Marine Sediments Research Articles

Dependence of the formation kinetics of carbon dioxide hydrate on clay aging for solid carbon dioxide storage

Clay-based marine sediments have great potential for safe and effective carbon dioxide (CO2) encapsulation by storing enormous amounts of CO2 in solid gas hydrate form. However, the aging of clay with time changes the surface properties of clay and complicates the CO2 hydrate formation behaviors in sediments. Due to the long clay aging period, it is difficult to identify the role of clay aging in the formation of CO2 hydrate in marine sediments. Here, we used ultrasonication and plasma treatment to simulate the breakage and oxidation of clay nanoflakes in aging and investigated the influence of clay aging on CO2 hydrate formation kinetics. We found that the breakage and oxidation of clay nanoflakes would disrupt the siloxane rings and graft hydroxyl on the clay nanoflakes. This decreased the negative charge density of clay nanoflakes and weakened the interfacial interaction of clay nanoflakes with the surrounding water. Therefore, the small clay nanoflakes enriched in hydroxyl would disrupt the surrounding tetrahedral water structure analogous to the CO2 hydrate, resulting in the prolongation of CO2 hydrate nucleation. These results revealed the influence of the structure-function relationship of clay nanoflakes with CO2 hydrate formation and are favorable for the development of hydrate-based CO2 storage.

Manganese reduction and associated microbial communities in Antarctic surface sediments.

The polar regions are the fastest warming places on earth. Accelerated glacial melting causes increased supply of nutrients such as metal oxides (i.e., iron and manganese oxides) into the surrounding environment, such as the marine sediments of Potter Cove, King George Island/Isla 25 de Mayo (West Antarctic Peninsula). Microbial manganese oxide reduction and the associated microbial communities are poorly understood in Antarctic sediments. Here, we investigated this process by geochemical measurements of in situ sediment pore water and by slurry incubation experiments which were accompanied by 16S rRNA sequencing. Members of the genus Desulfuromusa were the main responder to manganese oxide and acetate amendment in the incubations. Other organisms identified in relation to manganese and/or acetate utilization included Desulfuromonas, Sva1033 (family of Desulfuromonadales) and unclassified Arcobacteraceae. Our data show that distinct members of Desulfuromonadales are most active in organotrophic manganese reduction, thus providing strong evidence of their relevance in manganese reduction in permanently cold Antarctic sediments.

Effect of particle size distribution of sediments on development of polder soils in Japan

Abstract Purpose Polder soils develop from oceanic and lacustrine sediments covered with seawater, brackish water, and freshwater after artificial drainage. Because there are several concerns regarding the agricultural use of polder soils, soil genesis and properties have been considerably surveyed, mainly focusing on problematic soils developed from fine sediments. Although sediments have a wide range of particle size distributions due to different sedimentary conditions, particle size of parent materials have not been well addressed to understand the soil developmental process. In this study, Japanese polders with different reclamation ages and sedimentary conditions were surveyed to clarify the soil formation process and factors affecting pedogenesis. Materials and methods Soil samples were collected from 15 soil profiles in six Japanese polders under different land use types. Sedimentary conditions of polders were evaluated from particle size distributions using the hydrodynamic classification proposed by Pejrup (The triangular diagram used for classification of estuarine sediments: a new approach. Tide-influenced Sediment Environ Facies, pp 289–300, 1988). The major soil-forming factors of polders were extracted by principal component analysis (PCA) using general soil properties. Results and discussion Brackish lake and inner bay polders were characterized by calm hydrodynamic conditions comprising fine particles. Two polders reclaimed from a shallow inland sea were characterized by violent hydrodynamic conditions. Sandy sediments were also characteristic of immature soils reclaimed from a freshwater lake and an estuarine tidal flat. Soils on polders developed under calm hydrodynamic conditions enabled the accumulation of high total carbon content. The soil-forming process in the brackish bay oxidized pyrite, leading to an acidic soil reaction. Conversely, soils developed from sandy sediments were characterized by low iron content. The PCA extracted two factors explained by particle size and soil reaction relating to acidification and salt leaching. Conclusion Polder soils can be mainly discriminated by their particle size distributions, which are characterized by hydrodynamics under the sedimentary conditions, and the polder soil development is affected by water management in land uses after artificial drainage.

Elemental distributions in the marine sediments off Doha, Qatar: role of urbanisation and coastal dynamics

This research investigates the present status and decadal variability of element distributions in the marine sediments off Doha, on the east coast of Qatar. Twenty elements were considered from 11 sediment sampling stations and 3 dust sampling stations by grouping them into major elements, toxic elements, and other trace elements. The results show elevated concentrations of certain toxic and trace elements, including Ba, Be, Co, Cr, Cu, Fe, Mg, V, Zn, Mg, and Ti, in the nearshore region, primarily influenced by the settling of dissolved elements under weak hydrodynamic circulations in the Doha Bay. The relatively higher currents in offshore enable quick advection and dispersion of the elements. On the other hand, the dust deposits have caused significant contributions to the Al, As, Mg, Ca, Sr, Fe, Zn, and Cd concentrations. Decadal variability is evident in element concentrations, which are linked to the urbanisation of the capital city in the State of Qatar. The Cu, Ni, V, Zn, and Cd concentrations indicate a notable increase in recent years compared to the last two decades, with values of about 20.7, 17.9, 25.0, 25.9, 0.66 ppm in 2022. In contrast, a few other elements fluctuate between the decades/years. The results pointed out the increased elemental concentrations in the bay due to the vast expansion of infrastructure facilities in the vicinity of Doha Bay in recent years. The Geoaccumulation Index resulted in a slight pollution of Cd, while other elements are unpolluted. The Degree of Contamination reveals low degree of contamination of sediments, and the Pollution Load Index illustrates no significant pollution in the sediments off Doha.

A new pseudosuchian from the Favret Formation of Nevada reveals that archosauriforms occupied coastal regions globally during the Middle Triassic.

Recent studies suggest that both stem- and crown-group Archosauria encompassed high ecological diversity during their initial Triassic radiation. We describe a new pseudosuchian archosaur, Benggwigwishingasuchus eremicarminis gen. et sp. nov., from the Anisian (Middle Triassic) Fossil Hill Member of the Favret Formation (Nevada, USA), a pelagic setting in the eastern Panthalassan Ocean characterized by the presence of abundant ammonoids and large-bodied ichthyosaurs. Coupled with archosauriforms from the eastern and western Tethys Ocean, Benggwigwishingasuchus reveals that pseudosuchians were also components of Panthalassan ocean coastal settings, establishing that the group occupied these habitats globally during the Middle Triassic. However, Benggwigwishingasuchus, Qianosuchus, and Ticinosuchus (two other pseudosuchians known from marine sediments) are not recovered in a monophyletic group, demonstrating that a nearshore marine lifestyle occurred widely across Archosauriformes during this time. Benggwigwishingasuchus is recovered as part of an expanded Poposauroidea, including several taxa (e.g. Mandasuchus, Mambawakalae) from the Middle Triassic Manda Beds of Tanzania among its basally branching members. This implies a greater undiscovered diversity of poposauroids during the Early Triassic, and supports that the group, and pseudosuchians more broadly, diversified rapidly following the End-Permian mass extinction.

Interlaboratory Comparison of Branched GDGT Temperature and pH Proxies Using Soils and Lipid Extracts

AbstractRatios of glycerol dialkyl glycerol tetraethers (GDGT), which are membrane lipids of bacteria and archaea, are at the base of several paleoenvironmental proxies. They are frequently applied to soils as well as lake‐ and marine sediments to generate records of past temperature and soil pH. To derive meaningful environmental information from these reconstructions, high analytical reproducibility is required. Based on submitted results by 39 laboratories from across the world, which employ a diverse range of analytical and quantification methods, we explored the reproducibility of brGDGT‐based proxies (MBT′5ME, IR, and #ringstetra) measured on four soil samples and four soil lipid extracts. Correct identification and integration of 5‐ and 6‐methyl brGDGTs is a prerequisite for the robust calculation of proxy values, but this can be challenging as indicated by the large inter‐interlaboratory variation. The exclusion of statistical outliers improves the reproducibility, where the remaining uncertainty translates into a temperature offset from median proxy values of 0.3–0.9°C and a pH offset of 0.05–0.3. There is no apparent systematic impact of the extraction method and sample preparation steps on the brGDGT ratios. Although reported GDGT concentrations are generally consistent within laboratories, they vary greatly between laboratories. This large variability in brGDGT quantification may relate to variations in ionization efficiency or specific mass spectrometer settings possibly impacting the response of brGDGTs masses relative to that of the internal standard used. While ratio values of GDGT are generally comparable, quantities can currently not be compared between laboratories.

Genomic stasis over millions of years in subseafloor sediment.

One of the significant challenges in microbiology is to understand the extent and mechanisms of evolution within life beneath the surface of the Earth. The population bottleneck that microbes in deep marine sediment experience implies that mutational and population genetic forces could lead to higher levels of relaxed selection and an increase in pseudogenes. To investigate this hypothesis, a group of Thalassospira strains were isolated from subseafloor sediment that is 3 to 6 million years old, as reported by Orsi and colleagues in 2021. These isolates, representing lineages that have been buried for millions of years, offer an excellent opportunity to study the evolution of life beneath the seafloor over a long period. The existence of closely related strains from environments on the surface of the Earth enabled us to examine the impact of selection within each group. We discovered that isolates from beneath the seafloor show lineage-specific similarities to Thalassospira from the surface world, both in the overall intensity of selection on the genome and in the specific genes affected by mutation. We found no signs of increased relaxed selection or other notable genomic changesin the genomes of the Thalassospira isolates from beneath the seafloor, suggesting that these subseafloor isolates were awakened from a million-year near-stasis. The unique genomic characteristics of each Thalassospira lineage from beneath the seafloor must then reflect genetic changes that surface-inhabiting decendants acquired in the past 3-6 million years. Remarkably, Thalassospira lineages beneath the surface appear to have stably maintained their genomes in the midst of metabolic dormancy and extremely long generation times.

Morphological deformities in benthic foraminiferal assemblages from shallow marine and lagoonal environments of the western Arabian Gulf

Abstract This study examines larger and smaller benthic foraminiferal assemblages at six localities from western Arabian Gulf, documenting their diversity, abundance, and morphological deformities across a salinity gradient. Both unstained and stained samples were used to quantify species diversity, percent of deformities, and bulk quantity at each site. These samples revealed that 109 species were present and approximately one-quarter of specimens were alive during the sampling period. We observed different morphological deformities with various degrees of severity and an increasing overall percentage of deformities across a salinity gradient from 40 to 68.5 PSU (averaging >40%). Environmental analysis of marine sediment revealed no dangerous levels of anthropogenic stressors, such as trace metals or organic pollutants. Therefore, morphological deformities in the benthic foraminifera are likely salinity-induced (owing to a salinity gradient or seasonal change), as deformities are primarily observed in the adult specimens.

Return to the Ross Ice Shelf Project (RISP), Site J-9 (1977–1979): perspectives of West Antarctic Ice Sheet history from Miocene and Holocene benthic foraminifera

Abstract. In 1977–1978 and 1978–1979, the Ross Ice Shelf Project (RISP) recovered sediments from beneath the largest ice shelf in Antarctica at Site J-9 (∼82° S, 168° W), ∼450 km from open marine waters at the calving front of the Ross Ice Shelf and 890 km from the South Pole, one of the southernmost sites for marine sediment recovery in Antarctica. One important finding was the discovery of an active macrofauna, including crustaceans and fish, sustained below the ice shelf far from open waters. The sediment has a thin, unconsolidated upper unit (up to 20 cm thick) and a texturally similar but compacted lower unit (>1 m thick) containing reworked early, middle, and late Miocene diatom and calcareous benthic foraminiferal assemblages. A probable post-Last Glacial Maximum (LGM) disconformity separates the upper unit containing a dominantly agglutinated foraminiferal assemblage, from the lower unit consisting mostly of reworked Miocene calcareous benthic species, including Trifarina fluens, Elphidium magellanicum, Globocassidulina subglobosa, Gyroidina sp., and Nonionella spp. The presence of the polar planktic foraminiferal species Neogloboquadrina pachyderma and the endemic Antarcticella antarctica supports the late Miocene diatom age for the matrix of the lower unit. The microfossil assemblages indicate periods of ice sheet collapse and open-water conditions south of Site J-9 during warm intervals of the early, middle, and late Miocene, including the Miocene Climatic Optimum (∼17–14.7 Ma), demonstrating the dynamic nature of the West Antarctic Ice Sheet (WAIS) and Ross Ice Shelf during the Neogene. The foraminiferal assemblage of the upper unit is unique to the Ross Sea and suggests the influence of a sub-ice-shelf water mass proximal to the retreating post-LGM grounding zone. This unique assemblage is strongly dominated by the bathyal, cold-water agglutinated genus Cyclammina.

A multi-orientation system for characterizing microstructure changes and mechanical responses of fine-grained gassy sediments associated with gas hydrates.

Fine-grained marine sediments containing veiny and nodular gas hydrates will evolve into fine-grained gassy sediments after hydrate dissociation due to climate-driven ocean warming. The mechanical properties of the fine-grained gassy sediments are basically acquired by ocean engineering design. However, they have not been fully understood, largely due to the lack of microstructure visualization. In this paper, a new system is developed to jointly conduct x-ray computed tomography scans, oedometer tests, and seismic wave testing on a single specimen with temperature being well controlled, allowing varieties of experimental data to be acquired effectively and automatically. The results show that stress history can hardly affect the undrained stiffness of fine-grained gassy sediments, while the drained stiffness of fine-grained sediments without gas bubbles is stress history dependent. After being unloaded, many microstructure changes remain, and examples include the free gas distribution being more concentrated and the connectivity among gas bubbles becoming much better. The multi-orientation system lays the foundation for further studies on the microstructure changes and mechanical responses of fine-grained gassy sediments associated with gas hydrates.

Siliciclastic Reservoir Geo-modeling using TGS-SIS hybrid algorithm of the Upper Cibulakan Formation, Offshore Northwest Java Basin

Abstract The Upper Cibulakan is the primary hydrocarbon-producing formation in the Offshore Northwest Jawa area, operated by PHE ONWJ (Pertamina Hulu Energy Offshore Northwest Jawa). The productive interval in this formation comprises alternating sandstone and shale up to 45 feet of thick. Geologically, this interval is a shallow marine deposit with strong influence of tidal in the Ardjuna Sub-Basin, offshore part of Northwest Jawa Basin. The good quality reservoir layer is associated with Tidal Sand Ridges (TSR) facies characterized by lenticular sedimentary structures and the occurrence of shale intercalation in sandstone. The occurrence of shale, regarding its facies association package, varies greatly and significantly determines the quality of the reservoir. The geometry and quantity of facies distribution and association will significantly affect the calculation of hydrocarbon reserves during the modelling processes. Considering this, the selection of modeling methods and algorithms must be carried out appropriately. The use of the SIS (Sequential Indicator Simulation) algorithm in describing the TSR facies distribution still has shortcomings in randomness. Correspondingly, it requires to be combined with the TGS (Truncated Gaussian Simulation) method as it plays a great impact in calculating the distribution of sandstone and reservoir geometry. Meanwhile, SIS defines shale intercalation within TSR facies. Combining these two methods produces a more precise model of TSR facies associations. Besides, the concept of reservoir deposition is easier to explain based on the outcome result from the combined methods.

Palynology of the Albian–Turonian sediments from the Sumbe region, Kwanza Basin (Angola): Implications for paleoenvironment, paleoclimate, and paleogeography

Palynological investigations in the Sumbe region of the Kwanza Basin, Angola, have identified Albian to Turonian assemblages in four sections of the Quissonde Facies of the Mucanzo, Cabo Ledo, and Itombe formations. These studies aimed to determine their biostratigraphic ages and infer paleoenvironmental, paleoclimatic, and paleogeographic models. The presence of Odontochitina costata, Palaeohystrichophora infusorioides, and Xiphophoridium alatum cysts supports an upper Albian to lower Cenomanian age for the Mucanzo Formation. Litosphaeridium siphoniphorum cyst and the Elateroplicites africaensis pollen found In the Cabo Ledo Formation suggest a Cenomanian age, while Conosphaeridium striatoconum, Heterosphaeridium difficile, and Dinogymnium acuminatum supports a Turonian age for the lower part of the Itombe Formation. All samples predominantly contain fluorescent amorphous organic matter (AOM) derived from phytoplankton degradation, with increasing AOM in the uppermost units, indicating inner neritic marine deposition under dysoxic-anoxic conditions. During the Lower to mid-Cretaceous, the Gondwana breakup caused significant changes, with the palynological indicating a Tethyan affinity with some high-latitude taxa, suggesting a cosmopolitan distribution. The subtropical to tropical nature of the assemblages, along with high-latitude species, indicates a mid-Cretaceous water connection between the Central Atlantic and the South Atlantic oceans, extending to the Kwanza Basin.

Early diagenetic microbial induced cementation in Late Pleistocene (MIS 5e) shallow-water marine deposits of the Taranto Gulf (South Italy)

Early diagenetic microbial induced cementation in Late Pleistocene (MIS 5e) shallow-water marine deposits of the Taranto Gulf (South Italy)

Characteristics of sediments and regolith alterations in the Plio-Pleistocene succession, coastal cliff sections, St Vincent Basin, South Australia

Syn- and post-depositional alterations are distinguished in a detailed lithological and mineralogical study of the largely unconsolidated Plio-Pleistocene non-marine succession in coastal cliff sections in the St Vincent Basin south of Adelaide. At its base, the sequence interfingers with Late Pliocene estuarine marine sediments in places but mostly unconformably overlies older Cenozoic marine sediments or Neproterozoic bedrock. The fluvial and alluvial siliclastics have bioturbation, blocky-prismatic macro-peds and subtle Fe-mottling indicators of hiatuses in deposition, and imprints of soil and shallow groundwater environments. A relative abundance of kaolinite, illite and randomly interstratified illite-smectite reflects both sediment source and conditions in the local depositional environment. A thick deposit of aeolian calcareous silt with associated pedogenic calcretes blankets the succession. Conspicuous bleached Fe mega-mottled intervals and zones of alunite-halloysite within the sequence record post-depositional, groundwater-related alterations in regolith environments. These formed during incision and erosion of the sedimentary fill in the basin in response to regional falls in base level. Each marks a different time and specific geomorphic environment according to the chemistry of the discharge of local groundwaters from aquifers that were intersected by incision and scarp retreat.

MASS-WASTING INDUCED SHIFTS OF THE BASE OF THE GAS HYDRATE STABILITY ZONE: EXAMPLES FROM THE OFFSHORE NIGER DELTA BASIN, NIGERIA

Mass-wasting episodes lead to significant changes in the pressure and temperature regimes within shallow marine sediments and induce variations in the thickness of the gas hydrate stability zone. These variations are marked by vertical migrations of bottom-simulating reflections that typically mark the base of the hydrate zone. Using exploration seismic data from the Offshore Niger Delta, this study presents two examples involving the vertical migration of the base of the gas hydrate stability zones induced by mass-wasting events. The first is related to a slope failure surface along the forelimb of an active thrust-cored anticline with considerable bathymetric relief. Sediment removal has induced both a decrease in overburden pressure and an incursion of cooler temperature flux in strata in the anticline and led to a migration of the base of the gas hydrate stability zone to deeper levels. The second case is related to a recent erosional event that has led to sediment removal along a seafloor channel course. Evidence of ongoing migration of the base of the gas hydrate stability zone to deeper levels is provided by the lateral termination of a BSR along channel wall, its absence beneath the channel bottom and its apparent downward bend close to the channel fringes. Apart from unroofing hydrate systems and releasing free gas into the ocean and possibly the atmosphere, mass-wasting events on the seafloor, represent significant drivers influencing the formation of gas hydrates in shallow subsea sediments and the thickness and depths of the gas hydrate stability zone.

Sedimentology and biostratigraphy of the Biancone Limestone Formation of the Tolmin Basin (Southern Alps, NW Slovenia)

The Tolmin Basin constitutes the western part of the Slovenian Basin, a large Mesozoic interplatform basin that was bounded to the north by the Julian Carbonate Platform and to the south by the Dinaric Carbonate Platform. Today, it is found along the structural boundary between the Southern Alps and the External Dinarides in northwestern Slovenia. After the drowning of the Julian Carbonate Platform, the Tolmin Basin was dominated by pelagic deposits, namely the Toarcian marlstones (Perbla Formation), the Aalenian to lower Tithonian siliceous limestones and radiolarites (Tolmin Formation), and the upper Tithonian to the Berriasian Biancone Limestone Formation. In this study, a basin-scale sedimentary evolution and calpionellid biostratigraphy of the latter is presented. The Biancone Limestone Formation is a calpionellid-bearing pelagic limestone typical of all deepened segments of the Adria microplate in this time interval. It is generally monotonous but shows considerable vertical and lateral variations. The lower boundary with radiolarites is sharp, revealing a pronounced and rapid overturn in pelagic sedimentation. The lower Berriasian slumps indicate a tectonic pulse. Rare beds of resedimented limestones, assigned to the middle Berriasian, are similar in composition to those intercalated in the underlying radiolarites. They thus show that the factors that led to a significant shift in pelagic sedimentation had little or no effect on shallow-marine carbonate production. In the upper Berriasian, an increase in clay content is evident in the formation, which is explained by the uplift and erosion of the propagating thrust belt in the Neotethys area, superimposed by humidification.

Biogenic Calcium Carbonate: Phase Conversion in Aqueous Suspensions

Powdered biogenic calcium carbonate from butter clams shows variations in its tendency to convert from aragonite to calcite when suspended in water, depending on whether the suspension has additional calcite or not. Our investigations treat these biogenic samples as complex hierarchical materials, considering both their mineral and organic components. We assess the mineral composition from Attenuated Total Reflection Fourier Transform Infrared spectroscopy peak shifts, as well as quantitative assessments of lattice constant refinements (powder X-ray diffraction). To isolate the mineral portions, we compare results from samples where the periostracum is removed mechanically and samples that are heated to temperatures that are sufficient to remove organic material but well below the temperature for thermal phase conversion from aragonite to calcite. The results show that the total organic content does not play a significant role in the aqueous mineral phase conversion. These results have potential implications for understanding carbonate mineral interactions in ocean sediments.

Role of river transport and coastal abrasion in forming modern coastal and marine sediments in the Northwestern Black Sea

Role of river transport and coastal abrasion in forming modern coastal and marine sediments in the Northwestern Black Sea

Cretaceous geology and stratigraphy of Morocco and adjacent coastal basins

The Cretaceous marine sediments of Morocco and adjacent coastal basins provide an outstanding archive of environmental diversity from extended shelf seas and marginal basins along the Atlantic and Tethyan margins to deep oceanic basins of the western Tethys and eastern Atlantic Ocean. The geological highlights of Morocco's fascinating landscape include records of Lower Cretaceous Tethyan marginal and deep-water clastic sequences in the Rif mountain chain (submarine fan systems of the Massylian and Mauretanian flysch units), as well as siliciclastic sedimentary sequences in subsiding coastal basins (TanTan Delta), which extend offshore along the NW African Atlantic margin. Vestiges of the Aptian to Turonian greenhouse climate, sea-level highstands and oceanic anoxic events are exceptionally well preserved in Tethyan marginal and deep-water sedimentary successions of the Rif, in Atlantic coastal basins and as transgressive pulses on the Moroccan Meseta, Sahara platform and High Atlas rift system. Furthermore, sedimentary expressions of the tectonic movements between the African and European plates associated with the end Cretaceous climate and sea-level changes are documented in the Rif mountain chain, in coastal basins, and in the massive marginal marine phosphorite sedimentation in the Middle and High Atlas, on the Moroccan Meseta and Sahara platform. The Cretaceous sedimentary archives from Morocco and adjacent coastal basins still retain untapped potential to further contribute to our understanding of global eustatic sea-level changes and the response of the oceans and marine biota in upwelling driven oxygen minimum zones under greenhouse climate conditions.

Holocene Sediments оf the Adycha River Valley, Yakutia

Palynological analysis of radiocarbon-dated sediments from floodplain deposits and peat bogs preserved in the terraces along the Adycha River, a tributary of the Yana River, document the regional presence of larch forests over at least the last 10 500 14C BP (12 500 cal BP). The Adycha records indicate that the most favorable climatic conditions during this interval occurred during the Early Holocene, persisting up to 8 200 14C BP (9 200 cal BP), and during the Middle Holocene between c. 6 000-5 100 14C BP (6 900-5 800 cal BP). Climatic warming also happened between 400-190 calendar years ago, following the cooling of the Little Ice Age. The expansion of Pinus pumila into the Yana River basin occurred c. 7 000 14C BP (7 800 cal BP). A date of 8 200 14C BP falls within an interval of global cooling, referred to as the Bond 5 event, as defined from North Atlantic marine deposits.