Markovian Limit Research Articles

Quantum regression theorem for multi-time correlators: A detailed analysis in the Heisenberg picture

The quantum regression theorem is one of the central results in open quantum systems and is extensively used for computing multi-point correlation functions. Traditionally it is derived for two-time correlators in the Markovian limit employing the Schr\"odinger picture. In this paper we make use of the Heisenberg picture to derive the quantum regression theorems for multi-time correlation functions, which in the special limit reduce to the well-known two-time regression theorem. For the multi-time correlation function we find that the regression theorem takes the same form as it takes for the two-time correlation function with a mild restriction that one of the times should be greater than all other time variables. Interestingly, the Heisenberg picture also allows us to derive an analog of regression theorem for out-of-time-ordered correlators. We further extend our study for the case of non-Markovian dynamics and report the modifications to the standard quantum regression theorem. We illustrate all of the above results using the paradigmatic dissipative spin-boson model.

Quantum corrections to the primordial tensor spectrum: open EFTs & Markovian decoupling of UV modes

Perturbative quantum corrections to primordial power spectra are important for testing the robustness and the regime of validity of inflation as an effective field theory. Although this has been done extensively for the density power spectrum (and, to some extent, for the tensor spectrum) using loop corrections, we do so in an open quantum system approach to the problem. Specifically, we calculate the first-order corrections to the primordial gravitational wave spectrum due to (cubic) tensor interactions alone. We show that our results match expectations from standard loop corrections only in the strict Markovian limit, and therefore, establish a systematic way to relax this approximation in the future, as is generally necessary for gravitational systems.

Quantifying Non-Markovianity in Open Quantum Dynamics

Characterization of non-Markovian open quantum dynamics is both of theoretical and practical relevance. In a seminal work [Phys. Rev. Lett. 120, 040405 (2018)], a necessary and sufficient quantum Markov condition is proposed, with a clear operational interpretation and correspondence with the classical limit. Here we propose two non-Markovianity measures for general open quantum dynamics, which are fully reconciled with the Markovian limit and can be efficiently calculated based on the multi-time quantum measurements of the system. A heuristic algorithm for reconstructing the underlying open quantum dynamics is proposed, whose complexity is directly related to the proposed non-Markovianity measures. The non-Markovianity measures and the reconstruction algorithm are demonstrated with numerical examples, together with a careful reexamination of the non-Markovianity in quantum dephasing dynamics.

Modeling and physically interpreting dissipative dynamics of a charge qubit–atom hybrid system under the Born–Markov limit

In this study, we model the dissipative dynamics of a charge qubit–atom hybrid model under the Born–Markov limit. Especially, we focus on the physical relation between spectral density and dissipative dynamics. Analytically, we show that, if spectral density in the dynamics is a nearly linear function, then relaxation and dephasing noises separately affect the gate capacitor and Josephson junction, respectively, but if the spectral density is a genuine-nonlinear function, then these two noises affect both the gate capacitor and Josephson junction. Further, we observe that in a numerical way, when the spectral density is a genuine-nonlinear function, there are some cases in which the corresponding environment dramatically breaks quantumness including purity and entanglement.

Single-photon scattering in a giant-molecule waveguide-QED system

We study the coherent single-photon scattering in a one-dimensional waveguide coupled to a giant artificial molecule consisting of two coupled giant atoms. Since each giant atom couples to the waveguide via two coupling points, the couplings of the molecule with the waveguide have three different coupling configurations: the separated-, braided-, and nested-coupling cases. We obtain the exact expressions of the single-photon transmission and reflection amplitudes with the real-space approach. It is found that the behavior of the scattering spectra depends on the phase shift between two neighboring coupling points, the coupling configuration, and the coupling between the two giant atoms. Concretely, we study the photon scattering in both the Markovian and non-Markovian regimes, in which the photon propagating time between two neighboring coupling points is neglected and considered, respectively. Under the Markovian limit, the asymmetric Fano line shapes in different coupling configurations of the giant-molecule waveguide-QED system can be obtained by choosing proper phase shift, and the transmission window can be adjusted by the coupling strength between the two giant atoms in these three coupling configurations. In particular, multiple reflection peaks and dips in these configurations are revived in the non-Markovian regime. This paper will pave the way for the study of controllable single-photon devices based on the giant-molecule waveguide-QED systems.

Quantum Dynamics with Electronic Friction.

A theory of electronic friction is developed using the exact factorization of the electronic-nuclear wave function. No assumption is made regarding the electronic bath, which can be made of independent or interacting electrons, and the nuclei are treated quantally. The ensuing equation of motion for the nuclear wave function is a nonlinear Schrödinger equation including a friction term. The resulting friction kernel agrees with a previously derived mixed quantum-classical result by Dou etal., [Phys. Rev. Lett. 119, 046001 (2017)]PRLTAO0031-900710.1103/PhysRevLett.119.046001, except for a pseudomagnetic contribution in the latter that is here removed. More specifically, it is shown that the electron dynamics generally washes out the gauge fields appearing in the adiabatic dynamics. However, these are fully re-established in the typical situation where the electrons respond rapidly on the slow time scale of the nuclear dynamics (Markov limit). Hence, we predict Berry's phase effects to be observable also in the presence of electronic friction. Application to a model vibrational relaxation problem proves that the proposed approach represents a viable way to account for electronic friction in a fully quantum setting for the nuclear dynamics.

Quantum theory of electronic friction

Electronic friction is an important energy loss channel for atoms and molecules scattering off, reacting, or simply vibrating at metallic surfaces. It is usually well described by mixed classical-quantum approaches where the nuclei evolve classically according to Langevin-type equations of motion, and Born-Oppenheimer forces and friction kernels are obtained from first-principles electronic structure calculations. However, classical dynamics falls short when light atoms are involved, which is also the situation where electronic friction becomes the dominant dissipation channel and its role in the dynamics can be unambiguously assessed. Furthermore, the interplay between electronic friction and nuclear quantum effects in molecular processes at surfaces is largely unknown; in fact, it is not even clear how to include electronic friction in a quantum setting. Here we fill this gap by developing a fully quantum theory of electronic friction at $T=0\phantom{\rule{0.16em}{0ex}}\mathrm{K}$. The electronic bath is considered to be entirely general and can be made of interacting electrons, potentially in a strongly correlated state. The derived friction kernel agrees with a recently obtained mixed quantum-classical result [Dou, Miao, and Subotnik, Phys. Rev. Lett. 119, 046001 (2017)], except for a pseudomagnetic contribution in the latter that is removed here. The ensuing equation of motion for the nuclear wave function is a nonlinear Schr\"odinger equation with a frictional vector potential that depends on the past wave function behavior. The equation becomes local-in-time in the typical situation where the electrons respond rapidly on the slow timescale of the nuclear dynamics (Markov limit) and generalizes previously known Schr\"odinger-Langevin equations to coordinate-dependent, tensorial friction kernels.

Retardation-dependent decaying modes of a single excitation in an atomic array coupled to a one-dimensional waveguide

We investigate the effects of retardation on the collective emissions from a linear array of $N\ensuremath{\ge}2$ atoms interacting with a one-dimensional field continuum. Decaying modes consisting of a single excitation in a photon-atom superposition with definite decay rates and frequency shifts are determined as a function of a retardation parameter proportional to the separation between atoms. In particular, the structures of these decaying modes are examined in terms of their photonic and atomic components. In addition to modes that resemble Dicke states in the Markovian limit, higher modes that decay much faster than Dicke superradiance exist. We find that these modes are dominantly photonic with field excitation localized near the edges of the array.

Heat current and entropy production rate in local non-Markovian quantum dynamics of global Markovian evolution

We examine the elements of the balance equation of entropy in open quantum evolutions and their response as we go from a Markovian to a non-Markovian situation. In particular, we look at the heat current and entropy production rate in the non-Markovian reduced evolution, as well as a Markovian limit of the same, experienced by one of two interacting systems immersed in a Markovian bath. The analysis naturally leads us to define a heat current deficit and an entropy production rate deficit, which are differences between the global and local versions of the corresponding quantities. The investigation leads, in certain cases, to a complementarity of the time-integrated heat current deficit and the relative entropy of entanglement between the two systems.

Canonical derivation of the fermionic influence superoperator

We present a canonical derivation of an influence superoperator which generates the reduced dynamics of a Fermionic quantum system linearly coupled to a Fermionic environment initially at thermal equilibrium. We use this formalism to derive a generalized-Lindblad master equation (in the Markovian limit) and a generalized version of the hierarchical equations of motion valid in arbitrary parity-symmetry conditions, important for the correct evaluation of system correlation functions and spectra.

Optimal Control for Quantum Optimization of Closed and Open Systems

We provide a rigorous analysis of the quantum optimal control problem in the setting of a linear combination $s(t)B+(1-s(t))C$ of two noncommuting Hamiltonians $B$ and $C$. This includes both quantum annealing (QA) and the quantum approximate optimization algorithm (QAOA). The target is to minimize the energy of the final ``problem'' Hamiltonian $C$, for a time-dependent and bounded control schedule $s(t)\in [0,1]$ and $t\in \mc{I}:= [0,t_f]$. It was recently shown, in a purely closed system setting, that the optimal solution to this problem is a ``bang-anneal-bang'' schedule, with the bangs characterized by $s(t)= 0$ and $s(t)= 1$ in finite subintervals of $\mc{I}$, in particular $s(0)=0$ and $s(t_f)=1$, in contrast to the standard prescription $s(0)=1$ and $s(t_f)=0$ of quantum annealing. Here we extend this result to the open system setting, where the system is described by a density matrix rather than a pure state. This is the natural setting for experimental realizations of QA and QAOA. For finite-dimensional environments and without any approximations we identify sufficient conditions ensuring that either the bang-anneal, anneal-bang, or bang-anneal-bang schedules are optimal, and recover the optimality of $s(0)=0$ and $s(t_f)=1$. However, for infinite-dimensional environments and a system described by an adiabatic Redfield master equation we do not recover the bang-type optimal solution. In fact we can only identify conditions under which $s(t_f)=1$, and even this result is not recovered in the fully Markovian limit. The analysis, which we carry out entirely within the geometric framework of Pontryagin Maximum Principle, simplifies using the density matrix formulation compared to the state vector formulation.

Coherent single-photon scattering spectra for a giant-atom waveguide-QED system beyond the dipole approximation

We investigate the single-photon scattering spectra of a giant atom coupled to a one dimensional waveguide via multiple connection points or a continuous coupling region. Using a full quantum mechanical method, we obtain the general analytic expressions for the single-photon scattering coefficients, which are valid in both the Markovian and the non-arkovian regimes. We summarize the influences of the non-dipole effects, mainly caused by the phases accumulated by photons traveling between coupling points, on the scattering spectra. We find that under the Markovian limit, the phase decay is detuning-independent, resulting in Lorentzian lineshapes characterized by the Lamb shifts and the effective decay rates. While in the non-Markovian regime, the accumulated phases become detuning-dependent, giving rise to non-Lorentzian lineshapes, characterized by multiple side peaks and total transmission points. Another interesting phenomenon in the non-Markovian regime is generation of broad photonic band gap by a single giant atom. We further generalize the case of discrete coupling points to the continuum limit with atom coupling to the waveguide via a continuous area, and analyze the scattering spectra for some typical distributions of coupling strength.

Quantum simulation of open quantum systems in heavy-ion collisions

We present a framework to simulate the dynamics of hard probes such as heavy quarks or jets in a hot, strongly coupled quark-gluon plasma (QGP) on a quantum computer. Hard probes in the QGP can be treated as open quantum systems governed in the Markovian limit by the Lindblad equation. However, due to large computational costs, most current phenomenological calculations of hard probes evolving in the QGP use semiclassical approximations of the quantum evolution. Quantum computation can mitigate these costs and offers the potential for a fully quantum treatment with exponential speed-up over classical techniques. We report a simplified demonstration of our framework on IBM Q quantum devices and apply the random identity insertion method to account for cnot depolarization noise, in addition to measurement error mitigation. Our work demonstrates the feasibility of simulating open quantum systems on current and near-term quantum devices, which is of broad relevance to applications in nuclear physics, quantum information, and other fields.

Synchronization and non-Markovianity in open quantum systems

Detuned systems can spontaneously achieve a synchronous dynamics and display robust quantum correlations in different local and global dissipation regimes. Beyond the Markovian limit, information backflow from the environment becomes a crucial mechanism whose interplay with spontaneous synchronization is unknown. Considering a model of two coupled qubits, one of which interacts with a dissipative environment, we show that non-Markovianity is highly detrimental for the emergence of synchronization, for the latter can be delayed and hindered because of the presence of information backflow. The results are obtained considering both a master equation approach and a collision model based on repeated interactions, which represents a very versatile tool to tailor the desired kind of environment.

Excitation Energy Transfer Efficiency in Fluctuating Environments: Role of Quantum Coherence in the Presence of Memory Effects.

Several recent studies have interrogated the role of quantum coherence in affecting the transfer efficiency of an optical excitation to the designated "trap" state where the energy can be used for subsequent reactions, as in photosynthesis. However, these studies invoke a Markovian approximation for the time correlation function describing the environment-induced stochastic fluctuations. Here, we employ Kubo's quantum stochastic Liouville equation (QSLE) to include memory effects. We extend the existing QSLE scheme to introduce decay of a newly created excitation due to radiative and nonradiative channels and also by desired trapping toward the targeted chromophore. We show that the theoretical formalism based on the QSLE correctly reproduces the rate equation description in the Markovian limit, with the rate constants determined by an appropriate quantum limiting procedure. We find that under certain conditions, the efficiency of excitation transfer to the trap gains from the combined presence of quantum coherence and temporally correlated stochastic fluctuations. We work out different limiting situations in order to discover and quantify the optimum conditions for the energy transfer to the trapped state. We find that maximum energy transfer efficiency is achieved in the intermediate limit between coherent and incoherent transport.

Introducing Memory in Coarse-Grained Molecular Simulations.

Preserving the correct dynamics at the coarse-grained (CG) level is a pressing problem in the development of systematic CG models in soft matter simulation. Starting from the seminal idea of simple time-scale mapping, there have been many efforts over the years toward establishing a meticulous connection between the CG and fine-grained (FG) dynamics based on fundamental statistical mechanics approaches. One of the most successful attempts in this context has been the development of CG models based on the Mori–Zwanzig (MZ) theory, where the resulting equation of motion has the form of a generalized Langevin equation (GLE) and closely preserves the underlying FG dynamics. In this Review, we describe some of the recent studies in this regard. We focus on the construction and simulation of dynamically consistent systematic CG models based on the GLE, both in the simple Markovian limit and the non-Markovian case. Some recent studies of physical effects of memory are also discussed. The Review is aimed at summarizing recent developments in the field while highlighting the major challenges and possible future directions.

Effect of Memory and Inertial Contribution on Transition-Time Distributions: Theory and Simulations.

Transition paths refer to the time taken by molecules to cross a barrier separating two molecular conformations. In this work, we study how memory, as well as inertial contribution in the dynamics along a reaction coordinate, can affect the distribution of the transition-path time. We use a simple model of dynamics governed by a generalized Langevin equation with a power-law memory along with the inertial term, which was neglected in previous studies, where memory effects were explored only in the overdamped limit. We derive an approximate expression for the transit-time distribution and discuss our results for the short- and long-time limits and also compare it with known results in the high friction (overdamped) limit as well as in the Markovian limit. We have developed a numerical algorithm to test our theoretical results against extensive numerical simulations.

Quantum transport in non-Markovian dynamically disordered photonic lattices

We theoretically show that the dynamics of a driven quantum harmonic oscillator subject to non-dissipative noise is formally equivalent to the single-particle dynamics propagating through an experimentally feasible dynamically-disordered photonic network. Using this correspondence, we find that noise assisted energy transport occurs in this network and, if the noise is Markovian or delta-correlated, we can obtain an analytical solution for the maximum amount of transferred energy between all network's sites at a fixed propagation distance. Beyond the Markovian limit, we further consider two different types of non-Markovian noise and show that it is possible to have efficient energy transport for larger values of the dephasing rate.

Constructing many-body dissipative particle dynamics models of fluids from bottom-up coarse-graining

Since their emergence in the 1990s, mesoscopic models of fluids have been widely used to study complex organization and transport phenomena beyond the molecular scale. Even though these models are designed based on results from physics at the meso- and macroscale, such as fluid mechanics and statistical field theory, the underlying microscopic foundation of these models is not as well defined. This paper aims to build such a systematic connection using bottom-up coarse-graining methods. From the recently developed dynamic coarse-graining scheme, we introduce a statistical inference framework of explicit many-body conservative interaction that quantitatively recapitulates the mesoscopic structure of the underlying fluid. To further consider the dissipative and fluctuation forces, we design a novel algorithm that parameterizes these forces. By utilizing this algorithm, we derive pairwise decomposable friction kernels under both non-Markovian and Markovian limits where both short- and long-time features of the coarse-grained dynamics are reproduced. Finally, through these new developments, the many-body dissipative particle dynamics type of equations of motion are successfully derived. The methodologies developed in this work thus open a new avenue for the construction of direct bottom-up mesoscopic models that naturally bridge the meso- and macroscopic physics.

Stationary properties of a non-Markovian Brownian gyrator

We investigate the stochastic behavior of a non-Markovian version of an elementary Brownian gyrator. The model is defined by overdamped Langevin-like dynamics with a two-dimensional harmonic potential that presents distinct principal axes and is coupled to heat baths at different temperatures. The thermal noises are assumed to be Gaussian, and are related to friction forces through a dissipation memory kernel. The stationary states present rotational motion with non-trivial average torques due to harmonic, friction and fluctuating thermal forces. However, the Markovian limit of the system exhibits a zero average torque produced by fluctuating thermal forces. For the case of stochastic torque exerted by harmonic force, the cumulant-generating function is calculated exactly. We also study the average heat fluxes in the steady-state regime, where a memory-dependent behavior is observed.