A new method for evaluating the geometrical accuracy of a 5-axis Machining Center (MC) based on the measurement results of the machined workpiece has been developed. The strategy behind our method is to utilize, because of its accuracy, a Coordinates Measuring Machine (CMM) as a master gauge. Thus, the machine operator machines the workpiece and a technologist of precise measurement takes the measurements. In our study, non-rotational machining is utilized to copy and trace the machine trajectory on the workpiece, minimizing the machining error. The profiles of the machined workpiece are measured and evaluated by a CMM, and the geometric errors of the machining center are extracted. Themeasurement results are sufficiently accurate compared to those taken using the square master gauge calibrated by CMM previously. In this report, the machining setup, including workpiece design, tool design, and cutting conditions, is proposed, and the experimental procedures and results of the evaluation are given.