Suspended Particulate Matter Mass Research Articles

Seasonal and interannual variations of suspended particulate matter in a West-African lagoon (Nokoué lagoon, Benin): Impact of rivers and wind

This study, based on five years of monthly in situ data collected from 2018 to 2022, examines the seasonal and interannual fluctuations of suspended particulate matter (SPM) concentration in Nokoué Lagoon, Benin. Seasonally, SPM exhibits significant variations primarily influenced by changes in river discharge. During low-flow periods (December to May), SPM concentrations are relatively low (<15 mg L-1) throughout the lagoon. During this time, slight temporal variations are correlated with wind energy and likely associated with wind-induced resuspension of sediments. This is confirmed by slightly higher concentrations of SPM in the bottom layers compared to the surface. Resuspension appears to be lower in the west than in the east, likely due to the increased presence of acadjas (brush parks) in the west, reducing fetch and wind intensity, thus decreasing resuspension. At the onset of the river flood period (July–August), associated with the West African monsoon, increased river flow generates a significant turbid plume extending from the northeast of the lagoon to the Cotonou channel, connecting the lagoon to the Atlantic Ocean. SPM levels then increase considerably (>100 mg L−1), with a pronounced SPM gradient from the western to eastern regions of the lagoon. The less dense freshwater laden with sediment from the rivers flows over the denser saline water of the lagoon, leading to slightly higher SPM concentrations in the surface layers. Between September and November, SPM concentration gradually decreases as river flows reach their peak values. Thus, on a seasonal scale, the relationships between SPM and river discharge show a temporal lag, resulting in a clockwise hysteresis cycle. This is explained by the early mobilization of fine sediments during rising river flows, followed by reduced sediment availability and dilution effects as the flood peaks. On an interannual scale, SPM variations are relatively low with slight temporal shifts observed in the formation and expansion of the turbid plume and peak SPM levels. The total SPM mass in the lagoon ranges from 0.2 to 0.3 × 104 tonnes during low-flow periods to 20-30 × 104 tonnes at the onset of flooding. We also discuss uncertainties associated with SPM determination, estimated at approximately 5–15%. This study leverages a unique database in West Africa and provides valuable insights into the hydro-sedimentary dynamics of Nokoué Lagoon.

The Potential of Multibeam Sonars as 3D Turbidity and SPM Monitoring Tool in the North Sea

Monitoring turbidity is essential for sustainable coastal management because an increase in turbidity leading to diminishing water clarity has a detrimental ecological impact. Turbidity in coastal waters is strongly dependent on the concentration and physical properties of particles in the water column. In the Belgian part of the North Sea, turbidity and suspended particulate matter (SPM) concentrations have been monitored for decades by satellite remote sensing, but this technique only focuses on the surface layer of the water column. Within the water column, turbidity and SPM concentrations are measured in stations or transects with a suite of optical and acoustic sensors. However, the dynamic nature of SPM variability in coastal areas and the recent construction of offshore windmill parks and dredging and dumping activities justifies the need to monitor natural and human-induced SPM variability in 3D instead. A possible solution lies in modern multibeam echosounders (MBES), which, in addition to seafloor bathymetry data, are also able to deliver acoustic backscatter data from the water column. This study investigates the potential of MBES as a 3D turbidity and SPM monitoring tool. For this purpose, a novel empirical approach is developed, in which 3D MBES water column and in-situ optical sensor datasets were collected during ship transects to yield an empirical relation using linear regression modeling. This relationship was then used to predict SPM volume concentrations from the 3D acoustic measurements, which were further converted to SPM mass concentrations using calculated densities. Our results show that these converted mean mass concentrations at the Kwinte and Westdiep swale areas are within the limits of the reported yearly averages. Moreover, they are in the same order of magnitude as the measured mass concentrations from Niskin water samples during each campaign. While there is still need for further improvement of acquisition and processing workflows, this study presents a promising approach for converting MBES water column data to turbidity and SPM measurements. This opens possibilities for improving future monitoring tools, both in scientific and industrial sectors.

Ocean Color Remote Sensing of Suspended Sediments along a Continuum from Rivers to River Plumes: Concentration, Transport, Fluxes and Dynamics

This study investigates the capability of high and medium spatial resolution ocean color satellite data to monitor the transport of suspended particulate matter (SPM) along a continuum from river to river mouth to river plume. An existing switching algorithm combining the use of green, red and near-infrared satellite wavebands was improved to retrieve SPM concentrations over the very wide range (from 1 to more than 1000 g.m−3) encountered over such a continuum. The method was applied to time series of OLI, MSI, and MODIS satellite data. Satisfactory validation results were obtained even at the river gauging station. The river liquid discharge is not only related to the SPM concentration at the gauging station and at the river mouth, but also to the turbid plume area and SPM mass estimated within the surface of the plume. The overall results highlight the potential of combined field and ocean color satellite observations to monitor the transport and fluxes of SPM discharged by rivers into the coastal ocean.

Suspended particulate matter in a submarine canyon (Whittard Canyon, Bay of Biscay, NE Atlantic Ocean): Assessment of commonly used instruments to record turbidity

Nepheloid layers with elevated concentrations of suspended particulate matter (SPM) are found throughout the world's oceans. They are generated by both natural processes, involving resuspension of seabed sediment by bottom currents, and anthropogenic sediment resuspension due to bottom trawling, dredging and in the future potentially due to deep-sea mining. These nepheloid layers represent pathways of lateral SPM transport, including lithogenic and biogenic sediment, organic matter, (trace) metals, organic pollutants and plastics. For assessment of the dispersion of these materials, it is essential that SPM mass concentrations can be accurately quantified. However, this is not straightforward as the detected turbidity signal, which is used as a proxy for SPM mass concentration, not only depends on the concentration of particles, but also on physical characteristics of these particles, such as particle size, substance and shape. Here we present a comparative study of turbidity data to assess the potential implications different sensors have on the estimates of SPM mass concentration. Optical backscatter sensors (OBSs), transmissometers and both low- and high-frequency ADCPs were deployed simultaneously in the Whittard Canyon (North Atlantic Ocean), and water samples were collected for quantification of SPM mass concentration and ex-situ particle size analysis. We found that SPM mass concentrations inferred from the transmissometer are easily overestimated in the biologically productive surface layer due to higher light absorption by chlorophyll-bearing phytoplankton, compared to suspended detritic particles. Furthermore, we observed that depending on sensor type some particles are not, or less well, detected. This is due to differences in particle size sensitivities of these sensors towards the diverse range of particle sizes found in the Whittard Canyon, whereby the low-frequency ADCP was most sensitive for coarse-grained material and the high-frequency ADCP and OBSs most sensitive for fine-grained material. In future studies, we suggest to use a combination of different sensors as the use of only one type of sensor could potentially lead to misinterpretation and mis-quantification of particle transport processes and fluxes.

In situ Measurements of the Characteristics of Suspended Particles in the Barents Sea by the LISST-Deep Laser Diffractometer

The key indicators of marine sediment genesis are the particle size distribution (PSD) and volume concentration of suspended particulate matter (SPM). However, their study is not widespread in ship oceanology research. This paper reviews experience in using the LISST-Deep laser particle size analyzer for the study of marine SPM in situ. We present the first data on the volume concentration and PSD of SPM in the Barents Sea obtained during the 75th cruise of the RV Akademik Mstislav Keldysh in June 2019. We carried out an assessment of the adequacy of information display on the polydisperse system composition of the Barents Sea water body, which contains particles of a wide particle size spectrum of differing genesis and shape. This paper gives a regression and correlation analysis of LISST-Deep data with a Wet Labs turbidity meter and Multisizer 3 Coulter Counter, as well as the SPM mass concentration measured by the membrane filtration technique. All of them demonstrated reliable correlations between characteristics of SPM of the Barents Sea. Their correlation and determination coefficients varied from 0.6 to 0.8. The laser diffractometer produces more detailed vertical distributions of marine SPM parameters than does a turbidity meter, especially for euphotic zones. We found a significant correlation of LISST-Deep data with the concentration of dissolved oxygen, which increases for coarse–silty and sandy fractions (47.7–92.6 and 92.6–250 µm, respectively). Also, there is a correlation with SPM composition between parameters as organic carbon concentration and phytoplankton pigments. These correlations give some indirect indications of SPM composition from laser diffractometer measurements.

Effects of fish culture on particulate organic matter in a reservoir-type river as revealed by absorption spectroscopy and fluorescence EEM-PARAFAC

Dam construction and fish culture can change the biogeochemical processes in river, yet their impact on the spectral properties of particulate organic matter (POM) remains to be studied. This was investigated in a reservoir-type river (Minjiang river, SE China) using absorption spectroscopy and fluorescence excitation-emission matrices-parallel factor analysis (EEMs-PARAFAC). Five fluorescent components were identified from POM with PARAFAC. Four components C1–C4 were affected by the seasonal variations of rainfall and runoff, indicating the influences of hydrological condition and terrestrial inputs. The Chlorophyll a concentration (Chl a) correlated significantly with the humic-like C3 (p < 0.05) and the protein-like C4 (p < 0.01), indicating phytoplankton was an important source of C3 and C4. The Chl a and fluorescence intensities of C3–C4 were higher in the fish culture zones than in other areas, and the absorption coefficient a300 and C1–C4 were lower downstream the dam. These results indicated that fish farming in the reservoir probably promoted the production of POM. The a300 and C1 per unit mass of suspended particulate matter (a300/TSM and C1/TSM) correlated significantly with the median particle size (p < 0.01), which might be related to the contribution of micro-phytoplankton. The absorption spectra of POM showed a shoulder peak at ∼280 nm, and its intensity correlated significantly and positively with Chl a (p < 0.01). These results indicated that the peak was probably derived from phytoplankton production. Our results have implications for better understanding the influences of human activities on the dynamics of river POM.

How do particle number, surface area, and mass correlate with toxicity of diesel particle emissions as measured in chemical and cellular assays?

Increasingly stringent particulate matter (PM) emission standards have brought forth engine design improvements, cleaner-burning fuels, and aftertreatment technologies. Reductions in tailpipe PM mass have concomitantly reduced accumulation-mode particle emissions. However, some strategies promote the emission of nucleation-mode particles, which are typically quantified on a number (PN) basis. We previously demonstrated that PN emissions from heavy-duty diesel vehicles equipped with various aftertreatment systems were inversely correlated, and gravimetric PM mass was positively correlated, with two in vitro assays. This present work expands on the analysis of PM mass and PN with in vitro assays to also include four additional PM metrics: suspended PM mass, active particle surface area, aggregate particle surface area, and accumulation-mode particle number. This new analysis shows that like gravimetric PM mass, suspended particle mass and accumulation mode particle number are well correlated with dithiothreitol consumption rate (DTT) and macrophage reactive oxygen species consumption rate (ROS) assays (R2 = 0.61–0.96). Data suggest that PM mass emissions dominated by nucleation-mode particles induce equal or slightly greater toxicity compared to PM mass dominated by accumulation-mode particles. Data also show that among all PM metrics, those used for regulating PM in the United States and Europe, namely gravimetric mass and solid PN are overall most correlated with in vitro toxicity. Moreover, continued exploration of alternative, low-cost, and more appropriate PM metrics is warranted to better understand the reproducibility of these findings on other engine applications, fuel types, and aftertreatment platforms.

Optical properties of size fractions of suspended particulate matter in littoral waters of Québec

Abstract. Mass-specific absorption (ai∗(λ)) and scattering (bi∗(λ)) coefficients were derived for four size fractions (i = 0.2–0.4, 0.4–0.7, 0.7–10, and &gt; 10 µm, λ = wavelength in nm) of suspended particulate matter (SPM) and with samples obtained from surface waters (i.e., 0–2 m depth) of the Saint Lawrence Estuary and Saguenay Fjord (SLE-SF) during June of 2013. For the visible–near-infrared spectral range (i.e., λ = 400–710 nm), mass-specific absorption coefficients of total SPM (i.e., particulates &gt; 0.2 µm) (hereafter aSPM∗) had low values (e.g., &lt; 0.01 m2 g−1 at λ = 440 nm) in areas of the lower estuary dominated by particle assemblages with relatively large mean grain size and high particulate organic carbon and chlorophyll a per unit of mass of SPM. Conversely, largest aSPM∗ values (i.e., &gt; 0.05 m2 g−1 at λ = 440 nm) corresponded with locations of the upper estuary and SF where particulates were mineral-rich and/or their mean diameter was relatively small. The variability of two optical proxies (the spectral slope of particulate beam attenuation coefficient and the mass-specific particulate absorption coefficient, hereafter γ and Svis, respectively) with respect to changes in particle size distribution (PSD) and chemical composition was also examined. The slope of the PSD was correlated with bi∗(550) (Spearman rank correlation coefficient ρs up to 0.37) and ai∗(440) estimates (ρs up to 0.32) in a comparable way. Conversely, the contribution of particulate inorganic matter to total mass of SPM (FSPMPIM) had a stronger correlation with ai∗ coefficients at a wavelength of 440 nm (ρs up to 0.50). The magnitude of γ was positively related to FSPMi or the contribution of size fraction i to the total mass of SPM (ρs up to 0.53 for i = 0.2–0.4 µm). Also, the relation between γ and FSPMPIM variability was secondary (ρs = −0.34, P &gt; 0.05). Lastly, the magnitude of Svis was inversely correlated with aSPM∗(440) (ρs = −0.55, P = 0.04) and FSPMPIM (ρs = −0.62, P = 0.018) in sampling locations with a larger marine influence (i.e., lower estuary).

Investigation of alternative metrics to quantify PM mass emissions from light duty vehicles

We evaluated the performance of six alternative particulate matter (PM) metrics relative to the regulatory gravimetric method during chassis dynamometer testing of five light-duty vehicles over the Federal Test Procedure (FTP) and Supplemental FTP (US06) cycles. Alternative metrics included three mass-based metrics including black carbon (BC), two suspended PM mass using integrated particle size distribution (IPSD) method, and three number/surface-based metrics including total particle number (PN), solid particle number (SPN), and particle active surface area (PS). The results showed PM emissions over the FTP cycle were dominated by solid particles on a mass basis (BC to PM ratio = 0.6 ± 0.5), whereas over the US06 cycle were dominated by semi-volatile particles (BC to PM ratio = 0.2 ± 0.2). Moderate to strong correlations were reported between the gravimetric method and the six alternative metrics for FTP and US06 cycles separately (R2 = 0.69–0.91), i.e. the best-fit lines were strongly dependent upon the cycle. On the other hand, the six alternative PM mass and number metrics exhibited moderate to strong correlations regardless of the test cycle (R2 = 0.66–0.98). We attribute the observed cycle dependency between alternative metrics and the gravimetric mass method to the greater gravimetric sensitivity to organic and semi-volatile PM than for most alternative metrics.

Mutual relationships of suspended sediment, turbidity and visual clarity in New Zealand rivers

Abstract. Many river water quality monitoring programmes do not measure suspended particulate matter (SPM) mass concentrations despite significant interest in its multiple effects on aquatic ecosystems. Regular monthly sampling usually intercepts rivers in baseflow when suspended sediment mass concentrations and fluxes are relatively low and not of particular interest. New Zealand’s National Rivers Water Quality Network (NRWQN) is probably typical in not measuring SPM mass, although visual clarity and nephelometric turbidity are routinely measured. In order to better characterize SPM in NZ rivers, total suspended sediment (TSS) was temporarily added to the NRWQN. Turbidity, visual clarity and TSS are mutually inter-related over all 77 sites, although with considerable data scatter. However, within individual rivers turbidity and visual clarity are typically fairly closely related to TSS and provide fair to excellent surrogates. Therefore, TSS need not be measured routinely because it can be estimated with sufficient precision for many purposes from visibility or turbidity.

Observations of a narrow zone of high suspended particulate matter (SPM) concentrations along the Dutch coast

The objective of the study described in this paper is to localize the transport path of suspended particulate matter (SPM) in the Dutch coastal zone in the southern North Sea. It is known that a large mass of SPM is transported northward from the Strait of Dover, which is however mostly hidden from satellite and other surface measurements. The study area is located at 80km north of the Rhine-Meuse estuary mouth in the far-field plume of the region of freshwater influence (ROFI). We investigate the occurrence and persistence of a turbidity maximum zone (TMZ) in an area closer to the coast than studied in previous observational programs. Shipboard measurements of vertical profiles of SPM concentrations, density and current velocities with a high cross-shore spatial resolution are presented. A turbidity maximum zone is found at a distance between 0.5 and 3km from the coast along 30km of the coastline. Observed concentrations are shown to vary strongly within a tidal cycle, and also between contrasting meteorological conditions in terms of the spring-neap tidal cycle, the significant wave height and the wind force. Temporary stratification is observed during spring tides, and occurs on the ebb phase of the tidal cycle. Cross-shore transports at a transect perpendicular to the coast show an accumulation of SPM in the TMZ within one tidal cycle. Possible mechanisms for this accumulation close to the coast are discussed.

Satellite-derived suspended particulates in the Saint Lawrence Estuary: uncertainties due to bottom effects

Historical regional budgets of suspended particulate matter (SPM) in surface waters (i.e., 0–20 m depth) of the St. Lawrence Estuary (SLE) are not very accurate because of the lack of in situ measurements. The aim of this study was to improve the accuracy of SPM budgets in the SLE based on spaceborne ocean color measurements by investigating one kind of uncertainty on satellite-derived SPM concentration and related with the influence of the bottom depth and (or) bottom reflectivity (hereafter bottom effects) on water-leaving radiance. Theoretical results suggest that bias on optically derived SPM concentration due to bottom effects is greater in the lower estuary and can be up to 36.6% when the water depth is ≤10 m, sediments are dominated by sand, and water turbidity is relatively low (beam attenuation coefficient <1 m−1). Sea-Viewing Wide Field of view Sensor measurements and radiative transfer simulations suggest that bottom effects may introduce an uncertainty of 3.4% or 1.1 × 103 tonnes on 1 m vertically integrated SPM mass over the whole estuary. This error increases (up to 14.5% or 2.9 × 103 tonnes) when optically shallow areas were excluded from the regional SPM budget analysis.

Combining two filter paper‐based analytical methods to monitor temporal variations in the geochemical properties of fluvial suspended particulate matter

AbstractMany of the commonly used analytical techniques for assessing the properties of fluvial suspended particulate matter (SPM) are neither cost effective nor time efficient, making them prohibitive to long‐term high‐resolution monitoring. We present an in‐depth methodology utilizing two types of spectroscopy which, when combined with automatic water samplers, can generate accurate, high‐temporal resolution SPM geochemistry data, inexpensively and semi‐destructively, directly from sediment covered filter papers. A combined X‐ray fluorescence spectroscopy and diffuse reflectance infrared Fourier transform spectroscopy approach is developed to estimate concentrations for a range of elements (Al, Ca, Ce, Fe, K, Mg, Mn, Na, P, Si, Ti) and compounds (organic carbon, Aldithionate, Aloxalate, Fedithionate, and Feoxalate) within SPM trapped on quartz fibre filters at masses as low as 3 mg. Calibration models with small prediction errors are derived, along with mass correction factor models to account for variations in retained SPM mass. Spectral pre‐processing methods are shown to enhance the reproducibility of results for some compounds, and the importance of filter paper selection and homogeneous sample preparation in minimizing spectral interference is emphasized. The geochemical signal from sediment covered filter papers is demonstrated to be time stable enabling samples to be stored for several weeks prior to analysis. Example results obtained during a heavy precipitation event in October 2012 demonstrate the methodology presented here has considerable potential to be utilized for high‐resolution monitoring of SPM geochemistry under a range of in‐stream hydrological conditions. Copyright © 2013 John Wiley &amp; Sons, Ltd.

Can Surface Overflow Rate Predict Particulate Matter Load Capture for Common Urban Drainage Appurtenances?

Urban drainage appurtenances separate particulate matter (PM) and detritus unintentionally and by design. Such PM separation impacts conveyance, treatment, and maintenance practices. This study examines two common appurtenances: Gully pots (or catch basins) and screened hydrodynamic separators (HS). Under steady and controlled physical model testing, PM separation was measured for influent granulometry [particle size distributions (PSDs), PM specific gravity]. Catch basin separation ranged from 40 to 99% for a monodisperse (well-graded sand, SW) PSD and 60 to 83% for a hetero-disperse PSD. With similar testing, a clean HS (to avoid scour dominating PM separation), the HS was also loaded with a heterodisperse sandy silt (ML) and tested as a function of flow, with separation of 40 to 65%, as compared to 70 to 99% for the SW, similar to the catch basin. Physical model results were compared to the surface overflow rate (SOR) model, illustrating that the SOR overestimated PM separation by 3–13%. The SOR was extended to unsteady runoff events. For unsteady loading of an HS with complex hydrodynamics and short residence times, the SOR overpredicted measured PM separation by 3–22% on the basis of PM granulometry. For maintenance and coarse PM load inventories, the SOR can reasonably predict the fate of coarse PM, subject to Type I settling in an HS and catch basin units with similar PM separation behavior. If suspended PM mass dominates the particle size distribution (PSD), is the focus of treatment, or for units with long residence times, the continuous phase hydrodynamics must be coupled with a discrete phase model, requiring analytical or numerical models such as computational fluid dynamics (CFD). For conditions illustrated herein, the SOR is reasonably robust.

Storm influence on SPM concentrations in a coastal turbidity maximum area with high anthropogenic impact (southern North Sea)

Multi-sensor tripod measurements in the high-turbidity area of the Belgian nearshore zone (southern North Sea) allowed investigating storm effects on near bed suspended particulate matter (SPM) concentrations. The data have shown that during or after a storm the SPM concentration increases significantly and that high concentrated mud suspensions (HCMS) are formed. Under these conditions, about 3 times more mass of SPM was observed in the water column, as compared to calm weather conditions. The following different sources of fine-grained sediments, influencing the SPM concentration signal, have been investigated: wind direction and the advection of water masses; the previous history and occurrence of fluffy layers; freshly deposited mud near the disposal grounds of dredged material, navigation channels and adjacent areas; and the erosion of medium-consolidated mud of Holocene age. Based on erosion behaviour measurements of in-situ samples, the critical erosion shear stresses have been estimated for different cohesive sediment samples outcropping in the study area. The results have shown that most of the mud deposits cannot be eroded by tidal currents alone, but higher shear stresses, as induced by storms with high waves, are needed. Erosion can however occur during storms with high waves. Data suggest that in order to obtain very high SPM concentrations near the bed, significant amounts of fine-grained sediments have to be resuspended and/or eroded. The disposal grounds of dredged material, navigation channels and adjacent areas with freshly deposited mud have been found to be the major source of the fine-grained sediments during storms. This result is important, as it suggests that dredging and the associated disposal of sediments have made available fine-grained matter that contributes significantly to the formation of high SPM concentrations and high concentrated mud suspensions.

SEDVEL: An underwater balance for measuring in situ settling velocities and suspended cohesive sediment concentrations

An automated instrument (SEDVEL—Sedimentation Velocity) was developed to directly measure the mass-concentration and the mass-distribution of settling velocities of suspended particulate matter (SPM) in situ. This instrument consists of an underwater balance, which directly measures the variation in time of the immersed weight of particulate matter (PM) as it settles on a plate located at the bottom of a settling tube, under quiescent conditions. SEDVEL operates underwater and samples in situ for deployment periods of a few days. SEDVEL produced consistent and reproducible results when tested both in the laboratory and in the field under SPM dry-concentrations of 5 to 200 mg l − 1 . Errors in the estimates of maximum dry-concentrations from SEDVEL measurements were less than 30% in 69% of the cycles analysed in the laboratory. The corresponding figure for in situ measurements was 50%. These errors are likely related to uncertainties in the calculation of the dry-density of flocs and in the definition of the zero position (ZP) of the SEDVEL balance. The slow settling particles/flocs ( W s < 1 mm s − 1 ) represented 32–98% of the total mass of SPM at two sites of deployment in Cleveland Bay (Australia). Distinct settling behaviours were observed between the two sites and among different tidal stages associated with differences in the floc population; the aggregation of which probably varied as a function of the bottom grain size, shear stress, resuspension, advection and organic content of SPM.

In Situ Samplings and Remote Sensing Measurements to Characterize Aerosol Properties over Southeast Italy

Abstract Ground-based particulate matter (PM) samplers, an XeF Raman lidar operating in the framework of the European Aerosol Research Lidar Network (EARLINET), and a sun/sky radiometer operating in the framework of the Aerosol Robotic Network (AERONET) have been used to characterize vertical profiles, optical and microphysical properties, and chemical composition of aerosols during the 29 June–1 July 2005 dust outbreak that occurred over the central-eastern Mediterranean. Aerosol backscatter coefficient, total depolarization, and lidar ratio vertical profiles revealed that a well-mixed dust layer extending from ∼0.5 to 6 km was present over southeastern Italy on 30 June. Sun/sky radiometer measurements revealed a bimodal lognormal size distribution during all measurement days. The particle volume distribution was found to be well correlated either to the PM mass distribution measured at ground by a seven-stage cascade impactor and to the fine to total suspended PM mass ratio measured by ground-based PM samplers. Scanning electron microscopy and ion chromatography analyses on PM samples revealed that coarse-mode aerosols were mainly made of carbonate, aluminum-silicate, and sea salt particles. Carbon, sulfate, and nitrate particles were the main components of fine-mode aerosols representing more than 50% of the total aerosol load; the significant role of fine-mode anthropogenic particles during a dust event is highlighted. Finally, the potential capabilities of complementary measurements by passive and active remote sensing techniques and in situ observations to retrieve the vertical distribution of the particle number and mass concentration are analyzed and discussed.

Correction in aerosol mass concentration measurements with humidity difference between ambient and instrumental conditions

The influence of humidity is considered on the concentration of the suspended particulate matter (SPM) measured with a β-ray counter. The humidity condition inside a small observatory where the counter is located is, in general, different from the ambient condition outside the observatory. From the measured values, the ambient SPM concentration is derived considering the hygroscopic effect of common aerosol species of sea salt (SS), (NH 4) 2SO 4, NH 4NO 3 and NaNO 3. In a case study conducted during September 2005, temperature and humidity were measured both inside and outside the observatory. The average value of the relative humidity is 48% for inside and 78% for outside, resulting in approximately 53% larger SPM mass concentration after the correction. Accordingly, the value of mass extinction efficiency, which is given by the ratio between the optically measured extinction coefficient and the mass concentration, becomes lower after the correction.

Controlling factors of rhythmic sedimentation processes on an intertidal estuarine mudflat — Role of the turbidity maximum in the macrotidal Seine estuary, France

The aim of this study is to analyse and to quantify the fine particles transfer (i.e.< 63 μm) in the marine part of the man-altered macrotidal Seine estuary (France) by (i) an analysis of a two year time-series of altimeter data, which reveals the bed elevation variations on an intertidal mudflatd located at the Seine mouth and (ii) measurements of the concentration of suspended particulate matter (SPM) contained within the turbidity maximum (TM). The results of this analysis reveal that sedimentation on the mudflat is mainly controlled by the dynamics of the TM such that during the largest spring tides (i.e. tidal ranges > 7.1 m). Then, deposition of SPM from the turbidity maximum becomes important, allowing fine particles to settle on the mudflat, where the current velocities are low (< 0.4 m s − 1 ). On tides of lower range (< 7.1 m) bed elevation levels suggest that erosion of the mudflat surface dominates, however dewatering processes also occur in the soft mud deposits resulting in compaction. During periods of wave activity and periods of increasing river discharge, the mudflat surface experiences rapid erosion. These periods of erosion (sudden or progressive) imply a transfer of fine-grained material from the mudflat surface back into the TM. The long term (∼ 22 months), high frequency (1 measurement every 10 min) and high resolution (0.6 mm) dataset obtained from the altimeter allows quantification of the volume of material exchanged between the intertidal area and the estuarine standing stock of SPM. The maximum of deposition on the studied mudflat during the study was of 27 cm, with highest deposition occurring after the periods of highest river flow and implying that between 25 and 40% of the maximum estimated mass of SPM held within the estuarine TM (300,000–500,000 T) had been temporarily deposited on the mudflat. Likewise following periods of resuspension by wave activity, bed elevations reduced by an order of ∼ 1 cm, suggesting a release of between 1–1.5% of the TM load from the mudflat back into suspension. The study shows that lateral exchanges of sediment between the intertidal reaches of the estuary and the water column are an important part of the sediment budget, and that the supply of sediment available for deposition (i.e. the TM) has a causal relationship with sedimentation rates experienced by intertidal mudflats.

Optical backscatter of marine flocs

Marine flocs (defined here as aggregated particles >10 μm diameter) derived from phytoplankton culture ( Phaeodactylum tricornutum; PT) and water-based drilling mud (WBDM) waste were generated in an enclosed upwelling system in order to examine how optical backscatter coefficients at six wavelengths changed as flocs matured. Equilibrium was reached after death of the phytoplankton cells and was identified as a consistent particle projected-area concentration of flocs (>10 μm diameter) despite compensating changes in the number and average size of flocs. As the suspension of flocs matured, the particle backscatter coefficients at six optical wavelengths increased as a function of increasing particle projected-area concentration, despite a drop in the mass of suspended particulate matter (SPM). In this flocculating suspension, the mass of suspended particles and the particle projected-area concentration were not co-variates. These results indicate that the strong response of optical backscatter (OBS) to particle size in many previous studies may simply be due to the inappropriate use of weight concentration as the independent variable, rather than particle projected-area concentration.