Mantle Origin Research Articles

Development of a complex arc–back-arc basin system within the South Tianshan Ocean: Insights from the Wuwamen ophiolitic peridotites

Ophiolites within the South Tianshan orogenic belt directly record the nature and tectonic evolution of the South Tianshan Ocean (STO), which is key for understanding the accretionary history of the Central Asian Orogenic Belt. Here we present petrological and Os isotopic data for the Wuwamen mantle peridotites from the South Tianshan orogenic belt, which provide new insights into the tectonic origin of this ophiolite and evolution of the STO. The lherzolites have low spinel Cr# (0.1–0.2), similar to those of fertile oceanic or continental peridotites that have undergone low degrees of melting. However, the extremely high Na2O (1.5–1.8 wt%) and Al2O3 (5.5–6.2 wt%) contents of the clinopyroxenes are atypical of oceanic peridotites, and resemble those of subcontinental peridotites. The harzburgites have more refractory compositions, suggesting higher degrees of melt extraction. Both the lherzolites and harzburgites have low initial 187Os/188Os ratios (< 0.121), which reflect Proterozoic melt depletion and a long-term lithospheric evolution. These data confirm an ancient subcontinental lithospheric mantle origin for the Wuwamen peridotites. The replacive dunites have moderate spinel Cr# (0.3–0.4), reduced Os and enriched 187Os/188Os (0.142–0.160), indicative of reaction between host lherzolites and percolating mid-ocean ridge basalt (MORB)-type melts with radiogenic Os isotopic signatures, presumably in a subduction-related setting. This and the associated back-arc basin basalt (BABB)–type mafic crust suggest the Wuwamen ophiolite formed in a continental margin back-arc setting. A comparison with other ophiolites in the South Tianshan orogenic belt further indicates that a complex arc–back-arc system existed along the southern margin of the Central Tianshan, which was associated with northward subduction within the STO.

Crustal Derivation of theca. 475 Ma Eppawala Carbonatites in Sri Lanka

AbstractAlthough a mantle origin of carbonatites has long been advocated, a few carbonatite bodies with crustal fingerprints have been identified. The Eppawala carbonatites in Sri Lanka are more similar to orogenic carbonatites than those formed in stable cratons and within plate rifts. They occur within the Pan-African orogenic belt and have a formation age of ca. 475 Ma newly obtained in this study with no contemporary mantle-related magmatism. These carbonatites have higher (87Sr/86Sr)i ratios (0·70479–0·70524) and more enriched Nd and Hf isotopic compositions than carbonatites reported in other parts of the world. Model ages (1·3–2·0 Ga) of both Nd and Hf isotopes [apatite ɛNd(t) = −9·2 to −4·7; rutile εHf(t) = −22·0 to −8·02] are in the age range of metamorphic basement in Sri Lanka, and the carbon and oxygen isotopic compositions (δ13CPDB = −2·36 to −1·71; δ18OSMOW = 13·91–15·13) lie between those of mantle-derived carbonatites and marble. These crustal signatures are compatible with the chemistry of accessory minerals in the carbonatites, such as Ni-free olivine and Al- and Cr-poor rutile. Modeling results demonstrate that the Eppawala carbonatite magmas originated from a mixture of basement gneisses and marbles, probably during regional metamorphism. This interpretation is supported by the occurrence of the carbonatites along, or near, the axes of synforms and antiforms where granitic gneiss and marble are exposed. Therefore, we propose that the Eppawala carbonatites constitute another rare example of a carbonatitic magma that was derived from melting of a sedimentary carbonate protolith. Our findings suggest that other orogenic carbonatites with similar features should be re-examined to re-evaluate their origin.

Origin of spinel-hosted mineral inclusions in mantle peridotite from Setogawa in the Circum-Izu Massif Serpentine Belt, central Japan: Implications for the chromitite genesis

Plagioclase-impregnated mantle harzburgites from Setogawa area in the Circum-Izu Massif Serpentine Belt (of Miocene in age), central Japan, contain chromian spinel (chromite) grains that have minute globular inclusions composed of micas, amphiboles and pyroxenes. They are similar in texture and chemistry to those in chromitites as well as in some plutonic rocks, such as dunites and troctolites, form the Moho transition zone (MTZ). The Setogawa harzburgite host is similar in petrography and geochemistry to the MTZ harzburgite from the Oman ophiolite, and is possibly a low-pressure restite after melt-assisted partial melting or reaction with a percolating magma. The orthopyroxene-melt reaction, which is essentially responsible for producing those rocks from the peridotite (harzburgite), can precipitate chromian spinel as well as generate chemically heterogeneous melts along decomposing orthopyroxenes. The spinel-hosted melt inclusions in podiform chromitites are most frequently trapped at the reaction front between the spinel-oversaturated, spinel-loaden magma and mantle orthopyroxene (=harzburgite). The spinel-loaden magma had been produced via the same reaction at lower levels and moved upward. The spinel quickly overgrows to include chemically heterogenous melt drops, some of which are high in Cr/Al ratio and precipitate high-Cr spinel via reaction with the wall spinel. The chemical character (Cr/Al ratio) of podiform chromitites would be determined by the accumulative contribution from the melt derived from orthopyroxene decomposition during the passage of the melt through the upper mantle. We can speculate that the chromian spinel grains containing similar melt inclusions from the stratiform chromitite are transported as xenocrysts of mantle origin. The parental magma for layered intrusions possibly reacted with the peridotite when it passed through the mantle before arriving at a crustal magma chamber, showing a possible genetic linkage between the podiform and stratiform chromitites.

Rutile and zircon age and geochemistry in the evolution of the juvenile São Gabriel Terrane early in the Brasiliano Orogeny

Major issues in the tectonic evolution of continents include oceanic crust generation, the subduction of oceanic island arcs and their accretion to a craton. The understanding of geological events in the Neoproterozoic of South America and Gondwana is a challenge due to tectonic disturbance caused by the Brasiliano Orogeny. We selected key units in the South Atlantic Brasiliano Orogen to solve problems related to dating and environment of metamorphism, magmatism and metasomatism. Multiproxy methodology included aerogammaspectrometry in the Cambaizinho and Palma ophiolites. Rutile and zircon U–Pb geochronology combined with Lu-Hf-trace element analyses were conducted on metagabbro and chloritite. The aerogammaspectrometric survey delimitated the extent of ophiolite bodies. Rutile U–Pb dating in the Cambaizinho metagabbro provided a metamorphic age of 706 ± 11 Ma. Zircon U–Pb dating in the São Luís metagabbro yielded an age of 731.6 ± 0.5 Ma for the magmatic activity; chloritite yielded an 889.2 ± 2.3 Ma age for metasomatism. Zircon Hf analyses display positive εHf(t) values (metagabbro = +7.1 to +11.1; chloritite = +9.9 to +17.5). REE element diagrams show positive Ce anomalies for both metagabbro and chloritite zircons. Positive εHf(t) in zircon from metagabbro and chloritite indicates depleted mantle origin. Trace element contents of zircon (e.g., U, Yb) from the metagabbro are consistent with magma generation by partial melting of older juvenile crust; data from chloritite indicate a N-MORB magma source. We infer that the final phase of collision and thrusting of the São Gabriel arc over the Rio de La Plata Craton occurred at 706 Ma; the São Gabriel island arc had main activity at 731 Ma; mid-ocean ridge metasomatism in the ophiolite occurred at 889 Ma. Our studies provide evidence of geotectonic processes during Rodinia break-up and early Brasiliano orogeny and similar juvenile Tonian terrains within Gondwana.

Sulphur isotopes (δ34S and Δ33S) in sulphides from cratonic mantle eclogites: A glimpse of volatile cycling in ancient subduction zones

Multiple sulphur isotopic compositions of sulphides from Kaapvaal craton mantle eclogites allow to elucidate the recycling of sulphur into the deep Earth and to differentiate between recycled crust and mantle origins of eclogite-hosted sulphides, including the precious metals that they capture. We present multiple sulphur isotope ratio measurements by secondary ion mass spectrometry for sulphides from a collection of mantle-derived eclogite xenoliths from Proterozoic and Mesozoic kimberlite occurrences in South Africa (Premier, Roberts Victor, Jagersfontein). Previous work established that the host eclogites have elemental and oxygen isotopic compositions in support of seawater-altered oceanic lithosphere protoliths, and for many of these xenolith suites Archean ages have been suggested.The eclogite-hosted sulphides have δ34S values from −5.7 to +29‰, with the upper end of this wide range representing the highest-ever recorded δ34S composition of material derived from the Earth's mantle. The Δ33S values range from −0.29 to +0.18‰ and do not record significant mass-independent sulphur isotope fractionation, i.e., there is no compelling S-MIF signature. Most of the sulphide grains have δ34S values that fall within a range between −6 and +4‰, and they probably retain an isotopic record of sulphides that formed originally within altered oceanic crust. In contrast, the highly positive δ34S values from +13 to +29‰ detected in sulphide grains from a single eclogite xenolith are similar to those of marine sulphates, which were probably a minor sulphur component of the oceanic crustal protolith. The lack of a significant S-MIF signature in the eclogitic sulphides that show δ34S evidence for a recycled crust origin implies that this sulphur component stems from a <2.4Ga post-Archean surficial reservoir. This finding suggests that the cratonic mantle eclogites may have formed from post-Archean oceanic crust (e.g., Paleoproterozoic eclogite protoliths), or – as is preferred here – the ‘surficial’ sulphur was introduced into the cratonic root during relatively young metasomatic events and is thus unrelated to eclogite petrogenesis and Archean continent formation.

Lithium distribution and isotopic composition in zircon megacrysts as constraints for their mantle origin and volcanic transfer timescales

Lithium in zircon has attracted considerable attention for identifying magma sources and as a diffusion chronometer, despite the exact diffusion mechanisms remaining controversial. Zircon megacrysts sourced from Quaternary intraplate basaltic volcanoes in the Ratanakiri Volcanic Province of northeastern Cambodia were analyzed here for Li isotopic and elemental concentration profiles to constrain diffusion behavior of Li in zircon megacrysts entrained in high temperature melts. This is complemented by high-spatial resolution U-Pb geochronology, O-Hf isotope compositions and trace element abundances to refine the long-term pre-eruptive history of these zircon megacrysts. Ratanakiri zircon megacrysts yield a Tera–Wasserburg regression U-Pb age of 0.98 ± 0.02 Ma (n = 615 spot analyses) that is indistinguishable from eruption ages reported for the host basalts, although zircon was unstable in the enclosing magma as evidenced by marginal corrosion and abundant tubular channels within the crystals. Extreme Li-isotopic variations (within −30 to +96‰ on the δ7LiLSVEC scale) of the zircon megacrysts require kinetic Li fractionation due to diffusive mobilization, which is further supported by offsets in intracrystalline domain boundaries with different Li and Y abundances detected in scanning ion images. Complex abundance and isotopic ratio patterns for Li in zircon megacrysts point to multi-mode Li diffusion that is influenced by variable trace element inventories within individual crystals, which correlate with minor differences in the O-Hf isotopic compositions. The overall tendency of decreasing Li abundances along with increasing δ7Li values toward crystal rims indicates diffusion-driven equilibration between zircon and Li-depleted basaltic melt. Diffusion modeling of Li and δ7Li on domain-boundaries within crystals show pre-eruptive heating timescales of about 18 days, which is consistent with the magma transfer duration estimated from zircon megacryst settling rate calculations, implying the zircon megacrysts should be transported from their source region to the surface by ascending alkali basaltic magma within few weeks. Nearly one to two orders of magnitude longer Li diffusion model timescales were computed for crystal rim domains. This apparent faster diffusion of Li is attributed to H+ loss into a volatile phase during eruption, providing an additional driving force for Li+ diffusion, which might become more pronounced at the crystal boundary where zircon is exposed to strong chemical gradients in volatile elements due to decompression and concomitant degassing. Lithium isotope compositions for the innermost domains of zircon megacrysts are relatively heavy with δ7Li values of +12 to +22‰. These values are considered to be less influenced by Li-loss after entrainment by the host basalts than rim compositions. These values in combination with O (δ18O = +3.5 to +5.3‰) and Hf (εHf(0.98 Ma) = +6.5 to +7.9) isotopic compositions as well as inclusions and internal structures suggest that zircon megacrysts were originally derived from partial melting of a metasomatized lithospheric mantle source altered by fluid released from dissolved carbonates during subduction. Lithium isotopes in Ratanakiri zircon megacrysts provide novel insights into using Li isotopes as a tool to constrain the durations of magma transfer from the mantle to the surface, although Li diffusion mechanisms in zircon need to be further scrutinized.

Origins and pathways of deeply derived carbon and fluids observed in hot spring waters from non-active volcanic fields, western Kumamoto, Japan

Natural springs containing volcanic and magmatic components occur in association with these activities. However, features of deeply originated fluids and solutes were less documented from fields, where active volcanic and magmatic activities are not distributed. To characterize the presence of deep components and identify their major pathways 28 groundwater samples (~ 1230 m deep) were collected from hot spring sites located at western coast of Kumamoto, southwestern Japan, where the typical subduction related magmatisms are absent. The samples were measured for dissolved ion concentrations and stable isotope ratios (δ2HH2O, δ18OH2O, δ13CDIC and δ34SSO4) that were compared with data of 33 water samples from vicinity surface systems. The groundwaters were classified into three types based on major hydrochemistry: high Cl− fluid, low concentration fluid, and high HCO3− fluid. Our data set suggests that the high Cl− fluid was formed by saline water mixing with aquifer waters of meteoric origin and subsequently evolved by reverse cation exchange. The low concentration fluid is identical to regional aquifer water of meteoric origin that was subjected to cation exchange. The high HCO3− fluid showed the highest HCO3− concentrations (~ 3,888 mg/l) with the highest δ13CDIC (up to − 1.9‰). Based on our carbon mixing model and observed δ2HH2O and δ18OH2O shifts, it is suggested that dissolved carbon of mantle origin and small fraction of fluids generated in deep crust were transported towards surface through structural weakness under open tectonic setting. These deeply derived components were then mixed with waters in the surface systems and diluted. Their impacts on surface hydrological systems were limited in space except few locations, where deeply connected pathways are anticipated along active structural deformations.

Insights from Fumarole Gas Geochemistry on the Recent Volcanic Unrest of Pico do Fogo, Cape Verde

We report the results of the geochemical monitoring of the fumarolic discharges at the Pico do Fogo volcano in Cape Verde from 2007 to 2016. During this period Pico do Fogo experienced a volcanic eruption (November 23, 2014) that lasted 77 days, from a new vent ∼2.5 km from the fumaroles. Two fumaroles were sampled, a low (F1∼100°C) and a medium (F2∼300°C) temperature. The variations observed in the δ18O and δ2H in F1 and F2 suggest different fluid source contributions and/or fractionation processes. Although no significant changes were observed in the outlet fumarole temperatures, two clear increases were observed in the vapor fraction of fumarolic discharges during the periods November 2008–2010 and 2013–2014. Also, two sharp peaks were observed in CO2/CH4ratios at both fumaroles, in November 2008 and November 2013. This confirms that gases with a strong magmatic component rose towards the surface within the Pico do Fogo system during 2008 and 2013. Further, F2 showed two CO2/Stotalpeaks, the first in late 2010 and the second after eruption onset, suggesting the occurrence of magmatic pulses into the volcanic system. Time series of He/CO2, H2/CO2and CO/CO2ratios are low in 2008–2009, and high in 2013–2014 period, supporting the hypothesis of fluid input from a deeper magmatic source. Regarding to the isotopic composition, increases in air-corrected3He/4He ratios are observed in both fumaroles; F1 showed a peak in 2010 from a minimum in 2009 during the first magmatic reactivation onset and another in late 2013, while F2 displayed a slower rise to its maximum in late 2013. The suite of geochemical species analyzed have considerably different reactivities, hence these integrated geochemical time-series can be used to detect the timing of magmatic arrivals to the base of the system, and importantly, indicate the typical time lags between gas release periods at depth and their arrival at the surface. The high3He/4He ratios in both fumaroles in the range observed for mid-ocean ridge basalts, indicating that He is predominantly of upper mantle origin. This work supports that monitoring of the chemical and isotopic composition of the fumaroles of the Pico do Fogo volcano is a very important tool to understand the processes that take place in the magmatic-hydrothermal system and to be able to predict future episodes of volcanic unrest and to mitigate volcanic risk.

Identifying deep recycled carbonates through Miocene basalts in the Maguan area, SE Tibetan Plateau

Cenozoic mantle-derived magmas are widespread on the Tibetan Plateau, and provide evidence for the evolution of deep mantle and its influence on the Plateau development. Miocene basalts in the Maguan area on the southeastern Plateau have high MgO (9.13–13.10 wt%) and Mg# (0.60–0.70) with high Ce/Pb (10.6–32.5) and Nb/U (43.7–52.9) ratios, similar to those of oceanic basalts. Distinct from Eocene-Oligocene mantle-derived potassic magmas in Western Yunnan and Cenozoic basic volcanic rocks in Tengchong, these Maguan basalts are characterized by high large ion lithophile elements (LILEs) concentrations, positive anomaly in high field strength elements (HFSEs) and depleted SrNd isotopes, consistent with the melt of an asthenospheric mantle origin. The high Ce/Pb and Nb/Y (1.80–2.68) ratios together with low Ba/Y and Ba/Th ratios indicate a significant input of slab-derived melt into the asthenospheric source. Besides, Hf/Hf* and Ti/Ti* ratios are significantly lower than those of ocean island basalt (OIB), which are proportional to the lighter δ26Mg (-0.6‰ to -0.4‰) values. Based on the results of experimental petrology, the SrMg isotope mixing model suggests that the asthenospheric mantle beneath the Maguan area had undergone the significant metasomatism of recycled carbonates prior to the late Miocene. The above petrological and geochemical understanding, together with the geophysical data, allows us to propose that the mantle metasomatism is most probably associated with the Neo-Tethys seafloor subduction, which is further testified by the decoupling between depleted SrNd isotopes and elevated LILE concentrations.

High explosivity of the June 21, 2019 eruption of Raikoke volcano (Central Kuril Islands); mineralogical and petrological constraints on the pyroclastic materials

The small volcanic islands of the central Greater Kuril Chain (GKC) produce strong explosive eruptions, two of which occurred in the recent years. The latest eruption took place at Raikoke volcano, which occurred on June 21–25 (2019) and was one of the largest on the Kuril Islands in the 21st century. This study presents mineralogical, petrographic and geochemical data on the air fall ash and pyroclastic density current deposits to elucidate the causes of high explosivity of this eruption.The magma involved in the Raikoke volcanic eruption is likely to have had a mantle origin and basaltic composition. Prior to forming a near-surface reservoir, the magma fractionated (i.e. due to crystallization of olivine and pyroxene) at depths of about 26 km, which is close to the Moho discontinuity in the middle part of GKC. The presence of amphibole among the 2019 pyroclastic minerals indicates that the magma contained significant (i.e. no less than 4 wt%) amounts of water at depth. This magma was degassed prior to intrusion into a shallower reservoir. The magma in the shallow reservoir had high crystallinity and contained viscous felsic residual melts, which prevented the development of effusive eruptions or Strombolian explosions. It is likely that magmatic fluid bubbles were still present, but their abundance was insufficient for lava fragmentation in the conduit. This led to low degree of vesiculation of the erupting melts. The results of this study demonstrate that the explosivity of the eruption is most likely related to the interaction in the volcanic edifice between meteoric waters and the magma, which was largely degassed and contained significant amounts of crystals and felsic melt (i.e. had high viscosity and low mobility).

Paleoclimate Signals and Groundwater Age Distributions From 39 Public Water Works in the Netherlands; Insights From Noble Gases and Carbon, Hydrogen and Oxygen Isotope Tracers

AbstractKnowing the age distribution of water abstracted from public water supply wells helps to ensure customer trust in drinking water sources and underpin predictions of water quality evolution. We sampled the mixed water of 39 large public supply well fields for major ion chemistry, 3H, 3He, 18O, 2H, 14CDIC, 13CDIC and noble gases and determined the Noble Gas Temperature (NGT). We used a discrete travel time distribution model to quantify the age distributions using 3H, 4He, 14C apparent age and NGT as the 4 distinctive tracers. Helium‐4 and NGT provided information on the older part of the age distributions and showed that the 14C apparent ages are often the result of mixing of waters ranging between 2,000 and 35,000 years old, instead of being discrete ages with a limited variance as previously assumed. The results reveal a large range of age distributions, comprising vulnerable well fields with &gt;60% young water (&lt;100 years) and well fields with &gt;30% paleo groundwater (&gt;25,000 years) and all forms of intermediate distributions. The age distributions match the hydrogeological setting; well fields with age distributions skewed towards older ages appear in the Roer Valley Graben structure, where fluvial and marine aquitards and sealed faults provide protection from recent recharge. Waters from this graben exhibit paleoclimate signals, with a clear relation between NGT (range 3.2–9.3 °C), 4He (up to 3.3 × 10−6 ccSTP/g) and δ18O (range −8.5‰ to −5.9‰VSMOW). Moreover, 3He/4He ratios of these graben waters suggest a certain influx of He from mantle origin.

Contemporaneous opening of the Alpine Tethys in the Eastern and Western Alps: constraints from a Late Jurassic gabbro intrusion age in the Glockner Nappe, Tauern Window, Austria

Metabasic rocks of the ophiolitic sequences of the Glockner Nappe and Eclogite Zone in the south-central Tauern Window, Austria, reveal important insights into rifting and spreading of the Alpine Tethys. U–Pb dating of magmatic zircons yields a concordant 157 ± 2 Ma crystallization age for the precursor of a coarse-grained metagabbro from the Glockner Nappe. The Late Jurassic intrusion age is coeval with mafic plutonic activity in the Western and Central Alps. Although Penninic ophiolitic sequences in tectonic windows of the Eastern Alps are usually disrupted, an ocean–continent transition setting can be reconstructed for the Glockner Nappe, similar to many ophiolites in the Liguria–Piemont domain in the Western and Central Alps. Together, these observations strongly suggest a formation in the Liguria–Piemont branch of the Alpine Tethys and are inconsistent with a formation in the Valais domain. This finding has important implications for paleogeographic reconstructions of the Penninic realm in the Eastern Alps. Whereas the Glockner Nappe metagabbro and metabasalts clearly reveal their depleted mantle origin, the metabasic rocks of the Eclogite Zone record a more complex formation history involving depleted mantle melting and crustal assimilation in a continental margin setting.

Final–Stage Southward Subduction of the Eastern Paleo–Asian Ocean: Evidence from the Middle Permian Mafic Intrusions in the Northern Margin of the North China Craton

The northern margin of the North China Craton (NCC) contains widespread Permian magmatic rocks, but the origin of these rocks remains controversial. This uncertainty hampers us from better understanding of tectonic framework and evolution of the eastern Paleo-Asian Ocean, particularly with respect to its final-stage subduction and closure time. To address these questions, this study presents petrological, zircon U-Pb geochronological, whole-rock geochemical and in situ zircon Hf isotopic data for these Permian mafic intrusions in the northern margin of the NCC. Precise zircon U-Pb dating results indicate that these mafic intrusions were emplaced in the Middle Permian (ca. 260 Ma). Geochemically, the studied mafic intrusions have high MgO and transition metals element contents, with high Mg# values, indicating a mantle origin. These mafic intrusions are characterized by enrichments in large ion lithophile elements (LILEs; e.g., Rb, Ba, and K) and light rare earth elements (LREEs), and depletions in high field strength elements (HFSEs; e.g., Nb, Ta, and Ti) and heavy rare earth elements (HREEs), indicating that they were formed in a subduction-related setting. These geochemical features, together with zircon ∊Hf(t) values (–1.1 to +11.2), indicate that their parental magmas were derived from partial melting of heterogeneous mantle wedge metasomatized by subduction-related fluids, with the contributions of slab sediments. The studied mafic intrusions also show wide range of major and trace elements contents, and variable Mg# values, Eu and Sr anomalies, suggesting that their parental magmas had undergone variable degrees of fractional crystallization. Together with the E–W trending Permian continental arc along the northern margin of the NCC, we confirm that the generation of the Middle Permian mafic intrusions was related to southward subduction of the Paleo-Asian oceanic lithosphere beneath the NCC and the Paleo-Asian Ocean had not closed prior to the Middle Permian.

Mantle source of tephritic porphyry in the Tarim Large Igneous Province constrained from Mg, Zn, Sr, and Nd isotope systematics: Implications for deep carbon cycling

AbstractThe nature and source of magmatism associated with large igneous provinces (LIPs) remain disputed. Here we investigate the role of recycled materials that contributed to mantle heterogeneity in the Tarim Large Igneous Province (TLIP) in China through integrated Zn–Mg–Sr–Nd isotopes of a rare tephritic rock suite. The Sr–Nd isotopes [(87Sr/86Sr)i = 0.70368–0.70629; εNd(t) = −0.25–4.64] and δ26Mg values (−0.23&amp;#x89; to −0.34&amp;#x89;) of the tephritic porphyries are consistent with a normal mantle origin. In contrast, the whole rock and pyroxene phenocrysts yield δ66Zn values of +0.28&amp;#x89; to +0.46&amp;#x89; and +0.30&amp;#x89; to +0.39&amp;#x89;, which are slightly heavier than those of the terrestrial mantle (+0.16 ± 0.06&amp;#x89;) and mid-oceanic-ridge basalts (MORBs) (+0.27 ± 0.05&amp;#x89;). We exclude the possibility that the heavy Zn isotopes of the Wajilitag tephritic porphyries are caused by magmatic processes such as fractional crystallization and partial melting and correlate the isotopic features to the role of altered oceanic crust along with magnesite in the mantle source. The Wajilitag tephritic porphyry displays trace-element patterns similar to those of the melts from natural hornblendite, especially those of hornblendite + peridotite. Additionally, the geochemical characteristics such as enrichment in Nb and Ta, depletion in K, high TiO2, and constant Na2O/K2O ratios also suggest that the tephritic porphyries were derived from an amphibole-bearing source contributed by altered oceanic crust along with sedimentary carbonates. Our study provides insight into the contribution of subducted materials to the mantle heterogeneity beneath the TLIP and highlights the role of subduction in the deep carbon cycle and subducted slab-lithosphere-plume interaction in the generation of LIPs.

Sulfur Isotope Evidence for a Geochemical Zonation of the Samoan Mantle Plume

AbstractBasalts from the Samoan volcanoes sample contributions from all of the classical mantle endmembers, including extreme EM II and high 3He/4He components, as well as dilute contributions from the HIMU, EM I, and DM components. Here, we present multiple sulfur isotope data on sulfide extracted from subaerial and submarine whole rocks (N = 16) associated with several Samoan volcanoes—Vailulu‘u, Malumalu, Malutut, Upolu, Savai‘i, and Tutuila—that sample the full range of geochemical heterogeneity at Samoa and upon exhaustive compilation of S‐isotope data for Samoan lavas, allow for an assessment of the S‐isotope compositions associated with the different mantle components sampled by the Samoan hotspot. We observe variable S concentrations (10–1,000 ppm) and δ34S values (−0.29‰ ± 0.30 to +4.84‰ ± 0.30, 2σ). The observed variable S concentrations are likely due to sulfide segregation and degassing processes. The range in δ34S reflects mixing between the mantle origin and recycled components, and isotope fractionations associated with degassing. The majority of samples reveal Δ33S within uncertainty of Δ33S = 0‰ ± 0.008. Important exceptions to this observation include: (a) a negative Δ33S (−0.018‰ ± 0.008, 2σ) from a rejuvenated basalt on Upolu island (associated with a diluted EM I component) and (b) previously documented small (but resolvable) Δ33S values (up to +0.027 ± 0.016) associated with the Vai Trend (associated with a diluted HIMU component). The variability we observed in Δ33S is interpreted to reflect contributions of sulfur of different origins and likely multiple crustal protoliths. Δ36S versus Δ33S relationships suggest all recycled S is of post‐Archean origin.

Evolution of Archean Sanukitoids from the Otto Stock by Magma Mixing and Na–K Metasomatism: Evidence from Petrological Observations and Lithium Isotope Geochemistry

AbstractPetrogenetic models for the genesis of Archean sanukitoids are diverse in the literature but most point to the initiation of plate tectonics and the construction of the first proto-continents during the Late Archean. These rocks include diorites, monzonites, monzodiorites, quartz monzodiorites, trachyandesites, granodiorites and tonalites, and are defined as having SiO2 = 55–60 wt%, Na2O + K2O = 6 wt%, MgO &amp;gt; 6 wt%, Mg# &amp;gt; 60, Ni–Cr &amp;gt; 100 ppm, Sr and Ba = 600–1800 ppm, chondrite-normalized Ce and Yb values of 80–250 and 4–10, respectively, and no Eu anomalies. Petrogenetic models include the partial melting of mantle peridotite previously metasomatized by fluids of crustal or mantle origin, partial melting of subducted slabs and assimilation of peridotite, and partial melting of undepleted peridotite with subsequent mixing with tonalite–trondhjemite–granodiorite (TTG) crustal partial melts and addition of carbonatite, all of which may or may not include subsequent differentiation by fractional crystallization. Here, extraordinary textural relations unequivocally show that at the Late Archean Otto stock, Abitibi, Canada, sanukitoids resulted from the assimilation of clinopyroxenite by monzonitic magmas and coeval magmatic–hydrothermal Na–K metasomatism. The metasomatized monzonites (± quartz), melanogranites, granodiorites, and sanukitoidal melanoporphyries were subsequently cut by swarms of lamprophyre dykes hosting a different set of hydrothermal alteration assemblages, including propylitic alteration, biotitization, chloritization, and pyritization, along with associated enrichments in Au. These alterations are shown to be associated with the nearby Cadillac–Larder Lake Fault Zone and the world-class Kirkland Lake gold deposit. The Li isotopic compositions of these rocks correlate with Au concentrations and range from magmatic values of ∼ +4 ‰ up to +10·4 ‰ in Na–K metasomatized and Au-depleted rocks, and from magmatic values of ∼4 ‰ down to 0·6 ‰ in rocks hosting propylitic, chloritic, and biotitic alteration and Au enrichments of up to 2·9 ppm Au.

Mantle plumes and their role in Earth processes

The existence of mantle plumes was first proposed in the 1970s to explain intra-plate, hotspot volcanism, yet owing to difficulties in resolving mantle upwellings with geophysical images and discrepancies in interpretations of geochemical and geochronological data, the origin, dynamics and composition of plumes and their links to plate tectonics are still contested. In this Review, we discuss progress in seismic imaging, mantle flow modelling, plate tectonic reconstructions and geochemical analyses that have led to a more detailed understanding of mantle plumes. Observations suggest plumes could be both thermal and chemical in nature, can attain complex and broad shapes, and that more than 18 plumes might be rooted in regions of the lowermost mantle. The case for a deep mantle origin is strengthened by the geochemistry of hotspot volcanoes that provide evidence for entrainment of deeply recycled subducted components, primordial mantle domains and, potentially, materials from Earth’s core. Deep mantle plumes often appear deflected by large-scale mantle flow, resulting in hotspot motions required to resolve past tectonic plate motions. Future research requires improvements in resolution of seismic tomography to better visualize deep mantle plume structures at smaller than 100-km scales. Concerted multi-proxy geochemical and dating efforts are also needed to better resolve spatiotemporal and chemical evolutions of long-lived mantle plumes.

Superimposed mineralization in the deformed Yulekenhalasu porphyry Cu-Mo deposit (Northwest China): Rb-Sr geochronology, S isotope, and trace element analysis of chalcopyrite

The Yulekenhalasu porphyry Cu–Mo deposit is located ca. 40 km southwest of Qinghe, in the Chinese Altay-East Junggar section of the Central Asian Orogenic Belt, NW China. The belt preserves multistage tectonic-hydrothermal and porphyry Cu-Mo mineralization events associated with arc to syn- and post-collision environments over 87 m.y. The 359 Ma deformed granitic porphyries are characterized by positive εNd(t) (+0.62 to + 3.77) and (87Sr/86Sr)initial values (0.704304–0.705960), and old crustal model ages of 747 to 1216 Ma, whereas a 272 Ma sample from late chalcopyrite–molybdenite–pyrite–magnetite–feldspar–calcite–gypsum veins yielded (87Sr/86Sr)initial values of 0.704415 to 0.705764, high εNd(t) values (+5.81 to + 5.88) and young crustal model ages (715 to 614 Ma) suggesting an increasingly juvenile mantle source over time. Seven fragments of a single deformed chalcopyrite grain yielded an Rb-Sr isochron age of 358.6 ± 4.8 Ma (2σ, MSWD = 1.8), which is consistent with the 360 Ma recrystallized zircon grains in the deformed host granitic porphyries. Eight fragments of chalcopyrite from the chalcopyrite–molybdenite–pyrite–magnetite–feldspar–calcite–gypsum veins formed along cleavage planes yielded a younger Rb-Sr isochron age of 272.2 ± 2.6 Ma (2σ, MSWD = 1.8). The younger age is interpreted as the lower age limit for the Mo and Cu mineralization in the post-collisional stage. The heterogeneous initial Sr isotopic compositions of chalcopyrite in the Yulekenhalasu deposit are likely the result of phyllosilicate inclusions. Disseminated chalcopyrite crystals in the granitic porphyry have different trace elemental contents than chalcopyrite in the deformed granitic porphyry and late chalcopyrite veins. Our Rb-Sr and trace element data for chalcopyrite grains constrain the age and geochemistry of multistage mineralization in porphyry Cu-Mo deposits. In-situ S isotope data of chalcopyrite from the deformed granite porphyries and chalcopyrite-feldspar-quartz-muscovite veins display a similar mantle origin. The 272 Ma mineralization event at Yulekenhalasu is coeval with the formation age of the Cu-Ni-(PGE) sulfide deposit in the Chinese Altay, indicating that hydrothermal mineralization like that in porphyry deposits can form proximal to ultramafic–mafic rocks and potentially may have a genetic relationship with mantle-derived Cu-Ni-(PGE) sulfide deposits.

Early Neoproterozoic continuous oceanic subduction along the northern margin of the Tarim Block: Insights from ca. 910–870 Ma arc-related magmatism in the Aksu area, NW China

The Tarim Block in NW China records the tectonic transition from compression to extension during the Neoproterozoic, and hence is regarded as a component of the Rodinia supercontinent. To unravel the role of the Tarim Block in the Rodinia assembly during the early Neoproterozoic, new geochronological and geochemical analyses were conducted on the gabbroic diorite, plagiogranite and andesite exposed in the Aksu area, northwestern Tarim. Zircon U-Pb dating indicates that these magmatic rocks were formed at ca. 900–870 Ma. Geochemically, these magmatic assemblages have typical features of arc-type rocks, showing enrichment of LILEs and depletion of HFSEs (such as Nb, Ta and Ti). They all have positive zircon εHf(t) values (+6.8 to +12.7), positive εNd(t) values (+3.6 to +6.0), and low and constant (87Sr/86Sr)i ratios (0.70252 to 0.70485). The gabbroic diorites display geochemical features of boninitic rocks such as high SiO2 (53.4–56.3 wt%), MgO (5.79–9.15 wt%), low TiO2 (0.29–0.41 wt%) contents, indicating that they were derived by partial melting of residual mantle. The plagiogranites are characterized by high SiO2 (74.7–79.6 wt%), Na2O (3.87–4.74 wt%), moderate Al2O3 (11.5–13.2 wt%), low K2O (0.15–0.22 wt%) contents, with very low TiO2 (0.08–0.17 wt%) and total REEs (6.3–19.0 ppm) contents similar to oceanic plagiogranite, indicating a hydrous low-pressure melting of mafic protolith. The positive εNd(t) and zircon εHf(t) values and low (87Sr/86Sr)i ratios of the andesitic rocks in the Aksu area suggest a depleted mantle origin. The analysis of trace elements (e.g. Th, Zr, Nb) of these intrusive and volcanic rocks in the Aksu area indicates that their magma sources had been metasomatized by slab-derived fluids. Combined with trace element features, we infer that these early Neoproterozoic magmatic rocks in the Aksu area developed in an oceanic subduction setting with arc-back-arc system probably analogous to the Izu-Bonin (IB) subduction system in the western Pacific. These findings lead us to propose that continuous oceanic subduction beneath the northern margin of the Tarim Block occurred during ca. 910–870 Ma, corresponding to the Neoproterozoic circum-Rodinia subduction-accretion system, which provides new evidence for the accretionary process of the Tarim Block to Rodinia during the early Neoproterozoic.

Lithospheric mantle refertilization by DMM-derived melts beneath the Cameroon Volcanic Line\u2014a case study of the Befang xenolith suite (Oku Volcanic Group, Cameroon)

The origin and evolution of subcontinental lithospheric mantle (SCLM) are important issues of Earth’s chemical and physical evolution. Here, we report detailed textural and chemical analyses on a mantle xenolith suite from Befang (Oku Volcanic Group, Cameroon Volcanic Line), which represents a major tectono-magmatic structure of the African plate. The samples are sourced from spinel-facies mantle and are dominated by lherzolites. Their texture is cataclastic to porphyroclastic, and foliation defined by grain-size variation and alignment of spinel occurs in part of peridotites. Spinel is interstitial and has amoeboidal shape. Clinopyroxene REE patterns are similar to those of Depleted MORB Mantle (DMM) except LREEs, which vary from depleted to enriched. The A-type olivine fabric occurs in the subset of one harzburgite and 7 lherzolites studied by EBSD. Orthopyroxene shows deformation consistent with olivine. The fabric of LREE-enriched clinopyroxene is equivalent to those of orthopyroxene and olivine, whereas spinel and LREE-depleted clinopyroxene are oriented independently of host rock fabric. The textural, chemical and thermobarometric constraints indicate that the Befang mantle section was refertilised by MORB-like melt at pressures of 1.0–1.4 GPa and temperatures slightly above 1200–1275 °C. The olivine-orthopyroxene framework and LREE-enriched clinopyroxene preserve the protolith fabric. In contrast, the LREE-depleted clinopyroxene, showing discordant deformation relative to the olivine-orthopyroxene protolith framework, and amoeboidal spinel crystallized from the infiltrating melt. The major element and REEs composition of minerals forming the Befang peridotites indicate subsequent reequilibration at temperatures 930–1000 °C. This was followed by the formation of websterite veins in the lithospheric mantle, which can be linked to Cenozoic volcanism in the Cameroon Volcanic Line that also brought the xenoliths to the surface. This study therefore supports the origin of fertile SCLM via refertilization rather than by extraction of small melt fractions, and further emphasizes the involvement of depleted melts in this process.