Marine Limestones Research Articles

Cenozoic Dynamic Topography of Madagascar

AbstractIt has been proposed that Oligo‐Miocene regional uplift of Madagascar was generated and is maintained by mantle dynamical processes. Expressions of regional uplift include flat‐lying Upper Cretaceous‐Paleogene marine limestones that crop out at elevations of hundreds of meters along the western seaboard and emergent Quaternary coral‐rich terraces that rim the coastline. Here, we explore the history of subcrustal topographic support through a combined analysis of four sets of observational constraints. First, we exploit published receiver function estimates of crustal thickness and spectral admittance between gravity and topography. An admittance value of ∼+40 ± 10 mGal km−1 at wavelengths >500 km implies that ∼1 km of topography is supported by subcrustal processes. Secondly, new apatite fission‐track and helium measurements from 18 basement samples are inverted, constraining temperature and denudation histories. Results suggest that 0.5–1.6 km of regional uplift occurred after ∼30 Ma. Thirdly, we calculate a history of regional uplift by minimizing the misfit between observed and calculated longitudinal river profiles. Results suggest that topography was generated during Neogene times. Finally, inverse modeling of rare earth element concentrations in Neogene mafic rocks indicates that melting of the asthenospheric source occurred at depths of ≤65 km with potential temperatures of 1300–1370 °C. Melting occurred at higher temperatures beneath Réunion Island and northern Madagascar and at lower temperatures beneath the Comores and southern Madagascar. These inferences are consistent with shear wave velocities obtained from tomographic models. We conclude that Madagascar is underlain by thinned lithospheric mantle and that a thermal anomaly lies within an asthenospheric layer beneath northern Madagascar.

The Truong Son, Loei-Phetchabun, and Kontum Terranes in Indochina: Provenance, Rifting, and Collisions

The three main regions of Indochina are defined as the Truong Son, Loei-Phetchabun, and Kontum terranes. The aim of this review is to integrate numerous petrological studies with sedimentary, palaeontological, and provenance studies in order to construct a preliminary tectonic model which shows the terranes docked in the earliest Carboniferous (Truong Son with Loei-Phetchabun) and in the Permian (Kontum). The Kontum Terrane is characterized by Proterozoic magmatism, mid-Ordovician to Early Devonian granites, and Permian charnockites. Major carbonate platforms developed in the Givetian to earliest Tournaisian on Truong Son and from the Visean to mid-Permian across Truong Son and Loei-Phetchabun terranes. The Truong Son has Silurian granites and a Late Ordovician to Silurian magmatic arc along its southern and western borders caused by subduction of oceanic lithosphere, the remnants of which are now partially preserved in the Loei and Tamky sutures. A region to the east of the Loei Suture in the Loei Foldbelt has a similar-age volcanic arc extending northwards into Laos and is included in Truong Son. A platform-margin coral-stromatoporoid reef developed on Truong Son in the Frasnian and was coincident with a gap in magmatism until the Pennsylvanian with granite magmatism became widespread until the Late Triassic. In the Loei-Phetchabun Terrane, Devonian siliciclastics, volcanics are overlain by Givetian limestones and patch reefs and in turn overlain by Late Devonian to earliest Tournaisian radiolarian cherts and siliciclastics. Tournaisian to early Visean siliciclastic turbidites were coincidental with initial uplift and deformation and were replaced by Visean terrestrial evaporites and coal and marine limestones. Arc magmatism along the Loei-Phetchabun Terrane indicates intermittent eastward subduction from mid-Devonian to mid-Triassic. Carboniferous-Triassic volcanism extends eastward along the northern margin of Cambodia and is probably an extension of Loei-Phetchabun. Ordovician within-plate basalts in Kontum and the transition from shallow marine Ordovician siliciclastics to Silurian deep-marine sediments and a volcanic arc in Truong Son suggest rifting of both terranes from Gondwana in the Late Ordovician. Initial docking of Truong Son with South China was probably in the late Silurian to Early Devonian and docking of Loei-Phetchabun and Truong Son was in the late Tournaisian to early Visean.

Substantial heterogeneity of carbon and oxygen stable-isotope compositions of single layers or specimens of natural carbonate materials: New evidence from replicate sampling of continental carbonates affirms previous evidence from marine limestones

ABSTRACT The uncertainty of measurements of carbon and oxygen stable-isotope ratios of carbonate materials is commonly assumed to be the analytical uncertainty determined from replicate analyses of single samples, but this ignores the possibility that heterogeneity of the material studied is greater than the analytical uncertainty. To test this question, we took eight samples from each of 13 layers or specimens of various non-marine (“continental”) carbonates and found ranges of δ13C and δ18O of 0.3 to 5.1‰, all exceeding the range of the typical lab-reported analytical uncertainty, ± 0.1‰, placed around single samples. These results are similar to previous replicate sampling of marine limestone layers, which revealed ranges of 0.2 to 2.8‰. Both sets of results, and other published data, demonstrate that analytical uncertainty derived from replicate analysis of a single sample is not a valid estimate of the uncertainty of δ13C or δ18O values characterizing a layer or specimen, and they remind us that we should not place great credence in anomalies or events defined by single samples of layers or specimens, regardless of the replication of analysis of that single sample. Our results indicate that the required layer-level or specimen-level uncertainty can be derived only from replicate sampling at different locations in layers or specimens, and that the layer-level or specimen-level uncertainty is inevitably greater than typical lab-reported analytical uncertainty. Credibility of anomalies or events in time series would be increased by replicate sampling of a random or dispersed subset of layers to estimate the variability of all layers and/or by replicate sampling of layers at and around a potential but unconfirmed event. The significance of the variability discussed above is evident in use of δ18O data to estimate paleotemperatures, where a difference of 1‰ in δ18O implies a difference of 4°C in temperature. Use of a single sample resulting in mischaracterization of the δ18O of an ancient material by 1.5‰ relative to the true mean for that material (which our results suggest is quite possible) would lead to a corresponding misestimation of temperature of 6°C, a significant difference in paleoenvironmental studies.

Sedimentology and geochemistry of Carboniferous-Permian marine-continental transitional shales in the eastern Ordos Basin, North China

A continuously cored well covering the Carboniferous-Permian Benxi, Taiyuan, and Shanxi formations in the eastern Ordos Basin provides a rare window into environmental conditions of the marine-continental transitional strata. Integration of petrographic, mineralogical, and high-resolution geochemical data allows marine-continental investigating the depositional environment, organic abundance, detrital influx, paleoclimate, paleo-water salinity, and paleoredox conditions of transitional facies. The marine-continental transitional strata in the Upper Carboniferous to Lower Permian consist of complex interbedding of sandstone, shale, coal and limestone. TOC contents display a considerable change in the vertical direction, with high TOC content in coal, moderate TOC in shale, low TOC content in limestone and no noticeable TOC enrichment in sandstone. The Upper Carboniferous Benxi Formation is dominated by marine facies then changing into transitional facies. The Lower Permian Taiyuan Formation is characterized by multiple alternation of marine and transitional facies. Marine limestones are characterized by low detrital influx proxies, whereas transitional shales show high detrital influx input and oxic environment. The Lower Permian Shanxi Formation is a typical marine-continental transitional depositional system, which is characterized by complex interbedding of shales, sandstones and coals. Sandy intervals were deposited in deltaic and tidal flat environment and characterized by high Ti and Al content, low TOC (0.09–0.97%, avg. 0.31%), relatively low U/Th (0.11–0.32, avg. 0.17), showing limited influence of seawater. Shale intervals were deposited in a lagoonal environment with high TOC (0.94–40.64%, avg. 5.43%), Sr/Ba and trace elemental proxies values (U/Th, 0.18–3.27%, avg. 0.44%; MoEF, 0.95–32.3, avg. 8.56; UEF, 0.67–15.17, avg. 2.53). This study shows that high-resolution geochemical characteristics of elements could be reliable indicators for sedimentary facies analysis, and hence could provide broader implications for utilizing trace element geochemistry from marine-continental transitional periods in which sedimentary environment changes frequently and organic-rich sediment accumulated under varied conditions.

Landscape modification due to agricultural irrigation: Carbonate tufa formation on Tenerife, Canary Islands, Spain

The use of irrigation water on Tenerife has modified the hydrogeological system resulting in the formation of an anthropogenic carbonate tufa . The processes involved in its formation are: 1) infiltration of rainwater and mixing with groundwater rich in volcanic carbon dioxide (CO 2 ), 2) weathering of volcanic rocks increasing the ion content of the water, 3) extraction of this water from subterranean galleries and channels and spilling it onto the Lomo Morin slope, 4) mechanical CO 2 degassing and photosynthetic activity driving calcite precipitation. The tufa consists of boundstones of algae and coated stems of reeds, along with laminated microbial crusts. Textures range from microspar to coarse mosaics to fibrous-radial calcite, all containing biogenic features. The presence of the green macroalga Blidingia is noticeable. Carbon stable isotope ratio ( δ 13 C) varies between -3.58 and +1.03‰ VPDB (Vienna Pee Dee Belemnite) and oxygen stable isotope ratio ( δ 18 O) between -6.77 and -5.00‰ VPDB, highlighting the largely meteoric origin of the water with some addition of deep CO 2 . A strontium isotope ratio ( 87 Sr/ 86 Sr) of 0.7030 confirms the weathering of volcanic rocks as the source of calcium. The Lomo Morin tufa provides a scale model of how water use contributes to rapid landscape change through alterations in the hydrogeological system. It also provides a good example of a CO 2 sink in a continental setting, and is comparable to the global carbon cycle, which mostly involves marine limestones. Although anthropogenic processes are commonly viewed negatively, the human modification of the hydrogeological system reported in this study has produced changes to geological and ecological conditions that have increased the geo - and biodiversity of the island.

The Upper Jurassic Garedu Red Bed Formation of the northern Tabas Block: elucidating Late Cimmerian tectonics in east-Central Iran

The Garedu Red Bed Formation (GRBF) of the northern Tabas Block (Central-East Iranian Microcontinent, CEIM) is a lithologically variable, up to 500-m-thick, predominantly continental unit. It rests gradually or unconformably on marine limestones of the Esfandiar Subgroup (Callovian–Oxfordian) and is assigned to the Kimmeridgian–Tithonian. In the lower part, it consists of pebble- to boulder-sized conglomerates/breccias composed of limestone clasts intercalated with calcareous sandstones, litho-/bioclastic rudstones and lacustrine carbonates. Up-section, sharp-based pebbly sandstones and red silt-/fine-grained sandstones of braided river origin predominate. Palaeocurrent data suggest a principal sediment transport from west to east and a lateral interfingering of the GRBF with marine greenish marls of the Korond Formation at the eastern margin of the Tabas Block. Westwards, the GRBF grades into the playa deposits of the Magu Gypsum Formation. Red colours and common calcretes suggest arid to semi-arid climatic conditions. The onset of Garedu Red Bed deposition indicates a major geodynamic change with the onset of compressive tectonics of the Late Cimmerian Tectonic Event (LCTE), being strongest at the eastern margin of the northern Tabas Block. When traced southwards, the same tectonic event is expressed by extension, indicating a shift in tectonic style along the boundary fault between the Tabas and Lut blocks. The complex Upper Jurassic facies distribution as well as the spatio-temporal changes in tectonic regime along the block-bounding faults are explained by the onset of counterclockwise vertical-axis rotation of the CEIM in the Kimmeridgian. The block boundaries accommodated the rotation by right-lateral strike slip, transpressional in today’s northern and transtensional in today’s southern segments of the block-bounding faults. Rotation occurred within bracketing transcurrent faults and continued into the Early Cretaceous, finally resulting in the opening of narrow oceanic basins encircling the CEIM. Palaeogeographically, the GRBF is part of a suite of red bed formations not only present on the CEIM, but also along the Sanandaj-Sirjan Zone (NW Iran), in northeastern Iran and beyond, indicating inter-regional tectonic instability, uplift and erosion under (semi-)arid climatic conditions across the Jurassic–Cretaceous boundary. Thus, even if our geodynamic model successfully explains Late Jurassic tectonic rotations, fault motions and facies distribution for the CEIM, the basic cause of the LCTE still remains enigmatic.

Stratigraphy, chronology and palaeontology of the Tertiary rocks of the Cheringoma Plateau, Mozambique

The discovery of fossil plants, marine molluscs and mammals in the Mazamba Formation, Cheringoma Plateau, Mozambique, opens a new chapter in the study of this part of the African Rift System. The evidence suggests that the Mazamba Formation is older than previously reported, probably late Eocene rather than Miocene. The fossil wood and stems indicate a frost-free tropical humid environment and a high water table soon after deposition, and the marine molluscs and mammals indicate proximity to the sea. There is also evidence for the occurrence of pans in the area during the late Eocene which also suggest a near-surface water table. This paper discusses the history of interpretation of the geology of the Cheringoma Plateau and describes and interprets the fossil plants, molluscs and mammals collected in 2012 and 2013. It is concluded that the Mazamba Formation, which overlies the fully marine Lutetian-Bartonian Cheringoma Limestone, is a coastal facies (fluvio-deltaic, lagoonal and onshore deposits) that accumulated on top of the marine limestones as sea level dropped late in the Bartonian. Mammalian bones from the White Patch sites represent a heavily built species about the dimensions of a pygmy hippopotamus, probably belonging to the order Embrithopoda. If so, then the Mazamba Formation is likely to correlate to the latest Bartonian or early Priabonian rather than to the Miocene as previously assumed.

The Late Pennsylvanian flora of the Italian Carnic Alps

The Pennsylvanian flora from the Italian Carnic Alps, stored in the Museo Friulano di Storia Naturale in Udine, Italy, was revised taxonomically. Plant fossils come from the Bombaso Formation and Pramollo (Auernig) Group (Late Pennsylvanian) that correspond to the lower part of the paralic to shallow marine Carboniferous–Permian Pramollo (or Pramollo-Nasfeld) Basin succession. Most of the ~2500 studied plant fossils and also the highest number of species come from the the Bombaso, Meledis and Pizzul formations, whereas the middle and upper part of the Pramollo Group in the Italian Carnic Alps yielded only few plant remains, contrarily to the successions on the Austrian side. In total 73 plant taxa have been identified, which represent about 59 biological species. The ferns, especially marattialen ferns, are the most diverse plant group (33 species in total) followed by pteridosperms (15 species). The stratigraphic range of the Bombaso Formation and the Pramollo Group have been re-evaluated based on presence of stratigraphically important species from both the Italian and Austrian parts of the Carnic Alps. The studied interval ranges from a middle Barruelian to middle Stephanian B sensu Wagner and Álvarez-Vázquez (2010a) and spans about 3.5 Ma. The diversity of the Carnic Alps flora is comparable with well-documented contemporaneous floras in NW Spain, French Massif Central and the Czech Republic. Floral richness and diversity together with intercalations of plant-rich horizons with fossiliferous marine limestone bands makes the Carnic Alps a potential candidate as a stratigraphically important reference section for non-marine to marine correlations.

Dolomitization of the Ordovician subsalt Majiagou Formation in the central Ordos Basin, China: fluid origins and dolomites evolution

The Middle Ordovician subsalt Majiagou Formation in the Ordos Basin comprises pervasively dolomitized shallow marine limestone and is a major reservoir rich in natural gas resources. Four types of dolomite matrix and cement were identified based on petrographic textures: (very) finely crystalline, non-planar to planar-s matrix dolomite (Md1); finely to medium crystalline, planar-s to planar-e matrix dolomite (Md2); microbialites comprising dolomite microcrystals (Md3); and finely to coarsely crystalline dolomite cement (Cd). The Md1 and Md2 dolomites were controlled by alternating lagoon-shoal facies and have δ13C values (− 1.89 to + 1.45‰ VPDB for Md1, − 1.35 to + 0.42‰ VPDB for Md2) that fall within or are slightly higher than the coeval seawater, suggesting the dolomitizing fluid of evaporated seawater. Md2 dolomite was then subjected to penecontemporaneous karstification by meteoric water and burial recrystallization by sealed brines during diagenesis, as indicated by its relatively lower δ18O values (− 8.89 to − 5.73‰ VPDB) and higher 87Sr/86Sr ratios (0.708920–0.710199). Md3 dolomite comprises thrombolite and stromatolite and is interpreted to form by a combination of initial microbial mediation and later replacive dolomitization related to evaporated seawater. Cd dolomite was associated with early-formed karst system in the Md2 host dolomite. The lowest δ18O values (− 11.78 to − 10.18‰ VPDB) and 87Sr/86Sr ratios (0.708688–0.708725) and fluid inclusion data (Th: 123–175 °C) indicate involvement of hydrothermal fluid from which the Cd dolomite precipitated during deep burial. These results reveal the multi-stage dolomitization history of the Majiagou Formation and provide new constraints on fluid origins and dolomites evolution during deep burial in old superimposed basins, such as the Ordos Basin and elsewhere.

UAS-Derived Surficial Deformation around the Epicenter of the 2016 Mw 5.8 Pawnee, Oklahoma, USA, Earthquake

ABSTRACT Unmanned aerial systems (UAS) provide a framework for recording perishable surficial data or information. Open fractures exhibiting regular en-echelon patterns were captured by a 12-megapixel, FL-9 mm camera attached to a Phantom IV UAS over the epicenter of the magnitude (Mw) 5.8 earthquake of September 3, 2016, 15 months later. The Digital Surface Models (DSMs) and orthoimagery offered a spatial resolution (∼1 cm) sufficient to identify small-scale plastic deformations that appear to be controlled by en-echelon joint sets developed in the underlying formation. The fissure boundaries and intersections are remarkably linear and sharp. They appeared to have been recently formed, presumably by seismic swarms believed to have been associated with wastewater injection. The DSMs revealed a series of conjugate patterns suggestive of regional systematic joints with apparent subsidence of infilling up to 50 cm. The earthquakes emanated from the Precambrian metamorphic basement, with epicentral clusters at ∼5- and 8-km depths. Low energy release from depths >1.5 km appears to be locally attenuated by an unconsolidated “soil cap,” which likely formed an impedance contrast. The maximum deformation direction from the cumulative energy of earthquakes correlates with a wrench fault tectonics model that could conceivably produce the observed en-echelon joint sets observed in the orthoimagery and DSMs. These features were observed within 275 m of the reported Mw 5.8 epicenter. The remarkably linear repeating pattern of deformation appears to express fissures that preserve the wrench fault fractures generated by the Mw 5.8 earthquake emanating from discontinuity suites within marine sandstone, shale, and limestone of Pennsylvanian to Permian age.

Trace and Rare Earth Elements, and Sr Isotopic Compositions of Fluorite from the Shihuiyao Rare Metal Deposit, Inner Mongolia: Implication for Its Origin

Abundant fluorites occur in the Shihuiyao rare metal (Nb-Ta-Rb) deposit in Inner Mongolia of NE China, and they can be classified by their occurrence into three types. Type I occurs disseminated in greisen pockets of albitized granite. Type II occurs in the skarn zone between granite and carbonate host rocks, and it can be subdivided into different subtypes according to color, namely dark purple (II-D), magenta (II-M), green (II-G), light purple (II-P), and white (II-W). Type III are the fluorite-bearing veins in the silty mudstones. On the basis of petrography of the fluorites and their high contents of HFSEs (high field strength elements) and LILEs (large ion lithophile elements), strong negative Eu anomalies, and tetrad effects, we suggest that Type I fluorites crystallized in a late-magmatic stage with all the components derived from the granite. The high Y/Ho ratios suggest that the Type II fluorites crystallized in the early- or late-hydrothermal stage. The rare earth elements (REEs) characterized by various Eu anomalies of the Type II fluorites indicate a mixed origin for ore-forming metals from granite-related fluids and limestones, and the oxygen fugacity increased during fluid migration and cooling. Compared to the Type II fluorites, the similar trace element contents of the Type III suggest a similar origin, and remarkable positive Eu anomalies represent a more oxidizing environment. The Sr isotopic composition (87Sr/86Sr)i = 0.710861) of the Type I fluorites may represent that of the granite-derived fluids, whereas the (87Sr/86Sr)i ratios of the Type II (0.710168–0.710380) and Type III (0.709018) fluorites are lower than that of the Type I fluorites but higher than those of the Late Permian-Early Triassic seawater, suggesting a binary mixed Sr source, i.e., granite-derived fluids and marine limestones. Nevertheless, the proportion of limestone-derived Sr in the mixture forming the Type III fluorites is much higher than that of Type II. The rare metal Nb and Ta get into the granite-derived F-rich fluids by complexing with F and precipitate in the form of columbite-group minerals after the Type I fluorites crystallize. Most of Nb and Ta may have deposited as columbite-group minerals during the magmatic stage, resulting in no Nb-Ta mineralization in the hydrothermal stage when the Type II and III fluorites formed. Hence, the Type I fluorites in the Shihuiyao mining area can be used as an important exploration tool for the Nb-Ta mineralization.

Taphonomic evidence supports an aquatic lifestyle for Spinosaurus

A new locality near Tarda on the northern margin of the Tafilalt, south eastern Morocco exposes extensive sequences of the Ifezouane and Aoufous formations of the fluvial Kem Kem Group (Cretaceous, ?Albian-Cenomanian) on the south western flank of Ikfh n’Oufza escarpment of the Hamada du Meski. The stratigraphic sequence here differs significantly from better known exposures of the Kem Kem Group in the southern Tafilalt, and includes a heterolithic sequence of alternating grey mudstones and fine sandstones and a thin (~1.5 m) marine limestone. The locality is noteworthy for three vertebrate-bearing horizons within the upper part of the Ifezouane Formation. The upper two (Sites 1 and 2 in ascending order) are dominated by dental remains of the sawfish Onchopristis and the semi-aquatic theropod dinosaur Spinosaurus. Significantly, the remains of terrestrial dinosaurs constitute less than 1% of the total dental assemblage at Site 1 and 5.6% at Site 2. At Site 2 teeth of Spinosaurus outnumber the rostral “teeth” of Onchopristis. The remarkably high abundance of spinosaur teeth compared to remains of terrestrial dinosaurs, and even some aquatic animals strongly supports Spinosaurus being a largely aquatic animal spending much of its life in water where its teeth were shed and preserved.

Lower Cretaceous (upper Albian) enigmatic plant-like columnar structures, marine Comanche Shelf, Texas

Multiple well-preserved molds of a fossil stalk-like structure are in erect positions in marine limestone beds in the upper part of the upper Albian Fort Lancaster Limestone exposed in West Texas. The Albian molds have a seven-sided cross section and seven vertical ribs that are separated by shallow furrows; the ribs bear closely spaced rings surrounding shallow depressions. The Fort Lancaster Limestone is the uppermost Albian cyclical carbonate unit deposited on the Barremian–early Cenomanian Comanche Shelf and is about 104 Ma to 100 Ma in age. These molds represent Coliculus septimus gen. et sp. nov., which, in cross section, is analogous to that of the horsetail Equisetum L., and occupies a shallow marine environment as do modern large rooted alga and marine grasses. Discovery of molds of a plant stem in strata at about 100 Ma extends the geologic range of marine plants other than algae. These molds are named and described so that they may be recognized in other Cretaceous strata.

Implications of microbial mat induced sedimentary structures (MISS) in carbonate rocks: An insight from Proterozoic Rohtas Limestone and Bhander Limestone, India

A variety of microbial mat induced sedimentary structures (MISS) occur in the basal part of the Mesoproterozoic Rohtas Limestone and the Bhander Limestone, India. The combined outcrop and petrographic studies establish unicellular microbial origin of the MISS in the Rohtas Limestone and the Bhander Limestone. Micro-scale deformations associated with MISS imply the late cementation. Paradoxically MISS, once formed, has a better preservation potential in carbonate sediments because of their proneness to get cemented early. The studied basal sections of both the formations built up in a low energy depositional condition. In warm and arid tropical climate, high concentration of dissolved inorganic carbon exacerbated precipitation of aragonite crystals in successive stacks and sulfur concentration led to gypsum precipitation. However, the temperature in the palaeodepositional environment could have been high enough to restrict the sulfur reduction rate severely hampering the growth of sulphur reducing bacteria (SRB) population which was the most powerful post-Archaean calcification engine. The available results indicate Mesoproterozoic palaeotemperature raised up to 32°C at a mid-latitude location. In the Vindhyan sea straddling across the equator, temperature is predicted to have been considerably higher. The ancient marine limestone formations having MISS, irrespective of their age, developed in similar low palaeolatitudinal locations. Thus, it is reasonable to attribute that high temperature at depositional site cards carbonate sediments to acquire MISS by delayed cementation. Early cementation hinders MISS formation in carbonate sediments, till the sea water temperature crosses an optimal value.

A pelagic Upper Devonian sequence in Sarıyer, İstanbul

The Palaeozoic sequence in the Istanbul region is made up of a continuous transgressive sedimentary series extending from Ordovician continental clastic rocks to Lower Carboniferous turbidites. The middle part of this sequence consists predominantly of carbonates ranging from shallow marine Upper Silurian limestones to latest Devonian to earliest Carboniferous deep marine limestones and shales. Here, we describe a new Upper Devonian deep marine limestone-siltstone section from the Sariyer region in the European part of Istanbul. The 37-m thick section located in the campus of the Istanbul Technical University consists at the base of dark micritic limestones interbedded with carbonate-rich siltstones, which pass up into siltstones with rare micritic limestone lenses and beds. Conodonts indicate a late Famennian latest Devonian age for the ITU campus section; 5 conodont biozones are documented; Pseudopolygnathus granulosus, Polygnathus styriacus, Palmatolepis gracilis manca, Palmatolepis gracilis expansa, and Bispathodus aculeatus aculeatus. The Late Devonian fauna from the ITU Campus section are dominated by the important marker species of Palmatolepis, Bispathodus and Polygnathus. There are also some Branmehla, Mehlina, and Icriodus elements within the succession. The conodont assemblages are representative of the palmatolepid-bispathodid biofacies, which indicate deposition on an outer shelf to slope environment.

Sediment-derived origin of the putative Munnar carbonatite, South India

Metacarbonate assemblages in high-grade metamorphic terranes often pose challenges when trying to distinguish between mantle-derived carbonatite and sedimentary carbonate protoliths. We present a study of granulite-facies metacarbonate samples of the putative Munnar carbonatite described as decimeter-thick dikes and veins, and layers of a meter-thick metacarbonate and calc-silicate assemblage, respectively. Thin sections of the metacarbonate dike samples show absence of pyrochlore and ubiquitous scapolite, titanite, wollastonite, and detrital zircons are compatible with impure limestone protoliths. Nd and Sr isotope compositions indicate protoliths with Paleoproterozoic crustal residence times which contrast the mantle sources of Indian and global carbonatites. Trace-element patterns display the characteristics of upper crust, and Ce- and Y-anomalies in a number of samples suggest protolith formation under marine conditions. Carbon and oxygen isotope compositions of the metacarbonate samples interlayered with calc-silicate rocks are similar to those in marine limestone. The metacarbonate dikes, however, show mantle-like compositions which are interpreted as reflecting equilibration with mantle-derived CO2 during granulite-facies metamorphism. The dikes yielded a U-Pb zircon crystallization age of 1020 ± 70 Ma and a cross-cutting quartz syenite, thought to be cogenetic, a magmatic age of 620 ± 35 Ma; the hosting gneiss provided a magmatic age of 2452 ± 14 Ma. We conclude that the layered metacarbonate and calc-silicate rocks represent a former marine limestone and marl sequence and the metacarbonate dikes and veins small-volume melts of crust-derived carbonate-rich sediment.

Temporal changes in geochemical-isotopic systematics of the late Pleistocene Akkaya travertines (Turkey) – Implications for fluid flow circulation and seismicity

We investigate the temporal variations in stable carbon and oxygen and radiogenic Sr isotope as well as rare earth element contents of Akkaya travertine deposits in the Eskipazar region, northwest Turkey. U-Th age data indicate that studied travertines in the periphery of the 1944-earthquake rupture of the North Anatolian Fault Zone formed in a time span of 93 to 1.8 ka BP. The younger group is represented by fissure-filling carbonates whereas the older sequence is composed of veins with varying crystallization ages that are injected to bedded travertines. The age data on vein injections and fissure-ridge travertines in the Akkaya site indicate the seismic reactivation along the west-central part of the North Anatolian Fault Zone to be intensified at least 4 periods (1.8, 20, 47 and 88 ka BP) during the last 90 ka.δ18O and δ13C systematics of Akkaya travertines, which are precipitated by CO2–rich fluids depressurized during episodic seismic unrest, are in the range from −15.86 to −7.67‰ (VPDB) and 4.66–8.68‰ (VPDB), respectively. δ18O of the fluid equilibrating with the studied travertines is estimated in the range of −11.2 to −10.2‰ which is quite consistent with the average value (−12.3‰) reported for the Akkaya thermal spring. Stable isotope values of travertines indicate modification by rapid CO2 degassing associated with seismic events. Helium isotope compositions of gas phase and dissolved gas of thermal fluids in the area refer to mantle contribution up to 12 %. Sr isotope values of Akkaya travertines are probably originated from Upper Cretaceous marine limestones or mafic basement rocks. REY contents are about 3 orders of magnitude lower than those of basement lithologies.

Resetting Southern Tibet: The serious challenge of obtaining primary records of Paleoaltimetry

Abstract Over the last several decades a number of studies have attempted to reconstruct the rise of the Himalaya and Tibet since India-Asia collision began in the early Cenozoic, with rather contradictory results. Here, we evaluate the efforts at reconstructing the history of this major mountain-building event as archived in oxygen, carbon, and clumped isotope records from carbonates exposed on the southern Tibetan Plateau. We find that a number of potential isotopic records of paleoaltimetry from Tibet – using both conventional oxygen and clumped isotope systems–may have been reset during burial and heating. Without exception, the marine δ18O values of Cretaceous and Paleogene marine carbonates across the orogen have been reset from their primary values of 0 ± 4‰ (VPDB) to lower values between −5 and −20‰, most conspicuously in the Indo-Asian suture zone. For this and other reasons, we view isotopic records of paleoaltimetry from the suture zone and adjacent Gangdese arc with great caution, especially early Cenozoic basin sediments that have experienced similar burial and heating as the underlying marine limestones. Outside the suture zone/arc, marine carbonates retain the isotopic imprint of low-elevation, meteoric diagenesis, a result that supports paleoaltimetric reconstruction from these areas using younger non-marine carbonates. We are even more cautious about temperature reconstructions using clumped isotope analyses, which previous studies suggest are sensitive to resetting at modest burial temperatures. With a few possible exceptions, primary clumped isotope values have probably not withstood the elevated temperatures of the suture zone and magmatic arc, nor burial depths of >3 km in basins outside the suture. In light of susceptibility to alteration of oxygen isotopes in carbonates in orogenic belts, future paleoaltimetric reconstruction prior to the Miocene on the Tibetan Plateau should couple δ18O, Δ47, and Δ'17O analysis of carbonates with analysis of noncarbonate archives—such as silicates and organic matter— that are less susceptible to resetting. Carbon, unlike oxygen, isotopic values from paleosol carbonate are well preserved from all periods, due to the very low C/O ratio of most altering fluids. Samples from within the suture zone yield a record of paleo-vegetation change covering much of the Cenozoic. Carbon isotopic values from paleosols have no analog among modern Tibetan soils and most resemble in appearance and chemical composition the vegetated soils in the lowlands of northern India today. Carbon isotopes from paleosols depict a major reduction in vegetation cover in the suture zone since 20 Ma, probably due to a combination of uplift of the suture zone and global cooling. Northward on the Lhasa and Qiantang terranes, the landscape was less vegetated in the Oligocene compared to the contemporaneous suture zone, but more vegetated and less arid than it is today.

Rhizoliths in Devonian and Early Carboniferous Paleosols and Their Paleoecological Interpretation

Collected in situ rhizoliths (>20) from Devonian and Early Carboniferous paleosols in the southern part of the Russian Platform (Kaluga, Belgorod, and Voronezh oblasts) were studied by means of scanning electron microscopy, X-ray diffraction, XRF and mass spectrometry. In Devonian paleosols developed from volcanic–sedimentary deposits, rhizoliths are represented by petrified individual roots of different plants, rooting systems, and their diagenetically transformed products—ferruginous concretions and wedges. Mineralogically, they are dominated by goethite and siderite in different proportions. Some of them include charcoals and/or pyrite-substituted plant tissues. This kind of rhizoliths was developed under reducing conditions in (semi)hydromorphic paleosols or under flooding during the soil burial stage. In the Carboniferous period, paleosols developed from marine limestones contained several types of rhizoliths: casts (predominate), imprints and root channels (less abundant), and few rhizocretions with arbuscular mycorrhiza. All of them are characterized by complete mineralization of plant tissues. Casts and rhizocretions are substituted with calcite. The isotopic composition of C in the latter is within –5.68 < δ13C < –1.16‰. The data obtained show that rhizoliths are important sources of information on biodiversity, physiology of plants, and paleoenvironments at different scales, including the global scale. The volume of information depends on the type of rhizolith.

Late Jurassic theropod dinosaur bones from the Langenberg Quarry (Lower Saxony, Germany) provide evidence for several theropod lineages in the central European archipelago.

Marine limestones and marls in the Langenberg Quarry provide unique insights into a Late Jurassic island ecosystem in central Europe. The beds yield a varied assemblage of terrestrial vertebrates including extremely rare bones of theropod from theropod dinosaurs, which we describe here for the first time. All of the theropod bones belong to relatively small individuals but represent a wide taxonomic range. The material comprises an allosauroid small pedal ungual and pedal phalanx, a ceratosaurian anterior chevron, a left fibula of a megalosauroid, and a distal caudal vertebra of a tetanuran. Additionally, a small pedal phalanx III-1 and the proximal part of a small right fibula can be assigned to indeterminate theropods. The ontogenetic stages of the material are currently unknown, although the assignment of some of the bones to juvenile individuals is plausible. The finds confirm the presence of several taxa of theropod dinosaurs in the archipelago and add to our growing understanding of theropod diversity and evolution during the Late Jurassic of Europe.