Polymer Matrix Research Articles

Enhancement of Mechanical Properties of PCL/PLA/DMSO2 Composites for Bone Tissue Engineering

Bone tissue engineering shows potential for regenerating or replacing damaged bone tissues by utilizing biomaterials renowned for their biocompatibility and structural support capabilities. Among these biomaterials, polycaprolactone (PCL) and polylactic acid (PLA) have gained attention due to their biodegradability and versatile applications. However, challenges such as low degradation rates and poor mechanical properties limit their effectiveness. Dimethyl sulfone (DMSO2) has emerged as a potential additive to address these limitations, offering benefits such as reduced viscosity, increased degradation time, and enhanced surface tension. In this study, we investigate tailored composites comprising PLA, PCL, and DMSO2 to enhance mechanical properties and hydrophilicity. Through material characterization and mechanical testing, we found that the addition of DMSO2 led to improvements in the yield strength, modulus, and hydrophilicity of the composites. PCL and DMSO2 10, 20, and 30 wt% were premixed, and 20 wt% PCL + 10, 20, and 30 wt% DMSO2 were mixed with PLA. Specifically, PLA/PCL/DMSO2 composites exhibited higher yield strengths and moduli compared to pure PLA, pure PCL, and PLA/PCL composites. Moreover, the hydrophilicity of the composites increased with DMSO2 concentration, facilitating cell attachment. Fourier-transform infrared spectroscopy (FTIR) confirmed the presence of –COOH and –COH bands in PLA/PCL/DMSO2 composites, indicating chemical interactions between DMSO2 and the polymer matrix. Fractography analysis revealed enhanced interface adhesion in PLA/PCL/DMSO2 composites due to the hydrogen bonding. Overall, this study demonstrates the potential of PLA/PCL/DMSO2 composites in bone tissue engineering applications, offering improved mechanical properties and enhanced cell compatibility. The findings contribute to the advancement of biomaterials for additive manufacturing in tissue engineering and regenerative medicine.

Sustainable starch-based bioplastics reinforced with carob filler: characterization and biodegradability assessments

Starch-based thermoplastic polymer is a biopolymer that is being widely explored as a replacement for conventional polymers. Since thermoplastic starch suffers from mechanical defects, certain mechanical and thermal properties of starch-based polymers can be improved by incorporating fillers or reinforcements derived mainly from natural substances. This article reports the preparation, physicochemical, and mechanical characterization and biodegradation of starch-based bioplastics extracted from potato (Solanum tuberosum) peels using glycerol (G) as plasticizer and reinforced with carob powder, a readily growing plant in Mediterranean climates. The present study investigates the effect of incorporating different proportions (0, 2, 5, 10, and 15 wt.%) of carob powder (Cb) in the films thus prepared. These biopolymer films were fully characterized using analytical techniques including Fourier transform infrared spectroscopy with attenuated total reflection (FTIR/ATR), thermogravimetric analysis (TGA/DTG), X-ray diffraction (XRD), optical microscopy (OM), Scanning electron microscopy (SEM), mechanical evaluations, and biodegradability assessments. The biodegradability of the obtained bioplastic samples was evaluated. Scanning electron microscopy (SEM) revealed strong interfacial adhesion between the constituent filler and the polymer matrix.

Neutron Reflectivity Study on the Adsorption Layer of Polyethylene Grown on Si Substrate.

To investigate the structure of the interface between polyethylene films and substrates, the neutron reflectivity (NR) of deuterated polyethylene (dPE) thin films deposited on Si substrates was measured, demonstrating water accumulation at the interface, even under ambient conditions. After leaching the thermally annealed dPE films in hot p-xylene, NR measurements were conducted on the layers remaining on the substrate, clearly revealing that the adsorption layer of dPE grew during annealing and consisted of two layers, an inner adsorption layer and an outer adsorption layer, as previously proposed for amorphous polymers. The inner adsorption layer was approximately 3.7 nm thick with a density comparable to that of the bulk. The outer adsorption layer was several nanometers thick and appeared to grow insufficiently on top of the inner adsorption layer under the annealing conditions examined in this study. This study clarifying the growth of the adsorption layer of polyethylene at the interface with an inorganic substrate is useful for improving the performance of polymer/inorganic filler nanocomposites due to the wide utility of crystalline polyolefins as polymer matrix materials in nanocomposites.

Effect of the Chemical Nature of MQ Copolymers on the Rheological Properties of Compositions on Their Basis

The rheological and rheokinetic properties of the compositions based on low-molecular rubber polyisoprene and MQ copolymer particles with decyl terminal groups were studied. The effect of the ratio of M and Q units in the copolymer on the rheological and mechanical properties of the compositions was analyzed. An increase in the length of a hydrocarbon substituent in M units was shown to lead to an increase in the affinity of the copolymer to the carbon-chain polymer matrix. An increase in the content of Q units facilitates the growth of the elastic modulus of the cured composites.

Local fluorinated functional units enhance Li+ transport in acrylate-based polymer electrolytes for lithium metal batteries

Fluorinated polymer matrix emerges as a promising candidate owing to their enhanced anti-oxidation ability, but their application is plagued by the relatively low ion conduction ability and the ambiguous ionic conduction mechanism in the fluorinated polymer electrolytes (PEs). Herein, a series of acrylate-based electrolytes with different fluorinated functional units (fluorinated-FUs) of poly(ethyl methacrylate) electrolyte (0F PE), poly(trifluoroethyl methacrylate) electrolyte (3F PE) and poly(hexafluorobutyl methacrylate) electrolyte (6F PE) were investigated. Beneficial from the long fluorinated-FUs in the side chain, the 6F PE exhibits improved both ionic conductivity of 4.0×10−4 S cm−1 and Li+ transference number of 0.65 at 25 °C, which are superior to those of the 0F PE and the 3F PE. The enhanced ion conduction mechanism was clarified via combining the theoretical calculations and experimental data, where the integration of local fluorinated-FUs provides additional coordinating sites for the continuous Li+ migration and regulates the ion transporting pathways. This work demonstrates that the regulation of local fluorinated-FUs can provide a promising strategy for achieving high performance PEs applied in solid-state batteries.

Significant sliding speed effect on the friction and wear behavior of UHMWPE matrix composites

PurposeWith the rapid development of the pipeline transportation and exploitation of mineral resources, it is urgent requirement for the high-performance polymer matrix composites with low friction and wear to meet the needs of solid material transportation. This paper aims to prepare high-performance ultrahigh molecular weight polyethylene (UHMWPE) matrix composites and investigate the effect of service condition on frictional behavior for composite.Design/methodology/approachIn this study, UHMWPE matrix composites with different content of MoS2 were prepared and the tribological performance of the GCr15/composites friction pair in various sliding speeds (0.025–0.125 m/s) under dry friction conditions were studied by ball-on-disk tribology experiments.FindingsResults show that the frictional behavior was shown to be sensitive to MoS2 concentration and sliding velocity. As the MoS2 content is 2 Wt.%, composites presented the best overall tribological performance. Besides, the friction coefficient fluctuates around 0.21 from 0.025 to 0.125 m/s sliding speed, while the wear rate increases gradually. Scanning electron microscopy images, energy-dispersive spectroscopy and Raman Spectrum analysis present that the main wear mechanisms were abrasive and fatigue wear.Originality/valueThe knowledge obtained herein will facilitate the design of UHMWPE matrix composites with promising self-lubrication performances which used in slag transport engineering field.

Conductive/Insulating Bioinks with Multitechnology Compatibility and Adjustable Performance.

Conducting/insulating inks have received significant attention for the fabrication of a wide range of additive manufacturing technology. However, current inks often demonstrate poor biocompatibility and face trade-offs between conductivity and mechanical stiffness under physiological conditions. Here, conductive/insulating bioinks based on two-dimensional materials are proposed. The conductive bioink, graphene (GR)-poly(lactic-co-glycolic acid) (PLGA), is prepared by introducing conductive GR into a degradable polymer matrix, PLGA, while the insulating bioink, boron nitride (BN)-PLGA, is synthesized by adding insulating BN. By optimizing the material ratios, this work achieves precise control of the electromechanical properties of the bioinks, thereby enabling the flexible construction of conductive networks according to specific requirements. Furthermore, these bioinks are compatible with a variety of manufacturing technologies such as 3D printing, electrospinning, spin coating, and injection molding, expanding their application range in the biomedical field. Overall, the results suggest that these conducting/insulating bioinks offer improved mechanical, electronic, and biological properties for various emerging biomedical applications.

Improvement in dielectric properties of polyacrylate copolymers by engineering the interphase region with polymer-grafted reduced graphene oxide

In this study, an innovative interfacial design strategy aimed to investigate the effects of interfacial interactions between the matrix and reduced graphene oxide (rGO) on the dielectric properties of nanocomposites. The polymer matrices with varying comonomer ratios of butyl acrylate and methyl methacrylate were synthesized to deliberately engineer diverse interfacial interactions with polymer-grafted reduced graphene oxide. Through this approach, fine-tuned interfacial interactions between the polymer matrix and polymer-grafted rGO were achieved, which was verified by FE-SEM, DSC, and DMTA analysis. Subsequently, the dielectric properties of the nanocomposites were investigated to elucidate the relationship between interfacial strength and dielectric efficiency. It was found that polymer nanocomposites with enhanced interfacial interactions exhibit higher dielectric permittivity compared to the neat matrix. This enhancement was attributed to the increased charge storage in the interfacial area and improved alignment of polarizable polymer chains in the interphase between the polymer matrix and polymer-grafted rGO.

Enhancing fresh strawberry preservation: Fabrication and characterization of electrospun fibers decorated with functionalized graphene oxide

AbstractThis study focuses on developing an innovative packaging material for fresh strawberries composed of electrospun poly(ε‐caprolactone) (PCL)/poly(vinylpyrrolidone) (PVP) fibers decorated by pure graphene oxide (GO) and functionalized GOs with silane agents using the electrospinning technique. Initially, synthesized GO was first functionalized by silane agents, and followed by the fabrication of electrospun PCL/PVP fibers incorporating both pure GO and functionalized GOs. The surface morphological analyses revealed the uniformity, smoothness, and beadless in the fabricated fibers. The average fiber diameter of the PCL/PVP/0.5A‐GO fibers was found as 3244 ± 56 nm. Electrospun PCL/PVP/0.5A‐GO and PCL/PVP/0.5G‐GO fibers exhibited increased water absorption ratios over 20 days. The incorporation of GO into the polymer matrix, along with an increase in GO concentration, enhanced the tensile strength of the fibers, found as 5.149 ± 0.032 kPa. In preservation tests on fresh strawberries, PCL/PVP/0.5A‐GO fibers demonstrated superior freshness compared with unpacked strawberries and other variants. The study also highlighted the inhibitory effects of fibers decorated with 0.5% APTES‐GO, showing the highest inhibition zone. In summary, fibers incorporating 0.5% A‐GO effectively extended the shelf‐life of fresh strawberries, making them a promising packaging material for perishable goods.

Fabrication and Testing of Hybrid Polymer Composite Material by Using Carbon, Glass, Kevlar Fibers

Composites which made up of fiber reinforcements are universally endorsed option for the automobiles with a lightweight. Due to the unique properties of fiber-reinforced composites, it became a perfect alternative for traditionally used materials. Most of the automobile industries prefer polymer matrix fiber-reinforced composites for the reason that its light weight helps in carbon emission reduction and Additive manufacturing (AM) produces a complex shaped product from its data, layer by layer, with high precision and much less material wastage. As compared to the conventional manufacturing process, there are many positive environmental advantages of additive manufacturing technologies. Most importantly, there is less waste of raw material and the use of new and smart materials. In this work, we first focused on creating the composite material utilizing the Hand Lay-Up method with materials such as Carbon Fiber/Epoxy Composite with Copper Oxide (CuO) Nanoparticles and Banana Glass Fiber. Following that, we readied ASTMD638 specimens for both compressive and tensile testing. We created an ASTMD638 model for the investigation's tensile and compressive tests using Solid Works design program, and we then saved the design model in STL format. This STL format was uploaded into the CURA software for slicing. The slicing model was then saved into G-code format, and it was printed in a fused deposition modeling machine. Lastly, we tested both specimens using a compressive test setup in a Universal Testing Machine model (INSTRON-3369) UTM, and the results showed 3D printed files. Keywords: Glass Fiber, Banana Fiber, Carbon Fiber, Copper Oxide Nano filler, 3D printing Machine,Corbon Fiber Filament.

Solvent Vapor Annealing and Plasma Treatment Stabilize Silver Nanowire Layers

AbstractSilver nanowires (AgNW) find use in transparent conductive electrodes with applications in solar cells, touch screens, and wearables. Unprotected AgNW are prone to atmospheric corrosion and lose conductivity over time. Known passivation techniques either require submersion of pre‐deposited AgNW in liquid compounds or the modification of AgNW inks prior to deposition, which alters viscosity and complicates deposition. Here, new possibilities for stabilization of pre‐deposited AgNW networks without need for submersion are explored. It is demonstrated that AgNW networks can be stabilized either by argon or hydrogen plasma treatment or by solvent vapor annealing with ethanol, methanol, or ethyl acetate. These treatments yielded stable electrical resistance over at least nine weeks, whereas untreated or thermally annealed AgNW layers quickly lost conductivity. The potential of solvent vapor annealing is further explored by demonstrating a new processing technique for stable polymer matrix composites containing AgNW. Co‐deposited layers of AgNW with polystyrene microbeads are annealed in ethyl acetate vapor to stabilize the AgNW while at the same time merging polymer beads into a closed film around the AgNW. The resulting composites maintained stable resistance and transmittance for at least seven weeks.

In Vitro Biological Evaluation of an Alginate-Based Hydrogel Loaded with Rifampicin for Wound Care.

We report a biocompatible hydrogel dressing based on sodium alginate-grafted poly(N-vinylcaprolactam) prepared by encapsulation of Rifampicin as an antimicrobial drug and stabilizing the matrix through the repeated freeze-thawing method. The hydrogel structure and polymer-drug compatibility were confirmed by FTIR, and a series of hydrogen-bond-based interactions between alginate and Rifampicin were identified. A concentration of 0.69% Rifampicin was found in the polymeric matrix using HPLC analysis and spectrophotometric UV-Vis methods. The hydrogel's morphology was evaluated by scanning electron microscopy, and various sizes and shapes of pores, ranging from almost spherical geometries to irregular ones, with a smooth surface of the pore walls and high interconnectivity in the presence of the drug, were identified. The hydrogels are bioadhesive, and the adhesion strength increased after Rifampicin was encapsulated into the polymeric matrix, which suggests that these compositions are suitable for wound dressings. Antimicrobial activity against S. aureus and MRSA, with an increased effect in the presence of the drug, was also found in the newly prepared hydrogels. In vitro biological evaluation demonstrated the cytocompatibility of the hydrogels and their ability to stimulate cell multiplication and mutual cell communication. The in vitro scratch assay demonstrated the drug-loaded alginate-grafted poly(N-vinylcaprolactam) hydrogel's ability to stimulate cell migration and wound closure. All of these results suggest that the prepared hydrogels can be used as antimicrobial materials for wound healing and care applications.

Flexible ionic liquid aided “LAGP in PVDF” quasi-solid-state electrolyte for high performance and stable Li metal batteries

The NASICON-type ceramic Li1·5Al0.5Ge1.5(PO4)3 (LAGP) electrolyte has been proposed as the most competitive candidates of electrolyte materials toward solid-state Li metal batteries (LMBs) by reason of its high ionic conductivity, cyclic stability under extreme temperatures and wide voltage window. However, poor interface contact, high interfacial resistance and intractable mechanical properties greatly limit its practical applications. In this work, an inorganic-polymer “LAGP in PVDF” quasi-solid-state electrolyte (QSSE) is developed via solution casting method, in which pyr14TFSI ionic liquid (IL) and LiTFSI are combined as functional wetting interface. Benefiting from the coherent interaction of LAGP nanoparticles incorporated into the polymer matrix, and inherent protection of IL, the overall performance of the optimized QSSE include thermal stability, dense structure, flexibility and electrochemical properties. The XRD, SEM, XPS tests demonstrate that the IL using as a solid/electrolyte modified interlayer can enhance Li+ transport, interfacial infiltration and homogenize lithium deposition. The LiFePO4|PL-25LAGP|Li solid-state battery presents an excellent circulation performance under ambient temperature, which displayed an initial discharge specific capacity of 146.8 mAh g−1 at 0.5C and capacity retention of 96.25 % after 150 cycles. The flexibility PL-LAGP CSE shows superior safety and greater development potential for the “LAGP in PVDF” composite electrolyte in solid state LMBs.

New click chemistry scheme towards improvement of filler/polymer crosslinking in bio-based polymer composites

ABSTRACT The current study aims to develop a cutting-edge methodology to enhance compatibility between natural fiber and polymeric matrix in bio-composites. To achieve this, an innovative approach for grafting an azide functional group (Az) onto the surface of polypropylene (PP) was successfully developed and confirmed. The Az group contributed to enhancing the interfacial interaction between the polymer matrix and the bio-filler through chemical crosslinking. Crosslinking is achieved through an innovative and efficient chemical process known as click chemistry. In particular, a click reaction is established between the functionalized PP with an azide group and functionalized natural filler with an alkyne group. The effectiveness of the proposed technique is verified using Fourier Transform Infrared (FTIR) spectroscopy, X-ray Photoelectron Spectroscopy (XPS), Thermo-Gravimetric Analysis (TGA), and Scanning Electron Microscopy (SEM). The resulting bio-composite exhibits higher mechanical properties, better thermal stability, and improved biocompatibility compared to conventional materials. Specifically, the maximum tensile strength was achieved at 10% DPP loading, showing a 22% increase over the base material (DPP/PP) and a 7% increase over neat PP. A more significant enhancement was observed in Young’s modulus results across all samples. Therefore, the established method is beneficial for polymer modification, promoting the production of high-performance bio-composite materials.

A pH-sensitive film based on chitosan/gelatin and anthocyanin from Zingiber striolatum Diels for monitoring fish freshness

As a new type of packaging method, the anthocyanin-based pH-sensitive indicator film has gained much attention owing to low cost, small size, and visually informative property. In this study, an intelligent film based on chitosan/gelatin (CG) matrix with Zingiber striolatum Diels (ZSD) anthocyanin for fish freshness monitoring was developed. The film properties, including thickness, moisture content, color, mechanical properties, UV–vis light barrier property, as well as pH and ammonia sensitivity, were evaluated. The CG-ZSD films exhibited a more compact structure when compared with the CG film. The CG-ZSD20 film showed the highest elongation at break (6.33 ± 0.62%) and lowest tensile strength (20.0 ± 0.58 MPa). FTIR spectra revealed the strong hydrogen bond interactions between ZSD and polymer matrix. Film incorporated with 15% anthocyanin extract has increased melting temperature at 118.9 °C, and a lower weight loss (13.8%) at melting temperature. In pH 1–14 buffer, the color of CG-ZSD films underwent a significant change from red to yellow-green. The CG-ZSD15 film was utilized for monitoring fish freshness and showed visible color changes from deep purple to brown. The total volatile basic nitrogen content and pH value changes of fish were closely related to the visual color changes in film. This demonstrated that the film was a highly pH-sensitive film for quantifying fish freshness in real-time.

Electrical conductivity of polyvinyl alcohol/carboxymethyl cellulose doped by zinc oxide and hematite nanoparticles for optoelectronics devices

This research explores polymer nanodielectrics, a category of materials where nanoceramic fillers are incorporated into polymers. These hybrid materials are gaining significant interest because of their tunable optical and electrical characterization, making them potentially well-suited for applications in flexible optoelectronic and organic electronic devices. Polyvinyl alcohol (PVA), Carboxymethyl cellulose (CMC), zinc oxide (ZnO), and hematite (Fe2O3) nanoparticles were utilized to fabricate PVA/CMC-ZnO/Fe2O3 films XRD analysis indicated a reduction in the crystalline character of the PVA/CMC blend following the doping of ZnO/Fe2O3 nanoparticles (NPs). FTIR data approved the complexation between the PVA/CMC blend and the ZnO/Fe2O3, leading to a decrease in intermolecular interactions within the polymeric matrix and coordination with the ZnO/Fe2O3. Electrical analysis obtained an enhancement in σac values with the increase of ZnO/Fe2O3 NPs concentration up to 30 min of laser ablation times The findings from this study suggest the promise of these materials for applications in high-performance batteries, supercapacitors, or other next-generation energy storage and conversion devices.

Compressive Properties of Additively Manufactured Metal-Reinforced PLA and ABS Composites.

The development of multi-material filaments has enabled fused filament fabrication-based additive manufacturing to address demand for high-performance lightweight multifunctional components. In this study, polylactic acid (PLA) and acrylonitrile butadiene styrene based filaments with metallic reinforcements of magnetic iron (MI), stainless steel (SS), bronze (Br), copper (Cu), Bismuth (Bi), and Tungsten (W) were investigated to elucidate their complex processing-structure-property relationships. The microstructure of 3D-printed materials were characterized by microscopy and analyzed to determine the metal cross-sectional area percentage and the relationship between metal reinforcement, the polymer matrix, and porosity. Compression testing was conducted in directions parallel and perpendicular to the build direction in order to evaluate the effect of orientation and metal reinforcement on the mechanical properties. 3D-printed specimens experienced either fracture through print layers or layer-wise interfacial rupture for loads applied perpendicular and parallel to the print layers, respectively. A dependence of yield strength on loading orientation was observed for Br-PLA, Cu-PLA, SS-PLA, Bi-ABS, and W-ABS; however, MI-PLA and pure ABS specimens did not exhibit this sensitivity. Metal reinforcement also influenced the magnitude of compressive yield strength, with MI-PLA and SS-PLA demonstrating increased strength over Br-PLA and Cu-PLA, while ABS demonstrated increased strength over Bi-ABS and W-ABS. These results demonstrate the importance of considering orientation in printing and applications, the trade-off between various metallic reinforcements for added multifunctionality, and the potential of these tailored polymer composites for novel 3D-printed structures.

High performance flexible green triboelectric nanogenerator with polyethylene oxide/mica tribo-positive composite material

Innovating novel, green, biodegradable, and recyclable polymers are critical for the development of environmentally sustainable solutions, eliminating concerns of pollution and microplastic accumulation. Herin, this study presents remarkably enhanced tribo-positive polyethylene oxide (PEO) polarity, by incorporating for the first time, a clay inorganic filler, creating a novel biodegradable composite triboelectric material. The low-cost composite comprised a biodegradable polymeric PEO matrix, an abundant naturally sourced muscovite mica micro-platelet filler, and integrated simple material fabrication methods. A 4 cm2 PEO/Mica film was paired with polytetrafluoroethylene (PTFE), generating a peak-to-peak voltage, current density, and transferred charge density of respectfully, 296 V, 24.2 mA m−2, and 110.3 µC m−2. Reducing the film thickness to 40 µm dramatically enhanced the electrical output, resulting in a peak-to-peak voltage and instantaneous power density of respectfully, 424 V and 12.1 W m−2. The addition of mica greatly improved the dielectric permittivity, promoting the outstanding triboelectric performance. The composite material's long-term stability and flexibility demonstrated significant advantages for self-powering small electronic systems. Furthermore, PEOs facile water solubility allowed mica separation, recovery, recyclability, and integration within new PEO/Mica films, resulted in preserved triboelectric outputs. The PEO/Mica composite delivers exceptional sustainable, recyclable, and tribo-positive attributes, serving as an excellent energy harvesting solution.

Enhanced Mechanical Properties of Carbon Fiber/Epoxy Nanocomposites Modified with Amine-Functionalized Graphene

<div>Since the beginning of time, people have desired the best materials for production. Metals are often too heavy to be used in manufacturing. Polymer matrix composites (PMC) can be considered more dependable than metals in practical applications because of their high strength-to-weight ratio so it is a good alternative of metals. The article’s objective is to investigate the various PMC properties that are reinforced with carbon fiber. CFRP (Carbon fiber-reinforced polymer) was first made using the hand layup method with carbon fiber as a reinforcement and epoxy resin as a matrix after a thorough literature review. As CFRP have higher stiffness and superior “strength-to-weight ratio,” fiber-reinforced polymer (FRP) composites perform notably better than various conventional metallic materials. The qualities of the matrix can be changed to enhance the characterization of FRP composites. The mechanical qualities of FRP composites have risen as a result of significant advancements in the application of nanoparticles for betterment of the matrix and various tests were conducted to calculate the properties of the composite.</div>

Polymer Microspheres Carrying Schiff-Base Ligands for Metal Ion Adsorption Obtained via Pickering Emulsion Polymerization

Several traditional methods for producing polymer microparticle adsorbents for metal ions exist, such as bulk polymerization followed by milling and crushing the material to micron-size particles, precipitation from organic solvents, and suspension polymerization utilizing surfactants. Alternative methods that are easily scalable and are environmentally friendly are in high demand. This study employs Pickering Emulsion Polymerization Technology (PEmPTech) to synthesize nanostructured polymer microspheres that incorporate Schiff-base ligands, which can be utilized for metal ion adsorption, and specifically Cu(II) ions. Our innovative approach makes use of nanoparticle-stabilized, surfactant-free emulsions/suspensions, enabling the straightforward production of ligand-bearing microspheres while allowing for the precise modulation of the polymer matrix chemistry to maximize adsorption capacities. Through this method, we demonstrate notable enhancements in Cu(II) ion adsorption, which correlates with both the polarity of the monomers used and the concentration of Schiff-base ligands within the microspheres. Notably, our results offer insights into the structure–activity relationships essential for designing tailored adsorbents. This work provides a scalable method to produce high-performance adsorbents and also contributes to sustainable methodologies by excluding harmful surfactants and solvents.