Marine Conditions Research Articles

Ostracod turnover during the Carnian Pluvial Episode (Late Triassic) in the Western Neotethys

The Carnian Pluvial Episode (CPE) caused a biotic crisis and turnover in terrestrial and marine ecosystems in the Western Neotethyan realm. The expansion of deltaic systems on land and the increased siliciclastic input affected the distribution of benthic ostracods, both nearshore and offshore. Diversity changes of Carnian ostracod faunas from seven successions in the Transdanubian Range (TR), Western Hungary tracked the effects of the CPE, despite its distal hemipelagic depositional setting and position within an intraplatform basin. At the onset of CPE in the early Julian 2, the composition of the studied benthic ostracod assemblage was similar to that of the late Julian 1 communities albeit with decreased abundance of smooth bairdiids and healdiids. The ratio of healdiids and smooth bairdiids is likely related to the detrital supply with bairdiids colonizing primarily in intervals with decreased terrestrial input and carbonate platform progradation. During the maximum expansion of CPE in late Julian 2, the predominance of platycopid Bektasia indicates a shallowing trend, infilling of the Carnian basins and stressed environment due to clastic input and salinity stress. The Julian–Tuvalian boundary is characterized by high extinction rates among marine invertebrates simultaneously with the occurrence of a unique low diversity but abundant brackish water ostracod community with Simeonella and Renngartenella that can be traced along the entire Western Neotethys and northern Gondwana shelf. The appearance of this community is primarily linked to salinity variations during the CPE and the formation of restricted basin habitats in the TR with water stratification where the special community lived or was transported there with storms or river outflow. During the Tuvalian, fully open marine conditions were re-established with increased carbonate productivity in the platforms, favouring the colonization of stable shallow marine habitats with the appearance of ornate bairdiids in the ostracod faunas.

Enrichment pattern of tungsten in sediments under methane seepage environments: Applicability as a proxy for tracing and reconstructing (paleo-)methane seepage

The release of hydrogen sulfide by sulfate-driven anaerobic oxidation of methane (SD-AOM) during methane seepage activities has a strong impact on the evolution of marine redox conditions and the cycles of redox-sensitive elements (e.g. Mo and U). Consequently, the sedimentary enrichment or depletion of these elements is often used to trace and reconstruct (paleo-)methane seepage activity. In recent years, tungsten (W) has shown promise as an indicator of marine redox changes, but its applicability to trace methane seepage activity is unknown. This study identified significant differences in the W content of sediments in methane seepage environments compared to suboxic environments not influenced by methane seepage and oxic environments in the South China Sea. The sediments subjected to methane seepage were characterized by low W contents, similar to those of euxinic Black Sea sapropels. It is believed that the sulfidic environment resulting from SD-AOM is the primary cause of W depletion in sediments subjected to methane seepage. By examining W's interaction with its twin element, Mo, we present WMo enrichment patterns in various environments. In methane seepage environment (sulfidic environments), sediments had high MoEF (> 10) and low WEF (< 2) with a high Mo/W molar ratio (> 10); in suboxic environments not influenced by methane seepage, sediments exhibited a WMo enrichment pattern similar to the UCC (the MoEF and WEF values are predominantly below 1 and 2, respectively, with a low Mo/W molar ratio, <1.5); in oxic environments (enrichment of FeMn (oxy)hydroxides), sediments exhibited high MoEF (2 < MoEF < 10) and high WEF (> 2), with a medium Mo/W molar ratio (1.5–10). This further indicates that the Mo/W molar ratio has great potential in tracing and reconstructing (paleo-)methane seepage activities.

Effects of different marination conditions on the physico-chemical and microbiological quality of anchovy (Engraulis encrasicolus) fillets inoculated with Morganella psychrotolerans during cold storage.

This study is aimed to determine the effects of different marination conditions (1, 2, 3, 4% acetic and 6, 8, 10% NaCl) on the anchovy fillets inoculated with Morganella psychrotolerans during refrigerated storage (4±1°C) for three months. According to the results of study, marination has great inhibitory effects on the growth of M. psychrotolerans. Total psychrophilic bacteria, total lactic acid bacteria, total yeast and mold, Total Enterobacteriaceae and M. psychrotolerans growth were not observed in the groups treated with 3 and 4% acetic acid. Control groups and fillets marinated with 1% acetic acid showed lower sensory scores. Those groups were rejected on 30th, 45th and 60th days of the storage, respectively, while the groups marinated with 2%, 3%, and 4% acetic acid had higher sensory scores and they were still acceptable until at the end of the study. According to peroxide value (PV) and thiobarbituric acid reactive substances (TBARS) assessment, lipid oxidation was delayed in the fillets marinated with high acetic acid concentrations (3 and 4%) comparing with the control and other inoculated fillets. From this research it can be revealed that high acetic acid and salt concentrations suppress the bacteria growth in the anchovy fillets. Thus, marination process can be recommended to be used as a preservation method to inhibit bacterial growth in anchovy fillets for a safe consumption.

Biodegradability assessment of HDPE-based biocomposites: Influence of starch and fiber composition

This research aims to analyze the biodegradation dynamics of a tertiary composite blend, including High-Density Polyethylene (HDPE), starch and linen fiber, and their combined effect on decay processes in authentic environmental settings. It investigates the relationship between fiber content and decomposition rates, details the biodegradation mechanisms, and evaluates the reactive profiles of the involved constituents. Decay kinetics and the biodegradation mechanism of three formulations: HDPE60S40, HDPE60S20F20, and HDPE60S30F10, representing composites with 60 % HDPE, complemented by 40 %, 20 % starch and 20 %, 10 % linen fiber, respectively, are examined. HDPE60S30F10 is noted for its superior biodegradation rates, showing a 1.2 % weight loss in soil and 9.89 % in marine conditions and an increased resistance to shearing forces, whereas HDPE60S40 recorded a weight loss of 0,63 % in soil and 2.59 % in seawater against 1,7 % and 6.64 % in soil and seawtaer, respectively recorded with HDPE60S20F20. Density Functional Theory (DFT) and Molecular Dynamics (MD) simulations complement these findings, presenting HDPE60S40 as the most rigid, HDPE60S20F20 as the most ductile with a bulk modulus of 13.34 GPa, and HDPE60S30F10 exhibiting the best shear resistance with a shear modulus of 12.48 GPa. Scanning Electron Microscopy (SEM) and Fourier-Transform Infrared Spectroscopy (FTIR) analyses confirm microbial involvement and significant surface erosion, particularly indicating particularly starch degradation. The results suggest that integrating linen fiber into the composites enhances biodegradation.

Onverwacht Group, Barberton Greenstone Belt, South Africa: 300 m.y. development of a Paleoarchean stagnant lid

The 3.55−3.26 Ga Onverwacht Group, Barberton Greenstone Belt, South Africa and Eswatini, records nearly 300 m.y. of Paleoarchean history dominated by basaltic, komatiitic, and felsic volcanism. It provides the oldest well-preserved record of crustal development and the nature and evolution of associated surface environments, ocean, atmosphere, and biosphere on early Earth. Sedimentary layers within this 10- to 12-km-thick sequence represent a range of proximal to distal sedimentary environments relative to the centers of volcanism. Proximal deposits include coarse felsic breccias, conglomerates, and sandstones and mafic to komatiitic lapillistones that often show evidence for deposition in relatively shallow water. Distal deposits are composed of fine pyroclastic debris, chemical sediments, and biogenic materials deposited under subaqueous conditions during local volcanic quiescence. They show abundant current-produced features and are interpreted to have formed at water depths of a few hundred meters or less under the influence of tidal and/or ocean-circulation currents. Terrigenous clastic sediments formed by the weathering and erosion of older rocks are essentially absent. The Onverwacht Group was deposited under marine conditions on what appears to have been a water world with little evidence of large land areas and no evidence of active tectonism. It is interpreted to represent the upper part of a Paleoarchean stagnant lid overlying but decoupled from an active mantle. The Barberton Greenstone Belt and other Paleoarchean terranes offer a view of this lid over the past 300 m.y. of its development and during the early stages of its fragmentation and disruption.

Enhancing marine biodegradability of poly(butylene succinate) by blending with 16-hydroxyhexadecanoic acid and poly(ε-caprolactone)

One potential solution for reducing marine pollution from plastic waste is to replace conventional plastics with biodegradable alternatives. However, most chemosynthetically biodegradable aliphatic polyesters, such as poly(butylene succinate) (PBS), exhibit extremely slow biodegradation rates in marine environments. To address this problem, we present a novel method to enhance the marine biodegradability of PBS by blending it with 10 wt.% of 16-hydroxyhexadecanoic acid (16HHD) and poly(ε-caprolactone) (PCL). The weight loss rates of the PBS samples with 16HHD and PCL were 18.4- and 7.8-times faster than that of pristine PBS. Scanning electron micrographs of PBS blended with 16HHD and PCL after oceanic incubation for four months showed a rough surface, suggesting that enzymatic degradation occurred. Additionally, unlike pristine PBS, samples with 16HHD and PCL demonstrated biochemical oxygen demand (BOD) biodegradabilities of 90.4 % and 83.2 %, respectively, under marine conditions. Analysis of the microbial community of BOD testing using 16S ribosomal RNA gene sequencing indicated that the addition of 16HHD and PCL changed the microbial community compared to pristine PBS. These findings demonstrate how blending PBS with 16HHD and PCL enhances its marine biodegradability, thereby offering a promising avenue for addressing plastic pollution in marine ecosystems.

New Technique to develop Intelligent High reliable &amp; Efficient Unmanned Power Generation Modular

Primary aim of this research project is to develop Modular Generator Total Power Output: 1 MW or greater, integrated with High density diesel (NATO F76) generator. This modular comprises of Generators, Fuel Cells (MTBF), Gas Turbine Generators. Note that novelty will be sought on how to configure installation of multiple power units to allow for easy access for maintenance, quick removal and replacement as well as optimize operating life via controls. This proposed power modular will Operate in a marine environment condition such as salt air ingestion, ships motion in high sea states, shock, vibration. Note that novelty will be pursued on how to best optimize design to combine multiple power unit connections to a single ship interface.[1] Key words. Novelty, Corrective Maintenance and Preventive maintenance and Intelligent module.

Pre-Jurassic weathering crust of the Kalinovoe hydrocarbon deposit, Tomsk region: composition and structure characteristics

Abstract. The study of pre-Jurassic deposits in the southwestern part of Western Siberia is highly relevant due to their potential of increasing hydrocarbon resources. These deposits are considered prospective targets for the discovery of hydrocarbon accumulations. Weathering crusts developed on the upper part of the Paleozoic rocks in the Tomsk region exhibit a complex composition and structure, reflecting the interplay of various factors, including primary sedimentary processes and later alteration processes, including fracture-controlled fluid flow and metasomatism. Aim. To establish the characteristics of the mineralogical composition and structure of the Paleozoic weathering crust formations developed at the Kalinovoe oil-gas-condensate field. Methods. Optical microscopy, X-ray diffraction, scanning electron microscopy. Results and conclusions. The composition and structure of the deposits at the boundary zone between the Paleozoic and Mesozoic successions have been studied in detail in the section of one of the wells at the Kalinovoe oil-gas-condensate field. The factual material is represented by core and thin sections of weathering crust deposits. The primary rock-forming minerals are silica minerals (quartz, chalcedony and opal) and clay minerals, with a lesser amount of carbonate minerals (siderite). Different lithological units were identified based on the content of minerals and bioclast (radiolarians and sponge spicules), indicating their formation under marine conditions. The protoliths of the altered rocks were carbonate-siliceous rocks, argillaceous limestones, and radiolarian cherts, which as a result of multiple stages of hydrothermal alteration and metasomatic processes were transformed into argillaceous-silicified rocks. In these rocks, with intense post-alteration overprinting, good reservoir quality porosity can develop. This porosity includes biogenic voids, microcavities, micropores, and open fractures.

Numerical study on decomposition characteristics of natural gas hydrate based on molecular dynamics method

The molecular dynamics method is used to investigate decomposition characteristics of natural gas hydrate under different pressure and salinity. In this paper, the influence of pressure variation on the stability of natural gas hydrate under high pressure is studied from the molecular point of view based on the seabed pressure in Shenhu sea area. At the same time, taking the real marine conditions in the South China Sea as a reference, the effect of the synergistic effect of various salt ions on the decomposition of natural gas hydrate under the effect of salinity is studied. Its decomposition behavior is discussed by analyzing the parameters such as cell conformation, radial distribution function, mean square displacement and self-diffusion coefficient. The results show that pressure and salinity influence the decomposition of natural gas hydrate through modifying stable its conditions, from solid state to gas-liquid state. And the reduction of pressure accelerates the decomposition of natural gas hydrate under high pressure, while the increase of salinity promotes the decomposition of natural gas hydrate under the condition of high salinity.

Assessment of the physiological performance of the invasive oriental shrimp Palaemon macrodactylus from an atypical marine population.

Since 2000, a well-established population of the invasive oriental shrimp Palaemon macrodactylus has been present in fully marine conditions in the southwestern Atlantic Ocean (~38° S). To assess the physiological performance of this atypical population restricted to fully marine conditions, we conducted a laboratory experiment in which individuals were transferred from 35 ‰S (local seawater) to 2 ‰S; 5 ‰S; 10 ‰S; 20 ‰S; 50 ‰S and 60‰ for short (6 h), medium (48 h), and long (>504 h) acclimation periods. We measured the time course response of relevant parameters in the shrimp's hemolymph; activity of Na+, K+-ATPase (NKA), and V-H+-ATPase (VHA); and muscle water content. Shrimp showed great osmoregulatory plasticity, being able to survive for long periods between 5 ‰S and 50 ‰S, whereas no individual survived after transfer to either 2 ‰S or 60 ‰S. Shrimp hyper-regulated hemolymph osmolality at 5 ‰S and 10 ‰S, hypo-regulated at 35 ‰S and 50 ‰S, and isosmoticity was close to 20 ‰S. Compared to 35 ‰S, prolonged acclimation to 5 ‰S caused a decrease in hemolymph osmolality (~34%) along with sodium and chloride concentrations (~24%); the NKA and VHA activities decreased by ~52% and ~88%, respectively, while muscle water content was tightly regulated. Our results showed that the atypical population of P. macrodactylus studied here lives in a chronic hypo-osmo-ion regulatory state and suggest that fully marine conditions contribute to its poor performance at the lower limit of salinity tolerance (<5 ‰S).

Challenge for multifaceted data acquisition around active volcanoes using uncrewed surface vessel

Monitoring of volcanic eruptions, the atmosphere, and the ocean, along with their scientific understanding, can be achieved through multifaceted observations that include camera images, topographic deformations, elastic waves, geology, and the chemical constituents and temperatures of air and water. However, regions of increased volcanic activity and/or shallow waters are difficult to access by crewed ship due to danger or grounding risk. To overcome these difficulties, we used an uncrewed surface vessel (USV), Bluebottle, to operate multiple observation around oceanic volcanoes in the Bonin Island arc in May 2023. Even under adverse sea conditions, the USV successfully reached a remote observation site, Nishinoshima volcano, which is about 130 km away from Chichijima Island where the USV started out from. The USV conducted five days of observations at shallower than 500 m water depth around Nishinoshima Island, the first time after violent eruptions of Nishinoshima in June 2020. The USV is equipped with various sensors and data collection technologies, including a single-beam echosounder, oceanographic and meteorological sensors, an Acoustic Doppler Current Profiler, and a time-lapse camera. These tools have provided a multi-dimensional view of the underwater landscape and marine conditions near the volcano for the first time in the world. We obtained new bathymetric data, sub-bottom images, and measurements of temperature, salinity, and pH. This study leverages advanced technologies and innovative methodologies to enhance our understanding of marine and geological phenomena.

Response Extremes of Floating Offshore Wind Turbine Based on Inverse Reliability and Environmental Contour Method

Floating structures are subject to complex marine conditions. To ensure their safety, reliability analysis needs to be conducted during the design phase. However, because of the complexity of traditional full long-term analysis, the environmental contour method (ECM) based on the inverse reliability method, which can combine accuracy and efficiency, is extensively used. Due to the unique environment in the South China Sea, the probabilistic characteristics of three-dimensional (3D) environmental parameters of wind, wave and current are investigated. The ECs of the target sea are established via the ECM based on both the inverse first-order reliability method (IFORM) and inverse second-order reliability method (ISORM). It is found that the sea state forecasted by ISORM is more extreme and may lead to a more conservative design than IFORM. Furthermore, the wind–wave–current combination coefficient matrixes developed using the 3D ECs are proposed for the design of FOWTs in the South China Sea. The validity and practicality of the contours and matrixes are tested by using a floating offshore wind turbine (FOWT) as a numerical example. Then, the short-term response of the structure under the combined wind, wave and current conditions is calculated, providing a theoretical reference for the design of FOWTs.

Corrosion resistance behavior of enhanced passivation Cr-modified rebars and their service life prediction based on Monte Carlo simulation

This work investigates enhanced passivation and corrosion resistance of various Cr-modified rebars compared to carbon rebar. It also evaluates their service life through time-varying probability analysis based on Monte Carlo simulation, combined with the parameters obtained from sampling and testing reinforced concrete mortar samples exposed to various marine conditions over 5 years. The results show that the free energy required for oxide thickening of rebar decreases from 20.12 kJ/mol to 9.25 kJ/mol as the Cr content increases from 5 % to 11 % (wt.), which facilitates the developed Cr-modified rebars rapidly form a passive film, exhibiting a chloride threshold level 6–14 times higher than that of carbon rebar. In the harshest marine splash zone, sea sand concrete with Cr11 rebar ensures a theoretical 50-year service life, contrasting sharply with the much shorter lifespan estimated at 5–6 years for carbon rebar. The corrosion rate of Cr-modified rebars was notably lower than that of the carbon rebar, and the Cr oxides/hydroxides facilitate the transformation of FeO(OH) with larger volume expansion to Fe3O4 with smaller volume expansion, reducing from 130 μm in HRB to 70 μm in the case of the thinnest Cr11 rebar. The thin and dense rust layer of the developed rebars is advantageous in blocking Cl- and guarantees a smaller volume expansion of structure even if the rebars are corroded. This study underscores the suitability of Cr-modified rebars for sea sand concrete structures and sheds new light on rebar-reinforced concrete structure developments toward eco-efficient and sustainable infrastructures.

Effects of Molecular Weight on the Marine Biodegradability of Poly(l-lactic acid).

Poly(l-lactic acid) (PLA) is a biodegradable bioplastic with limited marine degradation. This study examines the impact of molecular weight on PLA's marine biodegradability. We synthesized PLA with terminal hydroxyl groups (PLA-OH) with degrees of polymerization (DP) between 14 and 642 and conducted biochemical oxygen demand (BOD) tests. Samples with a DP of 422 or 642 did not degrade, like commercial PLA. However, PLA-OH with a DP below 314 showed biodegradability, with DP 14 exhibiting a higher degradability than cellulose. Size exclusion chromatography (SEC) confirmed a decrease in molecular weight for samples with DPs below 314, indicating extracellular microbial activity. These findings suggest that PLA-OH with a DP under 314 can be degraded in marine conditions, unlike high-molecular-weight PLA. If the DP of high-molecular-weight PLA can be reduced to 314 by some specific method, then it is expected that PLA can be used to create marine biodegradable materials.

Stratigraphic and paleoceanographic alternations within a Mediterranean semi-enclosed, syn-rift basin during Marine Isotope Stage 5: The Gulf of Corinth, Greece

The Gulf of Corinth represents an ideal setting for studying the impact of sea level changes and regional climate on a semi-enclosed, syn-rift basin. Here we investigate the stratigraphic and paleoceanographic variability recorded in the sedimentary succession of the basin over the Marine Isotope Stage (MIS) 5 period when global sea level and climatic conditions along the eastern Mediterranean exhibited pronounced fluctuations. We used sedimentological (granulometry, composition), micropaleontological (planktic and benthic foraminifera), and isotopic (stable δ18O, δ13C, and clumped isotope) proxies on core samples from site M0079A (IODP Expedition 381) combined with additional data from the expedition overview and records from the surrounding area. The sedimentary succession comprises an alternating pattern of a) bioturbated, biogenic-rich deposits associated with increased hemipelagic sedimentation with b) partly bedded, detrital-rich sediments attributed to intercalated sediment gravity flows within the hemipelagic background under low oxic sea-surface conditions, and c) aragonite-rich laminated deposits, indicating either transitional conditions between marine and isolated environment or a highly stratified seawater column and low oxygen seafloor conditions. We find that the Gulf of Corinth lay under marine conditions for nearly the entire MIS 5 period, while the Rion sill would have been possibly shallower, even 10 m, than the current depth. Nevertheless, water exchange was restricted during the MIS 5a – MIS 4 transition when the sea level fluctuated very close to the sill height. The hydrological conditions within the Gulf during most of the highstands MIS 5a, 5c, and 5e reflect higher oxygen levels and/or increased nutrient availability compared to the Holocene and present-day regime. The combined effects of Ionian Sea inflows and enhanced riverine runoff led to increased water column stratification and low oxygen, eutrophic seafloor conditions in the Gulf of Corinth during times of high precipitation in southern Europe and deposition of sapropels S3, S4, and S5 throughout the eastern Mediterranean. In contrast, during periods of widespread cold and arid conditions in the eastern Mediterranean, water column mixing was intense within the Gulf. Prevalent marine conditions are also proposed during the MIS 5b and 5d lowstands, yet associated with predominately bedded-detrital sediments in the Gulf. A complementary investigation in the adjoining Patras Gulf is suggested to fully comprehend the dynamics of climate and sea level changes in complex rift systems.

Geochemical and palynological characteristics of the Maykop sections in the north-west of the Shamakha-Gobustan region (Azerbaijan)

The article provides a comparative analysis of the results of complex palynological and geochemical studies of rocks from natural outcrops of Lagich, Angekharan and Agsu in the north-west of the Shamakhi-Gobustan region. A comparison of the distribution features of palynomorph species with the lithofacies variability of sediments made it possible to reveal the conditions of sedimentation during the formation of the described sections. In addition, the age of the units identified in the Maikop deposits in Lagich and Angekharan was clarified by analogy with the formations and horizons of similar ages in the Western and Central Ciscaucasia. The boundary of Eocene and Oligocene deposits in the Lagich section is assumed to be in the interval of 80–115 m. Late Eocene deposits occurring at the base of the section are apparently an analogue of the boundary deposits of the Beloglinskaya and Pshekhskaya formations of the Ciscaucasia. The presence of cold-water dinocysts of the species I.recurvus and calcareous nannofossils Coccolithus pelagicus in the boundary interval corresponds to the existing ideas about climate cooling at the end of the Eocene - beginning of the Oligocene. The formation of sediments in the upper intervals of the section probably occurred in more open marine conditions, relatively warm water, but with low levels of nutrients (nitrates). This interval of sediments with a characteristic phytoplankton complex can be correlated with the middle part of the Khadum horizon, an analogue of the Nizhny Morozkinsky subformation and, possibly, with the upper clayey part of the Polbinsky formation of Western and Central Ciscaucasia. The accumulation of the lower units of the studied part in the Angekharan, dated to the Early Oligocene, most likely occurred in a marine, shallower environment with possible short-term transgressive impulses. Overall, it is possible to suggest a proximal environment of high nutrient content in well-mixed waters within the inner neritic zone. An analogue of the deposits of this interval can be the Lower Morozkinsky Formation and the lower parts of the Upper Morozkinsky Formation of the Ciscaucasia. The significant increase in deflandroids in the upper part of the Angekharan section is similar to the changes noted during the transition to the zone of Deflandrea spinulosa f. Majkopica in the upper part of the Batalpashinskaya Formation of the late Oligocene in Ciscaucasia. The accumulation of sediments probably occurred in a marine basin with signs of stagnation in brackish, eutrophic environment, with a short-term supply of material from the photic zone. The conclusions about the peculiarities of changes in the depositional conditions in the study area are also confirmed by the results of geochemical studies. The deposits of the studied sections are represented by both terrestrial and aquatic types of organic matter (OM). Terrigenous OM was more typical in rocks from the Lagich and Agsu outcrops. The OM of rocks from the Lagich section varies from marginally mature to mature. In the Angekharan section the OM is thermally immature, as evidenced by the low Tmax values. Despite the small thickness of the Agsu outcrop, rock samples from this section contain kerogen of various stages of transformation from immature to mature. The carbon isotope composition (CIC) of Corg in sediments within the studied sections is in the δ13C range, characteristic of Oligocene sediments in the Paratethys. There is a higher enrichment of the 13C isotope in OM in sediments from the Agsu section.

Long-term durability investigation of basalt fiber-reinforced geopolymer concrete in marine environment

The long-term durability of basalt fiber-reinforced geopolymer concrete (BFRGC) in marine environments is importance for the development of sustainable construction practices. This study examines the long-term durability of basalt fiber-reinforced geopolymer concrete exposed to dry-wet cycles and immersion treatment in marine conditions. A geopolymer concrete with 1% fiber content was prepared and subjected to dry-wet cycles and immersion treatments in a 5% sulfate solution (Tehmina et al., 2014; Nasir et al., 2016; John et al., 2016) [1-3]. Density measurements, ultrasonic pulse velocity tests, and uniaxial compression tests were conducted on the BFRGC after various treatment durations. The mechanical properties of BFRGC were compared with geopolymer concrete without fibers in marine environments. Additionally, the changes in compressive strength of geopolymer concrete with and without fibers in different immersion environments were further discussed. Using low-field nuclear magnetic resonance (LF-NMR) technology, the variations in pore structure were also analyzed. The results show that the mechanical property loss from dry-wet cycles was greater than from immersion treatment. In BFRGC, strength decreased by 10.1% after 192 days of dry-wet cycles, compared to a smaller decrease of 5.6% in immersion environments. The inclusion of basalt fibers effectively enhances stability. When in dry-wet cycle tests, BFRGC strength decreased from 49.6 MPa to 44.6 MPa, a reduction of 10.1%. Conversely, geopolymer concrete without fibers dropped from 49.7 MPa to 42.1 MPa, a reduction of 15.5%. LF-NMR test results show that the porosity of geopolymer concrete without fibers increased by 21.6% and 17.5% in dry-wet cycles and immersion environments, respectively. In contrast, the porosity of BFRGC increased by 16.1% and 12.7%.

Ship pitch prediction method based on LSTMC and multi-head attention

When ships sail in the sea, ship motion is unstable and stochasticity due to the ever-changing weather and marine conditions. Aiming to address the issue of low prediction accuracy in traditional prediction methods, short term predictions of ship pitch at 1 step, 3 steps, 6 steps, and 12 steps in advance are conducted, and the impact of input-output ratios on the prediction model is studied. The seven types of data of the marine environment and ship motion are taken as model inputs, with pitch as the model output. When predicting 1 step in advance, a prediction model based on LSTM and multi-head attention (LMA) is proposed. This model firstly uses LSTM layer to extract the temporal feature of the input sequence, and then uses the multi-head attention layer to assign larger weights to the key information to enhance prediction accuracy. When predicting 3 steps, 6 steps, and 12 steps in advance, as the input-output ratio increases, the length of the input sequence keeps growing. The model needs to sufficiently capture the local spatial characteristic and long-range dependency between multi-variable inputs, a deep prediction model based on Conv2d and LMA model is proposed. The model firstly uses two-dimensional convolution layer to extract local spatial feature of long sequences, and then through the attention layer, assign larger weights to temporal information and spatial information that are conducive to continuous prediction in order to enhance prediction accuracy. Research on the input-output ratio indicates that, as the number of predicted steps increases, the appropriate ratio continuously decreases, but the length of the input sequence keeps increasing. Finally, four evaluation metrics are used to evaluate the proposed algorithms on real ship data, and the prediction stability and accuracy of the LMA model and the LCMA model are also verified.

Assessing the accuracy of MUR high resolution satellite sea surface temperature data

Marine bivalve mollusks are valuable proxies for El Niño-Southern Oscillation (ENSO) events in paleoclimate research, reflecting changes in sea surface temperature (SST) and other ambient marine conditions in their shell chemistry. However, the use of several Peruvian species of bivalves as paleoENSO proxies needs to be established by comparing their shells’ δ18O-derived SST records with instrumental SST measurements. Along the Peruvian coast, the limited spatial coverage of in-situ coastal monitoring stations hinders such comparisons. This study aims to assess the accuracy of the Multi-scale Ultra-high Resolution (MUR) satellite-derived SST dataset as an alternative source of SST information for paleoENSO studies in Peru, which could advance research on Peruvian bivalve species. This study compares MUR satellite data with in-situ measured SST from ten coastal monitoring stations operated by the Instituto del Mar del Perú (IMARPE). The correlation between the datasets is evaluated, and systematic and non-systematic variations are examined. Environmental factors that may impact the accuracy of satellite SST measurements, such as clouds and aerosols, are also investigated. Results show that MUR data generally correlate with overall trends in SST variability captured by in-situ measurements. However, there are regional variations in the accuracy of MUR data, with some areas showing consistent temperature offsets. Differences in measurement methodologies and environmental variables are explored as potential causes of variations between the datasets. Overall, the study demonstrates the potential of using high-resolution satellite SST data for assessing δ18O SST records from bivalves in locations without local SST records. It provides insights into the accuracy and limitations of using MUR data as an alternative source of SST information for paleoENSO studies in coastal Peru.

Effect of Copper and Nickel Content on the Corrosion Mechanisms in Ferritic Matrix Gray Cast Irons under Simulated Marine Environments

This article investigated the influence of copper (Cu) and nickel (Ni) on atmospheric corrosion in gray cast iron under simulated marine conditions. The goal was to compare the effect of Cu and Ni addition in castings with weathering steels. Selected alloys were cast, cut, prepared, and heat-treated for microstructure homogenization. Accelerated corrosion tests were conducted using a salt spray chamber. Corroded samples were analyzed for corrosion thickness and deposits using scanning electron microscopy, X-ray diffraction, and electrochemical techniques. The results indicate that alloying elements significantly affect corrosion processes. In the long-term, Cu had a greater impact on the corrosion mechanisms than Ni. Both Cu and Ni exhibited similar effects on the corrosion mechanisms in gray cast iron and weathering steels. In the initial and final stages, the behavior was comparable to that of weathering steels, but in the intermediate stage, it differed from the literature, suggesting the presence of an additional mechanism between these stages.