Materials Science Engineering Research Articles

IMPROVING THE ENERGY EFFICIENCY OF THERMOELECTRIC ENERGY CONVERTERS – REVIEW

The results of an analytical review of a large number of publications on the problem of improving the efficiency of thermoelectric generators (TEG) over the past decade are presented. An analysis of historical data on the thermodynamic justification of the efficiency of thermoelectric generators is presented. The following areas are analyzed: the problem of increasing the figure of merit Z through the creation of new material science technologies and new materials, the creation of multi-segment thermoelectric elements for a wide temperature range (300 ÷ 1200 K), the efficiency of heat supply to the TEG and cooling. The methods for calculating the thermodynamic efficiency of TEG are presented. It is shown that the efficiency of TEG is limited to ½ of the Carnot value for ZT values of 1-3. Modern materials allow the production of TEG with ZT values less than 1. However, the application of TEG has promising prospects with the increase in the intensity of heat supply and cooling processes. The main directions and trends (physical, chemical, technological) in the creation and improvement of TEG are identified. Some practical solutions presented in the literature, as well as the authors' solution for improving the thermodynamic efficiency of boiler units using TEG, are shown.

Optimization of Dynamic Characteristics of Rubber-Based SMA Composite Dampers Using Multi-Body Dynamics and Response Surface Methodology

The suspension system of a commercial vehicle cab plays a crucial role in enhancing ride comfort by mitigating vibrations. However, conventional rubber suspension systems have relatively fixed stiffness and damping properties, rendering them inflexible to load variations and resulting in suboptimal ride comfort under extreme road conditions. Shape memory alloys (SMAs) represent an innovative class of intelligent materials characterized by superelasticity, shape memory effects, and high damping properties. Recent advancements in materials science and engineering technology have focused on rubber-based SMA composite dampers due to their adjustable stiffness and damping through temperature or strain rate. This paper investigates how various structural parameters affect the stiffness and damping characteristics of sleeve-type rubber-based SMA composite vibration dampers. We developed a six-degree-of-freedom vibration differential equation and an Adams multi-body dynamics model for the rubber-based SMA suspension system in commercial vehicle cabins. We validated the model’s reliability through theoretical analysis and simulation comparisons. To achieve a 45% increase in stiffness and a 64.5% increase in damping, we optimized the suspension system’s z-axis stiffness and damping parameters under different operating conditions. This optimization aimed to minimize the z-axis vibration acceleration at the driver’s seat. We employed response surface methodology to design the composite shock absorber structure and then conducted a comparative analysis of the vibration reduction performance of the optimized front and rear suspension systems. This study provides significant theoretical foundations and practical guidelines for enhancing the performance of commercial vehicle cab suspension systems.

Engineering Solutions for Drug Delivery System

This paper examines the evolution of engineering solutions in drug delivery systems, emphasizing the role of nanotechnology in overcoming current challenges in precision medicine. It addresses key challenges in drug delivery, including targeting specificity, minimizing adverse effects, and enhancing the efficiency of drug carriers. Both top-down and bottom-up engineering approaches are examined, with case studies highlighting successful applications in cancer therapy, gene delivery, and implantable devices. The paper also investigates future trends, such as smart and active delivery systems, and discusses the interdisciplinary collaboration required for these advances. By integrating material science, bioengineering, and pharmaceutical technology, this research presents innovative solutions aimed at improving therapeutic efficacy and minimizing toxicity. Keywords: Drug delivery systems, Nanotechnology, Top-down engineering, Bottom-up engineering, Gene therapy, Smart drug delivery.

Preface

The 2nd International Symposium on Frontiers of Mechanical and Material Engineering (MME2024) is a globally recognized event to be organized by the Hubei Digital Textile Equipment Key Laboratory, China, in collaboration with the Wuhan Textile University, China, Zhongnan University, East-Siberian State University of Technology and Management, Russia, Rongzhi Sciences and Technology Center, China, was held from 21-22 September 2024 in Hangzhou, China. Since its inception in 2014, MME has successfully encompassed a wide spectrum of cuttingedge research domains, developed into a premier international event held in China and which gathered the best scientists and world class experts to share leading edge and multidisciplinary research in various fields related to mechanical engineering, materials science and modern technologies. MME serves as a prestigious international platform, this conference will continue to facilitate the dissemination of cutting-edge advancements across a spectrum of disciplines, converge students, experts, researchers, scholars, and industry professionals from different nations to share and deliberate on their latest work. This volume comprises select proceedings of 18 papers from 56 contributions submitted to MME2024. All the papers underwent a meticulous peer-review process, with each paper being evaluated by at least one expert in the relevant field. It introduces latest advancements in the subjects of mechanical engineering, materials science and advanced manufacturing technology, et al. It will be beneficial for readers from both academia and industry to understand and tackle the challenges in an efficient manner and to adopt appropriate solutions in the mentioned fields above. We would like to extend our heartfelt gratitude to invited keynote speakers: Dr. Valeriy Buryachenko, Micromechanics & Composites LLC, Cincinnati, Ohio, USA; Prof. David BASSIR, French University of Technology UTBM, France; Prof. Raul Duarte Salgueiral Gomes Campilho, Department of Mechanical Engineering, ISEP - School of Engineering, Portugal, and Dr. Ghulam Yasin, Oxford Brookes University, UK, for their brilliant speeches. Thanks to all the international reviewers and program committee members for their valuable contributions and dedication. List of Conference Chair, Conference Co-Chair, Honorary Chair, Editors and Technical Program Committees are available in this Pdf.

Electronic, thermodynamic, NLO, and spectroscopic properties of OAFLC compounds via DFT: A focus on 1F6B, 1F6Bi, 1F6BiN, and 1F6BN

This study presents a comprehensive quantum mechanical investigation of four novel liquid crystalline compounds: 1F6B, 1F6Bi, 1F6BiN, and 1F6BN. Using Density Functional Theory (DFT) with the B3LYP functional and 6-311G(d,p) basis set, we optimized the molecular geometries and analyzed their electronic and vibrational properties. Atomic Polar Tensor (APT) charge analysis showed significant charge distributions. Electrostatic potential (ESP) mapping identified potential reactive sites, while Electron Localization Function (ELF) and Localized Orbital Locator (LOL) analyses depicted the electron density distributions. Thermodynamic parameters indicated the compounds’ vibrational stability and responsiveness to thermal changes. Non-linear optical (NLO) properties were characterized by significant dipole moments and polarizabilities, suggesting potential in optoelectronic applications. Frontier molecular orbital analysis indicated stability with HOMO-LUMO gaps ranging from 4.15 to 4.64 eV. UV–Vis spectra revealed key electronic transitions, while Raman spectroscopy detailed various vibrational modes. The study offers valuable insights into the molecular behavior of these compounds, laying the groundwork for their future applications in material science and advanced technologies.

Computational study of micromagnetorotation on the micropolar flow characteristics in a rectangular channel with continuous applied shear

The aim of this investigation is to computationally analyse the effect of micromagnetorotation on flow characteristics within magneto-micropolar flows. To the authors' knowledge such consideration has not been discussed in the literature in present context. The assumption in literature that the magnetization is parallel to the applied magnetic field is incorrect due to the anisotropic nature of micropolar flows. This allows to re-investigate the micropolar flows in the present of micromagnetorotation. To this end, the theory of magneto-micropolar flows is briefly described and a computational model governing the system dynamics is presented. Finite element code in FreeFem++ is developed and validated through an exact solution. It turns out that the numerical findings obtained are in strong agreement with the analytical results. The results obtained are significant because they can assist researchers in allied fields of electronics, materials science and biomedical engineering in finding solutions to a variety of real-world issues.

Electrically Conductive Nanomaterials: Transformative Applications in Biomedical Engineering - A Review.

In recent years, significant advancements in nanotechnology have improved the various disciplines of scientific fields. Nanomaterials, like, carbon-based (carbon nanotubes, graphene), metallic, metal oxides, conductive polymers, and 2D materials (MXenes) exhibit exceptional electrical conductivity, mechanical strength, flexibility, thermal property and chemical stability. These materials hold significant capability in transforming material science and biomedical engineering by enabling the creation of more efficient, miniaturized, and versatile devices. The indulgence of nanotechnology with conductive materials in biological fields promises a transformative innovation across various industries, from bioelectronics to environmental regulations. The conductivity of nanomaterials with a suitable size and shape exhibits unique characteristics, which provides a platform for realization in bioelectronics as biosensors, tissue engineering, wound healing, and drug delivery systems. It can be explored for state-of-the-art cardiac, skeletal, nerve, and bone scaffold fabrication while highlighting their proof-of-concept in the development of biosensing probes and medical imaging. This review paper highlights the significance and application of the conductive nanomaterials associated with conductivity and their contribution towards a new perspective in improving the healthcare system globally.&#xD.

Damage index correlation in massive granite-porous backfills under hydromechanical triaxial cyclic loading using acoustic emissions and X-ray computed tomography

The characterization accuracy of damage indices in massive and porous composite biomaterials under complex osmotic conditions has long been a challenge in engineering materials science. Establishing correlations between damage indices calculated using different methodologies is crucial to validate and improve defects characterizations. In this study, we investigated the damage index correlation of cylindrical massive granite-porous backfill structural composites under both dry and seepage conditions. A series of triaxial cyclic loading and unloading tests were conducted on specimens under hydromechanical conditions with varying osmotic pressures (0, 1, 3, 5, 7, and 9 MPa) and a confining pressure of 9 MPa involving acoustic emission monitoring and phase-based 3D nondestructive CT scanning. The results revealed the AE energy was lower under osmotic conditions compared to dry conditions. The AE Damage Index (DAE), defined by separating tensile and shear microcracking signals, significantly increased from 0.32 to 0.55 with rising osmotic pressure. 3D mesoscopic fracture visualization provided detailed insights into the fractures in granite and backfill interfaces. The number of small-angle cracks increased with osmotic pressure, and the crack inclination distribution range expanded from 63°- 85° to 49°–80°. The average crack angle showed a significant monotonic decrease with increasing osmotic pressure. An Energy Dissipation Damage Index (DED) was defined, and its correlation with the DAE under dry conditions was modeled using a reciprocal function DED=a/(DAE+bσ3)+c. This novel approach offers insights into the transition points between tensile and shear-dominated failure stages. Furthermore, an exponential function DV=aDAEb(b<0) was used to model the correlation between AE Damage Index and Visual Damage Index (DV) under osmotic conditions. The damage indices derived from different methods can be mathematically correlated, providing a comprehensive evaluation of material damage states. The study found the flow transition between different natural-human medias results in different damage mechanisms, which are all obey the correlation law. These damage mechanisms offered constructive recommendations for engineering applications based on varying ratios of osmotic pressure to confining pressure.

TARGETED TREATMENT OF CHRONIC CYSTITIS USING INTRAVESICAL INSTILLATION OF AN ENCAPSULATED FORM OF HYALURONIC ACID

Introduction. A new approach in the bladder diseases treatment is an intravesical instillation of drugs. However, the low therapeutic effectiveness and painfulness of the instillation procedure are significant limitations of this method. Often, therapy for chronic cystitis comes down to repeated drug instillation into the bladder, which can lead to irritation of the urethral canal and re-infection. Purpose of the study – an approach to the treatment of chronic cystitis by a combination of the local delivery  intravesical instillation, and advanced materials science technologies  emulsion microgels. Materials and methods. Hyaluronic acid (HA) was encapsulated in emulsion microgels based on whey protein isolate. To study the therapeutic effect, experimental animals were divided into 3 groups (5 pieces each): without therapy; with encapsulated HA therapy; with therapy of HA solution. Chronic cystitis modeling was carried out by intraperitoneal administration of a cyclophosphamide solution. For groups of the animals receiving therapy, intravesical instillation of HA in encapsulated and free forms was carried out four times on days 6, 10, 14 and 18 after the initiation of cystitis. The therapy effectiveness was assessed using classical histological analysis. Results. This work demonstrates the effectiveness of chronic cystitis therapy with hyaluronic acid immobilized in mucoadhesive carriers – emulsion microgels. Histological analysis confirmed a significant topical therapeutic effect in animals with intravesical administration of microgels with hyaluronic acid. Conclusions. The proposed strategy combines local delivery and the use of microcontainers containing a drug, which can be successfully used for local therapy of a wide range of bladder diseases.

Swift heavy ions induced transformations in the structural and magnetic properties of Co/Pt multilayer thin films for magnetic storage applications

The integration of CoPt nanoparticles into an insulating matrix has garnered significant attention in material science, nanotechnology, and electronic engineering, particularly for their potential use in magnetic storage media. Precise control over the size, shape, and ordering of these nanoparticles is crucial. This study investigates the impact of swift heavy ion irradiation (120 MeV Ag+9) with varying ion fluences (1 × 1013 and 3 × 1013 ions/cm2) on the structural and magnetic properties of sputter-deposited Co/Pt multilayer thin films on quartz substrates. X-ray diffraction (XRD) analysis of the pristine samples reveals the presence of an FCC-structured CoPt alloy. In contrast, films irradiated with a fluence of 1 × 1013 ions/cm2 exhibit superlattice peaks (001) and (110), indicative of L10-structured CoPt alloy, whereas films subjected to 3 × 1013 ions/cm2 retain the FCC structure. This suggests that a fluence of 1 × 1013 ions/cm2 promotes ordering, while 3 × 1013 ions/cm2 induces disordering. Selected area electron diffraction (SAED) patterns from TEM confirm these structural transitions, while SQUID magnetometry reveals an increase in coercivity at 1 × 1013 ions/cm2, followed by a reduction at 3 × 1013 ions/cm2, consistent with the observed structural changes. These results demonstrate that carefully controlled ion fluences can effectively tailor the structural and magnetic properties of Co/Pt multilayers, enhancing their suitability for advanced magnetic storage applications.

Experimental burn models for evaluating wound healing agents and its current situation and existing disadvantages: a literature review

BACKGROUND: Burns remain a crucial part of the structure of injuries in Russia and abroad. Therefore, providing high-quality medical care to burn victims is relevant. Despite the large number of proposed solutions to this condition, developments in the field of tissue engineering and medical materials science still lack standardization and consideration of specific features of animal burn models for their testing. Many studies showed minor and major disadvantages from a technical and descriptive point of view. AIM: To analyze and identify the main disadvantages of existing burn models to assess the effect of wound healing agents. MATERIALS AND METHODS: This article examines the search results in the databases Google Scholar and PubMed using the keywords “burns,” “rats,” “animal model,” and “wound healing.” Sixty publications were analyzed. RESULTS: Seven quality criteria for the animal burn model have been determined, which allow obtaining reliable results and reproducing the described experiment: indication of the terms of quarantine and conditions of keeping laboratory animals, detailed description of the technique of applying burn injury, presence of one burn on a laboratory animal, presence of a control biopsy, indication of the absolute value of the initial burn area, presence of surgical treatment of burn wounds, and correct use of formulas for the planimetric assessment of wound healing. CONCLUSIONS: A solution to the problem of creating a standardized model may be a more detailed description of techniques and following the proposed quality criteria.

Preface

Materials and technologies are significant elements for all kinds of high-tech industries that pave the road for advancements in the manufacturing area. With the rapid development of computer technology, communications technology, and network technology, the traditional manufacturing process has evolved to intelligent manufacturing that is more technologically flexible and efficient. The Sixth International Conference on Materials Science and Manufacturing Technology 2024 (ICMSMT 2024) was a premier interdisciplinary platform for researchers, academicians, and practitioners worldwide to present recent developments in materials sciences and manufacturing technology. The fifth edition of the ICMSMT conference series (ICMSMT 2024) has been organized with partnered by Akshaya College of Engineering and Technology, Coimbatore, and Diligentec Solutions, Coimbatore, India. The conference received submissions from 08 countries, and the editorial board of ICMSMT has accepted the papers after the stringent screening and review process. ICMSMT is a scientific event and aimed to be conducted in the second week of April every year. ICMSMT 2024 was organized in an hybrid model with both online and physical participations. Each presenter was given ten minutes for the presentation and three minutes for queries and discussion. The online meetings have been conducted using the Google Meet platform. Dr. Ramya Muthusamy Editor / Chair – TPC ICMSMT 2024 List of Organizing Committee, Editorial Committee, Review Committee and Technical Program Committee are available in this pdf.

Artificial Intelligence in Materials Science and Modern Concrete Technologies: Analysis of Possibilities and Prospects

Artificial Intelligence in Materials Science and Modern Concrete Technologies: Analysis of Possibilities and Prospects

Research progress on key technologies of flexible wearable electronic devices

Flexible wearable device is an innovative technology product, using soft, lightweight material design, can fit the curve of the human body, providing a comfortable wearing experience. These devices typically integrate a variety of sensors, batteries, and connectivity technologies to enable biometric monitoring, motion tracking, communication, and other intelligent functions. Traditional electronic products tend to give a "stiff" impression that they cannot withstand bending, twisting and stretching. In recent years, under the background of the integration of electronic technology and modern material science technology, the emerging flexible electronic wearable device has become a research hotspot with its more flexible material, more sensitive and accurate signal transmission, and more extensive monitoring range. The development of flexible electronic technology has greatly improved the user's wearing experience and is more suitable for the free movement of the human body. This paper summarizes the basic principle and classification of key technologies of wearable electronic devices, and introduces the research progress and research trend.

Design of a Human Muscle-Powered Flying Machine

This study explores the design and development of a human-powered aircraft (HPA), leveraging modern engineering techniques, materials science, and advanced CAD/CAM tools. The project addresses key aspects of aircraft design, including the geometry of wings and tail, control and power transmission mechanisms, propeller selection, and material identification to achieve ultra-lightweight construction. The 3DExperience platform facilitated comprehensive model creation, simulation, and production process development, while XFLR5 was employed for aerodynamic profile analysis using the vortex lattice and panel methods. JavaProp aided in evaluating propeller thrust and power requirements. Computational fluid dynamics (CFD) simulations using the SST k-ω turbulence model provided critical insights into flow behavior. The design was found to be theoretically capable of flight, although challenges arose in selecting appropriate software for aerodynamic analysis, leading to the use of XFLR5 for early-stage design and the more advanced 3DExperience platform for final evaluations. Although structural strength analyses were not performed due to the complexity of composite materials, future work in this area could enhance the precision of component selection and aircraft mass estimation.

Influence of Graphene Nanoplatelets and Post-Curing Conditions on the Mechanical and Viscoelastic Properties of Stereolithography 3D-Printed Nanocomposites.

This study presents an innovative approach to improving the mechanical and viscoelastic properties of 3D-printed stereolithography (SLA) nanocomposites by incorporating graphene nanoplatelets (xGNP) into photopolymer matrices. Utilizing an SLA 3D printer, photopolymer formulations with xGNP concentrations of up to 0.25 wt% were successfully produced. Post-print curing was carried out using two different methods: ultraviolet (UV) curing and high-temperature curing at 160 °C. Mechanical characterization using nanoindentation showed a significant increase in elastic modulus by 104% and an increase in hardness by 85% for nanocomposites containing 0.25 wt% xGNP. Furthermore, dynamic mechanical analysis (DMA) revealed a 39% improvement in storage modulus for samples without post-curing and an improvement of approximately 30% for samples subjected to high-temperature curing. These significant improvements highlight xGNP's potential to not only increase the performance of SLA 3D-printed components but also streamline the manufacturing process by reducing or eliminating energy-intensive post-curing steps. This innovative integration of graphene nanoplatelets paves the way for the production of high-performance, functional 3D-printed products and offers significant advances for various industries with a high impact. The results highlight the transformative role of nanomaterials in additive manufacturing and position this work at the forefront of materials science and 3D printing technology.

DNA-Based Complexes and Composites: A Review of Fabrication Methods, Properties, and Applications.

Deoxyribonucleic acid (DNA), a macromolecule that stores genetic information in organisms, has recently been gradually developed into a building block for new materials due to its stable chemical structure and excellent biocompatibility. The efficient preparation and functional integration of various molecular complexes and composite materials based on nucleic acid skeletons have been successfully achieved. These versatile materials possess excellent physical and chemical properties inherent to certain inorganic or organic molecules but are endowed with specific physiological functions by nucleic acids, demonstrating unique advantages and potential applications in materials science, nanotechnology, and biomedical engineering in recent years. However, issues such as the production cost, biological stability, and potential immunogenicity of DNA have presented some unprecedented challenges to the application of these materials in the field. This review summarizes the cutting-edge manufacturing techniques and unique properties of DNA-based complexes and composites and discusses the trends, challenges, and opportunities for the future development of nucleic acid-based materials.

Perceptions of Women in Science Students towards Online Instruction at A Tertiary Institution

This study delved into the nuanced perceptions of women in science students regarding online instruction at the tertiary level. The study adopted a qualitative paradigm where interviews and questionnaires were used to collect data from Chinhoyi University of Technology undergraduate women in science students. Data was collected from first year students to third year students aged between 19 and 26 years. Discussion of the findings is premised on the feminist approach to enable downscaling and understanding of the perceptions of women in science education on online learning experiences more holistically. Regardless of the benefits and advantages online learning has as opposed to traditional/physical learning, vulnerability, and resistance of women in science students at Chinhoyi University of Technology in the Institute of Materials Science Processing and Engineering Technology is worsened. The study found out that the great difference in how the women in science students perceive their experiences is hinged upon the student’s background, the age gap, academic level, geographical location and even technology proficiency. A gap in knowledge persists in the exploration of the nuanced challenges faced by women in science when transitioning from traditional classroom instruction to online learning at the tertiary level was identified in the study resulting from the socio-economic challenges that the students are experiencing. Insights from this study contribute to a deeper understanding of how women in science navigate online education, offering valuable considerations for educators, policymakers, and institutions striving to create inclusive and effective learning environments.

Recent Toolboxes for Chemoselective Dual Modifications of Proteins.

Site-selective chemical modifications of proteins have emerged as a potent technology in chemical biology, materials science, and medicine, facilitating precise manipulation of proteins with tailored functionalities for basic biology research and developing innovative therapeutics. Compared to traditional recombinant expression methods, one of the prominent advantages of chemical protein modification lies in its capacity to decorate proteins with a wide range of functional moieties, including non-genetically encoded ones, enabling the generation of novel protein conjugates with enhanced or previously unexplored properties. Among these, approaches for dual or multiple modifications of proteins are increasingly garnering attention, as it has been found that single modification of proteins is inadequate to meet current demands. Therefore, in light of the rapid developments in this field, this review provides a timely and comprehensive overview of the latest advancements in chemical and biological approaches for dual functionalization of proteins. It further discusses their advantages, limitations, and potential future directions in this relatively nascent area.

Self-Aligned Ionic Doping of TiO2 Thin-Film Transistors for Enhanced Current Drivability via Postfabrication Superacid Treatment.

Oxide semiconductor thin-film transistors (TFTs) have shown great potential in emerging applications such as flexible displays, radio-frequency identification tags, sensors, and back-end-of-line compatible transistors for monolithic 3D integration beyond their well-established flat-plane display technology. To meet the requirements of these appealing applications, high current drivability is essential, necessitating exploration in materials science and device engineering. In this work, we report for the first time on a simple solution-based superacid (SA) treatment to enhance the current drivability of top-gate TiO2 TFTs with a gate-offset structure. The on-current of these transistors is limited by the relatively low mobility of TiO2 due to its d-orbital conduction nature. It is found that the on-current of TiO2 TFTs is nearly doubled via a quick dip in a SA solution at room temperature in ambient air. A series of experiments, including comparative I-V measurements of TFTs with different treatments and gate structures, C-V measurements, X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry, and device simulation, were performed to uncover the underlying reason for the current enhancement. It is believed that the protons (H+) from SA are doped into the offset region of TiO2 TFTs, forming an electron double layer and thus boosting the on-current, with the top gate serving as a self-aligned mask for ionic doping. Furthermore, the ionic size and the proportion of the offset region to the channel play crucial roles in the effectiveness of ionic doping, while the position of the incorporated ions, whether in the channel or dielectric, may result in distinct shifts in the turn-on voltage (VON) and affect the functionality of ionic doping. This study provides a pathway for enhancing the current drivability of TiO2 TFTs via selective ionic doping enabled by SA treatment and deepens our understanding of ion incorporation in electronic devices. This approach could be applicable to other material systems and may also benefit TFTs with miniaturized dimensions, thus opening up unprecedented opportunities for TiO2 TFTs in future applications requiring high current drivability.