Marine Air Research Articles

Nitrous acid in the polluted coastal atmosphere of the South China Sea: Ship emissions, budgets, and impacts

Nitrous acid (HONO) can significantly contribute to hydroxyl radicals (OH) and thus regulate atmospheric oxidation chemistry; however, ambient HONO sources are not well quantified and vary in different environments. In this study, we conducted comprehensive field observations at a coastal site in the South China Sea and performed chemical box modelling to demonstrate contrasting budgets and impacts of diurnal atmospheric HONO derived from the sea, coastline and continent. The ship emission ratio of HONO/nitrogen oxides (NOx) (1.21 ± 0.99%) was calculated from hundreds of night-time fresh plume measurements. Offshore marine air was frequently influenced by ship exhausts, and the sea acted as an HONO sink. Heterogeneous conversions of nitrogen dioxide (NO2) on underlying surfaces and photolysis of adsorbed nitric acid (HNO3(ads)) were the major HONO sources in coastal air, when heterogeneous NO2 conversions on the ground surface and the homogeneous NO + OH reaction dominated HONO formation in continental air. HONO photolysis was a significant source of reactive radicals (ROx = OH + HO2 + RO2) in these air masses. Atmospheric box model including only homogeneous HONO source of the NO + OH reactions significantly underpredicted the OH concentration and atmospheric oxidising capacity in coastal and continental air. This study provides new insights into the complex sources and significant impacts of HONO in the polluted coastal boundary layer.

Marine Air Pollution in Israel: Extent, Proposed Mitigation Targets, Benefits and Feasibility

Marine air pollution is a major contributor to seaports and coastal air pollution, and Israel has yet to seriously confront this issue. This study aimed to update previous marine air pollution estimations in Israel’s two major ports: Haifa and Ashdod. The objectives were to examine technical and regulatory measures to address the problem, to propose mitigation targets and to estimate their potential benefits. Based on a model of emission-calculations that relies on an updated ship-inventory data as well as real-time ships’ location and movement tools, the combined marine NOx, SOx and PM2.5 annual emissions in these ports were found to be 18,415, 15,128 and 1453 tons, respectively. These values are considerably higher than previous estimates, are comparable to the constant pollution emitted at ground level from a 1000-MW coal powered city power plant and are 3–20 times higher than the industrial and land transportation sectors in these cities. Relatively high nickel concentration in PM was found in Israel only relatively adjacent to the Haifa and Ashdod ports. Since high nickel concentration in PM is today mainly associated with marine air pollution, this finding supports the hypothesis that marine air pollution worsens the air quality in these cities. SOx and PM2.5 emissions can be reduced by 78% and 27%, respectively, if Israel enforces the revised International Convention for the Prevention of Pollution from Ships (MARPOL) Annex VI regulations in its territorial waters. While the latter step can achieve external benefits of NIS 518.4 million/year (EUR 132 million/year), additional mitigation actions and local regulations are suggested, focusing on NOx emissions but also on other pollutant criteria. Such actions can achieve further benefits of NIS 274.3 million/year (EUR 70 million/year). Achieving the suggested targets is challenging yet attainable, and their potential benefits will probably outweigh their costs.

Local-thermal-gradient and large-scale-circulation impacts on turbine-height wind speed forecasting over the Columbia River Basin

Abstract. We investigate the sensitivity of turbine-height wind speed forecast to initial condition (IC) uncertainties over the Columbia River Gorge (CRG) and Columbia River Basin (CRB) for two typical weather phenomena, i.e., local-thermal-gradient-induced marine air intrusion and a cold frontal passage. Four types of turbine-height wind forecast anomalies and their associated IC uncertainties related to local thermal gradients and large-scale circulations are identified using the self-organizing map (SOM) technique. The four SOM types are categorized into two patterns, each accounting for half of the ensemble members. The first pattern corresponds to IC uncertainties that alter the wind forecast through a modulating weather system, which produces the strongest wind anomalies in the CRG and CRB. In the second pattern, the moderate uncertainties in local thermal gradient and large-scale circulation jointly contribute to wind forecast anomaly. We analyze the cross section of wind and temperature anomalies through the gorge to explore the evolution of vertical features of each SOM type. The turbine-height wind anomalies induced by large-scale IC uncertainties are more concentrated near the front. In contrast, turbine-height wind anomalies induced by the local IC thermal uncertainties are found above the surface thermal anomalies. Moreover, the wind forecast accuracy in the CRG and CRB is limited by IC uncertainties in a few specific regions, e.g., the 2 m temperature within the basin and large-scale circulation over the northeast Pacific around 140∘ W.

Assessment of radiative heating errors in Tropical Atmosphere Ocean array marine air temperature measurements

We assess the radiative heating error affecting marine air temperature (MAT) measurements in the Tropical Atmosphere Ocean array. The error in historical observations is found to be ubiquitous across the array, spatially variable and approximately stationary in time. The error induces spurious warming during daytime hours, but does not affect night-time temperatures. The range encompassing the real, unknown daily- and monthly-mean values is determined using daytime and night-time mean temperatures as upper and lower limits. The uncertainty in MAT is less than or equal to 0.5 °C and 0.2 °C for 95% of daily and monthly estimates, respectively. Uncertainties impact surface turbulent heat flux estimates, with potentially significant influences on the quantification of coupled ocean-atmosphere processes.

Passive air sampler-derived concentrations and carcinogenic potential of PAHs in oil/gas production city (Macaé, Brazil)

Urban centers cause atmospheric pollution and suffer the most from their emissions. Polycyclic aromatic hydrocarbons (PAHs) are persistent toxic substances (PTS) that can be air transported at urban sites and impact human health, causing skin allergies, respiratory diseases, and cancer. Macaé is a southeastern Brazilian coastal city that had an intense process of urbanization and population growth due to the installation of oil companies in the 1970s. The study aimed to evaluate Macaé's air quality regarding atmospheric PAH occurrence, measured using polyurethane foam passive air samplers (PUF-PAS). PUF disks were deployed along environmental gradients during the 2018–2019 spring/summer in Macaé city and its surroundings. In total, 22 individual PAHs were analyzed by gas chromatography coupled with mass spectrometry. Total PAH air concentrations ranged from 0.3 to 3.3 ng.m-3, pointing out three- to four-membered ring compounds as the most abundant (76%). Among them, phenanthrene, anthracene, and fluoranthene had the highest air concentrations, especially at sampling sites where fossil fuel combustion seemed more prominent. Compared to other cities worldwide, the lower PAH air levels reported in this study may be linked to the influence of marine air masses. As the most carcinogenic PAH compound is benzo[a]pyrene, the results are also given in benzo[a]pyrene-equivalent (BaPeq). BaPeq ranged from 0.02 to 0.10 ng.m-3. This study indicated an environmental trend along urban-industry-background spatial transects. Even though a prominent marine air mass might contribute to efficient air pollution dispersion, in urban/industrial areas, human exposure to carcinogenic chemicals is higher, probably due to local PAH sources inside the urban perimeter of Macaé.

Influence of biogenic emissions from boreal forests on aerosol–cloud interactions

Boreal forest acts as a carbon sink and contributes to the formation of secondary organic aerosols via emission of aerosol precursor compounds. However, these influences on the climate system are poorly quantified. Here we show direct observational evidence that aerosol emissions from the boreal forest biosphere influence warm cloud microphysics and cloud–aerosol interactions in a scale-dependent and highly dynamic manner. Analyses of in situ and ground-based remote-sensing observations from the SMEAR II station in Finland, conducted over eight months in 2014, reveal substantial increases in aerosol load over the forest one to three days after aerosol-poor marine air enters the forest environment. We find that these changes are consistent with secondary organic aerosol formation and, together with water-vapour emissions from evapotranspiration, are associated with changes in the radiative properties of warm, low-level clouds. The feedbacks between boreal forest emissions and aerosol–cloud interactions and the highly dynamic nature of these interactions in air transported over the forest over timescales of several days suggest boreal forests have the potential to mitigate climate change on a continental scale. Our findings suggest that even small changes in aerosol precursor emissions, whether due to changing climatic or anthropogenic factors, may substantially modify the radiative properties of clouds in moderately polluted environments. Emissions from the boreal forest biosphere can substantially increase aerosol load above the forest and influence the radiative properties of clouds, according to analysis of observations from a monitoring station in Finland.

Is the ocean surface a source of nitrous acid (HONO) in the marine boundary layer?

Abstract. Nitrous acid, HONO, is a key net photolytic precursor to OH radicals in the atmospheric boundary layer. As OH is the dominant atmospheric oxidant, driving the removal of many primary pollutants and the formation of secondary species, a quantitative understanding of HONO sources is important to predict atmospheric oxidising capacity. While a number of HONO formation mechanisms have been identified, recent work has ascribed significant importance to the dark, ocean-surface-mediated conversion of NO2 to HONO in the coastal marine boundary layer. In order to evaluate the role of this mechanism, here we analyse measurements of HONO and related species obtained at two contrasting coastal locations – Cabo Verde (Atlantic Ocean, denoted Cape Verde herein), representative of the clean remote tropical marine boundary layer, and Weybourne (United Kingdom), representative of semi-polluted northern European coastal waters. As expected, higher average concentrations of HONO (70 ppt) were observed in marine air for the more anthropogenically influenced Weybourne location compared to Cape Verde (HONO < 5 ppt). At both sites, the approximately constant HONO/NO2 ratio at night pointed to a low importance for the dark, ocean-surface-mediated conversion of NO2 into HONO, whereas the midday maximum in the HONO/NO2 ratios indicated significant contributions from photo-enhanced HONO formation mechanisms (or other sources). We obtained an upper limit to the rate coefficient of dark, ocean-surface HONO-to-NO2 conversion of CHONO = 0.0011 ppb h−1 from the Cape Verde observations; this is a factor of 5 lower than the slowest rate reported previously. These results point to significant geographical variation in the predominant HONO formation mechanisms in marine environments and indicate that caution is required when extrapolating the importance of such mechanisms from individual study locations to assess regional and/or global impacts on oxidising capacity. As a significant fraction of atmospheric processing occurs in the marine boundary layer, particularly in the tropics, better constraint of the possible ocean surface source of HONO is important for a quantitative understanding of chemical processing of primary trace gases in the global atmospheric boundary layer and associated impacts upon air pollution and climate.

First insights into northern Africa high-altitude background aerosol chemical composition and source influences

Abstract. Field measurements were conducted to determine aerosol chemical composition at a newly established remote high-altitude site in North Africa at the Atlas Mohammed V (AMV) atmospheric observatory located in the Middle Atlas Mountains. The main objectives of the present work are to investigate the variations in the aerosol composition and better assess global and regional changes in atmospheric composition in North Africa. A total of 200 particulate matter (PM10) filter samples were collected at the site using a high-volume (HV) collector in a 12 h sampling interval from August to December 2017. The chemical composition of the samples was analyzed for trace metals, water-soluble ions, organic carbon (OC/EC), aliphatic hydrocarbons, and polycyclic aromatic hydrocarbon (PAH) contents. The results indicate that high-altitude aerosol composition is influenced by both regional and transregional transport of emissions. However, local sources play an important role, especially during low wind speed periods, as observed for November and December. During background conditions characterized by low wind speeds (avg. 3 m s−1) and mass concentrations in the range from 9.8 to 12 µg m−3, the chemical composition is found to be dominated by inorganic elements, mainly suspended dust (61 %) and ionic species (7 %), followed by organic matter (7 %), water content (12 %), and unidentified mass (11 %). Despite the proximity of the site to the Sahara, its influence on the atmospheric composition at this high-altitude site was mainly seasonal and accounted for only 22 % of the sampling duration. Biogenic organics contributed up to 7 % of the organic matter with high contributions from compounds such as heneicosane, hentriacontane, and nonacosane. The AMV site is dominated by four main air mass inflows, which often leads to different aerosol chemical compositions. Mineral dust influence was seasonal and ranged between 21 % and 74 % of the PM mass, with peaks observed during the summer, and was accompanied by high concentrations of SO42- of up to 3.0 µg m−3. During winter, PM10 concentrations are low (<30 µg m−3), the influence of the desert is weaker, and the marine air masses (64 %) are more dominant with a mixture of sea salt and polluted aerosol from the coastal regions (Rabat and Casablanca). During the daytime, mineral dust contribution to PM increased by about 42 % because of road dust resuspension. In contrast, during nighttime, an increase in the concentrations of alkanes, PAHs, alkane-2-ones, and anthropogenic metals such as Pb, Ni, and Cu was found due to variations in the boundary layer height. The results provide the first detailed seasonal and diurnal variation of the aerosol chemical composition, which is valuable for long-term assessment of climate and regional influence of air pollution in North Africa.

Atmospheric particle number size distribution and size-dependent formation rate and growth rate of neutral and charged new particles at a coastal site of eastern China

Coastal new particle formation (NPF) may be complicated due to the influence of both continental and marine air masses. Here we presented the result of particle number size distribution and NPF event measurements at a coastal industrial park of eastern China from 2018 to 2019. The highest nucleation-mode particle number concentration (daytime maximum: 4.9 × 103 cm−3) and NPF frequency (8% of the observation days) were observed in the continental-marine air masses that originated from North China Plain and traveled along the coastline before arriving at the coastal site. The formation rates of 2 nm particles (J2) at this coastal site are similar to those reported in the urban environments around the world, probably due to the influence of local industrial emission. Ion to total particle number concentration ratios in 2–7 nm and 7–20 nm were 1.5% and 12%, respectively, during the NPF periods. Neutral new particle formation pathway thus dominated over ion-mediated pathway at this coastal site. Our observation also showed that number concentration and formation rate of neutral new particles decreased monotonically with particle size, while those of charged new particles increased with particle size. Such difference points to additional formation and loss mechanisms of charged particles, such as ion-aerosol attachment and ion-ion recombination in the atmosphere. The behavior of appearance time-based growth rates, however, are similar for neutral and charged particles.

Long-range transport of anthropogenic air pollutants into the marine air: insight into fine particle transport and chloride depletion on sea salts

Abstract. Long-range transport of anthropogenic air pollutants from East Asia can affect the downwind marine air quality during spring and winter. Long-range transport of continental air pollutants and their interaction with sea salt aerosol (SSA) significantly modify the radiative forcing of marine aerosols and influence ocean biogeochemical cycling. Previous studies poorly characterize variations of aerosol particles along with air mass transport from the continental edge to the remote ocean. Here, the research ship R/V Dongfanghong 2 traveled from the eastern China seas (ECS) to the northwestern Pacific Ocean (NWPO) to understand what and how air pollutants were transported from the highly polluted continental air to clean marine air in spring. A transmission electron microscope (TEM) was used to find the long-range transported anthropogenic particles and the possible Cl-depletion phenomenon of SSA in marine air. Anthropogenic aerosols (e.g., sulfur (S)-rich, S-soot, S-metal/fly ash, organic matter (OM)-S, and OM coating particles) were identified and dramatically declined from 87 % to 8 % by number from the ECS to remote NWPO. For the SSA aging, 87 % of SSA particles in the ECS were identified as fully aged, while the proportion of fully aged SSA particles in the NWPO decreased to 29 %. Our results highlight that anthropogenic acidic gases in the troposphere (e.g., SO2, NOx, and volatile organic compounds) could be transported to remote marine air and exert a significant impact on aging of SSA particles in the NWPO. The study shows that anthropogenic particles and gases from East Asia significantly perturb different aerosol chemistry from coastal to remote marine air. More attention should be given to the modification of SSA particles in remote marine areas due to the influence of anthropogenic gaseous pollutants.

PERANCANGAN PEMBERSIH GAS BUANG KAPAL DENGAN KAPASITAS 70.000 KG/JAM

Marine air pollution regulations require the use of low Sulfur fuels to reduce SOx gas. Scrubber offers lower operating costs by allowing the use of high-sulfur fuels that are cheaper for fuel, capital costs and operating costs as an alternative to low-sulfur fuels, such as Liquid Natural Gas (LNG). It is necessary to design a ship exhaust gas cleaner (Scrubber). In the IMO 2020 Rules and Marpol Annex VI there are no Scrubber design standards that regulate calculations, material selection, and others. However, IMO 2020 and Marpol require that the exhaust gas purifier produced by the scrubber released into the air must reach 97.5% ~ 99.5% cleaning and the minimum water pH is 3 which can be determined using the OLIanalyzer Software. The components of the scrubber consist of shell, body flange, scrubber head, nozzle, lug support scrubber, Spray Nozzle, Distributor Pipe, Packing Bed Support, Packing Bed, Venturi Scrubber, Demister. From three times doing scrubber simulation using OLIanalyzer Software on the Delta Pioneer engine, 80% performance was produced and produced gas output of 160 ppm and water pH of 6.6 pH. So that the scrubber design can be applied to the pioneer delta ship engine with a capacity of 70,000 Kg/h.

Measurement report: Regional characteristics of seasonal and long-term variations in greenhouse gases at Nainital, India, and Comilla, Bangladesh

Abstract. Emissions of greenhouse gases (GHGs) from the Indian subcontinent have increased during the last 20 years along with rapid economic growth; however, there remains a paucity of GHG measurements for policy-relevant research. In northern India and Bangladesh, agricultural activities are considered to play an important role in GHG concentrations in the atmosphere. We performed weekly air sampling at Nainital (NTL) in northern India and Comilla (CLA) in Bangladesh from 2006 and 2012, respectively. Air samples were analyzed for dry-air gas mole fractions of CO2, CH4, CO, H2, N2O, and SF6 and carbon and oxygen isotopic ratios of CO2 (δ13C-CO2 and δ18O-CO2). Regional characteristics of these components over the Indo-Gangetic Plain are discussed compared to data from other Indian sites and Mauna Loa, Hawaii (MLO), which is representative of marine background air. We found that the CO2 mole fraction at CLA had two seasonal minima in February–March and September, corresponding to crop cultivation activities that depend on regional climatic conditions. Although NTL had only one clear minimum in September, the carbon isotopic signature suggested that photosynthetic CO2 absorption by crops cultivated in each season contributes differently to lower CO2 mole fractions at both sites. The CH4 mole fraction of NTL and CLA in August–October showed high values (i.e., sometimes over 4000 ppb at CLA), mainly due to the influence of CH4 emissions from the paddy fields. High CH4 mole fractions sustained over months at CLA were a characteristic feature on the Indo-Gangetic Plain, which were affected by both the local emission and air mass transport. The CO mole fractions at NTL were also high and showed peaks in May and October, while CLA had much higher peaks in October–March due to the influence of human activities such as emissions from biomass burning and brick production. The N2O mole fractions at NTL and CLA increased in June–August and November–February, which coincided with the application of nitrogen fertilizer and the burning of biomass such as the harvest residues and dung for domestic cooking. Based on H2 seasonal variation at both sites, it appeared that the emissions in this region were related to biomass burning in addition to production from the reaction of OH and CH4. The SF6 mole fraction was similar to that at MLO, suggesting that there were few anthropogenic SF6 emission sources in the district. The variability of the CO2 growth rate at NTL was different from the variability in the CO2 growth rate at MLO, which is more closely linked to the El Niño–Southern Oscillation (ENSO). In addition, the growth rates of the CH4 and SF6 mole fractions at NTL showed an anticorrelation with those at MLO, indicating that the frequency of southerly air masses strongly influenced these mole fractions. These findings showed that rather large regional climatic conditions considerably controlled interannual variations in GHGs, δ13C-CO2, and δ18O-CO2 through changes in precipitation and air mass.

Conceptual design and assessment of a novel energy management system for LNG fueled ships with air separation

Medium and large ships always need to carry many different types of gas cylinders. Limited by the hull, their gas storage is small, restricting the ship's ocean voyage time. It is the most effective solution to use the air separation device and cabin air to prepare various purified gases on site. However, the traditional cryogenic air separation system has large energy consumption and low efficiency, which is not suitable for shipboard use. Therefore, this paper innovatively proposes the air separation systems for the cold energy utilization of onboard LNG-powered ships. According to the characteristics of ship engine power and pressure ratio change of LNG fuel supply system, LNG energy management systems (LNGEMSs) with high and low pressure matching cold energy utilization air separation unit processes are proposed and compared. The exergetic analysis model of the design was established using pinch point analysis, energy balance methods, and energy efficiency indexes. The applicability conclusion was determined through actual onshore process verification, comparison, and exergy analysis. The cryogenic air separation system on LNG fueled ships can adopt a different pressures heat exchange network solution to make full use of LNG cold energy to improve energy efficiency. The LNG cold exergy efficiency of the LNGEMSs can reach 83.2%, and the unit liquid product energy consumption is only 0.225 kWh·Nm−1. Due to the additional means of energy conversion and utilization, the ship design and operating indexes with the new system meet or exceed the current regulations and the current technical level. Additional oxygen obtained by air separation can further improve the combustion efficiency of marine gas turbines, which brings good prospects for marine air separation technology.

Airborne Bacterial Community Composition According to Their Origin in Tenerife, Canary Islands.

Microorganisms are ubiquitous in the environment, and the atmosphere is no exception. However, airborne bacterial communities are some of the least studied. Increasing our knowledge about these communities and how environmental factors shape them is key to understanding disease outbreaks and transmission routes. We describe airborne bacterial communities at two different sites in Tenerife, La Laguna (urban, 600 m.a.s.l.) and Izaña (high mountain, 2,400 m.a.s.l.), and how they change throughout the year. Illumina MiSeq sequencing was used to target 16S rRNA genes in 293 samples. Results indicated a predominance of Proteobacteria at both sites (>65%), followed by Bacteroidetes, Actinobacteria, and Firmicutes. Gammaproteobacteria were the most frequent within the Proteobacteria phylum during spring and winter, while Alphaproteobacteria dominated in the fall and summer. Within the 519 genera identified, Cellvibrio was the most frequent during spring (35.75%) and winter (30.73%); Limnobacter (24.49%) and Blastomonas (19.88%) dominated in the summer; and Sediminibacterium represented 10.26 and 12.41% of fall and winter samples, respectively. Sphingomonas was also identified in 17.15% of the fall samples. These five genera were more abundant at the high mountain site, while other common airborne bacteria were more frequent at the urban site (Kocuria, Delftia, Mesorhizobium, and Methylobacterium). Diversity values showed different patterns for both sites, with higher values during the cooler seasons in Izaña, whereas the opposite was observed in La Laguna. Regarding wind back trajectories, Tropical air masses were significantly different from African ones at both sites, showing the highest diversity and characterized by genera regularly associated with humans (Pseudomonas, Sphingomonas, and Cloacibacterium), as well as others related to extreme conditions (Alicyclobacillus) or typically associated with animals (Lachnospiraceae). Marine and African air masses were consistent and very similar in their microbial composition. By contrast, European trajectories were dominated by Cellvibrio, Pseudomonas, Pseudoxanthomonas, and Sediminibacterium. These data contribute to our current state of knowledge in the field of atmospheric microbiology. However, future studies are needed to increase our understanding of the influence of different environmental factors on atmospheric microbial dispersion and the potential impact of airborne microorganisms on ecosystems and public health.

Chemical Characterization and Source Apportionment of Organic Aerosols in the Coastal City of Chennai, India: Impact of Marine Air Masses on Aerosol Chemical Composition and Potential for Secondary Organic Aerosol Formation

Chemical Characterization and Source Apportionment of Organic Aerosols in the Coastal City of Chennai, India: Impact of Marine Air Masses on Aerosol Chemical Composition and Potential for Secondary Organic Aerosol Formation

An ensemble reconstruction of global monthly sea surface temperature and sea ice concentration 1000\u20131849

This paper describes a global monthly gridded Sea Surface Temperature (SST) and Sea Ice Concentration (SIC) dataset for the period 1000–1849, which can be used as boundary conditions for atmospheric model simulations. The reconstruction is based on existing coarse-resolution annual temperature ensemble reconstructions, which are then augmented with intra-annual and sub-grid scale variability. The intra-annual component of HadISST.2.0 and oceanic indices estimated from the reconstructed annual mean are used to develop grid-based linear regressions in a monthly stratified approach. Similarly, we reconstruct SIC using analog resampling of HadISST.2.0 SIC (1941–2000), for both hemispheres. Analogs are pooled in four seasons, comprising of 3-months each. The best analogs are selected based on the correlation between each member of the reconstructed SST and its target. For the period 1780 to 1849, We assimilate historical observations of SST and night-time marine air temperature from the ICOADS dataset into our reconstruction using an offline Ensemble Kalman Filter approach. The resulting dataset is physically consistent with information from models, proxies, and observations.

Problems, Challenges, and Removing Methods of Micro Plastics from Water

Abstract: Over the past few years, several studies have reported the presence of micro plastics in treated tap and bottled water, raising questions and concerns about the impact that micro plastics in drinking-water might have on human health. Microplastics are ubiquitous within the environment and are detected in marine water, wastewater, water, food, air and drinking-water, both bottled and water. Microplastics enter freshwater environments in a number of ways: primarily from surface run-off and both treated and untreated wastewater effluent, but also from combined sewer overflows, industrial effluent degraded plastic waste and atmospheric deposition. Further, the limited evidence indicates that some microplastics found in drinking-water may come from treatment and distribution systems for water and/or bottling of drinking water. Keywords: Fresh water, health, process.

Turbulence in The Marine Boundary Layer and Air Motions Below Stratocumulus Clouds at the ARM Eastern North Atlantic Site

AbstractMarine stratocumulus clouds are intimately coupled to the turbulence in the boundary layer and drizzle is known to be ubiquitous within them. Six years of data collected at the Atmospheric Radiation Measurement (ARM)’s Eastern North Atlantic site are utilized to characterize turbulence in the marine boundary layer and air motions below stratocumulus clouds. Profiles of variance of vertical velocity binned by wind direction (wdir) yielded that the boundary layer measurements are affected by the island when the wdir is between 90° and 310° (measured clockwise from North where air is coming from). Data collected during the marine conditions (wdir<90 or wdir>310) showed that the variance of vertical velocity was higher during the winter months than during the summer months due to higher cloudiness, wind speeds, and surface fluxes. During marine conditions the variance of vertical velocity and cloud fraction exhibited a distinct diurnal cycle with higher values during the nighttime than during the daytime. Detailed analysis of 32 cases of drizzling marine stratocumulus clouds showed that for a similar amount of radiative cooling at the cloud top, within the sub-cloud layer 1) drizzle increasingly falls within downdrafts with increasing rain rates, 2) the strength of the downdrafts increases with increasing rain rates, and 3) the correlation between vertical air motion and rain rate is highest in the middle of the sub-cloud layer. The results presented herein have implications for climatological and model evaluation studies conducted at the ENA site, along with efforts of accurately representing drizzle-turbulence interactions in a range of atmospheric models.

Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants

Abstract. We present an updated mechanism for tropospheric halogen (Cl + Br + I) chemistry in the GEOS-Chem global atmospheric chemical transport model and apply it to investigate halogen radical cycling and implications for tropospheric oxidants. Improved representation of HOBr heterogeneous chemistry and its pH dependence in our simulation leads to less efficient recycling and mobilization of bromine radicals and enables the model to include mechanistic sea salt aerosol debromination without generating excessive BrO. The resulting global mean tropospheric BrO mixing ratio is 0.19 ppt (parts per trillion), lower than previous versions of GEOS-Chem. Model BrO shows variable consistency and biases in comparison to surface and aircraft observations in marine air, which are often near or below the detection limit. The model underestimates the daytime measurements of Cl2 and BrCl from the ATom aircraft campaign over the Pacific and Atlantic, which if correct would imply a very large missing primary source of chlorine radicals. Model IO is highest in the marine boundary layer and uniform in the free troposphere, with a global mean tropospheric mixing ratio of 0.08 ppt, and shows consistency with surface and aircraft observations. The modeled global mean tropospheric concentration of Cl atoms is 630 cm−3, contributing 0.8 % of the global oxidation of methane, 14 % of ethane, 8 % of propane, and 7 % of higher alkanes. Halogen chemistry decreases the global tropospheric burden of ozone by 11 %, NOx by 6 %, and OH by 4 %. Most of the ozone decrease is driven by iodine-catalyzed loss. The resulting GEOS-Chem ozone simulation is unbiased in the Southern Hemisphere but too low in the Northern Hemisphere.

Historical increases in land‐derived nutrient inputs may alleviate effects of a changing physical climate on the oceanic carbon cycle

The implications of climate change and other human perturbations on the oceanic carbon cycle are still associated with large uncertainties. Global-scale modelling studies are essential to investigate anthropogenic perturbations of oceanic carbon fluxes but, until now, they have not considered the impacts of temporal changes in riverine and atmospheric inputs of P and N on the marine net biological productivity (NPP) and air-sea CO2 exchange (FCO2 ). To address this, we perform a series of simulations using an enhanced version of the global ocean biogeochemistry model HAMOCC to isolate effects arising from (1) increasing atmospheric CO2 levels, (2) a changing physical climate and (3) alterations in inputs of terrigenous P and N on marine carbon cycling over the 1905-2010 period. Our simulations reveal that our first-order approximation of increased terrigenous nutrient inputs causes an enhancement of 2.15PgCyear-1 of the global marine NPP, a relative increase of +5% over the simulation period. This increase completely compensates the simulated NPP decrease as a result of increased upper ocean stratification of -3% in relative terms. The coastal ocean undergoes a global relative increase of 14% in NPP arising largely from increased riverine inputs, with regional increases exceeding 100%, for instance on the shelves of the Bay of Bengal. The imprint of enhanced terrigenous nutrient inputs is also simulated further offshore, inducing a 1.75PgCyear-1 (+4%) enhancement of the NPP in the open ocean. This finding implies that the perturbation of carbon fluxes through coastal eutrophication may extend further offshore than that was previously assumed. While increased nutrient inputs are the largest driver of change for the CO2 uptake at the regional scale and enhance the global coastal ocean CO2 uptake by 0.02PgCyear-1 , they only marginally affect the FCO2 of the open ocean over our study's timeline.