Matching Properties Research Articles

Achieving Short-Wavelength Phase-Matching Second Harmonic Generation in Boron-Rich Borosulfate with Planar [BO3 ] Units.

Ultraviolet (UV) nonlinear optical (NLO) crystals which can produce short-wavelength lasers via a direct second harmonic generation (SHG) process are of great importance in modern laser technology. Currently, the exploration of UV NLO crystals in borosulfates is nearly stagnant since the non-phase matching (PM) property lies on the small birefringence induced by the intrinsically small optical anisotropy of the tetrahedral groups. Herein, for the first time, the planar [BO3 ] units were introduced into borosulfates leading to a boron-rich borosulfate (NH4 )2 B4 SO10 with unprecedented [B4 SO10 ]∞ layers and evidently enhanced birefringence. To the best of our knowledge, it achieves the shortest SHG PM wavelength of 252 nm in all reported borosulfates with deep UV cutoff edge (184 nm), large SHG response (1.1×KDP at 1064 nm and 0.15×β-BBO at 532 nm) and large birefringence (0.053 at 1064 nm) and is easy to grow single crystals via simple chemical vapor deposition method. These results confirm the feasibility of utilizing planar [BO3 ] units to optimize birefringence of borosulfates, and also open up broad prospects for UV NLO crystals in boron-rich borosulfates.

Structural, Electromagnetic and Microwave Properties of Magnetite Extracted from Mill Scale Waste via Conventional Ball Milling and Mechanical Alloying Techniques.

This study presents the utilization of mill scale waste, which has attracted much attention due to its high content of magnetite (Fe3O4). This work focuses on the extraction of Fe3O4 from mill scale waste via magnetic separation, and ball milling was used to fabricate a microwave absorber. The extracted magnetic powder was ground-milled using two different techniques: (i) a conventional milling technique (CM) and (ii) mechanical alloying (MM) process. The Fe3O4/CM samples were prepared by a conventional milling process using steel pot ball milling, while the Fe3O4/MM samples were prepared using a high-energy ball milling (HEBM) method. The effect of milling time on the structural, phase composition, and electromagnetic properties were examined using X-ray diffraction (XRD) and a vector network analyzer (VNA). XRD confirmed the formation of magnetite after both the magnetic separation and milling processes. The results revealed that Fe3O4 exhibited excellent microwave absorption properties because of the synergistic characteristics of its dielectric and magnetic loss. The results showed that the Fe3O4/CM particle powder had a greater absorption power (reflection loss: <−10 dB) with 99.9% absorption, a minimum reflection loss of −30.83 dB, and an effective bandwidth of 2.30 GHz for 2 mm thick samples. The results revealed the Fe3O4/MM powders had higher absorption properties, including a higher RL of −20.59 dB and a broader bandwidth of 2.43 GHz at a matching thickness of only 1 mm. The higher microwave absorption performance was attributed to the better impedance matching property caused by the porous microstructure. Furthermore, the magnetite, Fe3O4 showed superior microwave absorption characteristics because of the lower value of permittivity, which resulted in better impedance matching. This study presents a low-cost approach method by reutilizing mill scale waste to fabricate a high purity crystalline Fe3O4 with the best potential for designing magnetic nano-sized based microwave absorbers.

Fabrication of a multi-layered decellularized amniotic membranes as tissue engineering constructs

As a promising approach in tissue engineering, decellularization has become one of the mostly-studied research areas in tissue engineering thanks to its potential to bring about several advantages over synthetic materials since it can provide a 3-dimensional ECM structure with matching biomechanical properties of the target tissue. Amniotic membranes are the tissues that nurture the embryos during labor. Similarly, these materials have also been proposed for tissue regeneration in several applications. The main drawback in using amniotic membranes is the limited thickness of these materials since most tissues require a 3D matrix for an enhance regeneration. In order to prevent this limitation, here we report a facile fabrication methodology for multilayered amniotic membrane-based tissue constructs. The amniotic membranes of Wistar albino rats were first decellularized with the physical and chemical methods and utilized as scaffolds. Secondly, the prepared decellularized membranes were sutured to form a multilayered 3D structure. Within the study, 7 groups including control (PBS), were prepared based on physical and chemical decellularization methods. UV exposure and freezing techniques were used as a physical decellularization methods while hypertonic medium and SDS (sodium dodecyl sulfate) protocols were used as chemical decellularization methods. The combinations of both protocols were also used. In groups, A was the control and group B was applied just UV. In group C was applied UV and freezing. In addition to UV and freezing, in group D was applied hypertonic solution while group E was applied SDS (0.03 %). In group F was applied UV, freezing, hypertonic solution and SDS (0.03 %). In group G was applied UV, hypertonic solution, SDS (0.03 %) and freezing, respectively. Based on the histological and quantitative analyses, F and G groups were found as the most efficient decellularization protocols in rat amniotic membranes. Then, group F and G decellularized amniotic membranes were used to form scaffolds and thus-formed matrices were further characterized in vitro cell culture studies and mechanical tests. Cytotoxicity analyses performed using MTT showed a good cell viability in F and G groups scaffolds. The percentage viability rate was higher in G group (81.3 %) compared to F (75.33 %) and also cell viability in G group was found more meaningful according to p value which was obtained 0.007. Cellular adhesions after in vitro cell culture and morphology of scaffolds were evaluated by scanning electron microscopy (SEM). It was observed that the cells cultivated in equal amounts of tissue scaffolds were higher in the F compared to that observed in group G. The mechanical testing with 40 N force revealed 0.77 mm displacement in group F while it was 0.75 mm in group G. Moreover, according to force-controlled test, 2.9 mm displacement of F group and 1.2 mm displacement of G group was measured. As a result, this study shows that the multilayered decellularized amniotic membrane scaffolds support cell survival and adhesion and can form a flexible biomaterial with desired handling properties.

A fabric reinforced small diameter tubular graft for rabbits’ carotid artery defect

Tissue engineering small diameter artificial blood vessel is an indispensable graft for repairing extremity arterial injury. Previous researches demonstrated that suitable porosity and matching mechanical properties are two keys for tubular tissue reconstruction. In this study, we fabricated a fabric reinforced small diameter tubular graft (PPTG) from PLGA fabric and three-dimensional porous PEEUU with a structure of the bionic extracellular matrix for transplanting in situ combined braiding and thermally induced phase separation (TIPS). The prepared PPTG presented smooth and dense inner surface, fluffy and porous grafts wall, and tubular PLGA fabric evenly dispersed PEEUU matrix, which provide mechanical support for PPTG. The mechanical tests and hemolysis results showed that PPTG possess matched mechanical properties with autologous blood vessels and stable blood compatibility. Six weeks after rabbits’ carotid artery defect replacement indicated that there were no blockage occurred for PPTG group. Histological staining exhibited positive expression of endothelial cells on the inner surface of PPTG and distinct smooth muscle in the wall of PPTG, which migrated from peripheral tissues and flowing blood. Therefore, this fabric reinforced small diameter tubular graft provides a solution for endothelialization and tissue regeneration and have a potential application in vascular trauma. A fabric reinforced small diameter tubular graft from PLGA fabric and three-dimensional porous PEEUU with a structure of the bionic extracellular matrix exhibited matched mechanical properties, especially they demonstrate excellent performance to induce the migration of host cells to the wall of tubular graft and effective anti-thrombosis properties in rabbit carotid artery defect.

Dynamic response of a traditional hımış mansion using updated FE model with operational modal testing

Since ancient times, shelter has been one of the most basic needs of human beings. This basic need has been tried to be met by using different local materials considering both economic conditions and security understanding. The so-called “Hımış” houses formed by filling the gaps between the timber frames with masonry elements reflect the typical features of the Ottoman city structure. Despite being exposed to many earthquakes and environmental factors, these types of structures have gained the trust of man. The finite element model of composite and complex structures such as hımış systems requires the macro modeling method. However, it is an important issue in itself to transfer the material properties of exist composite structure to macro modeling by obtaining a conjugate value. Especially when material tests are not possible, matching material properties should be selected for macro modeling, and these values should really reflect the current state of the structure. This study focuses on examining the dynamic response of a traditional Hımış mansion in Fındıklı district of Rize city of Turkey using updated finite element model based on the operational modal analysis test results. Conjugate material values are obtained by macro and micro modeling, and the macro model is updated to create the final model representing the existing structure. Dynamic response of the traditional Hımış mansion is determined using updated finite element model. Displacements, principal stresses and principal strains are presented as contour diagrams and time dependent changes of maximum values. As a result of the analysis, it has been observed that the traditional Hımış structure has an effective structural performance under dynamic earthquake excitation. • Non-destructive experimental measurement results are presented. • FE model is constituted to extract the initial dynamic characteristics. • Modal updating procedure is conducted to minimize the differences. • Conjugate material values are obtained by macro modeling. • Dynamic response of the Hımış mansion is determined using updated FE model.

Optimization of Fe@Ag core–shell nanowires with improved impedance matching and microwave absorption properties

Ag-coated Fe (Fe@Ag) core–shell nanowires (NWs) with enhanced electromagnetic wave absorption were successfully synthesized by the liquid-phase reduction method and the layer-plus-island growth mode. Changing the molar ratio of Fe to Ag controlled the Ag shell thickness to produce different impedance matching and attenuation constants of the Fe@Ag core–shell NWs. The Fe@Ag core–shell NWs with a Fe:Ag ratio of 2:1 significantly improved optimal microwave absorption performance as compared to raw Fe NWs. At a mass fraction of 25%, the minimum reflection loss (RLmin) can reach − 58.69 dB at 7.53 GHz with a matching absorber thickness of 3.36 mm. In addition, the effective absorption bandwidth (EAB, RL ≤ − 10 dB) can be extended to 7.32 GHz, to cover the majority of the C and X bands. Three major aspects contribute to the superior microwave absorption performance: the complementary effect of the polarization of Fe-Ag interface, the impedance matching improvement stems from a proper eddy current, and the small-scale effect caused by a one-dimensional structure. This study demonstrates the promising high-efficiency microwave absorbing capabilities of Fe@Ag core–shell NWs for future use in practical applications.

Wideband strip antenna surrounding a ground plate

A wideband planar antenna, which is composed of a ground plate and a strip surrounding the plate, is proposed. Wideband impedance matching with fractional bandwidth over 130% is achieved by making the distance between the strip and the ground plate stepwise so that the distance becomes wider in the tip side. The electric field in the slot line changes its direction without changing the traveling direction at the stepped section, and it is enabled to leak and radiate while traveling. It was also found that the matching frequency band can be greatly extended to the high frequency side by bending and extending the slot line to surround the ground plate. The lowest impedance matching frequency can be controlled by the strip width at the tip with keeping wideband impedance matching property.

A hollow CuS@Mn(OH)2 particle with double-shell structure for Ultra-wide band electromagnetic absorption

Hollow materials have many advantages when acting as electromagnetic wave (EMW) absorber, such as excellent impedance matching properties, rich micro-interfaces and light weight. In this work, a novel hollow particle with double-shell composed with CuS and Mn(OH)2 is synthesized by coordination etching, precipitation and sulfuration using tetrakaidecahedral Cu2O as template. These hollow particles are expected to be used as improved EMW absorption property at an ultra-wide band. In this hollow particle, tetrakaidecaheral CuS acts as inner shell and Mn(OH)2 acted as outer shell, thus having rich heterogeneous interfaces which induce strong interfacial polarization. Moreover, the lower electrical conductivity and loose structure of the Mn(OH)2 shell facilitates the entry of EMW into the absorbers, and the hollow structure in this particle is beneficial to improve the impedance matching according to Maxwell-Garnett (MG) theory. Therefore, hollow CuS@Mn(OH)2 particles with double-shell exhibit excellent EMW absorption performance. The effective absorption bandwidth (reflection loss (RL) ≤ −10 dB) is 6.88 GHz (from 11.12 GHz to 18 GHz) at 2.3 mm thickness of sample.

The effect of scene articulation on transparent layer constancy.

In this article, we examine the influence of scene articulation on transparent layer constancy. We argue that the term articulation may be understood as an aspect of the more general concept naturalness of a stimulus that relates to the degree of enrichment compared with a minimal stimulus and to the extent to which a stimulus contains regularities that are typically found in natural scenes. We conducted two matching experiments, in which we used strongly reduced scenes and operationalized articulation by the number of background reflectances (numerosity). The results of the first experiment show that higher numerosity actually leads to an increase in transparent layer constancy when reflectances are randomly drawn from a fixed population. However, this advantage disappears if the spatial mean and the variation of the subset colors are controlled as in our second experiment. Furthermore, our results suggest that the mechanism underlying transparent layer constancy leads to a rather stable compromise between two matching criteria, namely, proximal identity and constant filter properties according to our perceptual model. For filters with an additive component, which appear more or less hazy, we observed improved recovered filter properties and correspondingly higher degrees of transparent layer constancy, suggesting an additional mechanism in this type of filter.

Development of MRI-based axillary numerical models and estimation of axillary lymph node dielectric properties for microwave imaging.

Microwave imaging (MWI) has been studied as a complementary imaging modality to improve sensitivity and specificity of diagnosis of axillary lymph nodes (ALNs), which can be metastasized by breast cancer. The feasibility of such a system is based on the dielectric contrast between healthy and metastasized ALNs. However, reliable information such as anatomically realistic numerical models and matching dielectric properties of the axillary region and ALNs, which are crucial to develop MWI systems, are still limited in the literature. The purpose of this work is to develop a methodology to infer dielectric properties of structures from magnetic resonance imaging (MRI), in particular, ALNs. We further use this methodology, which is tailored for structures farther away from MR coils, to create MRI-based numerical models of the axillary region and share them with the scientific community, through an open-access repository. We use a dataset of breast MRI scans of 40 patients, 15 of them with metastasized ALNs. We apply image processing techniques to minimize the artifacts in MR images and segment the tissues of interest. The background, lung cavity, and skin are segmented using thresholding techniques and the remaining tissues are segmented using a K-means clustering algorithm. The ALNs are segmented combining the clustering results of two MRI sequences. The performance of this methodology was evaluated using qualitative criteria. We then apply a piecewise linear interpolation between voxel signal intensities and known dielectric properties, which allow us to create dielectric property maps within an MRI and consequently infer ALN properties. Finally, we compare healthy and metastasized ALN dielectric properties within and between patients, and we create an open-access repository of numerical axillary region numerical models which can be used for electromagnetic simulations. The proposed methodology allowed creating anatomically realistic models of the axillary region, segmenting 80 ALNs and analyzing the corresponding dielectric properties. The estimated relative permittivity of those ALNs ranged from 16.6 to 49.3 at 5GHz. We observe there is a high variability of dielectric properties of ALNs, which can be mainly related to the ALN size and, consequently, its composition. We verified an average dielectric contrast of 29% between healthy and metastasized ALNs. Our repository comprises 10 numerical models of the axillary region, from five patients, with variable number of metastasized ALNs and body mass index. The observed contrast between healthy and metastasized ALNs is a good indicator for the feasibility of a MWI system aiming to diagnose ALNs. This paper presents new contributions regarding anatomical modeling and dielectric properties' characterization, in particular for axillary region applications.

Design and fabrication of compact triangular multiband microstrip patch antenna for C‐ and X‐band applications

SummaryModern portable communication devices require a compact antenna with superior performance and lower weight and size. The design and development of such a compact size antenna are a significant challenge for researchers. This proposed work compact slot‐based triangular patch antenna to work at the multiple resonance frequencies from 5 to 10 GHz using FR4 substrate is presented. The proposed antenna is simulated using High‐Frequency Structural Simulator (HFSS 2020R1). Simulated and fabricated antenna test results show that the proposed antenna can be suitably employed for the portable wireless transceivers in C and X bands. It has been inferred from the fabricated and measured results that the proposed slot‐based triangular patch antenna achieves the peak gain of 8 dBi and has excellent impedance matching properties such that return loss S11 is less than −10 dB and VSWR value is significantly closer to 1 at all the resonance frequencies.

Heating-activated radicals of fluorinated multiwalled carbon nanotubes assisted interfacial grafting rubber composites with electromagnetic wave absorption

Limited mechanical strength of rubbers due to poor interfacial bonding strength with fillers is a main factor to restrict further applications. In this article, chemical activity of dormant radicals on fluorinated carbon nanotubes (FCNTs) were proved to have temperature dependence, which was utilized to graft with natural rubbers during heat-vulcanization with well-combined interfaces. We adopted isoprene annealing with different FCNTs, High-Resolution Transmission Electron Microscopy (HR-TEM) images calculated different grafting thickness revealed the initiation abilities of FCNTs are highly related to their fluorine contents. Compared with neat natural rubber, tensile strength of FCNTs reinforced rubber composites improved by 105.1% at most, while the tensile strength of pristine carbon nanotubes reinforced rubber composites was increased by only 22.2%. Besides, according to the highly improved impedance matching property and remained conduction loss of FCNTs, the composite showed excellent microwave absorption properties that displays a minimum reflection loss (RL) of −64.31 dB in X band.

On the Effects of Balun on Small Antennas Performance for Animal Health- Monitoring and Tracking

This paper presents the performance evaluation of a sleeve Balun integration in the design of a flexible loop antenna for wildlife health monitoring and tracking applications. To verify the design concept, an experimental antenna is designed, fabricated, and measured in free-space and muscle mimicking phantom. Moreover, investigations are carried out for wearable and implanted antennas in planar and conformal arrangements. In free-space, the antenna is operating within the industrial, scientific, and medical ISM 5.8 GHz band. Balun integration in the antenna design efficiently chokes the currents excited on the outer surface of the feeding cable and provides a good impedance match between antenna and feed line, as demonstrated by simulation and measurement results. On the other hand, in phantom, the antenna has a wide bandwidth characteristic that covers the most used frequency bands for in-body devices. Balun integration, in this case, showed a negligible effect on antenna’s matching properties for two studied implantation depths; 2.5 cm and 5 cm. The proposed study offers a promising guideline in the design and realization of wearable and implanted antennas.

Architected fibrous scaffolds for engineering anisotropic tissues

Mimicking the native three-dimensional microenvironment is of crucial importance when biofabricating a new healthcare material. One aspect of the native tissue that is often omitted when designing a suitable scaffold is its anisotropy. Not only is matching native mechanical properties important when designing implantable scaffolds or healthcare materials, but matching physiological structure is also important as many cell populations respond differently to fiber orientation. Therefore, novel aligned electrospun scaffolds with varying fiber angles and spacing of bundles were created and mechanically characterized. Through controlling the angle between the fibers in each layer of the scaffold, a range of different physiological anisotropic mechanical properties were achieved that encompasses values found in native tissues. Extrapolation of this mechanical data allowed for any native tissue’s anisotropic Young’s modulus to be mimicked by electrospinning fibers at a particular angle. These electrospun scaffolds were then incorporated with cell-laden hydrogels to create hybrid structures that contain the benefits of both scaffolding techniques with the ability to encapsulate cells in the hydrogel. To conclude, this study develops a novel bundled fiber scaffold that was architected to yield anisotropic properties matching native tissues.

Orthogonal-array dynamic molecular sieving of propylene/propane mixtures.

Rigid molecular sieving materials work well for small molecules with the complete exclusion of large ones1-3, and molecules with matching physiochemical properties may be separated using dynamic molecular sieving materials4-6. Metal-organic frameworks (MOFs)7-9 are known for their precise control of structures and functions on a molecular level10-15. However, the rational design of local flexibility in the MOF framework for dynamic molecular sieving remains difficult and challenging. Here we report a MOF material (JNU-3a) featuring one-dimension channels with embedded molecular pockets opening to propylene (C3H6) and propane (C3H8) at substantially different pressures. The dynamic nature of the pockets is revealed by single-crystal-to-single-crystal transformation upon exposure of JNU-3a to an atmosphere of C3H6 or C3H8. Breakthrough experiments demonstrate that JNU-3a can realize high-purity C3H6 (≥99.5%) in a single adsorption-desorption cycle from an equimolar C3H6/C3H8 mixture over a broad range of flow rates, with a maximum C3H6 productivity of 53.5litresper kilogram. The underlying separation mechanism-orthogonal-array dynamic molecular sieving-enables both large separation capacity and fast adsorption-desorption kinetics. This work presents a next-generation sieving material design that has potential for applications in adsorptive separation.

Porous magnetic carbon CoFe alloys@ZnO@C composites based on Zn/Co-based bimetallic MOF with efficient electromagnetic wave absorption

To obtain lightweight and efficient electromagnetic wave absorbing materials, Fe2O3@ZnCo-MOF composites were prepared in this paper by in-situ growth method, and CoFe alloys@ZnO@C composites were obtained by subsequent annealing process. By varying the loading of Fe2O3 during the synthesis process, a series of composites were obtained. Among them, CoFe alloys@ZnO@C-0.1 has the best electromagnetic wave absorption performance, which can reach a reflection loss (RL) of −40.63 dB at a thickness of 2.2 mm, while the reflection loss is −44.13 dB at a thickness of 5.0 mm, and the maximum effective absorption bandwidth (EAB) is 5.84 GHz at a thickness of 2.4 mm. The excellent performance can be attributed to the synergistic effect of the dielectric and magnetic properties of the composites as well as the effective impedance matching properties. Thus, the CoFe alloys@ZnO@C composite is expected to be a lightweight and efficient material for electromagnetic wave absorption.

Manganese-catalyzed chlorosulfonylation of terminal alkene and alkyne via convergent paired electrolysis

Convergent paired electrolysis is an energy-efficient model in organic synthesis, although the main obstacle with its use is matching properties of the intermediates generated in two electrodes. With the development of anodic-coupled electrosynthesis in three-component difunctionalization of alkene, a proposal for two-component difunctionalization of alkene and alkyne using a difunctional reagent has been raised. Herein, we develop a manganese-catalyzed, atom-transfer radical addition of the terminal aryl alkenes and alkynes with sulfonyl chlorides, in which manganese salt has the role of a chlorine atom-transfer catalyst as well as a redox mediator. This method generates analogs of chlorosulfonylated products of high regio- and stereoselectivity, which are derivatives of pharmaceutical drugs and natural products. Manganese-catalyzed electrochemical process Convergent paired electrolysis Chlorosulfonylation of alkene and alkyne Atom-transfer radical addition reaction Convergent paired electrolysis is an atom-economical and energy-efficient model in organic synthesis. Atom-transfer radical addition (ATRA) reaction is a general and facile protocol to realize α, β-functionalization of alkene and alkyne. Here, Lei et al. develop a manganese-catalyzed chlorosulfonylation of terminal alkene/yne via convergent paired electrolysis through ATRA.

Elasticity Approach to Predict Shape Transformation of Functionally Graded Mechanical Metamaterial under Tension

The re-entrant structures are among the simple unit cell designs that have been widely used in the design of mechanical metamaterials. Changing the geometrical parameters of these unit cell structures, their overall elastic properties (i.e., elastic stiffness and Poisson’s ratio), can be simultaneously tuned. Therefore, different design strategies (e.g., functional gradient) can be implemented to design advanced engineering materials with unusual properties. Here, using the theory of elasticity and finite element modeling, we propose a fast and direct approach to effectively design the microarchitectures of mechanical metamaterials with re-entrant structures that allow predicting complex deformation shapes under uniaxial tensile loading. We also analyze the efficiency of this method by back calculating the microarchitectural designs of mechanical metamaterials to predict the complex 1-D external contour of objects (e.g., vase and foot). The proposed approach has several applications in creating programmable mechanical metamaterials with shape matching properties for exoskeletal and soft robotic devices.

Tunable Human Myocardium Derived Decellularized Extracellular Matrix for 3D Bioprinting and Cardiac Tissue Engineering.

The generation of 3D tissue constructs with multiple cell types and matching mechanical properties remains a challenge in cardiac tissue engineering. Recently, 3D bioprinting has become a powerful tool to achieve these goals. Decellularized extracellular matrix (dECM) is a common scaffold material due to providing a native biochemical environment. Unfortunately, dECM’s low mechanical stability prevents usage for bioprinting applications alone. In this study, we developed bioinks composed of decellularized human heart ECM (dhECM) with either gelatin methacryloyl (GelMA) or GelMA-methacrylated hyaluronic acid (MeHA) hydrogels dual crosslinked with UV light and microbial transglutaminase (mTGase). We characterized the bioinks’ mechanical, rheological, swelling, printability, and biocompatibility properties. Composite GelMA–MeHA–dhECM (GME) hydrogels demonstrated improved mechanical properties by an order of magnitude compared to the GelMA–dhECM (GE) hydrogels. All hydrogels were extrudable and compatible with human induced pluripotent stem cell derived cardiomyocytes (iCMs) and human cardiac fibroblasts (hCFs). Tissue-like beating of the printed constructs with striated sarcomeric alpha-actinin and connexin 43 expression was observed. The order of magnitude difference between the elastic modulus of these hydrogel composites offers applications in in vitro modeling of the myocardial infarct boundary. Here, as a proof of concept, we created an infarct boundary region with control over the mechanical properties along with the cellular and macromolecular content through printing iCMs with GE bioink and hCFs with GME bioink.

A Novel Approach to Obtain Diurnal Variation of Bio-Optical Properties in Moving Water Parcel Using Integrated Drifting Buoy and GOCI Data: A Case Study in Yellow and East China Seas

Ocean processes that can influence rapidly changing ocean color include water-mass movement and bio-optical property changes in the water parcel. Traditionally, diurnal variability of bio-optical properties relies on daily time series at fixed locations by satellite sensors or in situ observations. There is a lack of an effective way to observe diurnal variation of bio-optical properties in a moving water parcel on a large scale. In this paper, we propose a new method to acquire diurnal variation of bio-optical properties in a moving water parcel. The novel approach integrates drifting buoy data and GOCI data. The movement of surface current was tracked by a drifting buoy, and its spatiotemporally matching bio-optical properties were obtained via the GOCI data. The results in the Yellow and East China seas during the summers of 2012 and 2013 show that the variation of time series following the movement of water parcel was obviously different from that obtained at fixed locations. The hourly differences of the former are 15.7% and 16.3% smaller than those of the latter for Chl a and total suspended sediment (TSS), respectively. The value of ag440 was more stable within the moving water parcel than in the fixed location. Our approach provides a simple and feasible way for observing diurnal variability of bio-optical properties in a moving surface water parcel.