Massive Mineralization Research Articles

Spatial distribution and factors influencing the accumulation of toxic metals in soils in mountain agroecosystems, Rio De Janeiro, Brazil.

The concentrations of toxic metals (TM) were analyzed in 498 samples of agricultural soils used for intensive vegetable cultivation in the watershed of Barracão dos Mendes, Brazil. The goal of this study was to characterize the distribution of these elements and the main natural and anthropogenic factors affecting their accumulation. In general, the average concentrations of TM were higher than the reference quality values for cultivated soils in the region, with the exception of Cr, Co, Ni and Mn, and the average concentration of Cd was ten times greater. Three sources of variation in the distribution of TM concentrations were identified: one related to topographic relief, another related to lithology, and one related to the massive use of agrochemicals. These factors contributed to TM accumulation in the soil; moreover, the transport of toxic metal-enriched clay by runoff resulted in higher concentrations of these elements in the lower parts of the slope. The long-term application of massive amounts of fertilizers and pesticides resulted in the accumulation of Cr, Cu, Zn, Ni, Pb and Cd in the vegetable cultivation soils and promoted the enrichment of macronutrients, mainly P and K. Moreover, the spatial distribution of TM in the agricultural soils of this mountain agroecosystem was affected by intensive vegetable cultivation, which altered the natural TM distribution dynamics determined by variations in topographic relief and lithology. In intensive cultivation areas, the TM distribution was also influenced by soil management practices such as tillage along the slope direction and massive mineral and organic fertilization.

Re–Os isotopes and geochemistry of pyrite from the Dongguashan Cu(-Au) deposit, Eastern China: Implications for porphyry-skarn-stratabound mineralization systems

Stratabound deposits are widely distributed along the Middle-Lower Yangtze River metallogenic belt (Eastern China). The stratabound mineralization system in these stratabound deposits remains enigmatic as to whether it is associated with late Mesozoic intrusions or late Carboniferous sedimentary exhalative processes. Dongguashan is a typical stratabound deposit and is characterized by pyrite that formed in porphyry-skarn-stratabound orebodies, which makes it ideal for comparing porphyry, skarn, and stratabound mineralization systems by pyrite study. We classify pyrite types according to occurrence and generation. Specifically, the pyrite in the porphyry orebodies is composed of Py-p1 (potassic zone) and Py-p2 (propylitic and phyllic zone). Py-s, among garnet grains, occurs in the skarn orebodies. From top to bottom, the pyrite in the stratabound orebodies is composed of macrocrystalline pyrite (Py-m) in the massive mineralization zone, Py-l in the laminated mineralization zone, and coarse-grained pyrite (Py-v1) and microcrystalline pyrite (Py-v2) in the vein-like mineralization zone. Co, Ni, Se, As, and Au are most likely to occur as solid solutions in the Dongguashan pyrite. Pb and Bi are likely distributed in Dongguashan pyrite homogeneously as nanoinclusions. The Zn, Cu, and Mo in Dongguashan pyrite indicate that these elements occur as micromineral inclusions. The positive correlation between S and Fe, high Co/Ni ratios (mostly > 2), and coexistence with hydrothermal minerals imply a magmatic-hydrothermal origin for the Dongguashan pyrite. Py-m yields a Re–Os isochron age of 135.8 ± 2.8 Ma (MSWD = 1.8), which is interpreted as the stratabound ore-forming age. Combined with previous results, the porphyry-skarn-stratabound mineralization is the product of the same hydrothermal fluid system related to Early Cretaceous magmatic activity.

Multistage ore formation in the world’s largest REE-Nb-Fe deposit of Bayan Obo, North China Craton: New insights and implications

The Bayan Obo deposit in the northern margin of the North China Craton is a world-class REE-Nb-Fe deposit, the complex mineralization history of which remains unresolved. In this study, we employ SEM and Image J software combined with mineralogical data obtained by in-situ EDS and EPMA analyses to analyze petrographic images rapidly and to investigate the mineralogical assemblages of each type of rocks/ores from the Main Orebody in an attempt to understand the mineralization process and ore-formation mechanism of this deposit. We identify three metallogenic periods and six ore-forming stages based on the field occurrence of ores combined with published geochronological data. The Mesoproterozoic magmatic event comprises two stages, which were distinguished as the coarse-grained dolomite stage (stage 1) and the fine-grained dolomite stage (stage 2). Three stages were recognized in the Mesoproterozoic shear deformation-hydrothermal mineralization period, including the disseminated mineralization stage (stage 3), the banded mineralization stage (stage 4) and the massive mineralization stage (stage 5). The Paleozoic hydrothermal period involved the vein mineralization stage (stage 6). Based on detailed studies of the mineral assemblages and paragenesis, as well as the complex textures of the ores, we propose a model of the multi-stage metallogenic process as follows: (1) The REE minerals and rutile occurring as inclusions wrapped within magmatic idiomorphic dolomite grains indicate that the REE-Nb mineralization might have started during the magmatic period. (2) The Nb minerals, such as fergusonite and ilmenorutile, intergrown with REE minerals, such as monazite and bastnäsite, indicate that the Nb and REE were transported by the same ore-forming magma or fluid and precipitated during the same metallogenic process. (3) From the fine-grained dolomite stage to the massive mineralization stage (from stage 2 to stage 5), the mineral assemblages become more complex, with a gradual increase in the degree of hydrothermal alteration suggesting that more hydrothermal fluid was involved in the ore mineralization. (4) The complex mineralogical assemblages and textural relationships indicate multiple formation mechanisms for the REE-Nb-Fe minerals. We propose that the unusually large volume of REE-Nb-Fe resources in the Bayan Obo deposit was the result of combined magma and hydrothermal fluid activities in the Mesoproterozoic (from stage 1 to stage 5), whereas the fluids only caused reactivation of the ore materials previously deposited without the addition of exogenous materials in the Paleozoic stage (stage 6).

Microstructure, trace element systematics and in-situ sulfur isotopes of multistage sulfides in the Kalatag district (East Tianshan, NW China): Implications for formation of arc-hosted VMS deposit

The Early Paleozoic arc-hosted volcanogenic massive sulfide (VMS) deposits in the Kalatag arc are well-known for their well-preserved and high-grade Cu–Zn sulfide mineralization in the East Tianshan. Unfortunately, there is a puzzle on the ore-forming fluid and metal source as well as physicochemical condition of metallogenic process of these arc-hosted VMS Cu–Zn deposits. The Huangtupo was firstly reported Early Paleozoic arc-hosted VMS Cu–Zn deposit (300Kt@1.49 % Cu; 280Kt@3.51 % Zn) in the East Tianshan. In order to better recognize the physicochemical condition and formation processe of arc-hosted VMS deposits, this research takes the Huangtupo deposit as an example, combining the microstructure, in-situ sulfur isotope and trace element composition of multistage sulfides to conduct a comprehensive study. In the Huangtupo deposit, the overall mineralization process is divided into syndepositional mineralization stage, hanging-wall massive mineralization stage and channel hydrothermal stage according to the main mineral interpenetration relationship and horizon relationship. Pyrite can be divided into five types in the Huangtupo Cu–Zn deposit: 1) subhedral to anhedral pyrite in the silicious exhalite (Py1); 2) colloform pyrite in the hanging-wall massive pyrite + barite + sphalerite zone (Py2); 3) subhedral pyrite in the hanging-wall massive pyrite + chalcopyrite + sphalerite ± magnetite zone (Py3); 4) fine-grained (or disseminated) pyrite in the footwall pyrite + chalcopyrite + sphalerite stage (Py4); 5) euhedral pyrite in the footwall quartz + pyrite + chalcopyrite stage (Py5). Two types of chalcopyrite are identified, including hanging-wall massive chalcopyrite (Ccp1) and footwall stockwork chalcopyrite (Ccp2). In addition, three generations of sphalerite could be identified, namely (1) hanging-wall massive pyrite + barite + sphalerite zone (Sp1); (2) hanging-wall massive pyrite + chalcopyrite + sphalerite ± magnetite zone (Sp2); and (3) footwall pyrite + quartz + sphalerite + chalcopyrite stage (Sp3). In the upper massive orebody, LA–ICP–MS in-situ microanalysis shows that pyrite is enriched in Cu, Zn, Au, Ag, Pb, Sb, and Tl, while it is poor in Co, Ni, Se, Te, Ti, and Sn, indicating that it was formed in a metal-rich, medium–high temperature and more oxidizing hydrothermal environment. By contrast, pyrite from the footwall stockwork orebody contains low Au, Ag, Cu, Zn, Pb, Sb, Tl and high Co, Se, Te, Ti content, indicating that it is formed in the hydrothermal environment with a high temperature, reduction and trace metal deficit signature. Trace element compositions of sphalerite suggest that Fe, Mn, Ag, Se, In, Ge, and Ga are present as lattice. By contrast, Sn, Pb, Tl, and Bi are present as mineral microinclusions. The mineralization temperature is determined by sphalerite geothermometer (GGIMFis) and shows a decreasing trend from footwall stockwork mineralization to hanging-wall massive mineralization. Comparing with sphalerite, chalcopyrite is enriched in Ge, Ag, Zn, Se, Sn, and Cd, relatively poor in In and Ga. The integrated in situ sulfur isotopic (δ34S) composition and trace metal content of sulfides suggest that ore-forming material is most likely derived from a combination of host volcanics and seawater. In addition, the thermochemical sulfate reduction is also a key factor affecting sulfur isotope fractionation. Overall, the trace element compositions of multistage sulfides are robust monitor of the complex hydrothermal process and effectively reconstruct the metal enrichment process during the formation of arc-hosted VMS mineralization system.

Immobilization of Cr3+, Cd2+, and Pb2+ added to calcareous soil amended with composted agro-industrial residues

The bioavailability of trace metals in soils poses a major threat to the environment, especially with massive mineral fertilizers added to increase plant yield. A plot experiment was conducted for the effectiveness evaluation of compost and vermicompost, recycled from agro-industrial wastes, in immobilizing chromium, cadmium, and lead added to calcareous soil (artificially contaminated). Moreover, immobilization efficiency was compared to the natural occurrence of these metals in the soil without metal addition (uncontaminated soil). In both soils, amendments and mineral fertilizers were applied at three different levels alone and combined to each other. The experimental design was arranged in factorial complete randomized blocks using contamination, organic and mineral fertilizer levels, and their combination as categorical factors. The distribution of metal fractions and their bioavailability in soils and bioaccumulation in wheat grains were evaluated. Soil alkalinity, the contents of soil organic carbon and nitrogen, available phosphorus, and soil micronutrients were significantly improved under vermicompost and compost compared to mineral fertilizer and control. Vermicompost was more effective than compost in reducing metals bioavailability in contaminated soils by increasing the immobilized organic fractions, but it regressed when combined with mineral fertilizers. The bioavailability of the naturally occurring metal levels in uncontaminated soil did not change significantly compared to contaminated soil. Likewise, wheat yield, plant biomass, and nutrient enrichment in wheat grains improved due to enhanced soil nutrient availability. These composted agro-industrial residues, by-products from food industries, can be classified as environmentally-friendly soil amendments for their great potential to enrich soil nutrients, reduce mineral fertilizer addition, enhance plant growth, and stabilize Cr, Cd, and Pb in contaminated calcareous soils under wheat plants.

Delimitation of massive sulphide bodies – Mise‐à‐la‐masse method associated with induced polarization (IP) – A case history from Brazil

AbstractThis paper presents a successful application of the mise‐à‐la‐masse (MALM) or applied potential method in association with induced polarization (IP). MALM is known, since 1920, to be able to delimit electrically conductive massive mineralization. The method is used at the point where a drill hole intercepts a massive, mineralized body, to estimate its extent and shape. It is thus used as a complementary mineral exploration tool. IP is normally used in conjunction with resistivity. However, the acquisition of IP data together with the MALM method is rarely found in the literature. This survey shows that it is possible to successfully detect and delimit areas of disseminated sulphides using MALM with IP. In this paper, the MALM method is presented and discussed in detail. A short description of the IP method is also provided. Data are from the Camaquã Project (Caçapava do Sul, RS, Brazil) and the Santa Maria (lead, zinc and associated silver) deposit, 5 km south of Caçapava do Sul. In a well that intercepted a massive mineralization (borehole 8011) with electrical continuity, ∆V measurements delineated the extent, shape and orientation (NS) of a conductive sulphide body. Mineralization intercepted by other two wells (8011 and 8103) did not present enough electrical continuity to exhibit potential contours that could be associated to massive sulphides; it was, however, successfully detected by IP.

The Unconventional Peridotite-Related Mg-Fe-B Skarn of the El Robledal, SE Spain

The El Robledal deposit is a Mg-Fe-B skarn hosted in a dismembered block from the footwall contact of the Ronda orogenic peridotites in the westernmost part of the Betic Cordillera. The skarn is subdivided into two different zones according to the dominant ore mineral assemblage: (1) the ludwigite–magnetite zone, hosted in a completely mineralized body along with metasomatic forsterite, and (2) the magnetite–szaibelyite zone hosted in dolomitic marbles. In the ludwigite–magnetite zone, the massive mineralization comprises ludwigite (Mg2Fe3+(BO3)O2), Mg-rich magnetite, and magnetite, with minor amounts of kotoite (Mg3(BO3)2), szaibelyite (MgBO2(OH)), accessory schoenfliesite (MgSn4+(OH)6), and pentlandite. The ratio of ludwigite–magnetite decreases downwards in the stratigraphy of this zone. In contrast, the mineralization in the magnetite–szaibelyite zone is mainly composed of irregular and folded magnetite pods and bands with pull-apart fractures, locally associated with a brucite-, szaibelyite-, and serpentine-rich groundmass. The set of inclusions identified within these ore minerals, using a combination of a focused ion beam (FIB) and high-resolution transmission electron microscope (HRTEM), supports the proposed evolution of the system and reactions of the mineral formation of the skarn. The analysis of the microstructures of the ores by means of electron backscatter diffraction (EBSD) allowed for the determination that the ores experienced ductile deformation followed by variable degrees of recrystallization and annealing. We propose a new classification of the deposit as well as a plausible genetic model in a deposit where the heat source and the ore-fluid source are decoupled.

U–Pb and Re–Os geochronology of the Yundukala Au–Cu–Co deposit in East Junggar, NW China: Constraints on the timing of mineralization and ore‐bearing rocks

East Junggar is an important part of the Central Asia Orogenic Belt and has developed a multi‐epoch and multi‐type metallogenic system. Yundukala is a recently discovered large intrusion‐related Au–Cu–Co deposit. The No. 1 main mineralization zone mainly occurs in the contact area between fine‐grained diorite and basalt. Massive and vein mineralization have developed there, but the ore‐bearing stratum, ore‐bearing intrusive rocks, and metallogenic ages are not clear. Zircon SHRIMP U–Pb dating of the porphyritic diorite and fine‐grained diorite yields ages of 416.1 ± 3.9 Ma and 411.1 ± 7.5 Ma, respectively. The dioritoid intruded into the ore‐bearing stratum, indicating that this formation is part of the Early Palaeozoic strata rather than the Middle Devonian Beishan Formation. The Re–Os isochron age of the chalcopyrite in the massive mineralization is 402.6 ± 5.2 Ma; thus, the massive mineralization is related to fine‐grained diorite and formed in the Early Devonian. Six sulphides and four sulphides from the vein mineralization yield Re–Os isochron ages of 352.8 ± 1.8 Ma and 354 ± 23 Ma, respectively, and the limited vein mineralization was formed during 353–354 Ma. The massive and vein mineralizations in the Yundukala deposit were formed in the Early Devonian and Early Carboniferous.

Secondary Minerals from Minothem Environments in Fragnè Mine (Turin, Italy): Preliminary Results

The Fragnè mine, located in the Lanzo valley in the municipality of Chialamberto (Turin, Piedmont Region), represented the most important regional site for Fe–Cu sulfide exploitation over a period of more than eighty years (1884–1965). The entire mining area is part of a structural complex in the Lower Piedmont Unit of the Western Alps, characterized by the presence of amphibolite, metabasite (“prasinite”), and metagabbroic rocks. In particular, the pyrite ore deposit occurs as massive mineralizations within interlayered metabasites and amphibolites. In this work, we describe secondary minerals and morphologies of minothems from the Fragnè mine that are found only in abandoned underground works, such as soda straws, normal and jelly stalactites and stalagmites, jellystones, columns, crusts, blisters, war-clubs, and hair, characterized by different mineralogical associations. All minothems were characterized by minerals formed during acid mine drainage (AMD) processes. Blisters are composed only of schwertmannite, war-clubs by schwertmannite, and goethite with low crystallinity and hair by epsomite and hexahydrite minerals. Jelly stalactites and stalagmites are characterized by schwertmannite often in association with bacteria, while solid stalactites and stalagmites are characterized by jarosite and goethite. The results indicate that the mineralogical transformation from schwertmannite to goethite observed in some minothems is probably due to aging processes of schwertmannite or local pH variations due to bacterial activity. On the basis of these results, we hypothesize that all the jelly samples, in association with strong bacterial activity, are slowly transformed into more solid goethite, and are thus precursors of goethite stalactites.

Progress, Key Issues, and Future Prospects for Li-Ion Battery Recycling.

The overuse and exploitation of fossil fuels has triggered the energy crisis and caused tremendous issues for the society. Lithium-ion batteries (LIBs), as one of the most important renewable energy storage technologies, have experienced booming progress, especially with the drastic growth of electric vehicles. To avoid massive mineral mining and the opening of new mines, battery recycling to extract valuable species from spent LIBs is essential for the development of renewable energy. Therefore, LIBs recycling needs to be widely promoted/applied and the advanced recycling technology with low energy consumption, low emission, and green reagents needs to be highlighted. In this review, the necessity for battery recycling is first discussed from several different aspects. Second, the various LIBs recycling technologies that are currently used, such as pyrometallurgical and hydrometallurgical methods, are summarized and evaluated. Then, based on the challenges of the above recycling methods, the authors look further forward to some of the cutting-edge recycling technologies, such as direct repair and regeneration. In addition, the authors also discuss the prospects of selected recycling strategies for next-generation LIBs such as solid-state Li-metal batteries. Finally, overall conclusions and future perspectives for the sustainability of energy storage devices are presented in the last chapter.

Magnetite geochemistry and iron isotope signature of disseminated and massive mineralization in the Kalatongke magmatic Cu[sbnd]Ni sulfide deposit, northwest China

Magnetite is a common accessory mineral and an indicator to magma evolution and sulfide fractional crystallization in magmatic NiCu sulfide deposits. The Kalatongke magmatic sulfide deposit at the southern margin of the Central Asian Orogenic Belt is composed of 11 mafic intrusions. The sulfide orebodies (Y1, Y1 deep, and Y2) are hosted by three small mafic intrusions, and magnetite is common in all mineralized samples. Based on ilmenite exsolution texture, composition, and type of mineralization, three types of magnetite are identified, (1) primary Fe-rich magma-related magnetite (type 1), (2) sulfide liquid-related magnetite (type 2), and (3) hydrothermal magnetite (type 3). We speculate that Fe isotope equilibrium fractionation between early or co-crystallized light 54Fe-enriched sulfide and magnetite may account for the ultra-high magnetite δ56Fe value (0.70‰ to 1.35 ‰) in the magmatic magnetite (types 1 and 2). Enriched compatible elements in type 1 magnetite (TiO2 = 1.52 wt% to 7.89 wt%, V = 775 ppm to 2420 ppm, Cr = 2697 ppm to 14,658 ppm, and Ni contents = 478 ppm to 1256 ppm), reflect the characteristics of primary Fe-rich magmatic magnetite crystallized at relatively high temperature and low oxygen fugacity. Type 2 magnetite in massive ores has Ni (762 ppm to 1769 ppm) and δ56Fe (0.89 ‰ to 1.10 ‰) values similar to type 1 magnetite, but significantly lower TiO2, V and Cr contents (TiO2 = 0.07 to 3.72 wt%, V = 61 to 2314 ppm, Cr = 5 to 2937 ppm), indicating co-crystallization with an evolved sulfide liquid across a wide span of temperature and oxygen fugacity. Type 3 magnetite is of hydrothermal fluid origin, with low δ56Fe (0.29 ‰ to 0.41 ‰) and Ni (177 ppm to 377 ppm).Magnetite composition and Fe isotope signatures at the Kalatongke magmatic sulfide deposit can reveal the genesis of magnetite and the evolution of the melt and sulfide. The Y1 orebody was completely crystallized over a short period of time, while the Y1 deep and Y2 east orebodies underwent a protracted evolution during which magnetite co-crystallized from primitive Fe-rich melt, Fe-rich evolved melt and Cu-rich intermediate sulfide solution. Magnetite and sulfide in the Y2 west massive orebody likely formed last. The compatibility of both lithophile and chalcophile elements, combined with Fe isotopes in magnetite, makes magnetite a good indicator of silicate and sulfide melt evolution.

Complex, multi-stage mineralization processes in the giant Bayan Obo REE-Nb-Fe deposit, China

The Bayan Obo REE-Nb-Fe deposit with giant rare earth reserves, still has no unified understanding of the REE and Nb-bearing mineral evolution and the division of mineralization stages, due to the complicated metallogenic process and the huge controversy on the important issues such as the origin of ore-hosting dolomite. In this work, the whole process of carbonatite magma solidification and mineralization is divided into six stages: coarse dolomitic facies, fine dolomitic facies, disseminated mineralization, banded mineralization, massive mineralization and vein mineralization. The mineralogical composition and paragenesis of various types of rocks and ores have been systematically studied using the automatic mineral analysis technology-Advanced Mineral Identification and Characterization System (AMICS), supplemented by optical microscopy and cathodoluminescence. In order to establish the internal relationship between different stages, trace elements of six kinds of rocks and ores were analyzed. The mineralogical studies show that the rare earth minerals appear in the order of transition from the phosphate minerals in the brine-melt stage (fine dolomitic facies), through the fluorcarbonate minerals in the hydrothermal stage (disseminated, banded and massive mineralization), to the Ba-fluorcarbonate minerals in the Paleozoic vein mineralization, and all of these are generally associated with apatite, baryte, fluorite, aegirine and quartz. The distribution of niobium minerals in all kinds of ores is in the form of disseminated grains, and there is no obvious paragenetic relationship with other minerals, which indicate that niobium mineralization may only be related to the content of niobium in hydrothermal solution. The geochemical data show that all types of rocks and ores have positive anomalies of Ba and Nb, negative anomalies of U, Ta, Sr, Zr and Y. From coarse dolomitic facies to massive mineralization, the content of REE, Nb and Th increases, the content of Sr decreases, and the ratio of (La/Yb)N and (La/Nd)N increases, all of which change continuously. Vein mineralization has similar (La/Nd)N and (La + Ce + Pr)N/REE ratios compared with coarse dolomitic facies and has a wide range of Sr, Th, Nb and REE compositions, and elemental ratio and content of vein mineralization are within the distribution range of ore-hosting dolomite and different types of mineralization. Based on the above, it is considered that the main mineralization body at Bayan Obo was formed in the process of auto-metasomatism of Mesoproterozoic igneous carbonatite, while vein mineralization was the product of homogenization and re-precipitation of early ore-forming material by the Paleozoic fluids, without the addition of exogenous metallogenic materials.

Trace element geochemistry of sphalerite and chalcopyrite in arc-hosted VMS deposits

Trace element compositions of sphalerite and chalcopyrite have been investigated for four arc-hosted Cretaceous VMS deposits (María Teresa, Perubar, and Palma in Peru, and Cerro de Maimón in the Dominican Republic) using laser ablation inductively-coupled plasma mass spectrometry. In sphalerite, Fe, Mn, Cd, Hg, Ag, Sb, Se, In, Ge, and Ga are lattice-bound, whereas Sn, Tl, Bi, and Pb occur at least partly as mineral microinclusions. Significant variations in the contents of minor and trace elements are observed in sphalerite grains from individual deposits. A strong negative correlation between Fe (Inter-Quartile Range [IQR] 44,009–18,168 ppm) and Zn indicates a dominant Fe2+ ↔ Zn2+ simple isovalent substitution. Regarding potential high-tech by-products, the contents of In (IQR 42–1.6 ppm, up to 415 ppm) and Ga (IQR 31–5.9 ppm, up to 96 ppm) in the studied sphalerite are normally much higher than those of Ge (IQR 0.85–0.16 ppm, up to 9.3 ppm). Correlation trends suggest Cu+ + In3+ ↔ 2Zn2+, Cu+ + Ga3+ ↔ 2Zn2+, and more complex substitution mechanisms of Zn involving combinations of monovalent (Cu+, Ag+), divalent (Ge2+?), trivalent (In3+, Ga3+, [Sn3+?]), and quadrivalent (Ge4+, Sn4+) cations.As for chalcopyrite, Zn, Ag, Sn, Cd, Se, In, Ga, and Ge are interpreted to be lattice-bound, whereas Mo, Au, Tl, Sb, Pb, and Bi probably occur as microinclusions. Relative to sphalerite, chalcopyrite is depleted in In (IQR 28–8.4 ppm, up to 49 ppm) and Ga (IQR 8.3–2.9 ppm, up to 24 ppm) and enriched in Ge (IQR 5.9–0.70 ppm, up to 80 ppm). Of the other trace elements, Zn (IQR 426–190 ppm) is the most highly concentrated in the studied chalcopyrite, followed by Ag (IQR 136–23 ppm), Se (IQR 64–22 ppm), Sn (IQR 53–1.3 ppm), and Cd (IQR 12–6.0 ppm). General positive correlation trends between Zn, Cd, In, Ge, and Ga in chalcopyrite suggest varied coupled substitution mechanisms of Fe and Cu with fluctuating valences due to covalent bonding.Trace-element distribution patterns in sphalerite and chalcopyrite were studied for the zone-refined Sofía-D massive sulfide body in the María Teresa deposit, which comprises a lower lower portion of dominant pyrite sheathed upward by zones of chalcopyrite (Cu zone), sphalerite (Zn zone) and galena + sphalerite ± fahlore ± barite (Pb – Zn – Ag zone). Bottom to top of the sulfide body, sphalerite records progressive depletion in In, Cu, Mn, and Se, and enrichment in Ge. This distribution pattern agrees with increasing crystallization temperatures and/or volatile magmatic influx towards the lower portion of the massive mineralization. Distribution of trace elements in chalcopyrite is rather uneven except for a sustained enrichment in Se towards the basal portion of the sulfide body. The fact that such trends are preserved in spite of extensive recrystallization during thermal metamorphism in parts of the Sofía-D massive sulfide mineralization suggests i) a closed metamorphic system and ii) that element interdiffusion was prominently local. Accordingly, we propose that sphalerite lattice-bound trace elements distribution patterns described in this article can help determine the polarity of massive sulfide bodies in VMS districts in metamorphosed and tectonized terranes.

Hydrothermal-metasomatic systems as the most important factor for the formation of elements of the oil and gas-bearing complex in the Bazhenov-Abalak sediments

A model of the activity of hydrothermal-metasomatic systems confined to certain structural elements is proposed in the present article. The model is based on the analysis of a large volume of traditional studies: measurements of porosity coefficients, permeability, pyrolytic measurements - together with specific measurements: isotopic composition of carbonate rocks, temperature of homogenization of gas-liquid inclusions, studies of the composition of rocks with a scanning electron microscope, a description of petrographic thin sections. The model allows to generalize the results of the impact of hydrothermal-metasomatic systems on the reservoir properties of the rocks of the Bazhenov-Abalak complex: constructive – leaching processes and increasing reservoir properties, and destructive – massive mineral formation that fills the pore space, up to the formation of secondary seals.

Co-Ni-arsenide mineralisation in the Bou Azzer district (Anti-Atlas, Morocco): Genetic model and tectonic implications

The two main types of mineralisation in the Co-Ni-As Bou Azzer district, i.e., “contact” mineralisation” and “cross-cutting” structures have been re-defined based on new field, structural, textural and mineralogical observations. The main orebodies consist of elongated lenses of massive Ni-Co-Fe arsenide minerals. These lenses occur in a core of carbonate or siliceous gangue and are almost exclusively located along the contact between serpentinite and a quartz diorite intrusion. Vein system, cross-cutting the different lithologies, is ore-bearing only along segments in contact with the serpentinite and/or the massive mineralisation. The two orebody types share a rather similar mineralisation history, starting with a Ni-rich arsenide stage (mainly expressed within the massive mineralisation), followed by a massive Co-arsenide stage recognised in both mineralisation styles, and ending with Fe-rich arsenide and base metal sulphide stages. Detailed field observations, microstructural, tectonic, textural and mineralogical analyses led us to propose a genetic model for the Bou Azzer ore district in which massive mineralisation was formed by alteration and transformation of previously formed breccia levels composed of serpentinite (transformed to gangue) and magnetite/spinel (transformed to Co-Ni arsenide minerals) fragments. Inversely, a tectono-hydrothermal event controlled by a NE-oriented transtension generated the vein system, associated certainly with partial remobilisation and reconcentration of metals from the massive mineralisation because veins are principally mineralised when crossing massive orebodies. We discuss a possible temporal continuum between the two mineralisation styles: massive mineralisation, coeval with serpentinisation (serpentine neoformation), is related to the transformation of brecciated lenses, and vein mineralisation is formed as an infill of large fractures during transtensive tectonics. This model has significant tectonic implications, because serpentinite breccia lenses, favourable high-permeability environment for the massive mineralisation formation, can be compared to ophicalcic rocks developed in a context of mantle exhumation by detachment. Two types of textures can be differentiated within the massive mineralisation: i) Brecciated Massive Mineralisation, developed in the core of ophicalcic levels, and ii) Laminated Massive Mineralisation, supposed to form within ancient mylonitic serpentinite levels corresponding to intensive deformation zones. Although the geodynamic significance will not be addressed in this article, we propose and discuss an alternative model in which the presence of exhumed mantle rocks allows the formation of specific massive arsenide deposits.

Global Politics and Security Implications of Foreign Aids for African Development

Globalization has redefined the concept of (nation) independence, especially in terms of (absolute) sovereignty and economic dependence. Nevertheless, it has promoted the difference between developed and developing countries. African nations are described as developing economies and continually spoon-fed by the developed western nations. While the scramble for and partition of African nations is no longer about the physical presence and dominance of the countries by the 'developed' nations, global politics in foreign aids are engaged to perpetuate control and dictate governance and policies to African nations. Foreign aids support African nations' security, economic, environmental, social, and political development. Foreign aids are not limited to cash but could come in technical and operational support, including capacity buildings and long-term loans. However, history has shown the craving and determination of most African nations to receive cash donations or loans for nations' development. Most of these monies have also lubricated corruption as funds meant for the nations’ socio-economic development ended up in bank accounts of most political officeholders. The situation has plunged many African nations into huge debts, thereby overtly submissive to the dictates and controls of countries in the western world. Aware of this, many of these foreign countries have exploited many African nations of massive mineral and other natural resources, determined to keep the giver-taker relationship's status-quo. Foreign aids are two-edged swords with both positive and negative impacts. Many papers have reviewed these impacts on national development with the people's well-being and the foreign dominance attributes of these aids. This paper looks at the trajectory of foreign aids, security, leadership, and development.

Geology of the recently discovered massive and stockwork sulphide mineralization at Semblana, Rosa Magra and Monte Branco, Neves–Corvo mine region, Iberian Pyrite Belt, Portugal

AbstractThe recently discovered massive and stockwork sulphide mineralization of Semblana-Rosa Magra and Monte Branco, situated ESE of the Neves–Corvo volcanogenic massive sulphide (VMS) deposit in the Iberian Pyrite Belt (IPB) is presented. Geological setting and tectonic model is discussed based on proxies such as palynostratigraphy and U–Pb zircon geochronology. The mineralization is found within the IPB Volcano-Sedimentary Complex (VSC) Lower sequence, which includes felsic volcanic rocks (rhyolites) with U–Pb ages in zircons of 359.6 ± 1.6 Ma, and black shales of the Neves Formation of late Strunian age. Massive sulphides are enveloped by these shales, implying that felsic volcanism, mineralization and shale sedimentation are essentially coeval. This circumstance is considered highly prospective, as it represents an important exploration vector to target VMS mineralization across the IPB, in areas where the Lower VSC sequence is present. The Upper VSC sequence, with siliciclastic and volcanogenic sedimentary rocks of middle–late Visean age, shows no massive mineralization but a late Tournaisian (350.9 ± 2.3 Ma) volcanism with disseminated sulphides was also identified. Nevertheless, stratigraphic palynological gaps were found within the Strunian and in the Tournaisian sediments, between the Lower and Upper VSC sequences, reflecting probable erosion and uplift mechanisms linked with extensional tectonics. The Semblana and Monte Branco deposits and the Rosa Magra stockwork are enclosed by tectonic sheets that dismembered the VSC sequence in a fold-and-thrust tectonic complex, characteristic of the NE Neves–Corvo region. The methodologies used allow a geological comparison between Neves–Corvo and other IPB mine regions such as Lousal–Caveira, Herrerias, Tharsis and Aznalcollar.

Occurrence Modes of Niobium in Kaolin Clay From Guizhou, China

Niobium in kaolin clay from the Late Permian sequences was reported in the range of several hundreds of micrograms per gram and was considered as a potential resource for its high concentrations and large areal distribution. Ti-bearing minerals associated with kaolin clay were identified as the main host phase for niobium in some case studies. However, the correlation between the concentration of niobium and titanium is poor, and the types of Ti-bearing minerals and modes of occurrence of niobium are not clear. Typical kaolin clay samples from the Late Permian sequences from southwest China were characterized, and the final products derived from kaolin clay sample were investigated using XRF, ICP-MS, XRD, SEM, and TEM (EDS). The results reveal that there were three types of TiO2 mineral phases in the clay samples: (a) massive TiO2 minerals and (b) aggregates of nano TiO2 minerals did not contain niobium while (c) granular TiO2 minerals were the source of niobium from the EDS analysis. The granular TiO2 minerals included anatase and rutile, both of which were the sources of niobium in kaolin clay in the current study. The findings are of great theoretical implication for source and origin study of Ti-bearing minerals and guidance for separation and recovery of niobium from kaolin clay.

Petrogenesis of the Microgranular Enclaves and Their Host Granites from the Xitian Intrusion in South China: Implications for Geodynamic Setting and Mineralization

The South China Block had experienced a significant tectonic transition during the Mesozoic in response to the subduction of the Paleo- and the Pacific Ocean. Large-scale granitic intrusions with massive mineralization are widespread in South China, and their tectonic settings are not defined. The Xitian intrusion is ideal for probing the geodynamic setting and mineralization in South China because they comprise an abundance of microgranular enclaves (MEs) and diverse types of granite associated with mineralization. Age determined by zircon U-Pb dating suggests that the MEs and their host granites are coeval within error, of ca. 152 Ma. The MEs have a similar initial Hf-O isotopic composition as host granites, and the rapid cooling mineral textures indicate that they are autoliths. Geochemical data show that the host granites are high-K, calc-alkaline, and transitional from metaluminous to peraluminous, slightly enriched in light rare earth elements (LREEs) relative to heavy rare earth elements (HREEs), with obvious negative Eu anomalies, belonging to I-type. The Nb/Ta and Zr/Hf ratios indicate the volatile penetrates the magmatic-forming process, and the fluid with abundant volatile could extract metal element effectively from the mantle.

Celestine from Valea Sarii (Vrancea region): New Data and Crystal Structure Refinement

In the paper has been analyzed the crystal structure of a celestine sample from Valea Sarii (Vrancea region, Romania) located in the Eastern Carpathians Foredeep. The celestine sample was also studied by optical microscopy, chemical and thermal analysis. The unit cell parameters of the celestine structure refined in the space group Pnma were: a=8.39769 �, b=5.38415 �, c=6.88167 �, Z=4. The chemical composition of the celestine crystals was determined by EDX analysis. The optical characteristics of the sample were studied by optical microscopy. A new set of the unit cell parameters and fractional coordinates of the celestine crystal structure were determined. Also were determined the bond lengths in the Sr-O12 and SO4 polyhedra. The sample was collected in the massive mineralization area of the Valea Sarii ore deposit, the largest celestine ore deposit in Romania.