°, 31°, 38°, 45°, and 54°), in which the results show that the larger tilt angle has the wider bandwidth. The RTFGs with the tilt angle of 25°, 31°, 38°, 45°, and 54° have the 3dB bandwidth of 110 nm, 144 nm, 182 nm, 242 nm, and 301 nm, respectively. Besides, the degree of polarization (DOP) of the radiated light from RTFG with the different tilt angles are 0.876, 0.944, 0.967, 0.998, and 0.970, respectively, and the RTFG has the maximum DOP at the tilt angle of 45°, which could be used as single-polarization diffraction device. The experimental results show that with further increase or decrease of the tilt angle, the DOP of radiated light of RTFG would decrease. Both the theoretical and experimental results show that the smaller tilt angle could greatly improve the diffraction angular dispersion of RTFG, in which the 25°, 31°, 38°, and 45° RTFG have the angular dispersion of 0.2288 °/nm, 0.1026 °/nm, 0.0714 °/nm, and 0.0528 °/nm, respectively. Due to the broad working bandwidth, the diffraction angles of RTFG have ultra-low temperature crosstalk, where -0.00042, -0.00054, -0.00064, and -0.00099 degree / °C at the tilt angle of 25°, 31°, 38°, and 45°. Finally, we have demonstrated a miniaturized spectrometer integrated by a 25° RTFG, which has a high spectral resolution of 0.08 nm. The proposed RTFG would be an ideal in-fiber diffraction device and widely applied in spectral analysis, space optical communication, and Lidar areas.

Angularly anisotropic tunability of upconversion luminescence by tuning plasmonic local-field responses in gold nanorods antennae with different configurations

Abstract Optical polarization has attracted considerable research attention by extra detection dimension in angular space, flourishing modern optoelectronic applications. Nonetheless, purposive polarization controlling at nanoscales and even at the single-particle level constitutes a challenge. Plasmonic nanoantenna opens up new perspectives in polarization state modification. Herein, we report angular-dependent upconversion luminescence (UCL) of rare-earth ions doped upconversion nanoparticles (UCNPs) in both emission and excitation polarization via constructing angularly anisotropic plasmonic local-field distributions in gold nanorods (Au NRs) antennae with different configurations at a single-particle level. The UCL of UCNP tailored by plasmonic Au NRs nanoantennae is enhanced and exhibits linear polarization. The highest enhancement factor of 138 is obtained in the collinear Au NR-UCNP-Au NR configuration under parallel excitation. Simultaneously, the maximum degree of linear polarization (DOLP) of UCL with factors of 85% and 81% are achieved in the same structure in emission and excitation polarization measurements, respectively. The observed linear polarizations and UCL enhancements are due to varied resonant responses at 660 nm and the anisotropic near-field enhancement in different nanoantennae-load UCNP. The theoretical simulations reveal the periodic changing of near-field enhancement factors of nanoantennae in angular space with the incident light polarization angles and are well-matched with the experimental results.

Polarization performance of a polydisperse aerosol atmosphere based on vector radiative transfer model

The effect of aerosol particles in the atmospheric radiative transfer has great uncertainty. A computer code for accurate calculation of the optical properties and vector radiative transfer of polydisperse aerosol system has been written in C++ language. In this paper, the polydisperse aerosol system has been divided into multiple size regions according to the particle size, and the optical properties of each region have been calculated separately and applied in the radiative transfer calculation. The results show that this method is significantly different from the method that is not divided into regions, with an average error of about 5.77%. The radiance mode and polarization mode in different solar zenith angle (SZA, from 30° to 70°), aerosol optical depth (AOD, from 0.2 to 1.0), and three aerosol types have been also calculated. The results also show that the radiative transfer is highly sensitive to all parameters. The polarization distribution but not the degree of polarization (DOP) is affected by SZA. The depolarization effects of aerosol are affected by AOD and particle size distribution. The maximum DOP decreased by 0.2 and 0.3 with the increasing AOD and average particle size, respectively. The distribution of Stokes parameters and atmospheric absorption is mainly affected by the complex refractive index. The Stokes component distribution of water-soluble aerosol is different from dust and soot, and the atmospheric transmissivity from dust to soot decreases about 26%. In addition, the scattering angles of the maximum DOP of the three aerosol types are all greater than 90°, which reflects the important effect of the element P12 on the polarization mode. This research has guiding significance for many fields such as energy utilization, climate prediction, atmospheric remote sensing, and so on.

Optimization of a quantum control sequence for initializing a nitrogen-vacancy spin register

Implementation of many quantum information protocols requires an efficient initialization of the quantum register. In the present paper, we optimize a population trapping protocol for initializing a hybrid spin register associated with a single nitrogen-vacancy (NV) center in diamond. We initialize the quantum register by polarizing the electronic and nuclear spins of the NV with a sequence of microwave, radio-frequency, and optical pulses. We use a rate equation model to explain the distribution of population under the effect of the optical pulses. The model is compared to the experimental data obtained by performing partial quantum state tomography. To further increase the spin polarization, we propose a recursive protocol with optimized optical pulses. We also discuss the role of the relative values of the nuclear- and electronic-spin pumping rate in achieving the maximum degree of spin polarization.

Multifunctional Chiral 2D Lead Halide Perovskites with Circularly Polarized Photoluminescence and Piezoelectric Energy Harvesting Properties.

Introducing the chiral spacers to two-dimensional (2D) lead halide perovskites (LHPs) enables them to exhibit circularly polarized photoluminescence (CPPL), which could have applications in chiral-optics and spintronics. Despite that a great deal of effort has been made in this field, the reported polarization degree of CPPL at ambient conditions is still very limited, and the integration of multiple functionalities also remains to be explored. Here we report the structures, CPPL, and piezoelectric energy harvesting properties of chiral 2D LHPs, [R-1-(4-bromophenyl)ethylaminium]2PbI4 (R-[BPEA]2PbI4) and [S-1-(4-bromophenyl)ethylaminium]2PbI4 (S-[BPEA]2PbI4). Our results show that these chiral perovskites are direct bandgap semiconductors and exhibit CPPL centered at ∼513 nm with a maximum degree of polarization of up to 11.0% at room temperature. In addition, the unique configurational arrangement of the chiral spacers is found to be able to reduce the interlayer π-π interactions and consequently result in strong electron-phonon coupling. Furthermore, the intrinsic chirality of both R-[BPEA]2PbI4 and S-[BPEA]2PbI4 enables them to be piezoelectric active, and their composite films can be applied to generate voltages and currents up to ∼0.6 V and ∼1.5 μA under periodic impacting with a strength of 2 N, respectively. This work not only reports a high degree of CPPL but also demonstrates piezoelectric energy harvesting behavior for realizing multifunctionalities in chiral 2D LHPs.

Electrical control of orbital and vibrational interlayer coupling in bi- and trilayer 2H−MoS2

Manipulating electronic interlayer coupling in layered van der Waals (vdW) materials is essential for designing opto-electronic devices. Here, we control vibrational and electronic interlayer coupling in bi- and trilayer 2H-MoS$_2$ using large external electric fields in a micro-capacitor device. The electric field lifts Raman selection rules and activates phonon modes in excellent agreement with ab-initio calculations. Through polarization resolved photoluminescence spectroscopy in the same device, we observe a strongly tunable valley dichroism with maximum circular polarization degree of $\sim 60\%$ in bilayer and $\sim 35\%$ in trilayer MoS$_2$ that are fully consistent with a rate equation model which includes input from electronic band structure calculations. We identify the highly delocalized electron wave function between the layers close to the high symmetry $Q$ points as the origin of the tunable circular dichroism. Our results demonstrate the possibility of electric field tunable interlayer coupling for controlling emergent spin-valley physics and hybridization driven effects in vdW materials and their heterostructures.