Austenite Martensite Research Articles

The Effect of CWTSAW on the Toughness of Heavy-Gauge X70: Part I – Correlating HAZ Microstructure with Cold Wire Feed Rate

The effect of cold wire feed rate (CWFR) on martensite-austenite (MA) constituent morphology and prior austenite grain (PAG) size in the heataffected zone (HAZ) of heavy gauge (19.1 mm thick) X70 microalloyed steel welded by cold-wire tandem submerged-arc welding (CWTSAW) was studied. A series of single-pass CWTSAW trials were made using cold wire feed rates (CWFRs) of 0 mm/s, 16.9 mm/s, and 33.9 mm/s, which corresponded to effective heat inputs of 2.9 kJ/mm, 2.6 kJ/ mm, and 2.3 kJ/mm, respectively. The PAG size and MA constituent morphology (area and aspect ratio distribution) were measured using optical microscopy. The average PAG size in the coarsegrained HAZ (CGHAZ) was reduced from 139 μm to 83 μm as the CWFR was increased from 0 mm/s (2.9 kJ/mm) to 33.9 mm/s (2.3 kJ/mm). The total number of MA constituents and the area fraction of MA in the CGHAZ were lowest for the intermediate CWFR of 16.9 mm/s (2.6 kJ/mm).

Phase transitions in the Co-doped Heusler alloy Ni2Mn1−xCoxGa

The phase transitions of a series of Co-doped Heusler alloys, Ni2Mn1−xCoxGa (0⩽x⩽0.2), were investigated experimentally using the magnetization measurements, x-ray diffraction, and calorimetric measurements up to their respective melting points. With increasing Co concentration, the structural transition temperatures, Curie temperatures, and melting points, were observed to increase, while the order–disorder transition temperatures decreased. Temperature-dependent x-ray diffraction experiments revealed two different crystal structures in the low-temperature martensite phase for different Co concentrations. However, above their respective structural transitions, both low-temperature crystal structures transformed into the L21 cubic structure. These findings enabled the construction of a complete magnetic and structural phase diagram for Ni2Mn1−xCoxGa, spanning from cryogenic temperatures to the melting points. The temperature-dependent XRD results revealed the abrupt changes in interatomic Mn–Mn distances, which validates the crucial role of Mn–Mn interatomic distance and the effect of the magnetic coupling competition in the structural stability between the martensite phase and austenite phase.

PREDICTION OF WELD-ABILITY CHARACTERISTICS OF DUAL-PHASE STEEL HCT600X BY NUMERICAL SIMULATION

Dual-phase (DP) steel plates are characterized by very good absorption capacity, so they are used in the automotive industry for body deformation zone parts. They are attached to the frame of the car-body by welding. Laser welding of dual-phase steels is gaining increasing importance in the automotive industry. In the present paper, the possibility of predicting the strength and deformation characteristics of laser-welded HCT600X steel sheets was analyzed based on experiments and numerical simulations. Butt joints were formed by YLS-5000 laser in two variants, which differ by laser power input and welding speed. The HCT600X- HCT600X with welded joint was analyzed based on microstructure and mechanical tests. The tensile strength and hardness of the welded joints were greater than those of the base material (BM). The microstructure of the weld metal (fusion zone) consisted of martensite, austenite and bainite, in the heat-affected zone it consisted of a mixture of martensite, bainite, ferrite and residual austenite. In numerical simulation, the finite-element mesh was created by linear volume elements refined in the weld region, and the Gauss model of the surface heat source was applied when modelling laser welding. The results of numerical simulation of the microstructure and selected mechanical properties were correlated with the experimental results.

Chemical Composition Optimization and Isothermal Transformation of δ‐Transformation‐Induced Plasticity Steel for the Third‐Generation Advanced High‐Strength Steel Grade

A new low‐manganese transformation‐induced plasticity steel is designed with optimized nickel content to achieve superior strength and ductility while minimizing the use of expensive nickel. The steel is optimized using JMatPro software, then cast, and hot rolled. To assess the effect of intercritical annealing on austenite (martensite at room temperature) volume fraction and carbon content, hot‐rolled steel samples quenched from different annealing temperatures (680–1100 °C) are used. Additionally, hot‐rolled steel coupons are intercritically annealed at about 50% austenite formation temperature (740 °C) and then subjected to isothermal treatments at 300–425 °C for varying times (10–90 min). After optimizing these treatments to maximize retained austenite (RA), tensile specimens are heat‐treated first at 740 °C and then isothermally at 325 °C. Thermodynamic calculations suggest that aluminum combined with silicon may lead to the δ ferrite formation, and even minimal nickel content can stabilize a considerable amount of austenite. In the experimental studies, it is shown that lower‐temperature bainitic holding enhances austenite stability by enriching the carbon content. Optimized two‐stage heat treatments yield up to 25.8% RA, with a tensile strength of 867.2 MPa and elongation of 40.6%, achieving a strength‐elongation product of 35.2 GPa×%, surpassing the third‐generation advanced high‐strength steel grades minimum requirement of 30 GPa×%.

Yielding Behavior of Low Carbon Martensitic Steel Sheet Containing Retained Austenite

Yielding Behavior of Low Carbon Martensitic Steel Sheet Containing Retained Austenite

A Study of the Performance of Dissimilar Pulsed-Laser-Welded JSC590R/JAC980YL Steel Joints of Differential Thickness

To reveal the correlation between the mechanical properties of JSC590R/JSC980YL steel pulse-laser-welded joints and welding parameters, this study adopts the response surface analysis test method to determine the welding parameters, and examined the macroscopic morphology, microstructure, microhardness, and tensile properties of the cross-section of the welded joints. The results revealed that the key factors influencing welded joints quality, in descending order of importance, are distance to focus, welding speed, and single-pass heat input. The interaction between these factors is extremely significant. The weld zone of the joints is primarily composed of lath martensite, while the heat-affected zone is composed of ferrite, martensite, carburite, tempered martensite, and residual austenite. The optimized welding parameters align with actual expectations, yielding an average engineering stress of 616.9 MPa for the joint. Notably, the fracture area shifts from the heat-affected zone of JSC590R to the base material.

Impact response of pseudoelastic nitinol

The response of polycrystalline nitinol with solely austenite structure was studied in three series of planar impact tests characterized by loading of the nitinol samples of 0.5–10 mm thickness by 1 mm thick aluminum impactor accelerated up to velocities of about 387, 429, and 567 m/s. In all the tests, the velocities of the free surfaces of the samples were monitored by a laser velocity interferometer. It was found that in all three test series, the amplitude of elastic precursor wave, being initially greater than 4 GPa, rapidly decays with the propagation distance down to ∼2.5 GPa, below which the decay is hindered by atomic clusters of the nanometer size. Based on the part of the velocity histories indicating the shock-induced austenite–martensite transformation, the initial, of about 2.5 × 103 s−1, and the maximum, up to 1 × 105 s−1, rates of the transformation were determined. As well, the impact stress slightly greater than 4 GPa was determined as that required for the onset of the B2 → B19′ transformation under shock loading. The unloading parts of the same velocity histories allowed a rough estimate of the fraction of the shock-transformed martensite and the elucidation of the virtually complete reversibility of the transformation.

Microstructure evolution and mechanical properties of martensitic stainless bearing steels with different carbon nitrogen ratios

This study investigates the effect of adjusting the carbon nitrogen ratio on the microstructure and mechanical properties of martensitic stainless bearing steels, keeping the equivalent total carbon and nitrogen content. The results demonstrate that the sample with nearly equal weight percentages of C and N exhibits optimal comprehensive performance, achieving impressive yield strength, ultimate tensile strength, and uniform elongation of up to 1806.5 MPa, 2279.3 MPa, and 4.5%, respectively. Distinct phase ratios and morphologies observed across the three C/N ratios after identical heat treatment process suggest varying intrinsic mechanisms due to differences in C and N solid solubility in the matrix. The specimen with almost balanced C and N shows the highest interstitial atom solubility in the austenite phase, stabilizing austenite and lowering stacking fault energy. Abundant fine twins in martensite and stacking faults in austenite contribute to increased elongation without compromising strength. In contrast, specimen with higher N/C ratio exhibits numerous nitrides, limiting N atom solid solution in austenite during austenization, resulting in martensite with twins and dislocations. Specimen with higher C/N ratio shows extensive carbide precipitation and mainly dislocation-type martensite. The study deepens the understanding of C and N interactions in advanced bearing steels and provides a foundation for improving mechanical properties of such steels.

Effect of Intercritical Austenitization and Starting Matrix on Martensite Start Temperature and Austenite Carbon Concentration in Ductile Iron

AbstractIn this work, the effect of the intercritical austenitization temperature and time, Ni + Cu concentration and starting matrix (fully ferritic or fully pearlitic) on the volume fraction of austenite (fγ), martensite start temperature (Ms) and carbon concentration of the parent austenite (C0) in ductile iron was investigated using standard metallographic techniques and high-resolution dilatometry. The results showed that a fully pearlitic starting matrix gives higher fγ and C0 and lower Ms than a fully ferritic starting matrix at the same austenitization temperature under continuous heating. On the other hand, the austenitization time has an effect on the parameters under study only during the first minutes of intercritical austenitization. Finally, at the same intercritical austenitization temperature, the addition of Ni + Cu increases the volume fraction of austenite.

The Influence of Alloy Composition on Microstructure and Performance of Mixed-Smelting Alloy and Weld Metal.

In the present work, the Q345B low-alloy steel with different contents and ER309L stainless steel were melted together to obtain new alloys. The aim was to design the composition of weld metal (Q345B low-alloy steel as the base material and ER309L welding wire as the filler material) and improve the corrosion resistance of the weld metal. During the welding process, the composition of the weld metal was controlled to match the new alloys by changing the welding heat input. A relationship curve between fusion ration and welding heat input was obtained. The research focused on analyzing the effect of mixed-smelting ratio between Q345B and ER309L and welding heat input on the microscopic structure and corrosion performance of the prepared samples. The results show that the melted alloys containing 20% to 30% Q345B consist of a ferrite (δ) phase and austenite (A) phase, the samples containing 45% to 50% Q345B consist of a martensite (M) phase and austenite (A) phase, and the sample containing 40% Q345B consists of a martensite (M) phase, ferrite (δ) phase, and austenite (A) phase. As the mixed-smelting ratio of Q345B/ER309L increased, the corrosion resistance of samples decreased gradually. For the weld metal, the fusion ration between Q345B base material and ER309L welding wire increases with the welding heat input. When the heat input changed from 0.645 kJ/mm to 2.860 kJ/mm, the composition of the weld metal was consistent with the melted alloys containing 20-45% Q345B. The microstructure and corrosion resistance of the weld metal could be designed by the melting means, which has important guiding significance for engineering applications.

Generation of micrograph-annotation pairs for steel microstructure recognition using the hybrid deep generative model in the case of an extremely small and imbalanced dataset

Insufficient annotated samples coupled with class imbalance problem largely restrict the wide application of deep learning (DL)-based approach in microstructure recognition and quantification. In this work, we present a micrograph augmentation approach using the hybrid deep generative model to generate SEM image-annotation pairs for the establishment of a large-scale and well-balanced augmentation dataset. In this method, a generator is established to produce the desired annotations and then a translator is trained to translate these synthetic annotations into high-quality SEM images. The proposed method is successfully applied to an extremely small and imbalanced additively manufactured (AM) steel dataset containing only one SEM image-annotation pair with a very low martensite/austenite (MA) fraction, to significantly augment the initial dataset and achieve a more balanced distribution of phase fraction. The effectiveness of the present method is well demonstrated by the fact that the extensibility of microstructure recognition model to unseen micrographs is improved through the utilization of synthetic data. Furthermore, the impact of synthetic data proportion on the model's performance and the underlying reasons for synthetic data to improve the extensibility of trained models are also discussed in detail.

Multi-angle analysis of Mo on martensite–austenite component and toughness in SCGHAZ of X80 pipeline automatic ring welding

In order to solve the embrittlement problem of welded joint of pipeline steel, this paper proposes to study the influence of Mo on M-A component of the subcritically reheated coarse-grained HAZ (SCGHAZ), and Mo on bainite transformation. Through the welding thermal simulation experiment, two kinds of X80 pipeline steel with different Mo content were set different secondary thermal cycle peak temperatures to simulate the heat affected zone (HAZ). Samples in the SCGHAZ were selected to observe the microstructure, M-A component, microalloy-element distribution and fracture crack trend, and comprehensively analyze the reasons for the deterioration of impact toughness caused by the changes of Mo content. The results show that the increase of Mo content leads to the formation of twinning martensite, which is one of the reasons for the deterioration of toughness. Mo is enriched at the interface of ferrite and M-A component, reducing the binding energy at the interface, resulting in the desorption of M-A component from the matrix, the formation of pores and becoming the nucleation site of cracks, resulting in the generation of micro-cracks and the decrease of toughness.

Excellent low temperature superplasticity and its deformation mechanism in nano/ultrafine grained Fe–17Cr–6Ni stainless steel

Superplastic deformation typically occurs in non-ferrous metals at high temperatures, which results in severe surface oxidation and high energy consumption. In this study, we designed and manufactured a nano/ultrafine-grained stainless steel with a dual-phase microstructure that exhibits excellent low-temperature superplastic deformation capability. A maximum tensile elongation of approximately 500% was achieved when the tensile test was conducted at 700 °C with an initial strain rate of 5 × 10⁻⁴ s⁻1. Even after a 500% tensile elongation, the austenite grains in the gauge section of the tensile specimen still maintained an equiaxed grain shape, and the texture also weakened significantly, indicating that grain boundary sliding and grain rotation dominated the deformation process during superplastic flow. The outstanding superplasticity is mainly attributed to the dual-phase microstructure composed of nano/ultrafine austenite grains and martensite.

Achieving dual-phase structured Cu-Al-Mn-Si alloy with prominent shape memory properties via laser powder bed fusion

In this study, Cu-11.1Al-8.15Mn-0.37Si shape memory alloy was manufactured via laser powder bed fusion (LPBF) and compared with furnace-cooling cast samples. The LPBF-manufactured samples exhibited a dual-phase structure of L21 austenite and 2H martensite, along with uniformly distributed nanoscale Mn5Si3 precipitations observed via TEM. The 2H martensite presented a layer-like morphology and was confirmed to be induced by residual stress during the LPBF process. Such a dual-phase structure could be stabilized by Mn5Si3 precipitations, and yielded the concurrent presence of prominent superelastic (SE) and shape memory effect (SME) properties. Under 6 % pre-strain, LPBF-manufactured samples showed an 80 % SE rate and 83 % SME rate. The recovery SE and SME strain could be up to 4.2 % and 2.1 %. Compared to the cast sample, fracture compressive and tensile strain increased by 68.4 % and 33.3 %. This enhancement was due to regularly arranged columnar crystals and strong [001]//Z texture confirmed by EBSD. These findings suggest that LPBF has the potential to produce Cu-Al-Mn-Si alloys with prominent shape memory properties and provide references for an austenite-martensite dual-phase structure.

Induction assisted autogenous plasma arc welding of HSLA steel

In this work, a high frequency induction heating (HFIH) assisted plasma arc welding (IPAW) technique is proposed to weld 6 mm thick S690QL high strength low alloy steel plates in square butt joint configuration and without using any filler material. A 3D finite element based coupled electromagnetic-thermal analysis is carried out to ascertain the weld's thermal characteristics. Microstructure evolution and mechanical performance are investigated using scanning electron microscopy, electron back scattered diffraction, transmission electron microscopy, tensile test, Charpy impact test and micro hardness test. The results demonstrate that 15 s initial static heating using a co-directional current coil with magnetic flux concentrator predominantly improves the weld penetration by 48 % and joint efficiency reaches 90 % to the base plate strength. Microstructural study shows that the addition of HFIH promotes low angle grain boundaries (LAGB) with bainite ferrite and granular bainite micro-constituents in the fusion zone, which causes localised yielding and failure in this zone during tensile test. Further investigation reveals that the HFIH encourages the formation of BI-type bainite ferrite laths of 1.3–2.2 μm width, combined with slender martensite-austenite (M-A) island at the bainite ferrite lath boundaries. The results also reveal that the induction heating promotes the formation of M23C6 precipitates and B2 structured Cu-enrich nano precipitates in the fusion zone (FZ). The microhardness distribution indicates that the FZ and coarse grain heat affected zone are significantly reduced due to the assistance of the HFIH. The impact test result shows a lower energy absorption by the IPAW weldments due to dominance of the LAGB with unfavourable strain distribution.

Martensite-austenite transformation during dual-stage tempering and work-hardening characteristics of Mn–Ni–Mo steel

The reactor pressure vessel (RPV) in nuclear power plants is mainly made from Mn–Ni–Mo steel. After quenching, this steel's microstructure features martensite-austenite (M-A) islands. Tempering above 600 °C poses a challenge, as these islands can transform into harmful rod-like Fe3C precipitates, adversely affecting the RPV's tensile properties and structural integrity. This study explores the effects of M-A transformation during dual-stage tempering on the tensile properties of Mn–Ni–Mo steel, focusing on two austenite grain sizes (5 μm and 47 μm). The dual-stage tempering included a 2-h pre-tempering phase at temperatures between 200 °C and 500 °C, followed by a 3-h final tempering stage at 650 °C. Results showed that M-A transformation is temperature-dependent. At 200 °C, partial transformation led to rod-like Fe3C precipitates during final tempering, similar to direct tempering at 650 °C, reducing the critical stress for micro-crack nucleation and compromising tensile properties. Pre-tempering at 350 °C produced fine, aggregated precipitates that improved tensile strength by inhibiting dislocation movement. Conversely, pre-tempering at 500 °C resulted in coarser, more dispersed spherical precipitates. The Kocks-Mecking plot indicated that the 350 °C pre-tempered sample had the highest strain hardening capacity, with the strain hardening rate curve farthest from the origin and the shallowest slope during stage IV hardening. However, the 500 °C pre-tempered samples showed the best combination of elongation and strength.

Effects of Silicon and Aluminum Alloying on Phase Transformation and Microstructure Evolution in Fe–0.2C–2.5Mn Steel: Insights from Continuous–Cooling–Transformation and Time–Temperature–Transformation Diagrams

The impact of silicon and aluminum on phase transformation behavior, particularly bainite, and microstructure evolution in Fe–0.2C–2.5Mn steel are presented. Continuous–cooling–transformation (CCT) and time–temperature–transformation (TTT) diagrams are determined experimentally. An aluminum extended empirical formula is introduced to estimate the martensite start temperature (Ms) with a thorough assessment of existing formulae. Results show that aluminum significantly increases Ms and has a stronger influence on promoting ferritic microstructures than silicon. During continuous cooling, alongside bainite, formation of Widmanstätten structures is induced in aluminum‐alloyed steel at higher cooling rates due to increased prior austenite grain size. Silicon decelerates bainite transformation kinetics by enhancing austenite's chemical stability through carbon enrichment via preventing carbide precipitation and by strengthening austenite against displacive phase transformation via solid solution hardening. Although aluminum has similar effects, incubation time is shortened during isothermal treatment because of the increased driving force, which overcompensates for the retardation effects. A finer carbide‐free bainitic microstructure is achieved in aluminum‐alloyed steel with more pronounced film‐like retained austenite (RA) formation and superior carbon enrichment, improving RA stability and suppressing martensite–austenite island formation. Finally, with the proposed formula, an accurate approximation to experimental Ms is accomplished.

Achieving an excellent balance of strength, plasticity, and stretch flangeability in a 1000 MPa grade TRIP-assisted bainitic ferrite steel

To address the requirements for safety enhancement, weight reduction, and emission reduction, a novel transformation-induced plasticity-assisted bainitic ferrite (TBF) steel was processed by involving a pre-quenching (PQ) process. This steel was designed with varying PQ temperatures to achieve different fractions of intercritical ferrite and bainite, and its influence on mechanical properties of TBF steels was thoroughly investigated through tensile tests and hole expansion tests. The results demonstrated that the introduction of high-temperature PQ treatment before heat treatment can dramatically accelerate the formation of austenite during the secondary annealing process, thereby facilitating a more sufficient bainitic transformation in the subsequent isothermal process. With the increase of PQ temperature from 750 to 900 °C, abundant intercritical ferrite was replaced by lathy bainite. In comparison with conventional specimens, the high-temperature PQ treatment could reduce the fraction of intercritical ferrite and martensite-austenite (M-A) islands, in favor of delaying the initiation of microvoid and microcrack and improving local formability. In summary, the P-900 specimen exhibited optimal comprehensive mechanical properties, with the highest yield strength of 657 MPa, ultimate tensile strength of 1081 MPa, elongation of 28.7%, and hole expansion ratio of 35.1%.

The formation control and microstructure evolution of macrosegregation in laser offset welding on steel-nickel dissimilar alloy

To precisely control the melting of two base metals, laser offset welding is an effective method for managing the interfacial microstructure in dissimilar metal welds. Macrosegregation exhibits a markedly different morphology near the steel-nickel fusion line, which plays an important role in premature creep failure. In this study, it was found that an offset of the laser beam towards the nickel correlated with an increase in macrosegregation. When the laser beam was biased towards the steel, the partially mixed zone (PMZ) and transition zone (TZ) of 9Cr steel were identifiable within the macrosegregation, displaying a distinct solidification mode. Lath martensite and fine austenite formed in the PMZ, with alternating distributions of martensite and austenite observed in the TZ. Conversely, when the laser beam was biased towards the nickel, the unmixed zone (UMZ) of 9Cr steel was observed within the macrosegregation. Nanoindentation tests revealed that the maximum nanohardness in macrosegregation reached 5.90 GPa in the PMZ due to the formation of lath martensite, while the minimum nanohardness was 1.30 GPa in the TZ due to reduced martensite formation. Additionally, the TZ exhibited a significant reduction in resistance to plastic deformation. The various microstructures of macrosegregation were attributed to the solidification process and the dilution rate of 9Cr steel. When the liquidus temperature of WM exceeded 1455℃, a wide TZ formed in the macrosegregation due to adequate mixing. In contrast, when the WM had a significantly lower liquidus temperature than the 9Cr steel, only UMZ and PMZ formed in the macrosegregation due to preferential solidification and insufficient mixing. To minimize macrosegregation and eliminate the softening TZ, a laser beam offset towards the steel between 0.1 mm and 0.2 mm is recommended.

Martensitic transformation-governed Lüders deformation enables large ductility and late-stage strain hardening in ultrafine-grained austenitic stainless steel at low temperatures

Deformation-induced martensitic transformation that rapidly occurs generally leads to a significant reduction in elongation of metastable austenitic steels, particularly at low temperatures. However, we proved that the ultrafine-grained 304 stainless steel is an exception. Using a hybrid method of in situ neutron diffraction and digital image correlation, we found that this material exhibits Lüders deformation after yielding, in which the deformation behavior changes from a cooperation mechanism involving dislocation slip and martensitic transformation to one primarily governed by martensitic transformation, as the temperature decreases from 295 K to 77 K. Such martensitic transformation-governed Lüders deformation delays the activation of plastic deformation in both the austenite parent and martensite product, resulting in delayed strain hardening. This preserves the strain-hardening capability for the later stage of deformation, thereby maintaining a remarkable elongation of 29 % while achieving a high tensile strength of 1.87 GPa at 77 K. Insights from this study point to a feasible pathway to achieve both high strength and high ductility by rearranging the deformation modes of ultrafine-grained materials.