Electrolyte Mass Transport Research Articles

Voltage-Tunable Volume Transitions in Nanoscale Films of Poly(hydroxyethyl methacrylate) Surfaces Grafted onto Gold

Surface grafting of a polymerizable monomer onto Au was used to produce nanometer-scale planar hydrogel films with controllable volume. A self-assembled monolayer of 11-mercaptoundecanoic acid on a planar Au surface was activated through water-soluble carbodiimide and N-hyroxysuccinimide followed by reaction with 2-aminomethacrylate to produce a methacrylate-terminated surface layer, which readily polymerized under UV radiation in the presence of hydroxyethyl methacrylate monomer, ethylene glycol dimethacrylate cross-linker, and a photoinitiator. The reaction steps were characterized by external reflection mode Fourier transform IR spectroscopy. Under controlled UV exposure, thin (3 nm < d < 10 nm) hydrogel films were obtained from 1:1 ethanol/H(2)O. Surface plasmon resonance measurements were used to characterize both the synthesis of the hydrogel and the potential-induced volume changes. The nanometer-scale hydrogels thus produced undergo reproducible changes in thickness, when a potential is applied across the film. Thickness changes increasing with applied potential were obtained for both voltages in the range |V(appl)| </= 600 mV. In NaCl, electrolyte films swell with application of negative potentials and shrink with positive potentials, due to the imbibing or extrusion of hydrated Na(+) ions, respectively. Thickness changes as large as 50% can be achieved. An increase in the cross-linker content results in thicker films, but at the cost of dramatically restricted swelling. Response times are generally faster for smaller applied potentials, as expected if the volume change results from mass transport of electrolyte.

A study of current distribution in a DEM cell during bromate formation

The anodic oxidation of potassium bromide to potassium bromate is performed in an undivided cell with hydrogen evolution the major reaction at the counter electrode. The cell used is a dished electrode membrane (DEM) cell. Current density distribution, measured using a segmented electrode, shows a variation in the two principle dimensions; along the length of the electrode and over the width of the electrode. Current densities are highest at the electrolyte flow inlet and also exhibit a localized maximum along the electrode length. The variation in current density is due to the influence of electrolytic gas evolution on the effective electrolyte conductivity and mass transport and also due to the change in shape of the dished electrode, which influences mass transport, electrical potential field and flow at the cell inlet and exit.

Modelling and Analysis of Pulse Electrochemical Machining (PECM)

A small interelectrode gap in Electrochemical Machining (ECM) results in improved dimensional accuracy control and simplified tool design. However, using a small gap with conventional ECM equipment adversely affects the electrolyte flow or mass transport conditions in the gap, leading to process instability. The most remarkable breakthrough in this regard is the development of ECM using pulsed current. Pulse Electrochemical Machining (PECM) involves the application of a voltage pulse at high current density in the anodic dissolution process. PECM allows for more precise monitoring and control of machining parameters than ECM using continuous current. Small interelectrode gap, low electrolyte flow rate, gap state recovery during the pulse-off times and improved anodic dissolution efficiency features encountered in PECM lead to improved workpiece precision and surface finish when compared with ECM using continuous current. This paper presents mathematical models for the PECM process which take into consideration the nonsteady physical phenomena in the gap between the electrodes, including the conjugate fields of electrolyte flow velocities, pressure, temperature, gas concentrations, current densities and anodic material removal rates. The principles underlying higher dimensional accuracy and simpler tool design attainable with optimum pulse parameters are also discussed. Experimental studies indicate the validity of the proposed PECM models.

Considerations in Electrodeposition of Compositionally Modulated Alloys

High‐quality specimens of sufficient thickness for reliable testing are needed if the enhanced properties observed for ultrastructured multilayered metals are to be understood and exploited. In the present paper, factors affecting the quality of multilayers electrodeposited from a single electrolyte, via concerted modulation of the electrode potential and electrolyte mass transport, are discussed. The importance of precise control of the potential during deposition of the more noble metal is emphasized. Results obtained by a pulse technique show that Ni passivation does not occur under the conditions used to electrodeposit Ni‐Cu multilayers. Attainable deposit quality is illustrated by tensile test data for a series of 90%Ni‐10%Cu specimens that are twice as strong as Ni and for which the standard deviations for the ultimate tensile strength and modulus are only 1.5 and 3.9%, respectively.

Mass transport of electrolytes in membranes. 1. Development of mathematical transport model

Modele mathematique base sur les equations de Stefan-Maxwell; les parametres de transfert sont fonction de la composition, de la pression et de la position a l'interieur de la membrane. On considere les corrections des coefficients d'activite et les coefficients de distribution a l'interface membrane-solution

Mass Transport of Binary Electrolytes in Membranes. Concentration Dependence for Sodium Chloride Transport in Cellulose Acetate

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMass Transport of Binary Electrolytes in Membranes. Concentration Dependence for Sodium Chloride Transport in Cellulose AcetateD. N. Bennion and B. W. RheeCite this: Ind. Eng. Chem. Fundamen. 1969, 8, 1, 36–49Publication Date (Print):February 1, 1969Publication History Published online1 May 2002Published inissue 1 February 1969https://doi.org/10.1021/i160029a007RIGHTS & PERMISSIONSArticle Views119Altmetric-Citations20LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (1 MB) Get e-Alerts