Metasomatized Mantle Wedge Research Articles

Neoproterozoic Tectonics of the Arabian-Nubian Shield: Insights from U–Pb Zircon Geochronology, Sr–Nd–Hf Isotopes, and Geochemistry of the Deki Amhare Complex Granitoids, Central Eritrea

The Deki Amhare complex is located in central Eritrea, within the Arabian–Nubian Shield (ANS). It consists of an inner core of monzogranite porphyry and diorite enclaves (MMEs), surrounded outwardly by granodiorite and quartz diorite. The zircon U–Pb ages, whole-rock geochemistry, and Sr–Nd–Hf isotopic compositions of the Deki Amhare complex granitoids were used to discuss the Neoproterozoic tectonics of the ANS. The Late Tonian granodiorite and quartz diorite are metaluminous and calc-alkaline to slightly high-K calc-alkaline I-type plutons, with ages of 811.2 ± 4.8 Ma and 811.6 ± 5.7 Ma, respectively. They exhibit positive εHf(t) (7.6–9.5) and εNd(t) (3.9–4.7) values and relatively low (87Sr/86Sr)i ratios (0.70374–0.70463), indicating that they derived from the partial melting of a metasomatized mantle wedge during intra-oceanic subduction. The Ediacaran monzogranite porphyry and MMEs are subalkaline to alkaline A2-type granitoids with ages of 620.0 ± 4.3 Ma and 614.8 ± 3.9 Ma. These display positive εHf(t) (5.3–8.7) and εNd(t) (4.2–4.7) values, as well as low (87Sr/86Sr)i ratios (0.70310–0.70480), implying that they formed through crust–mantle magma mixing related to post-collisional slab break-off. Based on these data, three stages of regional tectonic evolution can be described: (1) from ~1200 Ma to ~875 Ma, the mafic oceanic crust was derived from depleted mantle during the opening of the Mozambique Ocean; (2) from ~875 Ma to ~630 Ma, intra-oceanic subduction and arc formation occurred with the development of I-type batholiths; and (3) from ~630 Ma to ~600 Ma, crustal and lithospheric reworking took place post-collision, leading to the formation of A2-type granitoids.

Composite Granitic Plutonism in the Southern Part of the Wadi Hodein Shear Zone, South Eastern Desert, Egypt: Implications for Neoproterozoic Dioritic and Highly Evolved Magma Mingling during Volcanic Arc Assembly

The Abu Farayed Granite (AFG), located in the southeastern desert of Egypt, was intruded during the early to late stages of Pan-African orogeny that prevailed within the Arabian–Nubian Shield. The AFG intrudes an association of gneisses, island arc volcano–sedimentary rocks, and serpentinite masses. Field observations, supported by remote sensing and geochemical data, reveal a composite granitic intrusion that is differentiated into two magmatic phases. The early granitic phase comprises weakly deformed subduction-related calc–alkaline rocks ranging from diorite to tonalite, while the later encloses undeformed granodiorite and granite. Landsat-8 (OLI) remote sensing data have shown to be highly effective in discriminating among the different varieties of granites present in the area. Furthermore, the data have provided important insights into the structural characteristics of the AFG region. Specifically, the data indicate the presence of major tectonic trends with ENE–WSW and NW–SE directions transecting the AFG area. Geochemically, the AFG generally has a calc–alkaline metaluminous affinity with relatively high values of Cs, Rb, K, Sr, Nd, and Hf but low contents of Nb, Ta, P, and Y. The early magmatic phase has lower alkalis and REEs, while the later phases have higher alkalis and REEs with distinctly negative Eu anomalies. The AFG is structurally controlled, forming a N–S arch, which may be due to the influence of the wadi Hodein major shear zone. The diorite and tonalite are believed to have been originally derived from subduction-related magmatism during regional compression. This began with the dehydration of the descending oceanic crust with differential melting of the metasomatized mantle wedge. Magma ascent was long enough to react with the thickened crust and therefore suffered fractional crystallization and assimilation (AFC) to produce the calc–alkaline diorite–tonalite association. The granodiorite and granites were produced due to partial melting, assimilation, and fractionation of lower crustal rocks (mainly diorite–tonalite of the early stage) after subduction and arc volcanism during a late orogenic relaxation–rebound event associated with uplift transitioning to extension.

Recycling of terrigenous sediments recorded in late Permian-early Triassic Fe-rich intrusions from Yunkai Massif, South China

The origin of Fe-rich intrusion remains debatable regarding the respective role of magmatic evolution and Fe enrichment in the source. Here, we report detailed mineral and bulk-rock geochemistry of Permian-Triassic (251–250 Ma) mafic intrusions from the Tengxian area in Yunkai Massif, South China. These rocks consist of hornblende norites, show Fe-rich affinities with high FeO*(FeO* = FeOt / (FeOt + MgO) in weight ratio, >0.8, based on total iron oxide in the rock), and exhibit significant enrichment in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) but depletion in Sr and high field strength elements (HFSEs), resembling subduction-related magmas. In addition, they show remarkable features that include very high δ18O values in zircon (δ18O = 8.8–10.6 ‰) and apatite (δ18O = 8.7–10.8 ‰), and extremely enriched SrPb [e.g. 87Sr/86Sr(i) = 0.7181–0.7196, 207Pb/204Pb(i) = 15.77–15.78, 208Pb/204Pb(i) = 38.95–39.05] and nonradiogenic NdHf isotopic compositions [e.g. εNd(t) = −11.1 ~ − 10.1, εHf(t) = −8.8 ~ −7.3] in bulk rocks. These characteristics distinguish the Tengxian norites from modern arc basalts and subduction-related magmas in the Paleo-Pacific Tectonic Domain. Instead, they are isotopically similar to Cenozoic Tibetan and Mediterranean potassic to ultrapotassic rocks in the Tethys Tectonic Domain. Regardless of variable influence by orthopyroxene and plagioclase accumulation, the intrinsically low SiO2 and high FeOt and Fe/Mn ratios in these rocks were likely attributed to significant contribution of a Fe-rich mantle component such as Si-poor pyroxenite, which might have formed through crystal accumulation of mafic magmas at mantle conditions. The highly evolved Sr-Nd-Pb-Hf isotopic signatures and very high δ18O values in zircon and apatite required substantial (10–20 %) involvement of recycled crust in the mantle source. The combined mineral and bulk-rock geochemical data suggest that the parental magmas for the Tengxian norites originated from a metasomatized mantle wedge through addition of terrigenous sediment-derived melt following the subduction of Paleo-Tethys Ocean beneath the Yunkai Massif.

Experimental constraints on the nature of multiphase solid inclusions and their bearing on mantle wedge metasomatism, Bohemian Massif

This study tests experimentally the hypothesis that calculated bulk compositions of multiphase solid inclusions present in minerals of ultrahigh pressure rocks, can be equated to the composition of the former trapped fluids. We investigated samples from the ultrahigh pressure garnet peridotites of the Bohemian Massif, spatially associated with ultrahigh pressure crustal rocks and representing a former subduction interface environment. Inclusions present in garnets, composed of amphibole + Ba-mica kinoshitalite + carbonates (dolomite + magnesite + norsethite), were taken to their entrapment conditions of c. 4.5 GPa and 1075 ºC. They (re)crystallized into a garnet fringe at the boundary between inclusion and host garnet, kinoshitalite ± olivine, carbonatite melt, and a hydrous fluid. Although the latter may have exsolved from the carbonatite melt upon quenching, microstructures suggest it was present at trapped conditions, and mass balance indicates that it corresponds to a Na-K-Cl-F-rich saline aqueous fluid (brine). Experiments demonstrate the stability of kinoshitalite at 4.5 GPa and 1075 ºC, and suggest that Ba-rich mica + carbonatite melt + brine coexisted at near-peak conditions. Barium is compatible in the carbonatite melt and mica with respect to the brine, with a partition coefficient between carbonatite melt and mica of ≈ 2.5–3. The garnet fringe formed from incongruent reaction of the former inclusion assemblage due to reversing the fluid(s)-host garnet reaction that occurred upon natural cooling/decompression. Loss of H2 or H2O from the inclusions due to volume diffusion through garnet and/or decrepitation, during geological timeframes upon decompression/cooling, may have prevented rehomogenization to a single homogeneous fluid. Our study shows that great care is needed in the interpretation of multiphase solid inclusions present in ultrahigh pressure rocks.

Reconstruction of Hualca Hualca volcano (southern Peru) based on geomorphological and geological evidence and 40Ar/39Ar dating

The volcanic history of many of the western Central Andes volcanoes, including Hualca Hualca in the northern Ampato Volcanic Complex, remains poorly constrained. Based on an updated 1:50,000-scale geological map, new cross-sections of the Ampato Complex, a compilation of published dates, new geochemical data and 40Ar/39Ar ages, we present new insights into its volcanic evolution. Our study identifies 7 principal geological units (4 were not reported on the previous geologic map) and 8, mostly constructive, volcanic phases. The 40Ar/39Ar dating supports that Hualca Hualca began its formation during the Early Pleistocene (>1.6 Ma) with the establishment of an ancient stratovolcano. This volcano underwent a massive sector collapse to the north that created a U-shaped large amphitheater. This collapse likely resulted in the temporary damming of the Colca River, though no dates or associated deposits have been identified. Subsequent eruptions led to the formation of a smaller volcano along the amphitheater's scar that emplaced andesitic and dacitic lavas. This volcano dubbed modern Hualca Hualca holds the main summit. One of the longest lavas of this edifice reach the Colca valley and was previously dated at 610 ka. Sometime around 550 ka, volcanic activity migrated to the interior of the amphitheater forming the Nevado de Puye, Cruz del Condor, and Ahuashune domes that produced lavas of andesitic and dacitic composition. Around 164 ka a dacitic lava flow was emitted between Nevado del Puye and the base of the modern Hualca Hualca inside the horseshoe crater. The youngest known collapse of the Hualca Hualca complex involved parts of Nevado de Puye dome and the modern Hualca Hualca volcano, emplacing a debris avalanche that again dammed the Colca River and formed an upstream temporary lake that emplaced lacustrine and volcaniclastic deposits. After this collapse, no other volcanic deposit of the Hualca Hualca complex has been identified. Subsequently, glacial erosion during the local Last Glacial Maximum (17–16 ka) modified the volcanic landscape. Geochemical characteristics of Hualca Hualca suggest that their magmas were produced in a metasomatized mantle wedge and likely underwent crustal contamination during their ascent through the thick continental crust.

The mafic–ultramafic roots of a Mesoarchean microblock in southern India: Insights from petrochemistry and isotope geochronology of the Coorg Block

The Coorg Block in southern India is an archive of Paleo-Mesoarchean arc magmatism and continental building in the early Earth. Here we investigate a suite of mafic and ultramafic rocks and associated lithologies to characterize the roots of this microcontinent. We present petrologic, geochemical, as well as U-Pb and Lu-Hf data on zircon and U-Pb data on monazite from these rocks which provide insights into the petrogenesis of the rocks as well as the timings of magmatism and subsequent metamorphism. The geochemical features of the mafic granulites indicate that the rock suite was derived from the fractionation of a sub-alkaline tholeiite magma. Most of the rocks correspond to arc setting in a subduction-related tectonic regime. The rocks exhibit relative enrichment in LILE, Pb, and LREE with depletion in HFSE such as Nb and Ta suggesting partial melting of a metasomatized mantle wedge. Their high LILE/HFSE and LREE/HFSE ratios indicate slab dehydration and mantle wedge melting in typical island arc settings. The overall trace element and REE patterns of the rocks indicate that the source magma of the ultramafic and mafic rocks might have been derived from a refractory mantle source followed by the metasomatic enrichment of lithospheric mantle wedge by incompatible elements through the influx of subduction-derived fluids/melts. We present comprehensive zircon U-Pb data and Lu-Hf data on a suite of mafic granulite, garnet-bearing granulite, tremolite actinolite schist, charnockite, and anorthositic gabbro as well as monazite U-Pb data from a charnockite sample. Most zircon grains show cores with magmatic crystallization features and many grains are mantled by metamorphic rims. The age data show a prominent peak at 3.1 Ga for most of the rocks suggesting that the major crustal building in the Coorg Block occurred during the Mesoarchean. Rocks on the margins of the block were affected by the younger (Neoarchean) tectonothermal event in the surrounding blocks. The Lu-Hf isotopic data on zircon grains with ca. 3.1 Ga ages show εHf(t) values ranging from −4.4 to + 3.7 (average + 0.3). In the εHf(t) versus 207Pb/206Pb age diagram, the plots are distributed close to the CHUR line suggesting Paleo-Eoarchean juvenile magma sources. The voluminous mafic lower crust at the root of the Coorg Block is consistent with addition of mafic magmas through slab melting induced by high mantle potential temperatures in the Archean, as well as the interaction of fluids/melts with the mantle wedge.

Constraints on crustal recycling from boron isotopes in Italian melt inclusions

Boron represents an important tracer of crustal recycling processes in subduction zones, because it is readily mobilised from the subducted lithosphere and different components in the slab are isotopically distinct. Profiles of boron content and isotope ratio across magmatic arcs generally show that B concentrations decrease with increasing slab depth, which implies decreasing amount of slab-derived fluids. To date, however, data on continental-collision zones and post-collisional subduction settings are scarce.This study examines Plio-Quaternary Italian magmatism to quantify crustal recycling in a complex subduction setting. Magmatic products vary from (ultra)potassic along the Tyrrhenian side in the north, to calcalkaline and Na-alkaline in the south.Combined major and trace element and [B] content and δ11B values are reported in 99 Melt Inclusions (MIs), analyses from a wide range of Italian lavas. [B] vary from 4 to 298 µg/g and δ11B from -29.2 to -3.9‰. The B isotopic values are considerably lower than previously reported in arcs and other post-collisional setting magmatism. We infer a role for phengite in the source of all studied Italian magmas (with the exception of Mt. Etna lavas). This white mica is stable to high pressures in subducted sediments of altered oceanic crust and records dehydration and 11B depletion due to dehydration processes.MIs hosted in highly fosteritic olivines (Fo >74; median of 89) from across Italy reveal that primary melts tap heterogeneous mantle including subducted oceanic and continental components that were introduced during the Alpine, and Adriatic and Ionian subduction phases.The combined geochemical data record the involvement of sediments that variably metasomatized the mantle wedge. We propose that slab detachment and consequent heat input from the inflow of hot asthenosphere was responsible for phengite breakdown in subducted sediments and locally produced metasomatism of the mantle wedge, imposing a characteristic B isotope signature to the overlying mantle. Continued heating due to asthenosphere inflow led to melting of the metasomatized mantle wedge and generation of the Italian magmatism. Mt. Etna represents an exception being dominated by asthenosphere upwelling through a slab window with minimal influence from active subduction.

The Geological and Tectonic Evolution of Feni, Papua New Guinea

Feni is located at the southeastern end of the NW-trending Tabar–Lihir–Tanga–Feni (TLTF) volcanic island chain, in northeastern Papua New Guinea. This island chain is renowned for hosting alkaline volcanics, geothermal activity, copper–gold mineralization, and mining. There is no agreed consensus on the tectonic and petrogenetic evolution of Feni. Thus, the purpose of our paper is to present the geology of Feni within the context of the regional tectonic evolution of the TLTF chain and offer a succinct and generic geodynamic model that sets the stage for our next paper. The methodologies used in this study include a critical review of published and unpublished literature in conjunction with our geological observations on Feni. The Pliocene-to-Holocene TLTF chain is a younger arc situated within the greater Eocene-to-Oligocene Melanesian Arc bounded by New Ireland to the west, the Kilinailau Trench and Ontong Java Plateau in the east, and the New Britain Trench to the south. The geological units mapped on Feni include a large volume of basaltic lava flow and trachyandesite stocks intruding a limestone and siltstone basement. Younger units include the trachyte domes, pyroclastic flow, and ash fall deposits. The major structures on Feni are normal or extensional faults such as the Niffin Graben. Feni magmatism is attributed to the petrogenetic processes of polybaric or decompression melting and crystal fractionation of magmas previously influenced by sediment assimilation, mantle wedge metasomatism, slab tears, slab melts, and subduction. Deep lithospheric normal faults provide the fluid pathways for the Feni alkaline magmas.

Triassic magmatism along both sides of the Simao terrane, SE Tibetan Plateau: Implications for the evolution of the Main Palaeo‐Tethyan Ocean and the Ailaoshan Ocean

Subduction and closure of the Palaeo‐Tethyan ocean in the south‐eastern (SE) Tibetan Plateau accounted for the amalgamation of the Indochina Block with the Sibumasu and Yangtze blocks during the Triassic, however, the spatial distribution of the Main Palaeo‐Tethyan ocean and the nature of the Ailaoshan ocean in this region remain controversial. This is partially due to the absence of related magmatic records in the middle‐north segment of the Lancangjiang tectonic belt (LTZ) and consequently, the lack of regional comparison with the Ailaoshan tectonic belt (ATZ). In this contribution, we reported for the first time the presence of subduction‐related Triassic dioritic‐granitic rocks from the Chongshan metamorphic belt (CMB) and the Diancangshan metamorphic belt (DMB) along both sides of the Simao terrane. Zircon U–Pb‐Hf isotopic and whole‐rock geochemical data for these dioritic‐granitic rocks and 135 previously published magmatic rocks in the LTZ, ATZ and the Longmu Co‐Shuanghu suture (LSS) are compared and place important constraints on (1) the spatial distribution of the Palaeo‐Tethyan ocean in this region and (2) the nature of the Ailaoshan Ocean. All these dioritic‐granitic samples from the CMB and DMB yielded Triassic crystallization ages from 225 to 251 Ma, representing late‐stage magmatic records for the Palaeo‐Tethyan evolution in the middle‐north segment of both the LTZ and ATZ in this region. These Triassic dioritic‐granitic rocks in the CMB and DMB share similar geochemical features. Dioritic samples display positive εHf(t) values and relatively high MgO, Cr, Ni contents, moderately differentiated rare earth element (REE) patterns and depletion in Nb‐Ta‐Ti, suggesting their generation from partial melts of metasomatized mantle wedge. Granitic rocks are mostly S‐type with low MgO contents but high K2O/Na2O and A/CNK ratios, mainly generated by regional clastic rocks dominant by juvenile contributions, except for granodiorite samples CS1601 and DC1734‐2, exhibiting identical geological features subduction‐derived hybridized magma from regional clastic sediments and basalts. Our discovery of the Triassic dioritic‐granitic rocks in the CMB stands as the first direct evidence for the Main Palaeo‐Tethyan evolution in the middle‐north segment of the LTZ. This discovery bridges 135 contemporaneous reported magmatic records and supports the spatial distribution of the Main Palaeo‐Tethyan ocean from the LTZ to the LSS. Our Triassic dioritic‐granitic rocks in the CMB and DMB recorded comparable late‐stage evolution involving slab break‐off of the Main Palaeo‐Tethyan ocean and the Ailaoshan Ocean, respectively. Together with previous studies, the Ailaoshan ocean should be a wide oceanic Basin that shares similar time span and evolution processes as the Main Palaeo‐Tethyan ocean.

Petrogenesis of Neoarchean granitoids beneath the Koyna-Warna region, Deccan Volcanic Province, India

• A new find of ca. 2.5 Ga granitoids in the western Dharwar craton. • These I-type clac-alkaline granitoids are bimodal in composition. • Trace element patterns are identical to Archean TTGs. • Precursor magmatic sources evolved in a Neoarchean subduction zone. The continental crust that is concealed beneath the voluminous flood basalt provinces of the Deccan Traps (India) is inaccessible except by few deep bore-holes. The well-core extracted from the deep borehole KBH-8 (> 1000 m) penetrating the massive flood basalt cover provides an exclusive opportunity to examine the Precambrian continental crust in this part of the Indian shield. Here, we present detailed petrology, geochemistry and zircon U-Pb geochronology of the KBH-8 granitoids, which are granodiorite and monzogranites by their normative composition showing a magnesian calc-alkaline metaluminous I-type geochemical affinity. The granitoids are categorically identical to low-and high-HREE TTGs. Their fractionated REE patterns exhibit positive Eu anomaly. Besides the negative Nb and Ti anomalies, they exhibit positive Sr and Zr anomalies. Such attributes are atypical of the granitoids formed from a reworked older (> 3.0 Ga) TTG crust. The geochemistry of these granitoids cannot be reconciled with assimilation and fractional crystallization of the felsic crust in the Dharwar craton. Alternatively, the Ba+Sr enrichments in these granitoids are ascribed to melting of a slab fluid/melt metasomatized mantle wedge. Further, the Sr-Y and La-Yb systematics are consistent with melting of a low-Mg amphibolite source with garnet in the restite. In addition to the above, the variable Gd N /Yb N =1-2.3 ratios and Nb-Zr systematics suggest that the melts were produced from variable depths involving both depleted and undepleted segments of the sub-arc mantle. Consequently, we propose that the KBH-8 granitoids were sourced from a heterogeneous thickened arc-like crust in a Neoarchean subduction zone.

Seismic signals induced by the Metasomatism of mantle wedge by siliceous melts: Insights from the elasticity of orthopyroxene at high pressure and temperature

Large amounts of silica held by slabs during subduction prefer to concentrate into the eclogite melts and further lead to the metasomatism of the overlying mantle wedge. However, the metasomatism process mediated by siliceous melts in the mantle wedge and the seismic signals associated remain poorly constrained. Peridotite in the mantle wedge is sufficiently silica undersaturated. Therefore, SiO2-rich melts would react with olivine in the peridotite to form orthopyroxene (opx). The local enrichment of opx has also been proposed to account for the observed low VP/VS ratio in the mantle wedges of a few subduction zones, revealing the metasomatism by silica saturated melts there. But the anomalously low VP/VS regions in a few subduction zones are inconsistent with the widespread metasomatism of the mantle wedge. In this study, we determined the elasticity of Fe-bearing opx (Mg0.875Fe0.125)SiO3 at high pressure and temperature (P-T) conditions. The VP/VS ratio of opx has a strong dependence on the pressure and temperature conditions, and only exhibits low VP/VS at low pressure and high temperature. Although the enrichment of opx may be widespread, it can only produce a discernible low VP/VS ratio at subduction zones with proper thermal conditions. Together with the elasticities of other major minerals in the upper mantle, we investigated the effect of opx enrichment on VP/VS ratio at mantle wedge conditions. The VP/VS ratio linearly decreases with the opx volume fraction (Ω), and the relationship can be described as VP/VS = 1.772 − 0.142Ω. Combining our high-quality mineral elasticity data with seismic tomography and thermal structure, we constrained the mineral proportions in the northern wedge of the Alaska subduction zone. The opx enriched area coincides well with the anomalously low VP/VS domain, indicating the strong metasomatism by siliceous melts in this mantle wedge.

Growth of early Paleozoic continental crust linked to the Proto-Tethys subduction and continental collision in the East Kunlun Orogen, northern Tibetan Plateau

The East Kunlun Orogen (EKO) in the northern Tibetan Plateau records two continental collisional orogenic events and magmatism in early Paleozoic and early Mesozoic. However, possible magmatic additions to the continental crust growth of the EKO in different tectonic stages of early Paleozoic collisional orogeny have been overlooked. Three phases of early Paleozoic plutons from the Xiangride-Kuhai area in the east of the EKO have been chosen for detailed investigation and the results are reported here. The oldest magmatic suite (Stage 1) includes the ca. 471 Ma Qurelong Monzodiorite and ca. 454 Ma granodiorite in the Zhiyu Intrusive Complex. The monzodiorite has a sanukitoid-like composition with high TiO2 and Y contents and is interpreted as being derived from partial melting of metasomatized mantle wedge lherzolite. The granodiorite is typified by its high SiO2 content, high Sr/Y ratio, and depleted Hf isotope, and is interpreted as an adakite-like melt derived from the melting of a subducted Proto-Tethys oceanic crust. The magmatism can be linked to northward subduction of the Proto-Tethys Ocean between 520 and 450 Ma. Stage 2 magmatism is represented by a plutonic suite emplaced during ca. 450−431 Ma with an I-type granitic composition. Of these, the ca. 447 Ma Kengdenongshe Intrusion composed of peraluminous granite with enriched Nd-Hf isotopes is indicative of a Mesoproterozoic igneous source in the orogen. The ca. 450−434 Ma monzogranite and granodiorite in the Walega and Zhiyu intrusive complexes exhibit variable element and isotope compositions. They would have been generated by magma mixing of felsic melts from the old crust and mafic magmas derived from the metasomatized lithospheric mantle, with a mafic melt proportion of >30%. The ca. 431 Ma quartz diorite in the Walega Intrusive Complex is formed through crustal assimilation and fractional crystallization of mafic magmas derived from the metasomatized lithospheric mantle, with a mafic melt proportion >60%. Stage 2 suite was emplaced during the closure of Proto-Tethys oceanic branches and subsequent continental collision during 450−426 Ma. Magmatism diminished between ca. 426 and 410 Ma during exhumation of the continental lithosphere as indicated by the presence of retrograde eclogites in the EKO. Stage 3 magmatic suite includes the ca. 408 Ma Langmuri Intrusion and ca. 403 Ma Niantang Syenogranite. These plutons are adakite-like or have an A-type granitic composition and are enriched in Nd-Hf isotopes. They might have been derived from the remelting of old and juvenile continental crust in a post-collisional extensional setting during 410−390 Ma. Identification of partial melts, derived from the subducted Proto-Tethys oceanic crust and metasomatized lithospheric mantle in stage 1 and 2 plutons, show that the subcrustal materials have been significantly transferred to the overlying continental crust. Hence the magmatism in oceanic subduction (Stage 1) and continental collision (Stage 2) settings contributes to the early Paleozoic juvenile continental crust growth of the EKO. The post-collisional extensional setting (Stage 3) is dominated by the reworking of a pre-existing continental crust. The early Paleozoic continental crust growth processes in the EKO are different from the previous view in which the continental collision orogens have no crust growth, and inconsistent with the proposal that crust growth is significant only in a continental collision setting.

Sources and oxidation state of the Permian arc magmatic rocks of SW Jilin Province in the eastern Central Asian Orogenic Belt: evidence from Li, Hf isotopes and oxygen fugacity

AbstractThe late Palaeozoic continental-arc magmatic rocks in the Gongzhuling area are located in the Liaoyuan Accretionary Belt. Here we present new zircon U–Pb ages, whole-rock major- and trace-element compositions, Li and zircon Hf isotopic compositions and oxygen fugacity of these rocks with an aim to constrain the lithium isotopic composition of the source region and origin of the magmas. These rocks were formed during 269–258 Ma in middle–late Permian time. The dioritic rocks were formed through mixing processes, with the mafic melts originating from a metasomatized mantle wedge and the felsic melts from the lower crust of a Neoproterozoic arc. The mantle wedge has been metasomatized by Li-rich fluids derived from subducted oceanic crust, as indicated by the δ7Li values of +0.4 ‰ to +3.5 ‰ and positive ϵHf(t) values (+0.7 to +13.1). Redox-sensitive Ce in the zircons indicates the fO2 of the magmas to be low to intermediate (FMQ−2.2 to FMQ+2.6; FMQ is the fayalite–magnetite–quartz redox buffer), precluding large-scale porphyry Cu–Mo mineralization. The middle–late Permian magmatic rocks represent the terminal magmatic record of the subduction of the Palaeo-Asian oceanic crust, meaning that the final closure of the Palaeo-Asian Ocean in the eastern Central Asian Orogenic Belt occurred at the end of the Permian Period. Recent identification of Mesoproterozoic (c. 1400 Ma) granites suggests some Palaeoproterozoic crustal fragments still exist in the Liaoyuan Accretionary Belt, but only in a small amount; therefore, it is concluded that the crustal growth of the Liaoyuan Accretionary Belt occurred mainly during the Neoproterozoic period.

Geochemistry of Khandadharpahar-Thakuranipahar metabasites from the western Singhbhum Craton, eastern India: implications for subduction-zone tectonics and mantle-wedge metasomatism

The identification of new rock types in the volcano-sedimentary sequences of the Singhbhum Craton has attractedmuch attention in recent years. The present study deals on newly identified Nb-Enriched Basalts (NEB) from theKhandadharpahar-Kadakala-Thakuranipahar (KKT) section, western Singhbhum Craton, which is comparablein composition to basalts-basaltic andesites and calk-alkaline in character. These metabasites have a porphyritictexture with phenocrysts of pyroxene and plagioclase, as well as a groundmass that has metamorphosed to thegreenschist facies. High Nb contents (7.5-22.8ppm) combined with high (Nb/Th)PM (0.28-0.59), (Nb/La)PM (0.40-0.69) and Nb/U (11.7-34.4) ratios, compared to arc basalts ((Nb/Th)PM= 0.10-1.19; (Nb/La)PMn 0.17-0.99, Nb/U<10), characterized them as NEB. Negative Nb, Zr, Hf and Ti anomalies, and Nb/Th vs La/Nb and Th/Nb vs. La/Sm relationships, collectively indicate typical arc volcanics. The available geochemical parameters suggest a genesisof KKT metabasites through i) slab melt migration from the downgoing oceanic crust, ii) low-degree melting ofthe garnet-bearing peridotite in the mantle wedge metasomatized by the slab melts, iii) slab melt - peridotiteinteraction triggering increasing Nb concentrations and iv) NEB generation in an arc-related environment. Thediscovery of KKT NEB sheds new information on Paleoproterozoic subduction-zone processes and crustal growthin the Singhbhum craton.

High- and low-Mg adakitic rocks in southern Tibet: Implication for the crustal thickening and geodynamic process in the late Cretaceous

The history of crustal thickening is critical for comprehending the evolution process of the Tibetan plateau. The genetic relationship and spatiotemporal distribution of adakitic rocks with high Sr/Y, (La/Yb) N ratios may impose fundamental constraints on specific geodynamic and crustal thickening processes. The Songka intrusive suite consists of adakitic rocks with high-Mg adakite (monzonites), low-Mg adakitic rocks (quartz monzonites), and gabbroic-diorites. Their geochemical characteristics, petrogenesis, and geodynamic implication is discussed in this paper. Songka high-Mg adakites formed when subducting Neo-Tethyan oceanic slab melts were assimilated by mantle peridotite at elevated temperatures (average Ti-in-zircon temperatures of sample SK1319 are 830 °C). Low-Mg adakitic rocks exhibit markedly different geochemical characteristics than those formed in the juvenile thickened lower crust. The least-squares mass balance and trace element simulations indicate that Songka low-Mg adakitic samples were formed at a degree of 60–65% fractional crystallization of melts resembling Songka high-Mg adakites. Songka gabbroic diorites are formed in the metasomatic mantle wedge. The genetic relationship between these rocks indicates that the crust of the southern Tibet did not appear to thicken obviously during the early stage of late Cretaceous (100–90 Ma). The intensive emplacement of late Cretaceous high-Mg adakites (Mg # > 50) and mafic rocks (SiO 2 < 52%) in the southern Lhasa terrane around 95–90 Ma, together with the slow convergence velocity of the Indian-Asian continent, can be explained by the response of rapid crustal thickening and Neo-Tethyan slab rollback at 95–90 Ma. • High-Mg adakitic rocks were formed from partial melting of Neo-Tethyan slab. • Coeval low-Mg adakitic rocks were produced by fractional crystallization. • Rapid crustal growth and Neo-Tethyan slab rollback occurred at 95–90 Ma.

Melt generation and trace element fractionation of intermediate arc magma from Andaman subduction zone

The submarine volcanoes, located in the southern part of Andaman Sea, north eastern Indian Ocean, result from the subduction of the Indo-Australian Plate beneath the Southeast Asian Plate and represent one of the less studied submarine volcanism among the global arc systems. The present study provides new petrological and geochemical data for the recovered rocks from the submarine volcanoes and documents the petrogenetic evolution of Andaman arc system. Geochemical attributes classify the studied samples as basaltic andesite, andesite, dacite to rhyodacite reflecting sub-alkaline, intermediate to acidic composition of the magma. Petrographic studies of the basaltic andesites and andesites show plagioclase [An38-An57 in basaltic andesites; An27-An28 in andesites] and clinopyroxene as dominant phenocrystal phase in a cryptocrystalline groundmass. Plagioclase (An25-An45) marks the principal phenocrystal phase in dacite with sub-ordinate proportion of biotite and amphibole of both primary and secondary origin along with minor amount of K-feldspar. The submarine volcanic rocks from Andaman arc system exhibit pronounced LILE, LREE enrichments and HFSE (negative Nb, Ta and Ti anomalies), MREE and HREE depletion thereby endorsing the influence of subduction zone processes in their genesis. Elevated abundances of Th with relatively higher LREE/HFSE than LILE/HFSE, LILE/LREE suggest significant contribution of sediments from the subducting slab over slab-dehydrated aqueous fluids towards mantle wedge metasomatism thereby modifying the sub-arc mantle. Partial melting curves calculated using the non-modal batch melting equation suggest primary magma generated due to ~31–35 % degree of partial melting of spinel lherzolite mantle beneath the arc system. Fractional crystallization model suggests fractionation of 45 % plagioclase, 40 % clinopyroxene, 5–10 % amphibole and 5–10 % biotite which is consistent with the petrographic observations. Further, the assimilation-fractional-crystallization (AFC) model for the studied rocks indicates nominal crustal contamination. Therefore, this study infers that the melt evolution history for the Andaman arc volcanic rocks can be translated in terms of (i) generation of precursor magma by ~31–35 % partial melting of a spinel lherzolite mantle wedge, metasomatized predominantly by subducted slab sediments and (ii) the parent magma generation was ensued by fractionation dominated melt differentiation with nominal input from arc crust.

Tectonic transition from the Paleo-Asian Ocean to the Paleo-Pacific Ocean in central Jilin (NE China): Constraints from the early Mesozoic high-Mg andesites

The Jilin–Yanji Suture is situated at the convergent margin between the North China Craton and Jiamusi-Khanka Massif, playing as a key hinge to link up the tectonic transition from the Paleo-Asian Ocean to the Paleo-Pacific Ocean. However, many parameters of this suture, e.g. the timing of its emplacement, tectonic setting and precise location remain controversial. For addressing these issues, we focused on the high-Mg andesites within the Seluohe Group which is a typical subduction-related volcanic association along the Jilin–Yanji Suture. Seven chlorite schist and six andesite samples were collected for petrological, geochemical and geochronological analyses. The geochemical results indicate the protoliths of chlorite schists and the andesite samples are high-Mg andesites, and their magma source was produced by the metasomatized mantle wedge by subducted slab-derived fluids in a continental island arc setting. Eight high-Mg andesites give the crystallization ages of 249 ± 3 Ma–246 ± 4 Ma, with a weighted mean age of 247 ± 1 Ma (MSWD = 0.27) yielded by 69 youngest zircons, indicative of an Early Triassic age. Based on our new results and the field investigation, we propose that the Seluohe Group is a set of Early Triassic volcanic-sedimentary association with continental island arc affinity related to the south-westward subduction of the Heilongjiang Ocean, rather than a Mesoproterozoic sequence or Late Permian accretionary complex as previously considered. Integrated with previous studies on the regional tectonic evolution, we suggest the Jilin-Yanji Suture belongs to the southern extension of the Jilin-Heilongjiang high-pressure metamorphic belt, which records the final collision between the Jiamusi-Khanka Massif and North China Craton during the Triassic caused by the subduction of the Paleo-Pacific Ocean, and the Late Permian-Late Triassic is a key period of tectonic transition from the Paleo-Asian Ocean to the Paleo-Pacific Ocean in the eastern edge of Eurasia.

Paleo-Mesoproterozoic magmatic-sedimentary events in eastern Bainaimiao micro-block: Implications for Precambrian tectonic evolution of a fragment from Columbia supercontinent

Identifying tectonic positions and origins of Precambrian micro-blocks within the Central Asian Orogenic Belt (CAOB) is essential for revealing global paleogeography and evolution of the early Earth. The Bainaimiao micro-block in the southeastern CAOB preserves multistage geologic records which can better reveal Precambrian tectonic history of micro-blocks within the Phanerozoic accretionary orogenic belt. This study presents integrated research of geochronology, geochemistry, and zircon Hf isotopes on the Chenjiatun metamorphic complex in the eastern Bainaimiao micro-block, which consists of meta-sedimentary rocks (plagioclase gneisses and mica schists), amphibolites and two-mica granites. The protoliths of amphibolites, two-mica granites and meta-sedimentary rocks were formed at 1.75 Ga, 1.38 Ga and 1.39–1.34 Ga, respectively, suggesting that they represent Paleo-Mesoproterozoic basement of the Bainaimiao micro-block. The detrital zircon age spectra of meta-sedimentary rocks show two representative age peaks at 1.80 Ga and 1.40 Ga, with zircon Hf isotopes varying from −11.11 to +10.67. Characteristic mostly positive zircon Hf isotopes and geochemical features of the Chenjiatun complex indicates that the Bainaimiao micro-block probably has tectonic affinity with the Laurentia-Baltica continent. Paleoproterozoic amphibolites with positive εHf(t) (+5.67 to +15.42) were derived from metasomatized mantle wedge mixed with sediment melts. They are characterized by arc-like geochemistry such as high Th/Yb (0.73–2.77), enrichment in LILEs and depletion in HFSEs (eg. Nb and Ta), similar to coeval arc magmatism in the Laurentia-Baltica continent, which indicate the Bainaimiao micro-block was possibly in a subduction convergent setting in the late Paleoproterozoic. By contrast, Mesoproterozoic two-mica granites, with mostly positive εHf(t) (−0.29 to +11.53), belong to typical S-type granites and could be generated from partial melting of meta-pelites with participation peritectic garnets. These two-mica granites, together with ∼1.40 Ga juvenile A-type grantioids from nearby and other Precambrian micro-blocks in the southern CAOB, exhibit relatively high alkalis and HFSEs contents, young Hf model ages (1.50–1.40 Ga) and were generated at high-temperature environment. These findings reveals that the Bainaimiao micro-block was in an extensional setting at 1.40 Ga coeval with the breakup evolution of the Columbia supercontinent.

Magmatic response to arc-arc amalgamation: Insights from latest Paleozoic igneous rocks from the Gangou section of the Eastern Tianshan

Multiple arc systems were developed in response to Neoproterozoic to Mesozoic consumption of the Paleo-Asian Ocean and their magmatic evolution is crucial for understanding the arc-arc amalgamation in the Central Asian Orogenic Belt. Here, we report whole-rock geochemical data as well as simultaneous in situ zircon U-Pb and Lu-Hf isotope results for the late Paleozoic magmatic rocks associated with the shear zones in the Gangou section of the Eastern Tianshan to constrain their petrogenesis and arc-arc amalgamation processes. We obtained ∼307 Ma and ∼270 Ma zircon U-Pb ages for the Late Carboniferous diorites and Middle Permian andesites, respectively. These rocks have high Mg# (∼65 and ∼47, respectively) values, and are enriched in large ion lithophile elements (LILEs) and depleted in high field strength elements (HFSEs), with depleted zircon εHf(t) values (+12.1 to +18.1), suggesting an origin from partial melting of the depleted mantle with various degree of differentiation. Furthermore, our results also provided ∼276 Ma zircon U-Pb ages for the Middle Permian granitic porphyries and ∼256 Ma zircon U-Pb ages for the Late Permian diabase rocks. The granitic porphyries are geochemically similar to A2-type granites, i.e., high K2O + Na2O, FeOT/MgO, Ga/Al and low CaO, Sr and Ba. They have high zircon εHf(t) (+9.0 to +13.7) values, indicating a possible derivation from juvenile lower crust. The diabase rocks show depletion of light rare earth elements (LREEs), resembling normal mid-ocean ridge basalt. These rocks have depleted zircon Hf isotopic compositions (εHf(t) = +8.9 to +15.8), demonstrating a possible derivation from partial melting of the depleted mantle. The available geochemical data from the Eastern Tianshan show that the Permian mafic rocks along the shear zones possess higher Nb/La and lower Ba/La ratios than their counterparts in the Carboniferous. These contrasting features imply that the Carboniferous mafic rocks originated from a metasomatic mantle wedge, while the Permian mafic rocks were likely derived from the depleted mantle with addition of enriched asthenosphere components. The high zircon saturation temperatures (mostly > 800 °C) of the Permian A-type granitoids and diverse magma sources of coeval mafic rocks also imply possible asthenosphere upwelling. Therefore, we propose that the Late Carboniferous magmatic rocks were likely resulted from subduction of the North Tianshan oceanic plate, while the spatial and temporal evolution of the Permian magmatic rocks were probably attributed to large-scale dextral transcurrent tectonics associated with arc-arc amalgamation.

Subduction initiation of the western Paleo-Asian Ocean linked to global tectonic reorganization: Insights from Cambrian island-arc magmatism within the West Junggar, NW China

Abstract The subduction initiation associated with the beginning of accretionary orogens has been thought to be related to global plate reorganization. To characterize the initial subduction within the western Central Asian Orogenic Belt, this integrated study focuses on Cambrian tholeiitic to calc-alkaline plutons in the Barleik-Mayile-Saleinuohai area of West Junggar, NW China. Zircon U-Pb results of felsic plutons reveal a wide range (511–488 Ma) of ages with older ages up to 514–511 Ma. The felsic rocks exhibit variable SiO2 (53.0–77.4 wt%) and K2O (0.05– 2.24 wt%) contents and can be classified as diorite, granodiorite, trondhjemite, and tonalite. On the basis of their low TiO2 (0.12– 0.71 wt%) contents and characteristic trace element trends as well as high zircon εHf(t) (+10.5 to +14.5) and mantle-like zircon δ18O (5.0 ± 0.48‰ to 5.4 ± 0.43‰, two standard deviations) values, we interpret that the Cambrian felsic rocks have diverse origins, involving differentiation of arc basalts and partial melting of subducted oceanic crust, arc mafic crust, and metasomatized mantle wedge. The Saleinuohai gabbroic pluton shows zircon δ18O ratios from 4.2 to 4.7‰, which are lower than those of igneous zircons in equilibrium with mantle and thus reflect modification of their mantle source by hydrothermal fluids with seawater-like oxygen isotopes at high temperature. Combined with regional data, we propose that the West Junggar arc represents the extending of the Boshchekul-Chingiz arc in the Early Cambrian, defining a long (&amp;gt;1000 km) E-W–trending subduction zone. The earliest island-arc tholeiitic felsic plutons in the West Junggar took place at ca. 514–511 Ma, which, coupled with other early subduction records (e.g., 530 Ma SSZ-type Kopu-relisay ophiolites) in the western Paleo-Asian Ocean, indicates that initial stages of subduction of the western Paleo-Asian Ocean probably occurred in the Early Cambrian. The simultaneity between the initial subduction of the western Paleo-Asian Ocean, Gondwana assembly, and Laurasia breakup suggests a causal link between the three, collectively correlated to a global plate adjustment event.