Mantle Reservoirs Research Articles

Trace element and Sr-Nd-Hf-Pb isotope evidence for a multi-magma chamber system beneath the Deccan Volcanic Province, India

With a size of over 500,000 km2, the Deccan Volcanic Province (DVP) covers a large area of the Indian subcontinent. Stratigraphically continuous lava flows piled up to 3000 m record about five million years of volcanic activity. The peak activity of one million years coincides with the migration of the Indian subcontinent across the Réunion plume. Previous studies inferred an isotopic “common signature” for most DVP basalts that is best explained by a mixture of early Réunion plume-related melts and melts from the depleted upper mantle. Further chemical variability of the DVP sequence was explained by the incorporation of material from the lithospheric mantle and continental crust possibly within a single magma chamber system. Yet, indications for a complex crustal magmatic system have also been brought forward by earlier studies and find recently more support in explaining the magmatic plumbing system of the DVP and Large Igneous Provinces in general.This study presents new major and trace element data, including high-precision concentration measurements of high-field strength elements by isotope dilution and Sr-Nd-Hf-Pb isotope compositions for basaltic samples that cover nearly the complete DVP main section. Based on significant variations in Nb/Th (and Th/Ta) over a wide range of MgO concentrations we identified three distinct magma differentiation trends. The distinct differentiation trends result from three types of parental melts that are best explained by different proportions of lower and upper mantle melts indicated by diluted Réunion plume-like trace element and isotope compositions. During their ascent, these separate melts assimilated variable amounts of metasomatized lithospheric mantle and crustal material. Most likely the assimilation occurred before any major differentiation events, thus fixing the Nb/Th (and Th/Ta) of each group regardless of the degree of differentiation. The chemical trends can also be replicated using a statistical numerical approach, confirming that their geochemical signature truly reflects individual differentiation of three distinct parental melts. Field relations require that lavas related to these three unique differentiation trends erupted contemporaneously. This is in contrast to the idea of a gradually evolving single magma chamber system and the concept of a general chemostratigraphy for the DVP main plateau. Rather, our study reveals fast-changing contributions of different mantle reservoirs and provides new insight into the magma-plumbing systems of Large Igneous Provinces that may be more complex.

Decoupling of short-lived radiogenic and helium isotopes in the Marquesas hotspot

The short-lived radiogenic 182Hf/182W (t½ = 9 Ma) and 146Sm/142Nd (t½ = 103 Ma) systems are useful tools to investigate differentiation processes in Earth's early history. Mantle reservoirs that have been preserved over long geological timescales could carry signatures formed early on in Earth's history and later could act as sources to modern mantle plumes. Negative μ182W anomalies in combination with high 3He/4He ratios have been detected globally as differently sloping negative trends in plume-derived ocean island basalts (OIB) from individual hotspots. Large low shear velocity provinces (LLSVP) and ultra-low velocity zones (ULVZ) are seismically anomalous regions in the lower mantle that have been suggested as sources of primordial mantle components near the core-mantle boundary (CMB) and accessed by deep-rooted mantle plumes.In this work, seven samples from the islands Hiva Oa and Fatu Hiva of the Marquesas Archipelago, showing a range in 3He/4He ratios, have been investigated motivated by its location above the Pacific LLSVP and a recently discovered “mega-ULVZ”. Despite elevated 3He/4He ratios of up to 14.4 R/RA, new high precision measurements using thermal ionization mass spectrometry revealed non-anomalous μ182W (−0.9 ± 4.9 ppm) and μ142Nd (1.3 ± 2.4 ppm, 95% confidence interval (c.i.)). These mark the Marquesas Archipelago as the first hotspot to show a decoupling of 3He/4He ratios and μ182W in OIB. A mixing model between an elevated 3He/4He-negative-μ182W and an EM2 or a HIMU endmember suggest that the addition of recycled material is not responsible for this decoupling. Instead, like many previously studied OIB, the Marquesas plume is most likely dominated by an LLSVP component proposed to contain high 3He/4He ratios and μ182W of 0. The unique observed absence of negative μ182W anomalies, on the other hand, implies a lack of involvement of the ULVZ source in the plume's melting region, despite the hotspot being located above a recently discovered mega-ULVZ. This may imply that the expression of ancient mantle domains in hotspot geochemistry is temporally variable, thus, delaying the arrival or involvement of ULVZ material in the origin of the Marquesas OIB.

Slab dehydration and potassium-lithium recycling in the forearc indicated by potassium and lithium isotope compositions of exhumed metabasites

Slab dehydration at subduction zones has broad implications for arc magmatism, mantle heterogeneity and elemental cycling. We present the petrography, mineral chemistry and whole-rock potassium (K) and lithium (Li) isotopic compositions of subducted metabasites exhumed from serpentinite mud volcanoes from the Mariana forearc that were recovered during International Ocean Discovery Program Expedition 366, to evaluate the capability of K and Li isotopes for tracking slab dehydration and the evolution of the slab-derived fluids at shallow subduction zones. The results show that the δ41K values of HIMU-type alkali metabasites recovered from the shallow-sourced site (i.e., Fantangisña, −0.34 ± 0.06‰, 2SD, n = 3) are slightly higher than those from the deep-sourced site (i.e., Asùt Tesoru, −0.42 ± 0.20‰, 2SD, n = 8). In addition, all the HIMU-type metabasites have homogeneous radiogenic isotope compositions (e.g., Sr, Nd and Hf), and the clinopyroxenes therein show similar trace elements patterns, indicating they have a common mantle source. These observations together with the positive correlation between δ41K and δ11B suggest that K isotope fractionation most likely resulted from metamorphic dehydration. In contrast, no such correlation was observed for Li isotopes (δ7Li ranging from +3.7‰ to +6.6‰). The Li isotope compositions can be modeled by low-temperature fluid/rock interactions with varying water/rock ratios, implying that the Li isotopic system was mainly controlled by fluid metasomatism within the subduction channel. Notably, EM-II-type metabasites have the lightest K isotope compositions (−0.72‰ to −0.67‰) and heaviest Li isotope compositions (+8.1‰ to +8.3‰) in this study. These anomalous signatures were accompanied with the lowest Nb/Th, εNd(t) and εHf(t), indicating that the K and Li isotope data of EM-II-type metabasites were indicative of their mantle source (e.g., EM-II mantle reservoir). Rayleigh fractionation modeling illustrates that the deeply subducted metabasites are characterized by high K and Li concentrations, and low δ41K, but MORB-like δ7Li. Thus, they may transfer large amounts of fluid-mobile elements into the deep mantle that contributes to the K isotopic heterogeneity in the mantle.

Cryptic trans-lithospheric fault systems at the western margin of South America: implications for the formation and localization of gold-rich deposit superclusters

We present a review of frontier research advances in the investigation of cryptic structures that transect the South American Andes at oblique strike directions. The intersections between these cryptic structures and the superimposed Andean belt correlate with the spatial distribution of gold-rich mineral deposit clusters. The deposit clusters can be described as superclusters, as they comprise various gold deposit types that formed at multiple times throughout the Phanerozoic, impinging repeatedly on the structural intersections. However, the cryptic inherited fault structures are difficult to detect, because their deeper-seated roots are often overlain by younger supracrustal successions, and/or their exposed surface manifestations are structurally obscured by subsequent tectonic-magmatic activity. Thus, it also remains a challenge to constrain the nature and timing of formation, and the respective subsequent evolutionary path, of these proposed pre-Andean structures. Based on various case studies, we demonstrate that the localization of identified Phanerozoic gold deposit superclusters along the western South American margin is fundamentally controlled by structural inheritance often dating back to at least the Mesoproterozoic. Integration of multi-approach observations and datasets allows insights into a larger-scale tectonic history that showcases the successive inheritance of major structures originating from the Amazonian Craton, over the Paleozoic Gondwana margin, into the Cenozoic magmatic belts of the Andes, and even into recent fractures within the subducting oceanic Nazca plate, recording >1.2-billion-years of progressive structural inheritance and growth at one of the longest-lived tectonic margins in Earth history. In contrast to previous models of the spatial distribution of gold deposits, based on statistical approaches and spatial periodicity in self-organized systems focusing on single subduction and/or accretion episodes and belts, we propose that the structural inheritance and intersections are key to the localization of gold deposits in the Andes. In combination with bulk-geochemical data from magmatic rocks, we suggest that inherited structures maintained a trans-lithospheric connectivity to pre-fertilized gold enriched upper mantle reservoirs, which were tapped during multiple tectono-magmatic reactivation episodes.

Carbonate-rich crust subduction drives the deep carbon and chlorine cycles.

The flux balances of carbon and chlorine between subduction into the deep mantle and volcanic emissions into the atmosphere are crucial for the habitability of our planet1,2. However, pervasive loss of fluids from subducting slabs has been thought to cut off the delivery of both carbon and chlorine to the deep mantle owing to their high mobility under hydrous conditions3,4. Our new high-pressure experiments show that most carbonates (>75 wt%) in carbonate-rich crustal rocks-one of the main subducting carbon reservoirs-survive devolatilization and hydrous melting in cold and warm subduction zones, indicating that their subduction has driven the deep carbon cycle since the Mesoproterozoic. We found that KCl and NaCl, respectively, become stable phases crystallizing from hydrous carbonatite melts with low chlorine solubility in warm and hot subduction zones, resulting in the sequestration of chlorine in the solid residue in downwelling slabs. Accordingly, the subduction of carbonate-rich rocks facilitated highly effective recycling of both chlorine and carbon into the deep mantle at intermediate stages of Earth's history and led to declining atmospheric pCO2 and the formation of carbon-rich and chlorine-rich mantle reservoirs since the Mesoproterozoic. This period of optimal carbon and chlorine subduction may explain the ages of eclogitic diamonds and the formation of the HIMU mantle source.

Petrology and mineralogy of the martian olivine gabbroic shergottite Northwest Africa 13581: Insights into the enriched martian mantle source

Gabbroic and microgabbroic shergottites are intrusive igneous rocks on Mars and exhibit a wide variety of mineralogical and geochemical properties. However, their source reservoirs, magmatic processes and the link to other shergottite subtypes are not well constrained. Northwest Africa (NWA) 13581 is a newly found permafic olivine gabbro, representing a cumulate member in the shergottite group. This sample provides new critical constraints on the characteristics of mantle sources and magmatic evolution of shergottites. The texture and mineral chemistry of NWA 13581 indicate a polybaric crystallization condition, with an increase in oxygen fugacity of approximately 1 log unit after ascent and emplacement. Geochemical studies suggest that the sample is young (150 ± 25 Ma) and may share a similar enriched mantle reservoir (initial ε176Hfi = −18.4, initial ε143Ndi = −7.1) with shergottites like Zagami (basaltic shergottite), NWA 10169 (poikilitic shergottite) and Larkman Nunatak 06319 (olivine-phyric shergottite). In addition, the presence of potassium-rich melt inclusions enclosed in early-formed minerals of NWA 13581 implies a fertile source, probably originating from a metasomatized mantle. The occurrence of similar potassium-rich components in other enriched shergottites may suggest a common process in their mantle reservoir and during crystallization. Overall, NWA 13581 resembles poikilitic shergottites closer than typical gabbroic shergottites in several aspects such as poikilitic texture, mineral chemistry, magmatic evolutionary path, and emplacement conditions. A simplified model is proposed for the formation of NWA 13581 and poikilitic shergottites in the same magma series. Magma mixing and/or assimilation are not the major mechanism that account for their slightly varied mineral modal abundances and quantitative textural characteristics. For samples derived from similar mantle sources, the textural and mineralogical diversities of shergottites are largely related to crystallization at different crustal levels.

I/Pu reveals Earth mainly accreted from volatile-poor differentiated planetesimals.

The observation that mid-ocean ridge basalts had ~3× higher iodine/plutonium ratios (inferred from xenon isotopes) compared to ocean island basalts holds critical insights into Earth's accretion. Understanding whether this difference stems from core formation alone or heterogeneous accretion is, however, hindered by the unknown geochemical behavior of plutonium during core formation. Here, we use first-principles molecular dynamics to quantify the metal-silicate partition coefficients of iodine and plutonium during core formation and find that both iodine and plutonium partly partition into metal liquid. Using multistage core formation modeling, we show that core formation alone is unlikely to explain the iodine/plutonium difference between mantle reservoirs. Instead, our results reveal a heterogeneous accretion history, whereby predominant accretion of volatile-poor differentiated planetesimals was followed by a secondary phase of accretion of volatile-rich undifferentiated meteorites. This implies that Earth inherited part of its volatiles, including its water, from late accretion of chondrites, with a notable carbonaceous chondrite contribution.

Isotopic Composition for Helium in Late Cenozoic South-Baikal and South-Khangai Volcanic Areas

The paper considers isotopic composition of helium (3Не/4Не = R) in groundwater of South-Baikal (SBVA) and South-Khangai volcanic areas (SKhVA) during the Late Cenozoic period. The differences in the behavior and magnitude of the parameters were established. It is found that the mentioned differences in 3Не/4Не concentrations within South-Baikal and South-Khangai volcanic areas correspond to mantle reservoirs with different helium isotope compositions. This confirms that the Late Cenozoic volcanism of South-Baikal and South-Khangai volcanic area is controlled by mantle sources related to mantle plumes of the Central-Asian hot mantle field.

The Paleoarchean Buffalo River komatiites: Progressive melting of a single large mantle plume beneath the growing Kaapvaal craton

Several Archean granitoid-greenstone terranes are exposed on the southeastern Kaapvaal craton in South Africa, but they received little scientific attention compared to the archetypal greenstone belt successions of the Barberton Mountain Land at the eastern craton margin. This study reports on a detailed field and geochemical survey of the Buffalo River Greenstone Belt at the southern Kaapvaal craton margin in KwaZulu-Natal, with focus on hitherto unstudied komatiites and basaltic rocks from this volcanic succession. Cross-cutting relationships and new U-Pb zircon age determinations for several granitoid units establish a minimum age of 3.26 Ga for komatiitic volcanism, possibly as old as ca. 3.5 Ga if a 3.47 Ga granodiorite sheet is interpreted as ‘intrusive’ into the greenstone succession.Geochemical data reveal three types of Paleoarchean komatiites at Buffalo River. Spinifex textured lava flows represent Al-depleted komatiites, with subchondritic Al2O3/TiO2 ratios and enrichment of LREE over HREE. The second type comprises Al-undepleted komatiites that have chondritic Al2O3/TiO2 and flat REE patterns. The third type identified comprises Al-enriched komatiites that display suprachondritic Al2O3/TiO2 ratios, with significant LREE depletion. The Al-depleted and Al-undepleted komatiites from Buffalo River are geochemically similar to komatiites from the 3.48 Ga Komati and 3.26 Ga Weltevreden formations of the Barberton Supergroup respectively, whereas the Al-enriched komatiites resemble the 3.33 Ga Commondale komatiites on the southeastern Kaapvaal craton.To explain the co-occurrence of three discrete komatiite types within a single volcanic succession at Buffalo River, we suggest that each major komatiite magmatic pulse originated from the same upwelling mantle source, from which melt was extracted at different pressure but similarly hot temperature conditions. 187Os/188Os data for the Al-depleted komatiites suggest an ultimate magma origin from a primitive mantle reservoir. The contrasting γOs values for Kaapvaal craton komatiites (zero to positive) and peridotitic mantle xenoliths (zero to negative) support a complementary nature of these lithologies as high-degree melts and depleted residues linked by vigorous mantle plume activity at around 3.5 Ga. Such a relationship can explain the contrasting Re/Os systematics of komatiites and lithospheric mantle peridotites, which creates the contrasting γOs over time.The highly siderophile element patterns of the Al-depleted komatiites from Buffalo River are similar to those of Barberton-type komatiites, for which an origin from the deepest upper mantle with high melt retention in an upwelling plume source was suggested. We confirm that this ca. 3.5 Ga mantle source had only 60–80 % of the platinum-group element budget of the modern ambient mantle, which points indirectly to a location at great depth in the aftermath of the meteoritic late accretion. Progressive melting of such an upwelling mantle source, to the point of majoritic garnet exhaustion, may explain the Al-undepleted and Al-enriched komatiites at Buffalo River. The presence of all three major komatiite types within a single volcanic succession may be linked to deep critical melting of a large mantle plume associated with growth of the Kaapvaal ‘continent’ at 3.5 Ga.

Supporting information for the paper entitled "Identification of Miocene olivine leucitites in southern Tibet: Implication for the presence of hidden carbonated mantle reservoir"

Supporting information for the paper entitled "Identification of Miocene olivine leucitites in southern Tibet: Implication for the presence of hidden carbonated mantle reservoir"

Eoarchean-Paleoarchean crustal material in the southern North China Craton and possible mantle reservoir of early Earth

The depleted mantle and the continental crust are largely geochemically and isotopically complementary. However, the question of when the depleted mantle reservoirs developed on Earth remains a topic of considerable debate. In this study, we report the existence of a ca. 3.8 Ga detrital zircon from the quartzite of the Paleoproterozoic Songshan Group in the southern North China Craton. In situ zircon hafnium isotopic characteristics of the 3.8–3.2 Ga detrital zircons indicate the presence of source rocks as old as ca. 4.5 Ga in the southern North China Craton. Together with the global zircon U-Pb-Hf isotope dataset from the North China Craton, Jack Hills, Acasta as well as available μ142Nd values of ancient rocks from Archean craton worldwide, the new results indicate that the silicate Earth has differentiated at 4.4–4.5 Ga almost immediately after accretion, developing continental crust and a complementary depleted mantle reservoir at that same time.

Reworking of aged mafic crust in a Palaeoarchaean layered complex inferred from coupled Sm-Nd and Lu-Hf isotope systematics, Stolzburg Complex, Barberton Greenstone Belt, South Africa

The Stolzburg Complex is a prominent and well-preserved Palaeo- to Mesoarchaean layered ultramafic-mafic complex in the vicinity of the Barberton Greenstone Belt. Whole rock Sm-Nd, Lu-Hf and 142Nd isotopic data obtained from a variety of lithologies, and augmented by major and trace element geochemistry, are presented to examine petrogenesis, magma source composition, and mantle differentiation as well as the geodynamic setting of emplacement. Geochemically, all samples are characterized by unfractionated normalized trace element patterns (La/Luchond. = 0.7–2.3, La/Gdchond. = 0.6–1.7, Sm/Luchond. = 0.9–1.4) associated with weak HFSE anomalies (Nb/[0.5Th + 0.5La]PRIMA = 0.5–2.3). Trace element concentrations vary as a function of mineralogy, but differences in trace element compositions are unsystematic across lithologies. The coherence of trace element characteristics is consistent with a common mantle source that underwent moderately large degrees of melting at mantle pressures within the spinel stability field. Whole rock Sm-Nd and Lu-Hf data yield well-defined apparent isochrons corresponding to ages of 3367 ± 62 (n = 12, MSWD = 1.5) and 3396 ± 36 (n = 11, MSWD = 2.1), respectively. Initial Hf and Nd isotopic compositions vary from +3.3 to +5.7 and + 0.9 to +1.7, respectively, indicative of derivation from slightly to moderately depleted mantle source(s). Isochron ages and a regressed initial Hf isotopic composition of +4.0 ± 0.9 (at 3.4 Ga) contrast with an established U-Pb emplacement age (zircon, titanite) of 3.25 Ga and εHf values for zircon of −2.5 to +3.0. Hydrothermal alteration or weathering, incorporation of evolved pre-existing (continental) crust and fractionation by high-pressure phases prior to melt extraction can all be ruled out to have significantly affected isotope systematics. Protracted magma chamber activity and non-synchronous emplacement of unrelated gabbroic magmas also fail to fully account for the discrepancy between whole rock and mineral age and isotopic data. Instead, the coherence in apparent isochron ages and variability of initial Hf and Nd isotopic composition is adequately explained by reworking (partial or near-complete remelting) of aged mafic-ultramafic (likely oceanic) crust in staging chambers with compositions indistinguishable from newly formed magmas. Thus, apparent isochrons represent mixing lines and do not record timing of crystallization. A subset of samples was also analyzed for 142Nd isotopic compositions to trace preserved mantle heterogeneities caused by early Archaean crust-mantle differentiation. The results (μ142Nd = −2.3 ± 2.2 to +1.7 ± 2.1) are not resolvable from the modern mantle value, indicating that 142Nd-enriched or depleted mantle reservoirs had not remained isolated from convective homogenization in the asthenosphere, or the volume of mantle underlying the layered complex was too small to sample mantle heterogeneities. The Stolzburg Complex was possibly emplaced in ancient oceanic lithosphere, followed by pervasive but inhomogeneous Ca-metasomatism as documented by exposed rodingites.

Evolution of the preserved European continental crust, constrained by U-Pb, O and Hf isotopic analyses of river detrital zircons

Integrated U-Pb, O and Lu-Hf isotopic analyses of detrital zircons, collected from fourteen European river sands and one beach sand from northern Germany, were carried out to study the evolution of the preserved European continental crust. The drainage area of these sand samples covers large areas in eastern and western Europe, which evolved independently until their amalgamation during the Paleozoic. U-Pb ages of detrital zircons from eastern and western Europe generally match the ages of the major magmatic events in the two tectonic regions. The combined histogram of 2403 zircon U-Pb ages, obtained for this study, shows five major periods of zircon crystallisation: 2.80–2.65, 1.95–1.35, 1.25–0.85, 0.65–0.40, and 0.40–0.25 Ga, which correspond broadly with the timing of supercontinent assembly. The correlation could be due to enhanced granitoid magmatism and zircon growth during the supercontinent amalgamation, or the high preservation potential of igneous rocks generated during continental collisions. The O and Hf isotopic data of the analysed European river zircons show wide spreads in δ18O and εHf(t) values at ca. 1.9 Ga and 650–250 Ma, contrasting with the limited range for the Mesoproterozoic zircons. This indicates that extensive reworking of pre-existing crustal rocks occurred during the late Paleoproterozoic and Paleozoic in the evolution of the European continental crust, whereas the formation of new crust played an important role during the Mesoproterozoic.Arc mantle Hf model ages for the detrital zircons were calculated to estimate when European juvenile crust was extracted from the mantle. Model age uncertainties were estimated using the bootstrap method, considering three sources of uncertainty: (i) uncertainty in the Hf isotopic composition of the mantle reservoir, (ii) uncertainty in the 176Lu/177Hf for the crustal source region, and (iii) analytical uncertainties. Two types of model ages are calculated based on constant crustal 176Lu/177Hf (TAMC), and on variable176Lu/177Hf (TAMV), the latter being constrained by zircon δ18O values. Histograms of the calculated TAMC and TAMV model ages both show major juvenile extraction events between the late Paleo- and Mesoproterozoic. Although the principal periods in the European crustal growth contrast with those identified in the African, Russian and Mississippi river basins, the overall growth curves for the four continents show comparable results: (i) the formation of little or no continental crust before 4.0 Ga, and (ii) the formation of 50 % of the present crustal volume by ca. 2.0–1.6 Ga.

Tectonomagmatic evolution of southwestern Laurentia: Insights from zircon U-Pb geochronology and hafnium isotopic composition of the Red Bluff Granite Suite, west Texas, USA

AbstractWe provide laser ablation–multicollector–inductively coupled plasma–mass spectrometry (LA-MC-ICP-MS) and high-precision chemical abrasion–isotope dilution–thermal ionization mass spectrometry (CA-ID-TIMS) U-Pb ages and Hf isotopic compositions of zircons from the Red Bluff Granite Suite and mafic dikes in the Franklin Mountains of El Paso, Texas, USA. Granitoids exposed in the Franklin Mountains were previously divided into five magmatic stages based on cross-cutting relationships. Major and trace element compositions showed that these granitoids are ferroan, alkaline, and A2 type. Homogeneity in the whole-rock geochemistry suggests that the granite stages are genetically related and share similar petrogenetic histories. Weighted mean zircon 206Pb/238U dates from the older magmatic stage 1 alkali-feldspar quartz syenite and stage 2 alkali-feldspar granite are 1112.36 ± 0.35 and 1112.46 ± 0.37 Ma, respectively. The weighted mean εHf(t) values varying from +5.3 to +7.2 are similar to those of other regional ca. 1.1 Ga magmatic rocks throughout southwestern Laurentia. Geochemical characteristics, petrological modeling, and enriched Hf isotopic composition suggest fractional crystallization of a basaltic magma that was produced by melting of an enriched mantle reservoir. However, zircon inheritance ages of ca. 1.3 Ga and 1.26–1.15 Ga are consistent with a minor contribution from felsic crustal basement. Our data and regional geology are consistent with a post-collisional slab break-off that facilitated asthenospheric upwelling and partial melting of the enriched mantle, possibly subcontinental lithospheric mantle, extending from Llano Uplift, Texas, in the southeast to California to the northwest. Magma thus generated upon differentiation produced ferroan and A-type granitoids.

Mantle mineralogy limits to rocky planet water inventories

ABSTRACT Nominally anhydrous minerals in rocky planet mantles can sequester multiple Earth-oceans’ worth of water. Mantle water storage capacities therefore provide an important constraint on planet water inventories. Here we predict silicate mantle water capacities from the thermodynamically-limited solubility of water in their constituent minerals. We report the variability of upper mantle and bulk mantle water capacities due to (i) host star refractory element abundances that set mantle mineralogy, (ii) realistic mantle temperature scenarios, and (iii) planet mass. We find that transition zone minerals almost unfailingly dominate the water capacity of the mantle for planets of up to ∼1.5 Earth masses, possibly creating a bottleneck to deep water transport, although the transition zone water capacity discontinuity is less pronounced at lower Mg/Si. The pressure of the ringwoodite-perovskite phase boundary defining the lower mantle is roughly constant, so the contribution of the upper mantle reservoir becomes less important for larger planets. If perovskite and postperovskite are relatively dry, then increasingly massive rocky planets would have increasingly smaller fractional interior water capacities. In practice, our results represent initial water concentration profiles in planetary mantles where their primordial magma oceans are water-saturated. This work is a step towards understanding planetary deep water cycling, thermal evolution as mediated by rheology and melting, and the frequency of ocean planets.

Long-term core–mantle interaction explains W-He isotope heterogeneities

The isotopic characteristics of ocean island basalts have long been used to infer the nature of their source and the long-term evolution of the Earth's mantle. Anticorrelation between tungsten and helium isotopic signatures is a particularly puzzling feature in those basalts, which no single process appears to explain. Traditionally, the high 3He/4He signature has been attributed to an undegassed reservoir in the deep mantle. Additional processes needed to obtain low 182W/184W often entail unobserved ancillary geochemical effects. It has been suggested, however, that the core feeds the lower mantle with primordial helium, obviating the need for an undegassed mantle reservoir. Independently, the tungsten-rich core has been suggested to impart the plume source with anomalous tungsten isotope signatures. We advance the idea that isotopic diffusion may simultaneously transport both tungsten and helium across the core-mantle boundary, with the striking implication that diffusion can naturally account for the observed isotopic trend. By modeling the long-term isotopic evolution of mantle domains, we demonstrate that this mechanism can account for more than sufficient isotopic ratios in plume-source material, which, after dynamical transport to the Earth's surface, are consistent with the present-day mantle W-He isotopic heterogeneities. No undegassed mantle reservoir is required, bearing significance on early Earth conditions such as the extent of magma oceans.

Rapid characterisation of Mars' mantle reservoirs by in situ laser ablation 87Sr/86Sr analysis of shocked feldspar (maskelynite)

The 87Sr/86Sr isotopic properties of martian meteorites, measured by isolation and purification of Rb and Sr fractions, have long been used to partially characterise Mars' mantle. However, this method is time-consuming, destructive, and subject to incorporation of terrestrial contamination due to precipitation of phases in fractures and/or grain boundaries prior to meteorite collection. In this study, we test the effectiveness of in situ acquisition of 87Sr/86Sr by laser ablation in maskelynite - a typically low Rb/Sr (<0.1) feldspar-composition glass formed during high-P shock metamorphism – as a method of rapid characterisation of Mars' mantle Sr isotope ratios. Element concentration maps and the results of unwashed and gently surface-leached bulk rock analyses indicate that terrestrial Sr has infiltrated the studied meteorites and affected bulk rock trace element budgets. However, maskelynite trace element concentrations are largely unaffected and their martian igneous Rb/Sr is preserved. In situ87Sr/86Sr analyses of maskelynite, checked against a newly developed Sr feldspar reference material (KAN, presented here and available on demand), accurately and precisely distinguish different shergottite mantle reservoirs. The measurements reproduce published data, have uncertainties on the 4th to 5th decimal place, and yield statistically indistinguishable results in analytical sessions separated by long periods of time. The data from 11 enriched shergottites reveal there to be subtle Sr isotope variation within the enriched shergottite mantle reservoir, or that there was crustal assimilation of radiogenic components into the shergottites, or that the shergottite liquids were extracted over a time period during which the mantle reservoir 87Sr/86Sr evolved. The limited published age range of the enriched shergottites, coupled with the absence of a correlation between in situ87Sr/86Sr and REE, Sr or Pb concentration in maskelynite, suggests that the isotope range is best explained by small variations in the enriched mantle reservoir. Given the presence of maskelynite (or plagioclase) in many meteorites, the in situ method will be useful when there are only very small volumes of material available and/or where terrestrial contamination is suspected.

Paleoproterozoic Layered Intrusions of the Monchegorsk Ore District: Geochemistry and U–Pb, Sm–Nd, Re–Os Isotope Analysis

The paper concerns the geochemical analysis of rocks from the ore-bearing layered intrusions that belong to two age groups of the Monchepluton and the Imandra–Umbarechka Complex (2.50 and 2.44 Ga) and the largest gabbro-anorthosite of the Main Ridge Complex (2.51–2.45 Ga). The intrusion of these complexes happened at different depths when the endogenous and geodynamic settings changed at the beginning of the Paleoproterozoic Era. Five megacycles are distinguished in a generalized cross-section of the two-chamber Monchepluton. The megacycles differ in rock composition, rock geochemical features, and mineralization types, i.e., the chromite, sulfide Cu–Ni–PGE and low-sulfide PGE types. The abrupt changes in isotope indicators (εNd, 87Sr/86Sr) mark their boundaries. At a depth of 2037–2383 m, the M-1 borehole intersects a standalone intrusive body that is essentially a magma feeder channel. The intrusive body’s geochemical characteristics and U–Pb isotope age correlate to the Monchepluton rocks. The gabbro-anorthosite massifs united in the Main Ridge Complex were intruded in the following order: the Monchetundra, Chunatundra, Volchetundra, and Losevo–Medvezhye tundras. The largest Monchetundra massif was formed as a result of multiple intrusions of mafic magmatic melt from the deep reservoirs. The melts intruded in two stages, i.e., 2.51–2.49 Ga and 2.48–2.47 Ga, and their composition changed gradually. The gabbro-pegmatites and coeval harrisite dykes are more recent ones (2.46–2.45 Ga). The summarized results of the U–Pb, Sm–Nd, and Re–Os systems research allowed us to establish genetic relations between the studied geological objects. We proposed a model where there was an uplift of a mantle plume to the lower crust area at the age of 2.5 Ga, the deep mantle reservoirs were formed, and a large-scale interaction happened between the parental magma and granulite–eclogite complex rocks. Local contamination and assimilation processes took place during the uplifting of magmas in areas where the magmatic feeding system contacted the host amphibolite–gneiss Archean complexes.

Temporal Evolution of the Swell and Magmatic Fluxes Along the Louisville Hotspot Chain

AbstractHawaii and Louisville are the two long‐lived hotspot chains in the Pacific basin. Characterizing the swell flux, Qs, a measure of the plume buoyancy, and the flux of the magmatic material accumulated along the chain, Qm, brings important constraints on the plumes' temporal evolution and on their interaction with the lithosphere. Numerous studies focus on the temporal evolution of the Hawaiian chain, but no study investigates the temporal evolution along the Louisville chain. In the present study we constrain the temporal evolution of the swell and magmatism fluxes along the Louisville chain, from volcano ages and bathymetry data. The overall Louisville magmatism flux appears nearly constant, that is, Louisville plume activity has exhibited remarkably little variation over the past 30 m.y., in agreement with geochemical data. These results are also in agreement with recent studies along Hawaii, which show that the Qm increase is due to plume migration toward a more fertile mantle reservoir. This means that, in general, long term variations in Qm relate to variations in the deep source of the plume. Along Louisville, we find short‐term variations occurring with a periodicity of ∼5–10 m.y. in both Qm and Qs, similar to the short‐term variations observed along Hawaii by former studies. As these variations occur along hotspot chains associated with either a heterogenous or homogeneous chemical signature, they must be created by shallow phenomena. The tilt of the plume conduit by large‐scale mantle advection is our preferred model, as it can account for both the geophysical and geochemical observations.

Abrolhos Magmatic Province petrogenesis and its link with the Vitória-Trindade Ridge, Southeast Brazilian Margin, South Atlantic Ocean

The Abrolhos Magmatic Province (AMP) is an example of an igneous province with about 63,000 km2 located at the Continent-Ocean Boundary (COB), into the Southeast Brazilian Margin. The AMP emerges as five small islands (Santa Bárbara, Redonda, Siriba, Sueste, and Guarita) which integrate the Abrolhos Archipelago located about 55 km offshore Brazil. The studied rocks belong to a transitional basalt series of alkaline affinity, with evolved rocks with high TiO2 contents. This work presents new detailed fieldwork mapping, petrographic, and whole-rock chemistry data, besides Sr–Nd isotopic compositions from AMP rocks. Mapped magmatic rocks in the Abrolhos Islands have been described as extrusive rocks, but we point out that they are shallow intrusions, mostly sills, and should be grouped into diabase units based on fieldwork and textural features. The AMP lithogeochemical and isotopic data suggest the operation of differentiation processes more complex than simple fractional crystallization or AFC. Our model mixing calculations based on new and compiled Sr-Nd-Pb isotopic data suggest a mixture with a prevailing depleted asthenosphere mantle source (represented by DMM; ca. 80%) metasomatized by an enriched mantle I (EMI) component (≤ 10%) and a possible HIMU-type constituent (up to 10%) in the AMP genesis. The assimilation of subducted slabs of the oceanic crust associated with the HIMU signatures is possibly linked to the Brasiliano Event due to the range of the AMP Nd TDM model ages, from 407 to 767 Ma. A viable mechanism for the EMI end-member contribution could either be a physical detachment of the South American subcontinental lithospheric mantle during the breakup of the Gondwana or lithospheric delamination of the South American plate caused by an edge-driven convection mechanism. The AMP and the Vitória-Trindade Ridge (VTR) show an eastward decreasing age pattern from the older ca. 60 Ma Abrolhos Province to the younger Martin Vaz and Trindade Islands (ca. 4 – 0.1 Ma), located ca. 1200 km away from the Brazilian coastline. The volcanic alignment between the VTR and AMP, along with the overlap of geochemical and isotopic data of their different igneous rocks, cannot be a random feature but instead represent the sampling of similar shallow mantle reservoirs, thus suggesting a cogenetic relationship. Finally, a possible petrogenetic link between the AMP and VTR magmatism is discussed.