The ability to replace non-renewable, low-atom economy chemicals with an efficient catalyst that can join the reactants to generate the required product makes catalysis a useful tool for sustainable synthesis. Through careful designs toward sustainability, inspiring efforts are made in bioproducts and self-sustaining technologies for the integrated synthesis of value-added goods and energies. In this paper, we review a new Ti-BDS MOF, activated carbon, Al-based MOF, and Graphene, because it is readily made at room temperature, MIL-125 is extensively used. It is prepared environmentally, energetically, and economically (3E) Therefore, it is theoretically scalable and has long-term sustainability. Furthermore, by combining Ti-BDC containing g-C3N4 and Ag3PO4, unique Ti-BDC-based ternary photo-catalysts were effectively created. It provides a summary of the application of high-throughput (HT) approaches in the domain of porous aluminumMOFs for both drug discovery and synthesis optimization. One of the carbon allotropes is graphene, which has its carbon atoms organizedin a single sheet. These atoms of carbon are arranged in a two-dimensional honeycomb lattice structure. Graphene is an electrically, mechanically, thermally, and structurally innovative material. The characteristics of graphene produced from biomass precursors are comparable to those of graphene from traditional sources. For the manufacture of biofuels and many other high-value goods, activated carbon is a promising and long-term solid catalyst.