Masaya Volcano Research Articles

Behaviors of Redox-Sensitive Components in the Volcanic Plume at Masaya Volcano, Nicaragua: H2 Oxidation and CO Preservation in Air

Multi-disciplinary volcanic gas observations, including FTIR, Multi-GAS, and Alkali filter pack, were made at Masaya Volcano, Nicaragua, in January 2018. During the observation period, a lava lake was present, and the majority of the volcanic gases were likely emitted directly from the lava without any hydrothermal alterations. It is expected that the volcanic gas composition reflects the conditions of the magma, exhibiting a high equilibrium temperature. The fractions of the major components showed good consistency with previous studies; however, we found the fraction of the combustible components (such as H2) were lower than expected. The RH [log(H2/H2O)] value was measured to be less than −6, compared to the equilibrium RH value calculated to be around −3 from the iron speciation. The equilibrium calculations suggest oxidation of the volcanic gases by high-temperature mixing with the air once they are emitted from the lava lake, lowering the H2 content of the plume. In contrast to H2, a small amount of CO, another combustible species, was detected and the derived CO2/CO ratio of ca. 1,000 is consistent with the equilibrium magmatic value. This indicates that CO is kinetically inert compared to H2. Our findings suggest that volcanic gases in the Masaya plume do not preserve information from when the gases were originally in equilibrium with the high-temperature surrounding magma.

Effectiveness of low-cost air quality monitors for identifying volcanic SO₂ and PM downwind from Masaya volcano, Nicaragua

Gas and particulate matter (PM) emissions from Masaya volcano, Nicaragua, cause substantial regional volcanic air pollution (VAP). We evaluate the suitability of low-cost SO2 and PM sensors for a continuous air-quality network. The network was deployed for six months in five populated areas (4-16 km from crater). The SO2 sensors failed and recorded erroneous values on multiple occasions, likely due to corrosion, requiring significant maintenance commitment. The PM sensors were found to be robust but data required correction for humidity. SO2 measurements could not be used as stand-alone tools to detect occurrence of VAP episodes (VAPE), but SO2/PM correlation reliably achieved this at near-field stations, as confirmed by meteorological forecasts and satellite imagery. Above-background PM concentrations reliably identified VAPE at both near-field and far-field stations. We suggest that a continuous network can be built from a combination of low-cost PM and SO2 sensors with a greater number of PM-only sensors.

Assessing the effectiveness of low-cost air quality monitors for identifying volcanic SO2 and PM downwind from Masaya volcano, Nicaragua

Gas and particulate matter (PM) emissions from Masaya volcano, Nicaragua, cause substantial regional volcanic air pollution (VAP). We evaluate the suitability of low-cost SO2 and PM sensors for a continuous air-quality network. The network was deployed for six months in five populated areas (4–16 km from crater). The SO2 sensors failed and recorded erroneous values on multiple occasions, likely due to corrosion, requiring significant maintenance commitment. The PM sensors were found to be robust but data required correction for humidity. SO2 measurements could not be used as stand-alone tools to detect occurrence of VAP episodes (VAPE), but an SO2/PM correlation reliably achieved this at near-field stations, as confirmed by meteorological forecasts and satellite imagery. Above-background PM concentrations reliably identified VAPE at both near-field and far-field stations. We suggest that a continuous network can be built from a combination of low-cost PM and SO2 sensors with a greater number of PM-only sensors.

Quantitative analysis of persistent volcanic fluoride risk reveals differential exposure pathways for adults and children downwind of Masaya Volcano, Nicaragua

Quantitative analysis of persistent volcanic fluoride risk reveals differential exposure pathways for adults and children downwind of Masaya Volcano, Nicaragua

Magmatic signature in acid rain at Masaya volcano, Nicaragua: Inferences on element volatility during lava lake degassing

Major, minor and trace element concentrations of single rainfall events were investigated at Masaya volcano (Nicaragua) in order to determine the relative contributions of volcanogenic elements. Most of the samples were collected in the summit area of the volcano around the Santiago crater, and two samples, representative of the local background, were collected at a 4.3 km upwind site. Samples from the summit are very acidic with pH down to 2.14 and contain large amounts of volcanogenic elements that can be clearly distinguished from the local background. These elements are released into the atmosphere from the continuously degassing lava lake of the Santiago crater, Masaya volcano. The emissions result in a volcanic plume that includes solid particles, acidic droplets, and gaseous species. The plume-rain interaction imprints the chemical signature of the volcanic emissions in falling raindrops. The most acidic gases (e.g. HCl and HI) readily dissolve in water, and so their ratio in rain samples reflects that of the volcanic plume. The transport of HF is mediated by the large amount of silicate particles generated at the lava–air interface. SO2 is only partially converted into H2SO4 that dissolves in water. The refractory elements dissolved in rain samples derive from the dissolution of silicate particles, and most of them (Al, Mg, Ca, Fe, Be, Ti, Mn, and Sr) are present at exactly the same molar ratios as in the rocks as well as rare earth elements (REEs). By contrast, Li, Na, K, Cr, Ni, Cu, Zn, Rb, Cd, Sb, Te, Cs, Tl, Pb, and Bi are enriched relative to the whole-rock composition, suggesting that they are volatilized during magma degassing. After correcting for the dissolution of silicate particles, we can define the relative volatility of these elements. The comparison with other volcanoes on the Pb emissions highlights the effect of oxygen fugacity in determining its volatility.

Top–down control on eruptive style at Masaya volcano inferred from melt composition

Highly explosive Plinian eruptions of basaltic magma are enigmatic because low melt viscosities should inhibit such eruptive style. Masaya volcano, Nicaragua, is a persistently active basaltic system capable of a wide range of eruptive styles, from open-conduit lava lake activity to voluminous Plinian eruptions; it is thus an ideal natural laboratory to constrain potential controls on basaltic eruption style. Here we report the major, trace, and volatile (CO2, H2O, S, Cl, F) element composition of olivine-, plagioclase- and clinopyroxene-hosted melt inclusions as well as matrix glasses from lava lake ejecta and two Plinian tephra deposits—the 2.1 ka Masaya Triple Layer and the 1.8 ka Ticuantepe Lapilli—to test whether pre-eruptive volatile contents and degassing history may be linked to eruptive style. All samples display a relatively narrow and largely overlapping basaltic–basaltic andesitic compositional range (51.7±1.0 wt.% SiO2, 4.8±0.4 wt.% MgO) with similar trace element signatures (e.g., Ce/Y=0.82±0.10, Ba/La=74±11). However, lava lake and Plinian samples show systematic differences in pre-eruptive volatile contents, forming distinct groups with mean H2O contents of 0.6±0.2 wt.% (lava lake), 1.1±0.2 wt.% (Masaya Triple Layer), and 1.9±0.3 wt.% (Ticuantepe Lapilli). Together, these groups generate broad positive correlations between S, Cl and H2O concentrations, with maximum values reaching 920 ppm, 1300 ppm and 2.3 wt.%, respectively, which are low compared to typical Central American arc magmas. Magma temperature estimates overlap and average at 1115±30°C, while volatile saturation pressures are low, mainly <100 MPa, although only lava lake samples record pressures <31 MPa. These observations reiterate the compositionally buffered state of the volcano's magmatic system highlighted by previous work and demonstrate that — regardless of eruption style — all Masaya magmas undergo variable, but extensive, pre-eruptive degassing at low pressure. Geohygrometry, gas emissions, and H2O/Ce–Ba/La systematics suggest initial, undegassed H2O contents on the order of 3.9–5.5 wt.%. Our results imply that pre-eruptive volatile contents are not the culprit for Plinian events at Masaya. Instead, we propose that the volcano's vigorous magma supply is modulated in a top–down manner to produce a wide range of eruptive styles, whereby temporary sealing of the conduit may instigate a transition to explosive behavior. In this model, rapid magma ascent is triggered when the seal eventually breaks from degassing-induced pressurization, yielding high degrees of undercooling, rapid microlite growth, and a dramatic increase in magma viscosity and explosive eruption potential. There may thus be a thin line between open-conduit conditions and Plinian eruptions at Masaya.

Using GIS to Create Hazard Maps and Assess Evacuation Routes around “The Gate to Hell”; Masaya Volcano, Nicaragua

Volcán Masaya in Nicaragua is made of a series of calderas and craters that lies 7 km from the city of Masaya with a population of over 100,000. Masaya is part of the Central American Volcanic Arc (CAVA) which contains hundreds of volcanoes. While many of the volcanoes of the arc produce small, quiescent eruptions, some are capable of large explosive events. The recent cycle of volcanism at Masaya began 7000 years ago. Initial eruptions were primarily lava, small ash flows, ashfalls, and degassing events which eventually gave way to climactic Vulcanian eruptions. The hazards presented from this system affect not only larger cities, but many underdeveloped communities surrounding Volcán Masaya. These communities require a simple map and action plan to use during an evacuation. While government-issued routes are in place, there are no known secondary options. The communities surrounding Masaya lack the education they need for having such a fierce geologic feature right in their backyard to base their own opinions on when and if to evacuate the area on their own accord. We visited the study area to gather data for the creation of an evacuation route and hazard map to help prepare the surrounding communities. By consolidating our research and field data, the maps we created give the communities surrounding Masaya more insight as to the behavior of the eruptions. This research gives the local population options for evacuation and more knowledge about their environment.

Halogen activation in the plume of Masaya volcano: field observations and box model investigations

Abstract. Volcanic emissions are a source of halogens in the atmosphere. Rapid reactions convert the initially emitted hydrogen halides (HCl, HBr, and HI) into reactive species such as BrO, Br2, BrCl, ClO, OClO, and IO. The activation reaction mechanisms in the plume consume ozone (O3), which is entrained by ambient air that is mixed into the plume. In this study, we present observations of the oxidation of bromine, chlorine, and iodine during the first 11 min following emission, examining the plume from Santiago crater of the Masaya volcano in Nicaragua. Two field campaigns were conducted: one in July 2016 and one in September 2016. The sum of the reactive species of each halogen was determined by gas diffusion denuder sampling followed by gas chromatography–mass spectrometry (GC-MS) analysis, whereas the total halogens and sulfur concentrations were obtained by alkaline trap sampling with subsequent ion chromatography (IC) and inductively coupled plasma mass spectrometry (ICP-MS) measurements. Both ground and airborne sampling with an unoccupied aerial vehicle (carrying a denuder sampler in combination with an electrochemical SO2 sensor) were conducted at varying distances from the crater rim. The in situ measurements were accompanied by remote sensing observations (differential optical absorption spectroscopy; DOAS). The reactive fraction of bromine increased from 0.20 ± 0.13 at the crater rim to 0.76 ± 0.26 at 2.8 km downwind, whereas chlorine showed an increase in the reactive fraction from (2.7 ± 0.7) × 10−4 to (11 ± 3) × 10−4 in the first 750 m. Additionally, a reactive iodine fraction of 0.3 at the crater rim and 0.9 at 2.8 km downwind was measured. No significant change in BrO / SO2 molar ratios was observed with the estimated age of the observed plume ranging from 1.4 to 11.1 min. This study presents a large complementary data set of different halogen compounds at Masaya volcano that allowed for the quantification of reactive bromine in the plume of Masaya volcano at different plume ages. With the observed field data, a chemistry box model (Chemistry As A Boxmodel Application Module Efficiently Calculating the Chemistry of the Atmosphere; CAABA/MECCA) allowed us to reproduce the observed trend in the ratio of the reactive bromine to total bromine ratio. An observed contribution of BrO to the reactive bromine fraction of about 10 % was reproduced in the first few minutes of the model run.

Two Independent Light Dilution Corrections for the SO2 Camera Retrieve Comparable Emission Rates at Masaya Volcano, Nicaragua

SO2 cameras are able to measure rapid changes in volcanic emission rate but require accurate calibrations and corrections to convert optical depth images into slant column densities. We conducted a test at Masaya volcano of two SO2 camera calibration approaches, calibration cells and co-located spectrometer, and corrected both calibrations for light dilution, a process caused by light scattering between the plume and camera. We demonstrate an advancement on the image-based correction that allows the retrieval of the scattering efficiency across a 2D area of an SO2 camera image. When appropriately corrected for the dilution, we show that our two calibration approaches produce final calculated emission rates that agree with simultaneously measured traverse flux data and each other but highlight that the observed distribution of gas within the image is different. We demonstrate that traverses and SO2 camera techniques, when used together, generate better plume speed estimates for traverses and improved knowledge of wind direction for the camera, producing more reliable emission rates. We suggest combining traverses and the SO2 camera should be adopted where possible.

Tracking the behaviour of persistently degassing volcanoes using noble gas analysis of Pele's hairs and tears: A case study of the Masaya volcano (Nicaragua)

We provide evidence that noble gasses (NGs) trapped in Pele's hairs and tears can be used as a tool to monitor the degassing behaviour of persistently active volcanic systems. We investigated 4He, 36Ar, 40Ar abundances and 4He/40Ar* and 40Ar/36Ar isotopic ratios in samples collected in March 2015 and March 2016 from Masaya volcano (Nicaragua). The resurgence of a lava lake in December 2015 provided the opportunity to monitor NG variations during a specific volcanic event. The variations in the NG abundances of individual glass particles are here attributed to solubility-controlled NG fractionation between melt and bubbles, and consequently correlated with sample vesicularity and vesicle size. Inhomogeneous incorporation of 36Ar, along with kinetic mass fractionation during magma degassing, vesiculation and fast-quenching of the samples after eruption, are the mechanisms that control the variability of the 40Ar/36Ar ratios observed in the samples. From March 2015 to March 2016, our data indicate a general increase of mean 40Ar* abundances from 1.9E−8 ± 1.4E−8 cc/g to 9.3E−8 ± 8.9E−8 cc/g and decrease in mean 4He/40Ar* ratios from 0.37 ± 0.15 to 0.18 ± 0.13. We ascribe this to the upward migration of a gas-rich magma from depth that recharged the shallow magmatic reservoir of Masaya at some point between the two collection periods. Since this model agrees well with the physical volcanology of Masaya and with gas plume measurements spanning our collection period, we suggest that NG in Pele's hairs and tears can be further used as a valuable tool to monitor degassing processes at Masaya volcano and, when samples are available, at other persistently degassing systems (e.g. Etna, Hawaii).

Automatic Detection of Volcanic Surface Deformation Using Deep Learning

AbstractInterferometric Synthetic Aperture Radar (InSAR) provides subcentimetric measurements of surface displacements, which are key for characterizing and monitoring magmatic processes in volcanic regions. The abundant measurements of surface displacements in multitemporal InSAR data routinely acquired by SAR satellites can facilitate near real‐time volcano monitoring on a global basis. However, the presence of atmospheric signals in interferograms complicates the interpretation of those InSAR measurements, which can even lead to a misinterpretation of InSAR signals and volcanic unrest. Given the vast quantities of SAR data available, an automatic InSAR data processing and denoising approach is required to separate volcanic signals that are cause of concern from atmospheric signals and noise. In this study, we employ a deep learning strategy that directly removes atmospheric and other noise signals from time‐consecutive unwrapped surface displacements obtained through an InSAR time series approach using an end‐to‐end convolutional neural network (CNN) with an encoder‐decoder architecture, modified U‐net. The CNN is trained with simulated synthetic unwrapped surface displacement maps and is then applied to real InSAR data. Our proposed architecture is capable of detecting dynamic spatio‐temporal patterns of volcanic surface displacements. We find that an ensemble‐average strategy is recommended to stabilize detected results for varying deformation rates and signal‐to‐noise ratios (SNRs). A case study is also presented where this method is applied to InSAR data covering Masaya volcano, Nicaragua and the results are validated using continuous GPS data. The results confirm that our network can indeed efficiently suppress atmospheric and other noise to reveal the noise‐free surface deformation.

Pre- and syn-eruptive conditions of a basaltic Plinian eruption at Masaya Volcano, Nicaragua: The Masaya Triple Layer (2.1 ka)

The Masaya Triple Layer tephra was deposited ~2100 years ago during a basaltic Plinian eruption of Masaya caldera, Nicaragua, and is one of few known examples of this extreme endmember of basaltic explosive volcanism. Masaya caldera is located approximately 25 km from Managua, the capital of Nicaragua, and a Plinian eruption presents a high potential risk to its population of 1 million people. Here we use geochemical and petrological tools to constrain the pre- and syn-eruptive physico-chemical magmatic conditions, in order to understand how low-viscosity basaltic magmas can erupt with Plinian style.By combining thermometric models with Rhyolite-MELTS simulations, we find that the Masaya Triple Layer magma was last stored between 1080 and 1100 °C and 21–42 MPa, with a pre-eruptive volatile content of ~2 wt% H2O. A small phenocryst volume fraction of 0.1 crystallised under water-saturated conditions within a shallow magma reservoir located at 0.8–1.6 km depth. During ascent, rapid microlite crystallisation occurred and lateral velocity gradients across the conduit produced heterogeneous inter-mingling regions of varying crystallinity, between 20 and 50 vol%. Crystal size distribution analysis shows substantial microlite crystallisation over a timescale of 1–5 min, which induced significant changes in viscosity and magma rheology during ascent, increasing the effective magma viscosity from ~10 Pa s to 106 Pa s and approaching the brittle fragmentation threshold. Comparable pre- and syn-eruptive conditions have been deduced for other examples of basaltic Plinian activity, indicating a common eruption mechanism. We find that the common requirements for a basaltic Plinian eruption are a low magmatic H2O concentration of ~2 wt%, storage at moderate temperatures of 1080–1100 °C, and rapid crystallisation during magma ascent. Ultimately, these conditions contributed to the production of this highly hazardous Plinian eruption of Masaya.

Unified quantitative observation of coexisting volcanic sulfur dioxide and sulfate aerosols using ground-based Fourier transform infrared spectroscopy

Abstract. We developed an optimal-estimation algorithm to simultaneously retrieve, for the first time, coexisting volcanic gaseous SO2 and sulfate aerosols (SA) from ground-based Fourier transform infrared (FTIR) observations. These effluents, both linked to magmatic degassing process and subsequent atmospheric evolution processes, have overlapping spectral signatures leading to mutual potential interferences when retrieving one species without considering the other. We show that significant overestimations may be introduced in SO2 retrievals if the radiative impact of coexistent SA is not accounted for, which may have impacted existing SO2 long-term series, e.g. from satellite platforms. The method was applied to proximal observations at Masaya volcano, where SO2 and SA concentrations, and SA acidity, were retrieved. A gas-to-particle sulfur partitioning of 400 and a strong SA acidity (sulfuric acid concentration: 65 %) were found, consistent with past in situ observations at this volcano. This method is easily exportable to other volcanoes to monitor magma extraction processes and the atmospheric sulfur cycle in the case of ash-free plumes.

Structure of Masaya and Momotombo volcano, Nicaragua, investigated with a temporary seismic network

Since the end of 2013, the region around the two volcanoes Masaya and Momotombo, which includes the Nicaraguan capital Managua, has shown an unusually high seismic and volcanic activity. In December 2015, the Momotombo volcano erupted after 110 years of quiescence. Since mid-December 2015, the Masaya volcano has also shown gradually increasing activity, including the formation of a lava lake in its main crater.By adding 30 broadband stations, we had temporarily (December 2016–March 2017) densified the permanent Nicaraguan seismic network around these volcanoes to study the local seismicity and image the subsurface structure. During the observation period, we observed an overall low level of seismicity. Recorded events around Momotombo likely consist of aftershocks of the M5.5 earthquake that struck this area on September, 26th, 2016. At Masaya, we did not observe volcano-tectonic events.Using the continuous waveform recordings, we perform a 3D ambient seismic noise tomography that reveals a first image of the subsurface velocity structure below the Masaya and Momotombo volcanoes. While Momotombo shows a typical elongated low shear-wave velocity anomaly that reaches depths of about 8 km, Masaya does not show indications of a deep plumbing system. At Masaya, we have indications of a shallow (0–3 km) magmatic chamber, offset to the west and not directly below the active Santiago vent, where the crater lake is located At greater depth (3–8 km) a low velocity anomaly towards the northeast coincides in location with a modelled positive gravity anomaly and could indicate the presence of a former intrusive body.With this study we want to trigger further interest in the diverse tectonic and volcanic features of Nicaragua. Future, long-term seismic imaging and monitoring projects are of critical interest for the estimation of seismic and volcanic risks in Managua and the surroundings.

Melt inclusion evidence for long term steady-state volcanism at Las Sierras-Masaya volcano, Nicaragua

Las Sierras-Masaya volcanic system is a persistently active basaltic caldera complex in Nicaragua. While there has been almost no juvenile material erupted since 1772, Masaya volcano has been persistently degassing for >150 years. An additional unusual behaviour for the Las Sierras-Masaya volcanic complex is its ability to produce large caldera-forming basaltic Plinian eruptions with the most recent occurring about 1800 years ago.Here we present melt inclusion analyses that provide constraints on the magmatic system over time. Melt inclusions hosted in plagioclase and olivine crystals were analyzed for major, trace and volatile elements (S, Cl, F, H2O). The data supports a consistent parental magmatic source with restricted compositional variability explained by simple fractional crystallization of plagioclase, olivine, clinopyroxene and magnetite at a nearly constant temperature. This broadly agrees with previous whole rock geochemical studies showing that the overall chemical signature of volcanic products at Masaya has remained largely unchanged for ~60,000 years and that both shallow fractionation and degassing processes dominate the whole evolution of the magmatic series. Based on volatile element in melt inclusions and gas composition and flux measurements, we determine the magmatic flux to be ~0.19 km3 yr−1 implying that up to 47 km3 of magma may have degassed since the last effusive eruption. As at other persistently active basaltic volcanoes (e.g., Mt. Etna, Italy; Kilauea, Hawaii, USA), this magmatic flux must involve significant endogenous storage which is likely accommodated by extensional tectonics. However, Masaya volcano differs in its apparent simplicity with respect to its stable chemistry and its fully interconnected magmatic system.

The PiSpec: A Low-Cost, 3D-Printed Spectrometer for Measuring Volcanic SO2 Emission Rates

Spectroscopy has been used to quantify volcanic gas emission rates, most commonly SO2, for a number of decades. Typically, commercial spectrometers costing 1000s USD are employed for this purpose. The PiSpec is a new, custom-designed, 3D-printed spectrometer based on smartphone sensor technology. This unit has ≈1 nm spectral resolution and a spectral range in the ultraviolet of ≈280–340 nm, and is specifically configured for the remote sensing of SO2 using Differential Optical Absorption Spectroscopy (DOAS). Here we report on the first field deployment of the PiSpec on a volcano, to demonstrate the proof of concept of the device’s functionality in this application area. The study was performed on Masaya Volcano, Nicaragua, which is one of the largest emitters of SO2 on the planet, during a period of elevated activity where a lava lake was present in the crater. Both scans and traverses were performed, with resulting emission rates ranging from 3.2 to 45.6 kg s−1 across two measurement days; these values are commensurate with those reported elsewhere in the literature during this activity phase (Aiuppa et al., 2018; Stix et al., 2018). Furthermore, we tested the PiSpec’s thermal stability, finding a wavelength shift of 0.046 nm/∘C between 2.5 and 45∘C, which is very similar to that of some commercial spectrometers. Given the low build cost of these units (≈500 USD for a one-off build, with prospects for further price reduction with volume manufacture), we suggest these units hold considerable potential for volcano monitoring operations in resource limited environments.

From Machu Picchu to Masaya Volcano: An Interdisciplinary Approach to offering Study Abroad Courses on International Disasters and Crisis Communication

As the nature of managing hazards and disasters grows increasingly complex, educating the next generation of emergency management practitioners and scholars requires innovative strategies. This article describes the utilization of a collaborative teaching approach when offering a study abroad course examining hazards, emergency management, and crisis communication in Central and South America. Co-taught cross-disciplinary courses provide opportunities for students to gain exposure to the different perspectives inherent in the study and management of hazards and disasters. This, coupled with the study abroad experience, offers students a unique viewpoint on how hazards, risks, and communication are managed and perceived in other countries. This paper highlights the recent research about benefits of co-teaching and study abroad courses, provides a description of our study abroad programs, and offers tips and suggestions for developing similar courses at other higher education institutions.

A Rapidly Convecting Lava Lake at Masaya Volcano, Nicaragua

Lava lakes provide a rare opportunity to study conduit flow processes through direct observation of the exposed magma surface. The recent lava lake activity at Masaya volcano (Nicaragua), which commenced in 2015, displayed several unusual phenomena. We report on the dynamics of this rapidly convecting lake, which, to the best of our knowledge manifested the highest lava flow velocities ever reported for a lava lake: 13.7–16.4 m s−1, in addition to unusual fluid dynamic behavior involving alteration in surface flow direction. We studied this system with multiparametric and high time resolution remote sensing measurements, performed during June 2017, including ultraviolet camera observations of SO2 emission rates, near infrared thermal camera measurements and video analyses of the lake surface. Median SO2 emission rates of 3.1 (±0.8) and 3.7 (±0.9) kg s−1 were found, which are lower than previously published estimates, and could represent challenging remote sensing conditions or a waning in lava lake activity. Video analyses enabled characterization of frequent bursts of approximately hemispherical spherical-cap bubbles on the surface with diameters ranging 0.6–8.5 m (median of 2.6 m), and calculation of individual bubble masses, which contribute to active bubble bursting values estimated at 1.9 to 3.9 kg s−1. We show that only a small fraction, 7–17%, of total emission volumes are contributed by these bubbles, based on estimated emission rates of 22.5 and 26.9 kg s−1. Furthermore, periodicity analysis reveals regular 200–300 s oscillations in SO2 emissions. These are not shared by any of our other datasets and particularly during the contemporaenously acquried thermal data, hence, we tentatively assign an atmospheric causal generation mechanism, driven by atmospheric transport and turbulence phenomena, such as eddying. Overall, we highlight the uniquely high velocity and fluid dynamic behavior of Masaya lava lake.

Using Drones and Miniaturized Instrumentation to Study Degassing at Turrialba and Masaya Volcanoes, Central America

AbstractGas measurements using unmanned aerial vehicles, or drones, were undertaken at Turrialba volcano, Costa Rica, and Masaya volcano, Nicaragua, in 2016 and 2017. These two volcanoes are the largest time‐integrated sources of gas in the Central American Volcanic Arc, and both systems are currently extremely active with potential for sudden destabilization. We employed a series of miniaturized drone‐mounted instrumentation including a mini‐DOAS, two MultiGAS instruments, and an optical particle counter, supplemented by ground‐based measurements. Payloads were typically 1–1.5 kg and flight times were 10–15 min. The measurements were both accurate and precise due to the inherent sensitivity of the instrumentation and the high gas concentrations, which the drones were able to sample. The quality of data obtained by our drones was comparable to that obtained by our ground‐based measurements. At Turrialba in April 2017, we measured an average SO2 flux of 1,380 ± 280 T/day, CO2/SO2 of 6.5, and H2O/SO2 of 27.8. Using these values, we calculated a CO2 flux of 6,170 T/day and an H2O flux of 10,790 T/day. At Masaya in May 2017, the average SO2 flux was 1,560 ± 180 T/day, with CO2/SO2 of 3.9 and H2O/SO2 of 62.3, giving a mean CO2 flux of 4,150 T/day and mean H2O flux of 27,330 T/day. The elevated carbon and water fluxes and ratios are indicative of underlying magmas that are enriched in these components, resulting in the high levels of activity observed.

Implementation of electrochemical, optical and denuder-based sensors and sampling techniques on UAV for volcanic gas measurements: examples from Masaya, Turrialba and Stromboli volcanoes

Abstract. Volcanoes are a natural source of several reactive gases (e.g., sulfur and halogen containing species) and nonreactive gases (e.g., carbon dioxide) to the atmosphere. The relative abundance of carbon and sulfur in volcanic gas as well as the total sulfur dioxide emission rate from a volcanic vent are established parameters in current volcano-monitoring strategies, and they oftentimes allow insights into subsurface processes. However, chemical reactions involving halogens are thought to have local to regional impact on the atmospheric chemistry around passively degassing volcanoes. In this study we demonstrate the successful deployment of a multirotor UAV (quadcopter) system with custom-made lightweight payloads for the compositional analysis and gas flux estimation of volcanic plumes. The various applications and their potential are presented and discussed in example studies at three volcanoes encompassing flight heights of 450 to 3300 m and various states of volcanic activity. Field applications were performed at Stromboli volcano (Italy), Turrialba volcano (Costa Rica) and Masaya volcano (Nicaragua). Two in situ gas-measuring systems adapted for autonomous airborne measurements, based on electrochemical and optical detection principles, as well as an airborne sampling unit, are introduced. We show volcanic gas composition results including abundances of CO2, SO2 and halogen species. The new instrumental setups were compared with established instruments during ground-based measurements at Masaya volcano, which resulted in CO2 ∕ SO2 ratios of 3.6 ± 0.4. For total SO2 flux estimations a small differential optical absorption spectroscopy (DOAS) system measured SO2 column amounts on transversal flights below the plume at Turrialba volcano, giving 1776 ± 1108 T d−1 and 1616 ± 1007 T d−1 of SO2 during two traverses. At Stromboli volcano, elevated CO2 ∕ SO2 ratios were observed at spatial and temporal proximity to explosions by airborne in situ measurements. Reactive bromine to sulfur ratios of 0.19 × 10−4 to 9.8 × 10−4 were measured in situ in the plume of Stromboli volcano, downwind of the vent.