Maximum Concentration Levels Research Articles

Contamination profile and hazards of neonicotinoid insecticides in honey from apiaries in Beijing, China.

The residues of neonicotinoid insecticides in honey have raised global concern for their adverse effects on non-target organisms. However, information on the presence of neonicotinoids in raw honey in China is limited. Our study investigated the distribution profiles of neonicotinoids in raw honey samples collected from apiaries in plain and mountainous areas surrounding Beijing City. At least one of four neonicotinoids, imidacloprid, thiamethoxam, acetamiprid, or clothianidin, was found in 46.9% of samples. Neonicotinoids in multi-floral honey in plain areas exhibited higher concentrations and prevalence than in uni-floral honey collected from mountainous areas. These results indicated that neonicotinoid residues in honey were linked to the agricultural ecosystems influenced by geographies, particularly the intensity of agriculture and nectariferous plant types. The dietary risks to adult and children health from neonicotinoid exposure were deemed de minimis, while risks to honeybees at the maximum concentration level require much attention through refined, higher-tier assessments and possible mitigation measures for the use of these products.

Geochemical state of small rivers of Syrym District of West Kazakhstan region (on the example of the Rivers Buldyrty, Yesenankaty, Shiderty, Olenty)

Despite the fact that small rivers are called Small, their importance in terms of ecology is high. This is because the condition of large rivers will depend on smaller rivers. The degradation of small rivers negatively affects the state, is an important and urgent task. The purpose of the study was to geochemically analyze the composition of the waters of small rivers in the Syryms district and assess their quality. Water samples were taken from each river ecological state of medium and large rivers, because they feed at the expense of these small rivers. It is easy to see that every day the waters of these rivers are receding and the banks are expanding. Currently, one of the main tasks that environmental science sets for itself is to monitor the ecological state of water bodies. In connection with the conditions of increasing anthropogenic factors, determining the ecological state of small rivers plays an important role in maintaining the composition of the natural ecosystem. Small rivers are very sensitive to anthropogenic factors and react to these factors in the opposite way. The study of the chemical composition of small river waters, as well as their ecological state, is an important and urgent task. The aim of the study is a geochemical analysis of the composition of small river waters in the Syrymsky district and an assessment of their quality. Water samples were taken from each river to determine the composition of the water quality. The cameral stage was held in the laboratory of environmental and biogeochemical testing of M. Utemisov West Kazakhstan University. Chemical analysis was carried out using the widely used methods GOST 26449.1 — 85. After analyzing the indicators of water samples taken from the research area, it was found that the maximum raual concentration level did not exceed, except for the total hardness.

Precipitation, temperature, and landcovers drive spatiotemporal variability of groundwater nitrate concentration across the Continental United States

Groundwater nitrate contamination, especially in agriculturally active regions, is a well-recognized environmental concern. Understanding how this contamination evolves across the continental USA (CONUS) and through time is important to designing effective mitigation strategies. Despite extensive research on nitrate contamination, no existing studies can accurately predict changes in groundwater nitrate concentrations over time across the CONUS. To bridge this gap, we compiled a comprehensive dataset for a systematic evaluation of the potential influence of climate dynamics, landcover changes, and crucial soil and geological properties on groundwater contamination. We employed an interpretable machine learning approach, using 293,775 groundwater nitrate observations and 12 independent variables, to estimate annual groundwater nitrate concentrations at the county level from 2001 to 2020. Our model is the first one capable of accurately forecasting temporal changes in groundwater nitrate concentration across the entire CONUS. Our analysis reveals county level groundwater nitrate concentration changes occurred over the past two decades, particularly in regions initially with high concentrations in 2001, ranging from −16.2 mg/L-N to +6.5 mg/L-N between 2001 and 2020. 27 counties in the country appeared to have new concentrations greater than or equal to the maximum concentration level (MCL) at least once during this period. We revealed direct relationships between groundwater nitrate concentrations and climate factors, including that temperature and precipitation dominate the interannual variability in groundwater nitrate concentration in 75.2 % of counties. Notably, we have established a clear correlation between groundwater nitrate concentration and precipitation. Specifically, when annual precipitation falls below a threshold of about 748 mm, an increase of precipitation can directly result in elevated nitrate concentrations in groundwater, indicating heightened vulnerability to contamination due to climate change. This study forms a pivotal foundation for forecasting groundwater nitrate concentration changes across the continent and assessing the potential impact of climate change on future groundwater nitrate concentrations.

Proposed Detection Limits for Radioactivity Concentrations in Water in the Decommissioning and Dismantling of Nuclear Facilities

The Dismantling and Decommissioning (D&D) of nuclear facilities poses several challenges for radioactivity measurement laboratories involved in environmental radiation monitoring plans. One of them is the definition of the detection limits to be achieved for the radionuclides analysis in different samples. The detection limits should be set in such a way that the obtained concentration values for each radionuclide are easily discriminated from certain maximum activity concentration levels. These maximum activity concentration levels are usually set in view of the respective dose contributions from each radionuclide. There are some national legislations that settle detection limits for drinking water. However, there is no regulation containing detection limits for groundwater or surface water. In this way, different institutions or companies require very different detection limits for radioactivity concentration assessment in those types of water associated with D&D activities. In this work, we focus on the detection limits required for the D&D activities in rainwater, surface water and groundwater. We propose detection limits obtained by applying the WHO methodology for maximum activity concentration levels and compare with those requested by radioactive waste management agencies and regulatory bodies. Some real cases where our proposal allows identification of events are analysed and conclusions are extracted.

Overcoming the challenge of potent endogenous interferences in limaprost quantification: An innovative methodology combining differential mobility spectrometry with LC-MS/MS for ultra-high sensitivity, selectivity and significantly enhanced throughput

Limaprost, an orally administered analogue of prostaglandin E1, possesses potent vasodilatory, antiplatelet, and cytoprotective properties. Due to its extremely low therapeutic doses and exceedingly low plasma concentrations, the pharmacokinetic and bioequivalence studies of limaprost necessitate a highly sensitive quantitative method with a sub-pg/mL level of lower limit of quantification. Moreover, the intensity of endogenous interferences can even exceed the maximum concentration level of limaprost in human plasma, presenting further challenge to the quantification of limaprost. As a result, existing methods have not yet met the necessary level of sensitivity, selectivity, and throughput needed for the quantitative analysis of limaprost in pharmacokinetic and bioequivalence investigations. This study presents a new methodology that combines differential mobility spectrometry (DMS) with liquid chromatography-tandem mass spectrometry (LC-MS/MS) and utilizes a distinctive strategy to achieve more accurate DMS conditions. This integration yields a method that is currently the most sensitive and features the shortest analytical time, making it the sole technique capable of meeting the requirements for limaprost pharmacokinetic and bioequivalence investigations. This method demonstrates robustness and is successfully employed in a pharmacokinetic investigation of limaprost in human subjects, underscoring that the combination of DMS with LC-MS/MS serves as an efficacious strategy for overcoming the challenges inherent in analyzing biological samples afflicted by multiple interferences.

DEVELOPMENT OF A MATHEMATICAL MODEL FOR ANALYSING THE HAZARDOUS IMPACT ON THE STATE OF GROUNDWATER IN CITY AGGLOMERATIONS FROM MISSILE AND ARTILLERY ATTACKS

The authors have developed a mathematical model for analysing the hazardous impact on the groundwater in urban agglomerations from missile and artillery attacks. The mathematical model consists of a system of four analytical dependencies. The first analytical dependence describes determining the area of groundwater intake from the groundwater level, considering the presence of artificial coatings, infiltration, evaporation, and transpiration, as well as the effect of evapotranspiration. The second dependence determines the area of influence of the missile and artillery danger from the type of weapon, the explosive charge, calibre (diameter), and territorial conditions, the key indicators of the content of which in the territory of the critical infrastructure object, which suffered damage, are further determined by expert calculation using natural samples of soils and groundwater. The third dependence determines the impact of harmful (polluting) substances on groundwater in the territory of the critical infrastructure object, which suffered damage, depending on the process of groundwater movement in the area of the emergency, taking into account the hydraulic pressure and water yield coefficient; the process of distribution of chemically dangerous substances in groundwater, taking into account the coefficient of hydrodynamic dispersion and the velocity of groundwater; convective diffusion of chemically hazardous substances, taking into account the kinetics of sorption. The fourth dependency allows us to choose an efficient concept for the organisation of groundwater monitoring on the territory of a critical infrastructure object that suffered damage based on the variation of formalised parameters for solving individual problems. The initial conditions of the mathematical model are related to the presence of chemically dangerous compounds in groundwater at the maximum permissible concentration level. The boundary conditions of the mathematical model relate to the non-overgrowth of consequences beyond the object level in terms of the number of victims. Keywords: mathematical model, groundwater, missile and artillery damage, critical infrastructure object, emergency prevention.

Assessment of pesticide contamination in groundwater bodies in the Jucar River Basin (Spain) and its spatial distribution

Exposure to the pesticides used in agriculture is a threat to human health and the environment. Nowadays, the world experiences a number of global changes, such as anthropogenic climate change and agricultural expansion which are associated to an increased consumption of water, fertilisers, and pesticides. This has increased the risk of soil and groundwater contamination. In this study, the model Pesticide Root Zone Model 5 (PRZM 5) has been applied to model the behaviour of pesticides in groundwater bodies within the Júcar River Basin (JRB) in Spain. We consider a groundwater body to be at risk of contamination if pesticide estimated concentrations exceed the Maximum Concentration Levels (MCL) and two additional indicators. We identified that Mancha Oriental groundwater body presents a high risk of Atrazine contamination. In the case of the Bromacil risk indicators, Castellón groundwater body was the most likely to be contaminated. Regarding Terbuthylazine risk maps, the probability of exceeding the threshold is low, thus posing a minimal risk in the studied area. Conversely Terbumeton risk maps, showed a high risk of contamination, detecting new areas of contamination that had not been studied for contamination for any pesticide. The spatial distribution of pesticides corresponds to areas mostly dedicated to irrigated agriculture which are associated to regular pesticide applications. Therefore, it can be concluded that the amount of pesticide applied on the field is the most important factor influencing pesticide concentration in groundwater bodies.

EXPERIMENTAL INVESTIGATIONS ON THE ELECTROCHEMICAL MACHINING OF D3 DIE STEEL MATERIAL AND MULTI-OBJECTIVE PARAMETER OPTIMIZATION

The removal of metal in the form of sludge can be termed an ECM process, having primary salient features consisting of the tool, workpiece, power supply and electrolyte solution. ECM is a potential nontraditional machining process that includes too many factors contributing to process performance. Therefore, obtaining optimal factor combinations for higher efficiency is complex. In this research work, machining parameters are voltage, powder concentration and electrolyte concentration, based on which material removal rate (MRR) and surface roughness (SR) are derived. Regression analysis, signal-to-noise ratios and analysis of variance (ANOVA) are performed to determine the optimal levels and to examine the effects of machining parameters on MRR and SR. The results derived from the experiments noticed that the MRR decreases when the voltage level is increased and surface roughness decreases for the applied voltage. In case of an increase in powder concentration, MRR decreases from range 4 to 6 and further reduces to 6–8. In case of SR, it additionally decreases on the maximum level of powder concentration. In electrolyte concentration, the MRR decreases on the increment of electrolyte and increases after a short period of time; simultaneously SR is increased from range value 10–20 and decreased with a maximum level 20–30 of NaCl solution. A comparison of MOORA-PCA and TOPSIS-PCA demonstrates the superiority of TOPSIS over MOORA technique. Statistical results (95% confidence level) indicate that the voltage, powder concentration, and electrolyte concentration affect the surface roughness by 69.50%, 8.67% and 14.59% in the electrochemical machining of d3 die steel. Therefore, the optimum combination of process parameters corresponding to voltage: 45[Formula: see text]V, powder concentration: 4[Formula: see text]g/L, and electrolyte concentration: 10 NaCl/L, respectively, were found to yield the desired result. The prediction accuracy of the TOPSIS-PCA hybrid approach model is found better than MOORA-PCA technique.

Reduction by air purifier of particulate concentration during orthodontic procedures: a pilot study

BackgroundThe SARS-CoV-2 pandemic has raised awareness of the importance of air quality. This pilot study arose from the need to reduce the concentration of particulate matter in the dental office during orthodontic procedures. To evaluate the efficacy of using an air purifier during orthodontic care in the dental office to reduce the concentration of ambient particulate matter.ResultsSignificant reductions in particle numbers were obtained for all particle sizes except the largest particles counted (10 μm) through use of the air filter. A marked association between higher humidity levels and higher particle counts was also observed.ConclusionsUsing an air purifier during dental care achieves a significant reduction in the concentration of ambient particles in the dental office. There is a correlation between higher relative humidity and higher particle concentration. The probability of obtaining a maximum particulate concentration level of 0.3 and 0.5 μm is 1000 times lower when using an air purifier.

Superspreading of SARS-CoV-2 at a choir rehearsal in Finland-A computational fluid dynamics view on aerosol transmission and patient interviews.

COVID-19 pandemic has highlighted the role of aerosol transmission and the importance of superspreading events. We analyzed a choir rehearsal in November 2020, where all participants, except one who had recently earlier recovered from COVID-19, were infected. We explore the risk factors for severe disease in this event and model the aerosol dispersion in the rehearsal room. Characteristics of participants were collected by interviews and supplemented with patient records. A computational simulation of aerosol distribution in the rehearsal room and the efficacy of potential safety measures was conducted using the Large-Eddy Simulation approach. Infection risk was studied by analyzing quanta emission and exposure with the Wells-Riley equation. The simulation showed that airborne transmission likely explains this mass contagion event. Every singer was exposed to the virus in only 5 min from the beginning of the rehearsal, and maximum concentration levels were reached at 20 min the concentration levels started to approach a steady state after 20 min. Although concentration differences existed in the room, risk levels near (1 m) and far (5 m) from the aerosol source were similar for certain singers. Modeling indicated infection risk levels of 70-100% after one hour; the risk would have been considerably reduced by wearing high-filtration respirators. Age and pre-existing comorbidities predicted more severe disease. The high incidence of illness may be partly attributed to the relatively high median age of individuals. Additionally, those admitted to the hospital had multiple underlying health conditions that predispose them to more severe disease. Airborne transmission and indoor space can explain this mass exposure event. High-filtration respirators could have prevented some infections. The importance of safety distances diminishes the longer the indoor event. The concept of safety distance is challenging, as our study suggests that long range airborne transmission may occur in indoor events with extended duration. We encourage informing the public, especially persons at risk, of safety measures during epidemics.

Qualitative and quantitative concentration-response modelling of gene co-expression networks to unlock hepatotoxic mechanisms for next generation chemical safety assessment.

Next generation risk assessment of chemicals revolves around the use of mechanistic information without animal experimentation. In this regard, toxicogenomics has proven to be a useful tool to elucidate the underlying mechanisms of adverse effects of xenobiotics. In the present study, two widely used human in vitro hepatocyte culture systems, namely primary human hepatocytes (PHH) and human hepatoma HepaRG cells, were exposed to liver toxicants known to induce liver cholestasis, steatosis or necrosis. Benchmark concentration-response modelling was applied to transcriptomics gene co-expression networks (modules) to derive benchmark concentrations (BMCs) and to gain mechanistic insight into the hepatotoxic effects. BMCs derived by concentration-response modelling of gene co-expression modules recapitulated concentration-response modelling of individual genes. Although PHH and HepaRG cells showed overlap in deregulated genes and modules by the liver toxicants, PHH demonstrated a higher responsiveness, based on the lower BMCs of co-regulated gene modules. Such BMCs can be used as transcriptomics point of departure (tPOD) for assessing module-associated cellular (stress) pathways/processes. This approach identified clear tPODs of around maximum systemic concentration (Cmax) levels for the tested drugs, while for cosmetics ingredients the BMCs were 10-100-fold higher than the estimated plasma concentrations. This approach could serve next generation risk assessment practice to identify early responsive modules at low BMCs, that could be linked to key events in liver adverse outcome pathways. In turn, this can assist in delineating potential hazards of new test chemicals using in vitro systems and used in a risk assessment when BMCs are paired with chemical exposure assessment.

Vascular Repair for Iatrogenic Injury during Microsurgical Procedures: Clinical Investigation and Review of 18 Cases at a Single Institution.

Intracranial vascular injury (VI) due to surgery is a critical complication that can lead to serious neurologic deficits. To our knowledge, only a few review articles on VI during an operation have been published so far. We retrospectively investigated the type, cause, and measurement of VI during surgery at our institution. Unexpected VI cases occurred in 18 of 2,228 craniotomy procedures, including 794 aneurysm clippings and 357 tumor resections. We investigated the causes and coping techniques of the VI cases, as well as their full details. There were six cases of aneurysm neck tear, one case of sylvian vein injury, and one case of superior trunk perforation during direct clipping. Regarding tumor resection procedures, nine cases of arterial injury and one case of cortical vein injury were extracted. Almost all VIs were caused by carelessness or basic manipulation mistakes. We repaired all these cases with simple placement of suture threads with or without pinch clips, flow alteration using bypass techniques, and in 16 cases no neurologic deficit or deterioration on imaging occurred; however, 3 patients were verified to have ischemic changes on postoperative imaging. Most VIs were directly caused by a simple error and carelessness of an operator or an assistant. Many of these injuries can be avoided if a basic set of rules are followed and remembered during the surgical procedure. However, the surgical procedure involves human work, and errors cannot be eradicated even upon maximum concentration levels. Neurosurgeons should be prepared for an eventual quick repair of an unexpected cerebral VI.

Radiological Impact Assessment of Natural Radionuclides and Heavy Metal Contamination in Industrial Tin-Tailing Processing Effluent

This study investigates the radiological hazard and heavy metal contamination of water effluents from Malaysian tin-tailing processing plants. Samples were collected from retention ponds in seven separate tin tailing processing plants scattered throughout the state of Perak, Malaysia. Samples were analysed for radioactivity and heavy metal concentration using Gamma-ray Spectrometry System and Inductively Coupled Plasma-Mass Spectrometry, respectively. The analysis indicates that the concentration of Radium-226 (226Ra), Radium-228 (228Ra), and Potassium-40 (40K) in samples ranged from 2.4 - 34.9 Bq/l, 0.8 - 14.7 Bq/l, and 19.5 - 299.4 Bq/l, respectively. These levels surpassed the control limits (5 Bq/l and 10 Bq/l for 226Ra and 228Ra) set by the regulatory authority. The analysis of the heavy metal contamination showed that the concentration of Arsenic (As) and Lead (Pb) werehigher than the Maximum Concentration Level (MCL) of 0.01 and 0.015 mg/L, respectively. Further evaluation of radiological impact showed that the average Annual Effective Doses (AED) by water ingestion and AED for external exposure are 1.43±0.67 mSv/y and 1.71±0.79 mSv/y, respectively. While for non-carcinogenic and carcinogenic risk assessments, the value of hazard index and lifetime cancer risk is 2.1×10-10 and 1.2×10-7, respectively. These research findings suggest that effective treatment of the effluent should be implemented before discharge into the drainage system to prevent the accumulation of radionuclides and heavy metals in the environment, which may pose a risk to public health.

Pharmacokinetics of Enrofloxacin and its Metabolite Ciprofloxacin in Badri Cows

Background: Breeds of animals differ with respect to anatomical, physiological and behavioural traits hence the study of inter-breed variation in pharmacokinetics becomes necessary. The aim of the current investigation was to determine the pharmacokinetics of enrofloxacin following intravenous bolus administration to assess the influence of breed on drug pharmacokinetics and availability. Methods: In the present study the pharmacokinetics of a common antimicrobial drug, enrofloxacin and its metabolite, ciprofloxacin was studied in adult, non-pregnant and dry Badri cows, wherein a commercial preparation of enrofloxacin (10% v/v) was administered at a dose rate of 7.5 mg/kg intravenously as a single dose. The plasma samples were collected at regular intervals and subjected to analysis by HPLC after appropriate processing. The results obtained were analysed using a software tool, “PK Solver” to obtain the pharmacokinetic parameters. Result: From the study, it was revealed that the Badri cattle showed a distribution half-life of 0.11 h, a volume of distribution of 7.63 L.kg-1, an elimination half-life of 4.27 h and an MRT of 5.93 h for enrofloxacin. Whereas, a maximum plasma concentration level of 0.12 µg.ml-1 was observed for ciprofloxacin in the current study. According to the results obtained in the pharmacokinetic study, an individualized dosage regimen containing a priming dose of 5 mg/kg and a maintenance dose of 4.5 mg/kg with an interval of 24 hours was suggested for the enrofloxacin in Badri cattle. The results of our current study when compared with the previously available literature on other cattle breeds suggested that the Badri cattle differed with respect to pharmacokinetic properties and further studies will be required to determine the conclusive reason for the differences.

Content of Trace Elements in Tissues of Gastropod Mollusks of the Family Buccinidae (Gastropoda) off the Coasts of South-Eastern Sakhalin (the Sea of Okhotsk)

The content of Pb, Cd, Cu, Cr, Mn, Ni, Fe, and As in the muscle, mantle, and digestive glands of the gastropod mollusks Neptunea excelsior, N. behringiana, N. multistriata, and N. varicifera, as well as Buccinum verkruezeni, living near the coasts of the South-Eastern Sakhalin has been estimated. Representatives of the ge-nera Neptunea and Buccinum showed some differences in the ranges of variation and series of value sequences of trace element concentrations in the muscle. Exceeding the hygienic standard for the content of As in the hepatopancreas was found in all the studied mollusks, and in the muscle – in all, except for N. behringiana. The maximum permissible level of Cd concentration was exceeded in the hepatopancreas of N. multistriata.

Elevated methylmercury in Antarctic surface seawater: The role of phytoplankton mass and sea ice

Methylmercury is a neurotoxin that is biomagnified in marine food webs. Its distribution and biogeochemical cycle in Antarctic seas are still poorly understood due to scarce studies. Here, we report the total methylmercury profiles (up to 4000 m) in unfiltered seawater (MeHgT) from the Ross Sea to the Amundsen Sea. We found high MeHgT levels in oxic unfiltered surface seawater (upper 50 m depth) in these regions. It was characterized by an obviously higher maximum concentration level of MeHgT (up to 0.44 pmol/L, at a depth of 3.35 m), which is higher than other open seas (including the Arctic Ocean, the North Pacific Ocean and the equatorial Pacific), and a high MeHgT average concentration in the summer surface water (SSW, 0.16 ± 0.12 pmol/ L). Further analyses suggest that the high phytoplankton mass and sea-ice fraction are important drivers of the high MeHgT level that we observed in the surface water. For the influence of phytoplankton, the model simulation showed that the uptake of MeHg by phytoplankton would not fully explain the high levels of MeHgT, and we speculated that high phytoplankton mass may emit more particulate organic matter as microenvironments that can sustain Hg in-situ methylation by microorganisms. The presence of sea-ice may not only harbor a microbial source of MeHg to surface water but also trigger increased phytoplankton mass, facilitating elevation of MeHg in surface seawater. This study provides insight into the mechanisms that impact the content and distribution of MeHgT in the Southern Ocean.

The effect of size and shape of pores on the prediction model of compressive strength of foamed concrete

The Balshin’s model is the most well-known of the models used to predict the compressive strength of aerated concrete. Among the pore characteristics such as the amount of porosity, the size of the pores, and their shape, Only the amount of porosity is placed as a specific parameter in the Balshin’s model. The impact of the other two characteristics, on the other hand, is included in the power value of the Balshin’s equation. Compressive strength tests and identifying the characteristics of air voids using microscopic imaging were performed on the mixtures produced in this study, which had weight ratios of sand to the cement of 1, 1.5, and 2, and the percentage of foam volumes of 0, 15, 25 and 35. In this study, a review of some of the factors influencing the change in the pore characteristics was performed, including the porosity of the foamed mixture and the size of sand used, in addition to the effect of the pore characteristics such as size and shape on the compressive strength of the foamed mixture. This study aims to conduct a comparative analysis of the models introduced in previous research to determine the effect of the pore characteristics of semi-structural and structural foamed mixtures (with sand) caused by mixture porosity and the sand size on the Balshin’s model. Among the types of relationships presented for the Balshin’s model, the relationship based on the paste fraction porosity was used. According to the findings of this study, foam porosity is the most important factor influencing pore size change, followed by sand size. The increase in the size of the pores and their non-sphericality decreased the relative compressive strength and, as a consequence, increased the power of the Balshin’s model because the maximum level of stress concentration was created adjacent to the middle diameter of the pores at the period of concrete rupture.

The effects of soil properties and sorbent amendments on immobilization of perfluorooctane sulfonate (PFOS) in contrasting soils: Experimental and numerical study

Per- and polyfluoroalkyl substances (PFAS), a class of manmade organo-fluorine chemicals, are a serious challenge to water supplies. In this study, the effects of physicochemical properties of Florida topsoil and Ringold formation Hanford site sediment as well as the influence of immobilizers on the sorption behavior of PFOS were tested. Activated charcoal (AC) and food waste compost amendments were added to the soil and sediment at 0.1 and 3 wt% concentration, respectively. The PFOS adsorption fits best to pseudo second-order kinetic and Freundlich isotherm models. PFOS uptake was greater in Florida topsoil compared to Hanford site sediment, indicating that organic matter played a key role in the retention of PFOS. The food waste compost amendment at 3 wt% had no impact on PFOS uptake. However, AC amendment at 0.1 wt% enhanced PFOS sorption in Florida topsoil by 80% and Hanford site sediment by 99% through increasing the soil/water partitioning coefficients (kd value). A one-dimensional model was used to simulate the influence of AC in Florida topsoil on the leaching of PFOS to the groundwater by the percolation of rainwater over time. The results demonstrated the addition of 0.1 wt% AC, to the soil dramatically inhibits or delays the leaching of PFOS for up to one year under certain conditions to below the guideline for maximum concentration level (0.02 ng/L). The amendment could control PFOS release for more than 10 years by increasing the kd value by 10 times.

Porous-polymer monolith decorated with dithizone for greener visual and spectrophotometric sensing of Hg(II)

This paper describes a hydrophobic porous polymer monolith for visual and spectrophotometric determination of Hg(II). The monolith was synthesized in the coffins of 2.0 mm i.d. transparent polypropylene ink-pen tubes using stearyl methacrylate (SMA) as the functional monomer and ethylene glycol dimethacrylate (EDMA) as the crosslinker by fast UV-mediated polymerization. The poly(SMA-co-EDMA) monolith retained dithizone, an anchor for the Hg(II) and colorimetric reagent. Besides the monolith's fast preparation, the polypropylene transparency enabled the naked-eye visualization of all color changes occurring in the solid phase extraction steps (conditioning, loading, washing and elution). This feature also enabled the unprecedented use of a simple ruler for detection since the distance occupied by Hg(II) inside the column was linearly related to Hg(II) concentration. Loading the column with 12.0 mL of sample and elution with 1.0 mL of ethanol contributed to the green analytical chemistry and provided a detection limit of 7.9 µg L−1, which was enough to determine Hg(II) in certified estuarine sediment (ERM-CC580) and urine samples. A sample volume of 45 mL provides a detection limit of 0.59 μg L−1, allowing the detection of trace Hg(II) levels in the Billings reservoir waters, an anthropized water reservoir located in the São Paulo Metropolitan Area of São Paulo State (Brazil), thus attending the maximum concentration levels preconized by the United States Environmental Protection Agency (1.0 µg L−1) and World Health Organization (6.0 µg L−1). The proposed method is simple, cheap and can be easily implemented in field measurements for sample trials.

Presença de pesticidas organoclorados selecionados (OCPs) em sedimentos e biota do Rio Satluj, Paquistão: primeiro relatório

In the developed countries, the use of OCPs (organochlorine pesticides) has been banned. However, in South Asia several of them are still in use. In Pakistan and India a constant addition of OCPs into the atmosphere has been indicated by various researchers. In this study levels of selected organochlorine pesticide residues were assessed in sediment and biota collected from four (4) water reservoirs (3 Barrages & 1 Siphon) on the River Satluj Pakistan, along 231 miles (372 km) of River stretch which was further divided into 12 sampling sites. It was aimed to find out the levels of organochlorine pesticide (OCPs) residues in sediments and from selected fish species (Labeo rohita, Wallagu attu, Cyprinus carpio) of the River Satluj Pakistan. The Organochlorine residues (seven pesticides) present in samples of sediments and biota were investigated through multi residue method, using Gas Chromatograph (GC-ECD).In the current study, the concentration of DDT, was investigated in Wallago attu (0.786-3.987 ppb), Labeo rohita (0.779-4.355 ppb) and Cyprinus carpio (1.234-5.654 ppb). DDE was also found in Cyprinus carpio (1.244-6.322 ppb), Wallag attu (0.877-4.221 ppb) and Labeo rohita (2.112-5.897 ppb). Aldrin was not observed in Labeo rohita and Wallago attu. Currently, lindane and DDE was found predominately high in the sediments of study area at SZ-4 (Panjnad Barrage) ranging (2.238-8.226 ppb) and (4.234-6.876 ppb), respectively. Heaptachlor was found only at SZ-4 (Panjnad Barrage) from the sediments with concentration ranging (0.032-234 ppb). In short all other residues investigated were found below the MCL (maximum concentration level) in all the compartments of the study area set by various agencies like WHO/FAO- Codex Alimenterious.