The Industrial Internet of Things (IIoT) accelerates smart manufacturing and boosts production efficiency through heterogeneous industrial equipment, intelligent sensors, and actuators. The Industrial Internet of Things is transforming from a traditional factory model to a new manufacturing mode, which allows cross-domain data-sharing among multiple system departments to enable smart manufacturing. A complete industrial product comes from the combined efforts of many different departments. Therefore, secure and reliable cross-domain access control has become the key to ensuring the security of cross-domain communication and resource-sharing. Traditional centralized access control schemes are prone to single-point failure problems. Recently, many researchers have integrated blockchain technology into access control models. However, most blockchain-based approaches use a single-chain structure, which has weak data management capability and scalability, while ensuring system security, and low access control efficiency, making it difficult to meet the needs of multi-domain cooperation in IIoT scenarios. Therefore, this paper proposes a decentralized cross-domain access model based on a master–slave chain with high scalability. Moreover, the model ensures the security and reliability of the master chain through a reputation-based node selection mechanism. Access control efficiency is improved by a grouping strategy retrieval method in the access control process. The experimental benchmarks of the proposed scheme use various performance metrics to highlight its applicability in the IIoT environment. The results show an 82% improvement in the throughput for the master–slave chain structure over the single-chain structure. There is also an improvement in the throughput and latency compared to the results of other studies.