Mass Balance Research Articles

Investigating the Operational Feasibility of Waste Management at Integrated Waste Management Sites in Balikpapan City

Referring to the Balikpapan City Medium-Term Development Plan for 2021-2026, the percentage of waste transported to the Final Waste Processing Site (FWPS) is 75.45%, which is higher than the percentage of waste management. As of now, there are 2 Integrated Waste Management Sites (IWMS) in Balikpapan, namely MRF and ITF. Based on data from 2019, waste management at MRF decreased by 51.14%. Meanwhile, ITF only utilizes 25.98% - 31.31% of total incoming waste, with the remainder being sent to Manggar FWPS. This decline in performance is also related to the deteriorating condition of approximately 62% of waste management infrastructure in Balikpapan, so evaluation of the operational aspects of waste management becomes a crucial factor in addressing this issue. In addition, the ideal condition of waste management according to standards serves as the main indicator in assessing the performance of waste management. This research aims to evaluate operational aspects of waste management at Balikpapan IWMS by applicable regulations. Analysis methods used are mass balance analysis and operational performance analysis. Research findings show that waste management at IWMS Balikpapan City can reduce the volume of waste in Balikpapan City. However, the operational performance of MRF did not meet established standards, especially in terms of waste removal and processing systems, with a score of 19. On the other hand, ITF is considered sufficient by provisions of PUPR Minister Regulation Number 03 of 2013 and Indonesian National Standard 19-2454-2002 with a score of 23.

New stability indicating RP-HPLC methods for the determination of related substances and assay of trametinib acetic acid: a mass balance approach.

New stability indicating related substances and assay methods for trametinib acetic acid by RP-HPLC have been developed and validated through forced degradation and mass balance studies for the first time. In related substances (RS) method, trametinib acetic acid was successfully separated from its six related substances namely, cyclopropanamide impurity, desiodo trametinib, desacetyl trametinib, trione acetamide intermediate, trione intermediate, and trione PTSA intermediate using YMC-Triart C18 (150 × 4.6mm, 3µm) column. Orthophosphoric acid (0.15%) in water was used as buffer. Gradient elution was programmed using mobile phase-A (buffer and acetonitrile mixture in 80:20 v/v ratio) and mobile phase-B (buffer and acetonitrile mixture in 20:80 v/v ratio). Acetonitrile and methanol mixture (1:1 v/v) was used as diluent. Flow rate, injection volume, column temperature, and wavelengths were kept as 0.8mL/min, 10µL, 55°C, and 240nm, respectively. Desacetyl trametinib and cyclopropanamide impurity were identified as potential degradation impurities in acid and base degradation conditions, respectively. Assay method specific to above six related substances was also developed. Assay of forced degradation samples was also determined, and the mass balance was established by adding total impurities formed in RS method to assay of trametinib acetic acid.

Complementary Foods Formulated from Orange-flesh Sweet Potato, Soybean, and Date Palm Flour Blends Improves the Proximate, Rheological and Sensory Properties of Children’s Formulas

This study evaluated the proximate, rheological and sensory properties of complementary foods produced from orange flesh sweet potato, soybean and date palm flour blends. Complementary foods were produced from orange flesh sweet potato (OFSP), soybean and date palm flour blends. The samples were formulated by material balancing with all samples having 16% protein/ 100g. The samples were coded as CON, CFA, CFB, CFC, CFD and CFE with sample CON being the control. The samples were subjected to rheological and sensory analysis using standard method. Their proximate composition were; moisture (2.51-7.38%), ash (2.27-3.02%), fibre (2.11-4.22%), fat (9.13-10.11%), protein (15.12-16.11%), and carbohydrate (63.06-65.01%). Rheological properties of the gruels were as follows; consistency index (m) (90.57-186.21 Nsn/m2), Flow behaviour index (n) (0.256-0.411), Coefficient of regression (r2) (0.9765-0.9928) and Standard error (0.318-0.405). The sensory attributes gave the following results; appearance (7.77- 8.07), aroma (7.20-8.63), taste (6.80- 8.23), mouth feel (6.87- 8.27), and overall acceptability (6.80- 8.33) and these results when interpreted on appoint hedonic scale. Higher scores generally indicated better sensory attributes and overall acceptability of the food formulation which was observed in sample CFB and CON. There were significant differences between most of the bread samples at (p< 0.05).

Extraction recovery and speciation of selenium in Se-enriched yeast.

The complete characterization of selenium-enriched yeast in terms of selenium species has been the goal of extensive research for the last three decades. This contribution addresses the two outstanding questions: the mass balance of the identified and reported selenium species and the possible presence of inorganic selenium. For this purpose, four procedures have been designed combining, in diverse order, the principal steps of selenium speciation analysis in Se-rich yeast: extraction of the Se-metabolome, derivatization of cysteine and Se-cysteine (SeCys) residues, proteolysis, and definitive Se recovery using SDS extraction, followed by mineralization. The recovery of selenium in each step and its speciation were controlled by ICP MS and by reversed-phase HPLC-ICP MS, respectively. The study, carried out for the SELM-1 reference material, demonstrated the presence of about 10% of inorganic selenium and a serious risk of losses of SeCys during derivatization and proteolysis. As result of our work, we postulate the following values for SELM-1: Se-metabolome fraction (SeMF) 14.8 ± 0.7%; total selenomethionine (SeMet) 66.2 ± 2.7% (including ca. 1.5% SeMet present in the SeMF); total SeCys 12.5 ± 1.5% (including 2% of SeCys present in the Se-MF); total inorganic selenium 9.7 ± 1.7%, accounting for > 99.8% of the selenium.

Dissolved Cu isotope compositions in hydrothermal plumes over back-arc volcanoes in the Northeast Lau Basin, Southwest Pacific Ocean

Seafloor hydrothermal venting may be an important source of marine Cu and affect the biogeochemical cycling of Cu in the oceans. The distribution of Cu and its isotope compositions (δ65Cu) can provide insight into seafloor hydrothermal processes and their role in the mass balance of global Cu. To date, there are no published Cu isotope data for hydrothermal plumes and very few reports on Cu concentration distributions. This study presents both Cu concentrations and dissolved Cu isotope (δ65Cu) in hydrothermal plumes from back-arc volcanoes in the Northeast Lau Basin. The dissolved Cu (dCu) concentrations range from 2.14 to 5.66 nM most of which are higher than the deep seawater concentrations. However, the concentrations for some plume samples were lower than the deep seawater dCu concentrations due to adsorption onto particles in the plumes. The δ65Cu of hydrothermal plumes vary from 0.25 to 1.05 ‰. As plumes dispersed, the Cu isotopes from high-temperature Mata Fitu and Mata Ua vents shifted towards light values. In contrast, the δ65Cu in plumes from low-temperature East Mata and West Mata vents show increasingly higher values with plume dispersal. Rayleigh distillation models are built based on the adsorption of dCu onto Fe particles and complexation with organic ligands to describe the dCu isotope evolution in hydrothermal plumes. The results suggest that the adsorption and organic complexation may be the likely explanations for the observed dCu isotope compositions in plumes from high- and low-temperature venting, separately, besides the mixing with background seawater. Our measured δ65Cu in three fluid samples (0.08, 0.09 and 0.20 ‰) are lower than that of the characterized sinks (∼0.3 ‰) in the oceans, indicating that hydrothermal fluids might be a source of light Cu isotopes. However, the δ65Cu (0.53 ‰ on average) in plume samples are higher than 0.3 ‰ and these seafloor hydrothermal plumes do not seem to be a source of light Cu isotope of dCu, at least near the venting sites. Our study first reveals the Cu isotope compositions and evolution in hydrothermal plumes and provides new hints about the impact of seafloor hydrothermal venting on the modern oceanic Cu isotope budget.

Washing machine filters to mitigate microplastics release: Citizen science study to estimate microfibers capture potential and assess their social acceptability

The accumulation of microplastics in the environment, particularly due to the significant contribution of synthetic clothing washing water, leads to a need for developing source-based retention solutions. The project's objective is to assess the capability of washing machine filters to capture microfibers from domestic wastewater under real laundry conditions. This involves developing a protocol for quantifying microfibers tailored to washing machine lint samples, estimating the potential microfiber capture by washing machine filters, and evaluating the social acceptability of using such filters in households. Volunteers were recruited and they used their washing machines normally, collecting lint in the filter over a 6-month period and documenting information for each load. Various reagents were tested using plastic controls and lint samples to select the most efficient one for removing organic matter without affecting microplastics. Microscopic visual alterations, chemical signatures via FTIR, and the efficacy of the digestion protocol were assessed through mass balance and visual counting. After discarding digestion protocols affecting plastic integrity, those ensuring the most efficient mass loss of organic matter were identified as H2O2 30 % for 5 days at room temperature (RT), NaOCl 3 % for 24 h at RT, and H2O2 30 % at 40 °C for 24 h. Polyester, acrylic, and polyamide controls were tested with NaOCl 3 % for 24 h and H2O2 30 % for 5 days, showing no changes in SEM images. The FTIR successfully recognized the chemical signature. More significant alterations on positive samples (cotton and cellulose) were observed after NaOCl exposure. The mean mass of microfibers remaining after digestion was estimated at 4.62 mg per liter of washing water or 61 mg/kg of washed garment. The survey revealed that 67.8 % of volunteer participants found the filter installation challenging, and 21.4 % had to hire a plumber, highlighting potential challenges associated with implementing washing machine filters on a large scale.

Drivers of change behind the spatial distribution and fate of typical trace organic pollutants in fresh waste leachate across China

There have been growing concerns regarding the health and environmental impacts of trace organic pollutants (TOPs). However, fresh leachate from municipal solid waste (MSW) has been overlooked as a potential reservoir of TOPs. Therefore, we investigated 90 legacy and emerging TOPs in fresh leachate from 14 provinces and municipalities in China. Additionally, the fate and final discharge impacts of TOPs in 14 leachate treatment systems were analyzed. The results revealed that the detection rate of 90 TOPs was over 50 % in all samples. Notably, polychlorinated biphenyls, banned for 40 years, were frequently detected in fresh leachate. The concentration of pseudo-persistent TOPs (105–107 ng/L) is significantly higher than that of persistent TOPs (102–104 ng/L). Spatial distribution patterns of TOPs in fresh leachate suggest that economy, population, climate, and policies impact TOPs discharge from MSW. For example, economically developed and densely populated areas displayed higher TOPs concentrations, whereas warmer climates facilitate TOPs leaching from MSW. We confirmed that waste classification policies were a key driver of the decline in multiple TOPs in leachate. Mass balance analysis shows that the final effluent and sludge from current dominant leachate treatment systems contain refractory TOPs, especially perfluoroalkyl acids, which must be prioritized for control. This paper was the first comprehensive investigation of multiple TOPs in fresh leachate at a large geographic scale. The factors affecting the occurrence, spatial distribution, and fate of TOPs in fresh leachate were revealed. It provides a valuable reference for the establishment of policies for the management of TOPs in MSW and the associated leachate.

Isotope Evidence for Rice Accumulation of Newly Deposited and Soil Legacy Cadmium: A Three-Year Field Study.

Biogeochemical processes of atmospherically deposited cadmium (Cd) in soils and accumulation in rice were investigated through a three-year fully factorial atmospheric exposure experiment using Cd stable isotopes and diffusive gradients in thin films (DGT). Our results showed that approximately 37-79% of Cd in rice grains was contributed by atmospheric deposition through root and foliar uptake during the rice growing season, while the deposited Cd accounted for a small proportion of the soil pools. The highly bioavailable metals in atmospheric deposition significantly increased the soil DGT-measured bioavailable fraction; yet, this fraction rapidly aged following a first-order exponential decay model, leading to similar percentages of the bioavailable fraction in soils exposed for 1-3 years. The enrichment of light Cd isotopes in the atmospheric deposition resulted in a significant shift toward lighter Cd isotopes in rice plants. Using a modified isotopic mass balance model, foliar and root uptake of deposited Cd accounted for 47-51% and 28-36% in leaves, 41-45% and 22-30% in stems, and 45-49% and 26-30% in grains, respectively. The implications of this study are that new atmospheric deposition disproportionately contributes to the uptake of Cd in rice, and managing emissions thus becomes very important versus remediation of impacted soils.

Primarily experimental study of the energy performances of a humidification-dehumidification seawater desalination system coupled with a heat pump

The study presented in this article explores a comprehensive analysis of a humidification-dehumidification (HDH) seawater desalination system integrating a heat pump for heating seawater intended for distillation, and incorporates additional condensation plates supplied with cold seawater. This system was the subject of an experimental investigation to simultaneously evaluate the energy performance of the heat pump and the thermal behavior of the desalination unit, focusing on seawater and condensation wall temperatures, as well as the stratification of temperatures of humid air inside the unit compared to the evaporation surface. Experimental results showed an average daily production of distilled water of approximately 32.75 kg/m² per day, with an electrical consumption of 37.68 kWh/day, which was reduced to 26.72 kWh/day through the integration of photovoltaic solar energy. Based on heat and mass balance equations of all the system’s components, the study used a detailed thermodynamic model. The system's energy performance was analyzed by calculating the coefficient of performance (COP), the specific energy consumption (SEEC), and the gain output ratio (GOR), reflecting the overall energy efficiency of the HDH system coupled with the heat pump, as well as the recovery ratio (RR), indicating the proportion of the recovered water compared to the input water.

Long-term measurements of aerosol composition at rural background sites in France: Sources, seasonality and mass closure of PM2.5

Fine particulate matter (PM2.5) was monitored at five rural background locations in France from 2012 to 2021. Annual PM2.5 ranged from 5 to 15 μg m−3, all sites repeatedly exceeding the 2021 annual World Health Organization guideline. Chemical speciation including organic and elemental carbon (OC, EC), secondary inorganic aerosols (SIA: NO3−, SO42−, NH4+) and other major water-soluble ions (Cl−, Na+, Mg2+, Ca2+, K+) were monitored on 24-h filters covering 14% of the year. A source apportionment of OM was undertaken based on fine potassium and using representative ratios for domestic biomass burning (BB) and fossil fuel (FF) emissions. The latter dominated the EC fraction (55–60%) while BB was the main primary source of OM (27–54%). The average mass balance of PM2.5 at the French rural background atmospheric sites was: secondary organic aerosol (18–35%), BB (17–27%), non-sea-salt sulphate (12–17%), nitrate (6–22%), ammonium (7–11%), FF (4–6%), mineral dust (3–9%) and sea salt (1–2%). Secondary aerosols were the main component of PM2.5 through all seasons, with SIA dominating in spring episodes. The contribution of OM to PM2.5 was larger at the southern sites whereas the contribution of SIA was larger at the northern sites. The mean OC/EC ratio and the good correlations between OC, EC, and fine potassium suggested that BB was the main primary source contributing to carbonaceous aerosols, 27–54% to total OM depending on the site; and also, to PM2.5 (17–27%). Stronger regulations of OM sources including BB, nitrate from combustion, and ammonium from agricultural sources are needed to reduce PM2.5 at rural background sites on an annual and episodic basis, respectively.

Design optimization of cubic-shaped pressurant tank for CubeSat propulsion system

From a technical and economic point of view, cold gas propulsion for nanosatellites is one of the more rational systems. There is a problem, however: the optimal spherical shape for a high-pressure vessel only takes up half the cubic volume of the CubeSat unit. To increase the volume, it is proposed to switch to a cubic-shaped tank. The aim of this work is to synthesize the more rational structural design of a pressurant tank that fits within a cubic constraint, which provides the perfect balance between the mass of the structure and the delta-V budget available for the propulsion system. The proposed variants are as follows: a set of four cylinders with spherical bottoms; 14 equal spheres arranged in a face-centered cubic packing; a thin-walled cube supported by ribs, the location and parameters of which provide the smallest mass of the structure; a cube, the reinforcement scheme of which is calculated using topology optimization method; an original polyspheric and bypass design schemes where the filling of the volume of the cube is created by a set of spherical and cylindrical shells of different radii. All the considered vessel variants can be obtained using additive technologies, such as selective laser sintering. For each variant, the internal volume and mass of the vessels were obtained, as well as the delta-V budget, taking into account the mass of the tank and the mass of the stored gas. The analysis of the results reveals that there are two structures that are more rational. The new bypass scheme provides the largest delta-V budget, but it has a 1.6 times larger mass than the initial spherical vessel design. It should be noted that the difference in vessel mass is not crucial for CubeSat form factor satellites. Choosing a rational design may require a larger delta-V budget. The possibility of increasing the reserve delta-V of the CubeSat cold gas propulsion system by 25–35 % due to the transition from a spherical to a cube-shaped tank has been demonstrated. At the same time, the mass of the tank structure increases by 1.6–6.3 times, which can be considered an acceptable price for increasing the efficiency of the propulsion system. The new bypass scheme offers the optimal balance of mass and delta-V reserve.

Modeling moisture change of packaged dry tablet dosage forms under consumer use condition

A simple mathematical model based on product’s moisture sorption isotherm and package’s moisture transmission was developed to predict moisture content of dry solid tablets during consumers’ use, which is useful for determination of in-use shelf life (ISL) or secondary shelf life. The moisture increase depending on amount of product remaining in the package was accounted for in the mass balance equation on the package. The model was first verified by literature data of desiccant canisters in a plastic bottle of high density polyethylene exposed to two environmental conditions (25 °C and 60% relative humidity (RH); 40 °C and 75% RH) simulating in-use of removing one canister each day. Then an experimental work was conducted on dry refresher candies in a polyethylene terephthalate bottle at 25 °C with two tablets taken out every day, which confirmed the model’s capability to predict the product moisture content during in-use storage of 76% and 90% RH. Its use can provide science-based accurate determination of ISL, which may work as consumer guideline. The model is also expected to be helpful for recommending management scheme of whole product life.

Propagation and evaporation of contaminated droplets, emission and exposure in surgery environments revealed by laser visualization and numerical characterization

The contaminated liquid mixture containing mucosalivary fluid and blood would be aerosolized during medical procedures, resulting in higher-risk exposures. The novelty of this research is integrating laser visualization and numerical characterization to assess the propagation and evaporation of contaminated droplets, and the interactive effects of humidity and temperature on exposure risks will be numerically evaluated in surgery environments. The numerical model evidenced by experiments can predict the mass balance of ejection droplets, the minimum required fallow time (FT) between appointments, and the disinfection region of greatest concern. Around 98.4 % of the ejection droplet mass will be removed after the cessation of ultrasonic scaling, while the initial droplet size smaller than 72.6μm will dehydrate and become airborne. The FT recommendation of 30 min is not over-cautious, and the extended FT (range of 28–37 min) should be instituted for low temperature (20.5 °C) and high humidity levels (60 %RH). The variation of the temperature and humidity in the range for human thermal comfort has little influence on the area of the disinfection region (0.15m2) and the cut-off size (72.6μm) of droplet deposition and suspension. This research can provide scientific evidence for the guidelines of environmental conditions in surgery rooms.

Development of a dissolution method for analyzing the elemental composition of fuel debris using sodium peroxide fusion technique

ABSTRACT A dissolution method for analyzing the elemental composition of fuel debris using the sodium peroxide (Na2O2) fusion technique has been developed. Herein, two different types of simulated fuel debris (such as solid solution of (Zr,RE)O2 and molten core – concrete interaction products (MCCI)) were taken. At various temperatures, these debris samples were subsequently fused with Na2O2 in crucibles, which are made of different materials (Ni, Al2O3, Fe, and Zr). Then, the fused samples are dissolved in nitric acid. Effects of the experimental conditions on the elemental composition analysis were evaluated using inductively coupled plasma-atomic emission spectroscopy (ICP – AES), which suggested the use of a Ni crucible at 923 K as an optimum testing condition. The optimum testing condition was then applied to the demonstration tests with Three Mile Island unit-2 (TMI-2) debris in a shielded concrete cell, thereby achieving complete dissolution of the debris. The elemental composition of TMI-2 debris revealed by the proposed dissolution method has good reproducibility and has an insignificant contradiction in the mass balance of the sample. Therefore, this newly developed dissolution method can be effectively utilized in practical applications by dissolving fuel debris and analyzing its elemental composition.

Inorganic carbon migration and transformation in groundwater evaporation discharge area

During groundwater evaporation discharge, a series of carbon-related water-rock interactions potentially impact the terrestrial carbon cycle significantly. However, the migration and transformation of carbon in groundwater evaporation discharge area remain inadequately understood. Using the Tumochuan Plain in Inner Mongolia as a case study, this paper constructs a carbon balance equation for groundwater evaporation discharge area by employing mass balance principles and hydrogeochemical simulation methods, thereby analyzing the mechanisms of carbon diversion during groundwater evaporation. The result showed that evaporation discharge area of Tumochuan Plain was a ‘carbon sink’. Carbon emission rate to atmosphere in study area was 7.35 g/(m2·a), while carbon fixation rate by calcite precipitation and dissolved inorganic carbon (DIC) into groundwater was 37.15 g/(m2·a). The precipitation of calcite and the dissolution of dolomite were the main water-rock interactions controlling the migration and transformation of DIC. The carbon absorbed by dolomite dissolution reached 21,698.02 t/a (30.56 g/(m2·a)), offsetting a significant portion of the CO2 emitted during calcite precipitation. In addition, the calcium released by the dissolution of dolomite and anorthite effectively promoted the precipitation of calcite, which was the primary factor for groundwater to become a carbon sink in this area.

Lithium isotopic records of anthropogenic activity in the Xiaoqing River basin, eastern China

The environmental impact of the discharge of lithium (Li) by anthropogenic activity has been overlooked. By analyzing Li concentrations and isotope compositions (δ7Li) of water and sediment samples, this study evaluates the influence of anthropogenic Li discharge on the Xiaoqing River and Laizhou Bay, which are heavily polluted areas in China. High Li concentrations of the river water (up to 7.8 μmol/L) should be linked to anthropogenic Li discharge. However, no profound δ7Li anomalies were observed, preventing identification of the exact discharge sources. In the river sediments, Li concentrations (19.0–45.0 μg/g) were weakly correlated with Zn, Cu, and Cr concentrations, whereas δ7Li values ranged from 0.6 ‰ to 13.9 ‰ with high values being accompanied by high contents of total organic carbon and heavy Cr isotope compositions (δ53Cr). All these point to significant influence of anthropogenic activity on the Li budget of river sediments. A simple mass balance calculation indicates that smelters, Li-bearing therapeutic drugs, and secondary Li-ion batteries are the main anthropogenic Li sources. In contrast to river sediments, marine sediments in the Laizhou Bay were broadly homogeneous at both spatial and temporal scales, indicating no significant influence of anthropogenic Li discharge. Overall, our data indicate that Li isotope systematics in river sediments, especially sediments near intense anthropogenic activity, are effective at tracing potential Li pollution and can help obtain accurate results for environmental inspection.

Energy assessment and heat integration of biofuel production from bio-oil produced through fast pyrolysis of sugarcane straw, and its upgrading via hydrotreatment

Sugarcane processing is one of the most important economic activities in Brazil, producing ethanol and sugar for domestic and international markets. Utilising the lignocellulosic residues of this industry, specifically bagasse and straw, would increase the second-generation biofuel production without increasing the sugarcane planted area. Among the processes available, the fast pyrolysis is a thermochemical conversion process that produces mainly bio-oil, a liquid with several advantages over solid biomass, regarding transportation, pumping, storage, and handling. Moreover, the bio-oil can be upgraded to obtain biofuels of higher added-value. Among feasible upgrading technologies, the hydrotreatment is one of the most promising methods for eliminating the reactive functionalities of the bio-oil by removing oxygen or cracking large molecules in the presence of hydrogen; however, this comes at the expense of a significant hydrogen consumption. Thus, the aim of this study is to evaluate the biofuel production through the fast pyrolysis of sugarcane straw, followed by the upgrading of the produced bio-oil via hydrotreatment. The evaluation is carried out by way of energy and mass balances of the processes, performed using the software Aspen Plus. Furthermore, the possibilities of integrating the bio-oil production and upgrading into the conventional ethanol and sugar production process will also be assessed through heat integration, applying the Pinch analysis. Results showed the potential for renewable gasoline and diesel production with yields of 0.086 kg/kg of dry straw and 0.08 kg/kg of dry straw, respectively. Additionally, integrating the pyrolysis process, including the bio-oil upgrading, into the ethanol production process can achieve a liquid fuel production (ethanol, gasoline and diesel) of 2289.8 MJ/t cane, which represents an increase of 29 %, while the surplus electricity increases in 5.3 %, when compared to the conventional ethanol production plant.

Advancing architectural frameworks for vibration signature classification in rotating machinery

Advancements in data-driven predictive maintenance have significantly improved digital twin applications for rotating machinery, offering robust solutions for smart manufacturing challenges. These improvements are crucial since equipment failures can cause extensive and costly disruptions to both maintenance schedules and operations. As precision and reliability are critical in production processes, undetected fluctuations in operating frequencies can swiftly escalate to complete part failure, leading to prolonged repairs and productivity loss. This study explores an integrated dataflow pipeline, specifically through Siemens’ MindSphere, to enable continuous predictive maintenance and enhance data acquisition and management. Particularly, conditions such as normal operation, mass balance, rotating imbalance, and mechanical looseness are classified using support vector machine (SVM), neural network (NN), and K-Nearest Neighbor (KNN) methods for the purpose of comparing results. Our results highlight the efficacy of ensemble techniques in collecting and diagnosing vibration signatures, thereby enabling proactive maintenance. To classify various failure signatures, we have proposed a framework to interpret time-series and frequency-dependent data for determining failure types. This research exemplifies how merging data-driven methods with digital twin can improve the accuracy and reliability of condition monitoring. Additionally, we introduce a cloud-based architecture for the diagnosis of rotating machinery, utilizing Application Programming Interface (API) configurations, and develop a real-time dashboard for streaming and visualizing classified data, fostering immediate and informed decision-making.

Using net anthropogenic nutrient inputs at fine spatial scales benefits decision‐making in watersheds to protect water quality

Abstract Excessive nutrient loadings from various human activities on land to inland and coastal waters result in water quality degradation through cultural eutrophication. Accurately identifying and quantifying the main nitrogen and phosphorus sources on land is essential to implement proper intervention strategies to reduce loadings in order to preserve water quality for the long term. The Net Anthropogenic Nitrogen/Phosphorus Inputs (NANI/NAPI) mass balance approach has successfully been used to quantify nutrients added on land to sustain human activities and predict the fraction exported to water. However, the rich detail of information used to generate the mass balance is typically merged and upscaled to whole watersheds, averaging out highly heterogeneous patterns on land, which would be key to identify regions that disproportionately load nutrients to receiving waters. Here we present NANI and NAPI at increasingly finer scales (watershed, county, and municipal) in eight catchments of the Saint‐Lawrence Basin in Québec, Canada, and compare input changes between two different decades (1981 and 2021). In 2021, NANI ranged from 828 to 6602 kg km−2 at the watershed scale whereas the range at the municipal one was much greater from near 0 to 27,413 kg km−2, highlighting the importance of using the municipal scale to pinpoint specific regions of high inputs. We then show how partitioning individual NANI components (the same could be done for NAPI) could reveal the dominant input type among urbanisation, crop‐intensive, or livestock‐intensive agriculture, which can help decision makers choose the most effective intervention strategy based on dominant input type. Finally, we discuss how information derived over time can further be used to enhance understanding around mitigation strategies. Policy implications. The use of the detailed components of NANI and NAPI at the finest scale possible provides relevant quantitative information and acts as an effective communication tool between scientists and decision makers. We suggest that the use of this approach can better enable targeted nutrient reduction strategies based on scientific evidence to protect water quality.

The Varied Role of Atmospheric Rivers in Arctic Snow Depth Variations

AbstractThe state and fate of snow on sea ice are crucial in the mass and energy balance of sea ice. The function of atmospheric rivers (ARs) on snow depth over sea ice has not been measured thus far, limiting the understanding of the mechanism of snow depth changes. Here, the effect of ARs on snow depth changes was explored. We found that increased AR frequency is responsible for winter‐autumn snow accumulation and spring‐summer snow melting. The 2 m air temperature (T2m), rainfall, snowfall, mean net longwave radiation (NLR), mean net shortwave radiation (NSR) and cloud radiative effect (CRE) during ARs explain the changes in snow depth triggered by AR occurrence. This work helps us understand how ARs affect snow depth changes through related physical processes, promotes an understanding of climate systems and provides a theoretical basis for snow treatment in sea ice models.