Mantle-derived Magmas Research Articles

The birth of the Alps: Ediacaran to Paleozoic accretionary processes and crustal growth along the northern Gondwana margin

New whole-rock geochemical and coupled U–Pb and Lu–Hf LA-ICP-MS zircon data of metasedimentary rocks of the Austroalpine, South Alpine and Penninic basement domains are presented, to disentangle the pre-Variscan tectonic evolution of the proto-Alps. The studied units seem to record distinct stages of protracted Late Ediacaran to Carboniferous tectonosedimentary processes prior to the Variscan collision. In the case of Austroalpine and South Alpine units, nevertheless, no major differences in terms of provenance are observed, since most detrital zircon samples are characterized by a major Pan-African peak. Their detrital zircon spectra record a provenance from the northeastern Saharan Metacraton and the Sinai basement at the northern Arabian-Nubian Shield, being thus located along the eastern Early Paleozoic northern Gondwana margin, whereas sources located further west are inferred for the Penninic Unit, which might have been placed close to the Moldanubian Unit of the Bohemian Massif. In any case, it is thus clear that the Alpine basement remained in a close position to the Gondwana mainland at least during the Early Paleozoic. The Late Ediacaran to Silurian tectonic evolution, which includes Cadomian and Cenerian tectonometamorphic and magmatic processes, seem thus to record a continuum related to a retreating-mode accretionary orogen, with diachronous back-arc basin opening and possibly discrete compressional/transpressional pulses linked to changes in subduction zone dynamics. On the other hand, it is inferred that the Alpine basement essentially comprises Pan-African metasedimentary and subordinate metaigneous rocks, possibly with very few Early Neoproterozoic relics. This basement was significantly reworked during the protracted Paleozoic orogenic evolution, due to anatexis and/or assimilation by mantle-derived juvenile magmatism.

Multistage Evolution of Proterozoic Crust of East Antarctica by the Example of the Filla Terrane (Rauer Islands): New Geological and Isotope Data

Abstract —The paper presents new data on the Rauer Islands, one of the unique objects of the East Antarctic Shield. The interest in this area is triggered by its complex geologic structure, including both Archean and Proterozoic fragments of the Earth’s crust, and by its multiphase formation. A detailed scheme of the geologic structure of the area is proposed, new petrologic complexes are revealed, and the stages of tectonomagmatic activity at ~1400–1320 Ma and 1150 Ma are reliably dated. This serves as a factual basis for comparison the study area with other regions of East Antarctica. Based on the geological and isotope data obtained, the Meso–Neoproterozoic Filla Terrane in the area of the Rauer Islands is recognized. It is composed of metamorphic and primarily intrusive rocks, whose protoliths formed in the time interval 1400–950 Ma. Three periods of tectonothermal activity have been established in the Filla Terrane: Mid-Mesoproterozoic (1400–1320 Ma), Meso–Neoproterozoic (1150–886 Ma), and early Cambrian (536–504 Ma). The first period is the formation time of Mesoproterozoic crust, and it is time-correlated with the tectonogenesis phase in the adjacent Rayner province. The second period corresponds to the later phase of tectonothermal activity in the Rayner province. In the Filla Terrane, this period can be divided into two intervals, 1150–1100 Ma and 1010–886 Ma. The former interval is treated as intense crustal growth in the course of granitoid and mantle magmatism. The latter interval is a period of tectonothermal processes accompanied by intense deformations, high-temperature metamorphism, and intrusion of porphyritic granitoids. Apparently, the gap between the first and the second intervals is the time of deposition of the sedimentary protolith of paragneisses, which, together with the surrounding rocks, underwent high-temperature metamorphism and deformations at 950–914 Ma. The synchronous evolution of the Archean block and the Filla Terrane began at least within 1100–1000 Ma. The youngest, early Cambrian period of tectonic activity coincides with the development of local low-temperature mylonite zones and the intrusion of synkinematic pegmatite veins. Thus, the tectonothermal evolution of the Filla Terrane includes almost the same main phases of crustal growth and transformation as the Rayner province. This indicates that the Filla Terrane is a fragment of the Rayner province, which accreted to the Archean terrane at least in the late Mesoproterozoic.

Mush, Melts and Metasediments: a History of Rhyolites from the Okataina Volcanic Centre, New Zealand, as Captured in Plagioclase

Abstract The Okataina Volcanic Centre (OVC), located in the Taupo Volcanic Zone, New Zealand, is a dominantly rhyolitic magmatic system in an arc setting, where eruptions are thought to be driven by mafic recharge. Here, Sr–Pb isotopes, and compositional and textural variations in plagioclase phenocrysts from 10 rhyolitic deposits (two caldera, one immediately post-caldera, four intra-caldera, and three extra-caldera) are used to investigate the OVC magmatic system and identify the sources and assimilants within this diverse mush zone. Plagioclase interiors exhibit normal and reverse zoning, and are commonly in disequilibrium with their accompanying glass, melt inclusions, and whole-rock compositions. This indicates that the crystals nucleated in melts that differed from their carrier magma. In contrast, the outermost rims of crystals exhibit normal zoning that is compositionally consistent with growth in cooling and fractionating melts just prior to eruption. At the intra-crystal scale, the total suite of 87Sr/86Sr ratios are highly variable (0·7042–0·7065 ± 0·0004 average 2SE); however, the majority (95 %) of the crystals are internally homogeneous within error. At whole-crystal scale (where better precision is obtained), 87Sr/86Sr ratios are much more homogeneous (0·70512–0·70543 ± 0·00001 average 2SE) and overlap with their host whole-rock Sr isotopic ratios. Whole-crystal Pb isotopic ratios also largely overlap with whole-rock Pb ratios. The plagioclase and whole-rock isotopic compositions indicate significant crustal assimilation (≥20 %) of Torlesse-like metasediments (local basement rock) by a depleted mid-ocean ridge mantle magma source, and Pb isotopes require variable fluid-dominant subduction flux. The new data support previous petrogenetic models for OVC magmas that require crystal growth in compositionally and thermally distinct magmas within a complex of disconnected melt-and-mush reservoirs. These reservoirs were rejuvenated by underplating basaltic magmas that serve as an eruption trigger. However, the outermost rims of the plagioclase imply that interaction between silicic melts and eruption-triggering mafic influx is largely limited to heat and volatile transfer, and results in rapid mobilization and syn-eruption mixing of rhyolitic melts. Finally, relatively uniform isotopic compositions of plagioclase indicate balanced contributions from the crust and mantle over the lifespan of the OVC magmatic system.

Evolution of Syenite Magmas: Insights from the Geology, Geochemistry and O-Nd Isotopic Characteristics of the Ordovician Saibar Intrusion, Altai-Sayan Area, Russia

In this paper, we provide insight into the evolution of syenite magmas based on geological data and petrographic, geochemical, and O-Nd isotope parameters of rocks of the Saibar intrusion located within the Minusinsk Trough, Altay-Sayan area. The intrusive suite includes predominant syenites, few bodies of melanocratic and leucocratic nepheline syenites (foyaites), and granites. In addition, dykes of granites and mafic rocks are present. The U-Pb zircon age from the melanocratic foyaites was determined to be 457 ± 10 Ma? Examined rocks show fractionated light rare earth element patterns, normalized to chondrite, with (La/Sm)n varying from 4 to 9, and a weakly fractionated distribution of medium and heavy rare elements, with (Dy/Yb)n from 0.35 to 1.23 and (Sm/Yb)n from 0.63 to 2.62. The spidergram normalized to the primitive mantle shows negative Ba, Sr, Nb, Ta, Ti, and Eu anomalies (Eu* = 0.48–0.60) and positive Rb, Th, and U anomalies. The δ18O values vary within 6.3 to 10.2‰, and εNd(t) from +4.1 to +5.0. We observe gradual transitions from syenites to foyaites. Assimilation by syenite magma of the host carbonate rocks was followed to transition from silica-saturated to silica-undersaturated conditions and removal of anorthite from the melt, which then led to nepheline. Granites of the main phase show depleted lithophile incompatible elements in comparison with syenites and foyaites. They originate via interaction of magmas at the marginal part (endocontact zone) of the intrusion, corresponding to north contact of the granites with the host felsic rocks. In comparison, the rock composition of granite dykes is enriched in lithophile incompatible elements, except for Zr, Hf, and Ti. These rocks are formed due to the differentiation of syenite magma without a significant effect of host rock assimilation. Mantle magmas must be used as parent magmas for syenites based on analysis of the formation model of other alkaline intrusions, which are similar in age to the Saibar intrusion. In the line of syenite intrusions of the Altai-Sayan province, the Saibar intrusion is no exception, and its origin is related to the evolution of mafic magmas that arose during the melting of the mantle under the influence of a mantle plume.

Early Mesozoic crustal evolution in the NW segment of West Qinling, China: Evidence from diverse intermediate–felsic igneous rocks

Continental convergent margins are commonly considered as significant sites for understanding crustal reworking and growth, but the geodynamic processes involving crustal growth remain highly debatable. Triassic intermediate–felsic intrusive rocks are widespread in the northwestern segment of the West Qinling orogenic belt on the NE Tibetan Plateau. These rocks well document the evolution of one branch of the Paleo-Tethys oceans (i.e., the A'nyemaqen Ocean) in East Asia. Here we present a comprehensive study of zircon UPb and LuHf isotopic data, along with whole-rock elemental and SrNd isotopic data to decipher the origins of intermediate–felsic intrusions and crustal evolution of the West Qinling in the Triassic. Two episodes of magmatism were detected in this study, i.e., the early high-Mg diorite porphyry–granodiorite–granodiorite porphyry assemblage (Episode #1, ~244–230 Ma), followed by a later monzogranite–granodiorite–granite porphyry assemblage (Episode #2, ~228–203 Ma). These two episodes of magmatism are interpreted as products related to oceanic subduction and continental collision, respectively. In Episode #1, the mafic magmatic enclaves were mainly mantle-derived and were indicative of magma mixing. The high-Mg diorite porphyries were likely derived from partial melting of the mantle wedge metasomatized by sediment-derived melts, whereas the coeval granodiorites and granodiorite porphyries mainly originated from partial melting of amphibolites with significant addition of mantle-derived components. By contrast, the granodiorite porphyries in Episode #2 probably originated from the lower crust-sourced melts with insignificant mantle contribution. The contemporaneous granodiorites and monzogranites were generated by partial melting of the crustal amphibolites or metagreywackes. The proportion of positive zircon εHf(t) values decreased from Episode #1 to Episode #2, indicating a decreasing tendency of the mantle or juvenile component contribution. Our study suggests that the addition of mantle-derived magmas to the continental crust during oceanic subduction processes played an important role in crustal growth.

A newly discovered Late Cretaceous metamorphic belt along the active continental margin of the Neo-Tethys ocean

Abstract High-grade metamorphic rocks and crustal melts provide crucial evidence for growth and differentiation of the continental crust, and are widespread in collisional orogens. However, their importance in the evolution of continental arcs remains poorly understood. Metamorphism and related anatexis in the preserved continental margin of the Neo-Tethys ocean serves as a key natural laboratory to investigate this process. Along the Neo-Tethyan arc margin, the Gaoligong shear zone, Yunnan region of China, is an important locality for linking Lhasa in the north with Sibumasu and Burma in the south. Here, Late Cretaceous granulite-facies metamorphism and crustal anatexis have been identified for the first time in the Gaoligong area. Zircon and monazite U-Pb dating indicates that S-type granites formed at 87–73 Ma, granites and buried pelitic sediments were simultaneously metamorphosed at 75–70 Ma during Neo-Tethyan subduction, and all lithologies were overprinted by a younger 40–30 Ma magmatic and strike-slip event related to India-Asia collision. Phase equilibria modeling of high-grade anatectic gneiss in the MnO-Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O-TiO2 system indicates peak pressure-temperature (P–T) conditions of 780–800 °C and 6.5–7.5 kbar and defines a cooling and decompressional P–T path for the metapelites. This demonstrates that sediments within the Neo-Tethyan active continental arc were buried to >20 km depth at 75–70 Ma. In combination with the metamorphic record of the Lhasa, Burma, and Sibumasu blocks, an extensive Late Cretaceous metamorphic belt must have formed along the Neo-Tethyan subduction zone. This spatially correlates with coeval gabbro-diorite suites exposed in the Gangdese, Sibumasu and Burma terranes that were triggered by thinning of the lithospheric mantle. This prolonged Late Cretaceous mantle-derived magmatism and lithospheric thinning may have provided a regional-scale heat source for high-grade metamorphism and crustal anatexis along the active continental margin of the Neo-Tethys ocean.

Reconstruction of primary alkaline magma composition from mineral archives: Decipher mantle metasomatism by carbonated sediment

Alkaline magmas play a key in understanding crust-mantle interaction and deep carbon recycling. Here, petrography and in situ mineral analyses of evolved alkaline rocks from the North China Craton are reported to decipher mantle metasomatism by recycled carbonated sediments via reconstruction of primary magma composition. The alkaline rocks are nepheline syenites for which new, consistent zircon and titanite UPb ages of ~235 Ma are presented. The rocks are highly evolved (SiO2 = 58.1–60.0 wt%) with negative anomalies for Sr, Ba, Ti, P and Eu, and relative depletion of MREE, indicating fractional crystallization of feldspar, apatite, titanite and amphibole. Core-rim variation of 87Sr/86Sr (0.7052–0.7092) of late-crystallized low Mg# clinopyroxene and feldspar are attributed to crustal assimilation.The origin of primary alkaline magma is recorded in early high Mg# (70–84) clinopyroxenes with weak Eu anomalies (Eu/Eu* = 0.94–1.29), suggesting that they crystallized from a little-differentiated mantle-derived magma (Mg# > 60). Their variable 87Sr/86Sr ratios (0.7031–0.7060) correlate positively with Sr/Y and (La/Yb)N and negatively with Ti/Eu ratios, but are not correlated with Mg# or Eu/Eu*. Moreover, the REE patterns of melt equilibrated with high 87Sr/86Sr clinopyroxene is similar to coeval alkaline rocks from adjacent areas. These features indicate that the primary alkaline magma was derived from the mixing of depleted mantle and enriched mantle metasomatized by carbonatite melts from subducted crustal materials. Low zircon εHf(t) values (−1.4 to −2.8) imply that the subducted crustal material was carbonated sediments. Calcite and CO2 inclusions occur in early-crystallized olivine, clinopyroxene and zircon, and amphibole and fluorapatite both reveal a volatile-rich (H2O, F and CO2) alkaline magma derived from mantle enriched by carbonate metasomatism. The mineral archives of alkaline rocks not only record mantle metasomatism by recycled carbonated sediments, but also fractional crystallization and assimilation during magma evolution.

Early Cenozoic partial melting of meta-sedimentary rocks of the eastern Gangdese arc, southern Tibet, and its contribution to syn-collisional magmatism

AbstractContinental magmatic arcs are characterized by the accretion of voluminous mantle-derived magmatic rocks and the growth of juvenile crust. However, significant volumes of meta-sedimentary rocks occur in the middle and lower arc crust, and the contributions of these rocks to the evolution of arc crust remain unclear. In this paper, we conduct a systematic study of petrology, geochronology, and geochemistry of migmatitic paragneisses from the eastern Gangdese magmatic arc, southern Tibet. The results show that the paragneisses were derived from late Carboniferous greywacke, and underwent an early Cenozoic (69–41 Ma) upper amphibolite-facies metamorphism and partial melting at pressure-temperature conditions of ~11 kbar and ~740 °C, and generated granitic melts with enriched Hf isotopic compositions (anatectic zircon εHf(t) = −10.57 to +0.78). Combined with the existing results, we conclude that the widely distributed meta-sedimentary rocks in the eastern Gangdese arc deep crust have the same protolith ages of late Carboniferous, and record northwestward-decreasing metamorphic conditions. We consider that the deeply buried sedimentary rocks resulted in the compositional change of juvenile lower crust from mafic to felsic and the formation of syn-collisional S-type granitoids. The mixing of melts derived from mantle, juvenile lower crust, and ancient crustal materials resulted in the isotopic enrichment of the syn-collisional arc-type magmatic rocks of the Gangdese arc. We suggest that crustal shortening and underthrusting, and the accretion of mantle-derived magma during the Indo-Asian collision transported the supracrustal rocks to the deep crust of the Gangdese arc.

Mineralization age, tectonic setting and ore genesis of the Wuxing Pt–Pd-rich magmatic Cu-Ni sulfide deposit, Northeast China

• Wuxing deposit with age of 516.7 Ma is reported. • Wuxing intrusive rocks experienced independent diagenetic processes. • The Wuxing deposit was formed in a post–collision extensional setting. The Wuxing deposit in Northeast China, tectonically located in the Jiamusi–Khanka Block, is a Pt–Pd-rich Cu-Ni sulfide deposit related to mafic–ultramafic rocks. The zircon U–Pb ages of pyroxenites , gabbros , porphyritic granites , and leucogranits in the mining area are 516.7 ± 2.6, 513.8 ± 2.0, 505.4 ± 2.3 and 499.5 ± 2.9 Ma, respectively, indicating that the diagenesis and metallogenesis of the Wuxing deposit occurred during the Cambrian. The ore-forming complex is cut by quartz diorite porphyritic and plagiogranite porphyry dikes. Zircon U–Pb ages of the quartz diorite porphyrite and plagiogranite porphyry are 206.6 ± 2.1 and 201.6 ± 1.3 Ma, respectively. The U–Pb ages indicate the metallogenic age constraint of 516.7 ± 2.6 Ma for the Wuxing deposit, rather than Cambrian and Triassic magmatic activities. The Hf isotopic composition ε Hf (t) of zircons in the pyroxenites and gabbros are −11.5 to −7.7 and −5.8 to −2.5, with the two–stage model ages (t DM2 ) of 2198–1958 and 1841–1633 Ma, respectively. Geochemically, the mafic–ultramafic complexes are enriched in light rare earth elements (LREE) and large ion lithophile elements (LILE), and depleted in high-field strength elements (HFSE), indicating these rocks originated from the enriched mantle. The porphyritic granites are high-K calc-alkaline rocks (Rittman index δ = 1.92–2.00), and the leucogranites are low-K alkaline rocks ( δ = 4.76–4.86) with ε Hf (t) and t DM2 of −9.2 to +0.8 and 2037–1411 Ma, respectively. The porphyritic granites and leucogranites are characterized by low A/CNK values (0.91–1.05), 10,000 Ga/Al values (1.76–2.36), and Zr saturation temperature (731–823 ℃) similar to those of I-type granites. Along with contemporaneous intrusions, the Wuxing deposit is inferred to have formed in a post-collisional extension environment. Consequently, the origin of the Wuxing deposit is likely related to the evolution of enriched mantle magma during the Cambrian post-collision extensional setting of the Jiamusi–Khanka Block.

Petrogenesis of early Eocene granites and associated mafic enclaves in the Gangdese batholith, Tibet: Implications for net crustal growth in collision zones

Granitoids and related mafic microgranular enclaves (MMEs) in continental collision zones may provide crucial insights into the formation and evolution of continental crust. In this paper, we report an investigation into the mineralogy, zircon U–Pb geochronology, whole-rock major and trace elements, and Sr–Nd–Hf isotopic geochemistry of granodiorites and hosted MMEs, as well as monzogranites, from the Zhaxiding intrusive complex in the Gangdese batholith, southern Tibet. Zircon U–Pb dating suggests that these rocks were emplaced during the early Eocene (49 to 47 Ma). Field investigation and petrological observations indicate that the MMEs represent globules of a mafic magma that was injected into the host felsic magma. On the basis of depleted zircon Hf (εHf(t) values of +6.5 to +9.2) and whole-rock Sr–Nd (εNd(t) values of +1.6 to +2.6) isotopic compositions, along with their whole-rock compositions, the MMEs are interpreted as having resulted from mixing of mantle-derived magma with juvenile crust-derived melts. The granodiorites and monzogranites are metaluminous and have positive zircon εHf(t) (+6.3 to +8.9 for granodiorites and +1.7 to +10.2 for monzogranites) and whole-rock εNd(t) (+1.6 to +1.9 for granodiorites and +0.5 to +1.1 for monzogranites) values. The granodiorites further exhibit continental crust-like chemical compositions (e.g., enrichment in Rb, K, and Pb and depletion in Nb and Ta) and high Mg# values, suggesting that they originated from partial melting of juvenile crust with the involvement of mantle-derived melts. However, the monzogranites have lower P, Ti, and total rare earth element contents, similar Rb, Ba, and Sr contents, and uniform Eu anomalies compared with the granodiorites, and were likely generated by fractional crystallization of amphibole and Fe–Ti oxides from juvenile crust-derived magma. We propose that underplating of mantle-derived magma likely triggered coeval crustal magmatism and that mixing of the mantle- and crust-derived magmas and subsequent crystallization differentiation formed the intermediate to felsic Zhaxiding intrusive complex in the Gangdese batholith. The continental crust-like bulk compositions of the intermediate to felsic magmatic rocks represent a net addition of juvenile material to continental crust. Our study thus indicates that magma mixing and differentiation play a significant role in the formation of andesitic to dacitic continental crust in collision zones.

Protracted intra- and inter-pluton magmatism during the Acadian orogeny: evidence from new LA-ICP-MS U-Pb zircon ages from northwestern Maine, USA

Devonian granitoid plutons comprise a major part of the bedrock of northwestern Maine representing the magmatic expression of the Acadian orogeny in this part of the northern Appalachian orogen. They are petrographically diverse with minerals characteristic of both I- and S-type granites, in some cases within the same intrusion, and some are compositionally zoned. New LA-ICP-MS ages presented here elucidate the timing and duration of this magmatism. The earliest phase of granitoid magmatism began around 410–405 Ma with the emplacement of the Flagstaff Lake Igneous Complex, and the presence of contemporaneous mafic rocks suggests that mantle-derived magmas were also produced at this time. Late Devonian ages, ca. 365 Ma, for many intrusions, such as the Chain of Ponds and Songo plutons, reveal that magmatism continued for 45 million years during which compositionally diverse I- and S-type magmas were produced. In addition, there is evidence that intrusive activity was prolonged within some plutons, for example the Rome-Norridgewock pluton and the Mooselookmeguntic Igneous Complex, with 10–15 myr between intrusive units. The new ages suggest a break in magmatism between 400 Ma and 390 Ma apparently separating Acadian magmatism into early and late pulses. The production of lower crustal I-type magmas appears to have been concentrated later, ca. 380–365 Ma, although several S-type granitoids were also emplaced during this period. These Late Devonian plutons display abundant zircon inheritance with ages around 385 Ma, which suggests that the crust was experiencing enhanced thermal perturbations during this extended timeframe. The new data for granitoid plutons in northwestern Maine are consistent with tectonic models for other parts of Ganderia which propose initial flat slab subduction followed by slab breakoff and delamination.

Discovery of multi-crustal rejuvenations for the formation of the Lincang granitic batholith, Southwest China: magmatism relating to Changning–Menglian Paleo–Tethyan termination

ABSTRACT The consumption of the Changning–Menglian Palaeo-Tethys ocean in the Triassic formed the Lincang granitic batholith in the southwestern China, once the oceanic supra-subduction zone. The batholith provides us a critical window to understand the nature of the crustal basements and the process of Palaeo-Tethyan termination. Here we report zircon U-Pb ages and Hf isotopes, and whole-rock elements and Sr-Nd isotopes of granitic samples from the central part of the Lincang batholith. The geochemical results reveal two genetic types of granites indicated by low-K and high-K affinities, respectively. The Group 1 low-K granitoids dated at 237–229 Ma are low-K calc-alkaline and metaluminous to peraluminous (A/CNK = 0.75–1.29), with K2O contents of 0.13–1.33 wt%, K2O/Na2O ratios of 0.03–0.30, Rb/Sr ratios < 0.18, and initial 87Sr/86Sr = 0.71693 and εNd(t) = −10.8. In contrast, the Group 2 high-K granitoids dated at 239–200 Ma are calc-alkaline and peraluminous (A/CNK = 1.02–1.20), with higher K2O contents (3.15–4.7 wt%), K2O/Na2O ratios (1.15–2.00) and Rb/Sr ratios (0.77–2.62), and more enriched isotopic compositions (initial 87Sr/86Sr = 0.73129 to 0.74037, εNd(t) = −13.1 to −11.0) as well as highly negative zircon εHf(t) values of −16.8 to −6.7. The formation time of these granitoids is compatible with that of the post-collision of the Palaeo-Tethys, subsequently to the magmatic gap (250–240 Ma) coupling with the syn-collision stage. The magmatic source discriminations suggest that the low-K granitoids were derived from partial melting of the dehydrated low-K amphibolite source and the high-K granitoids were dominantly from the psammitic source with minor mantle-derived magma involvement. Using the geochemical variations of the granitic rocks related to the Palaeo-Tethyan closure, we reveal melting of multiple crustal sources rather than a sole source to construct the Lincang batholith.

Multiple isotope (He-Ar-Zn-Sr-Nd-Pb) constraints on the genesis of the Jiawula Pb-Zn-Ag deposit, NE China

• Mantle fluid and atmospheric water are two most important sources for the ore-forming fluid of the Jiawula deposit. • Zn isotopic variation was most likely caused by kinetic Rayleigh fractionation. • Coeval magma played a key role in the formation of the deposit. The large Jiawula Pb-Zn-Ag deposit is located in the Manzhouli area, northeast China. The Pb-Zn-polymetallic mineralization in the Jiawula deposit is present as ore veins distributed in Early Mesozoic sedimentary and magmatic rocks and was controlled by NWW to NNW trending faults. He and Ar isotope analysis results of fluid inclusions hosted in pyrite show that 40 Ar/ 36 Ar ratios are 280.5–300.1, which is close to the atmospheric value (295.5). 3 He/ 4 He ratios vary from 40.15 × 10 −7 to 71.68 × 10 −7 . The calculated mantle He are in a range of 35.8–64.0%, with an average of 51.0%. He-Ar isotopic data reveals that the ore-forming fluids of the Jiawula deposit were derived from mixture of two fluid end-members: (1) mantle-derived fluid, which has provided a considerable proportion of He; and (2) crustal fluid, which is characterized by almost atmospheric Ar and crustal He. The sphalerite from the Jiawula deposit have a narrow range of δ 66 Zn JMC values, varying from 0.15 to 0.307‰, with a mean value of 0.236‰. We suggest that the variation of Zn isotope values of sphalerite from the Jiawula deposit was most likely caused by kinetic Rayleigh fractionation. The Zn isotope analysis result, combined with previous S isotopic data, indicate that the ore-forming material of the Jiawula deposit was derived from a single source. The intrusive rocks in the deposit have low initial 87 Sr/ 86 Sr ratios, relatively high ε Nd (t) values, and young T DM2 Nd model ages, indicating a high proportion of juvenile material in the petrogenesis. Combined with Sr-Nd-Pb isotopic data of intrusive rocks that are coeval with mineralization in the deposit, He-Ar-Zn isotope analysis results, and previous studies, we propose that the mantle component in the ore-forming fluid and material of the Jiawula deposit was most probably derived from the simultaneous magma, which was derived from partial melting of crust with involvement of mantle magma in an extensional setting during the late Jurassic to the early Early Cretaceous.

Identification and Geological Significance of Early Jurassic Adakitic Volcanic Rocks in Xintaimen Area, Western Liaoning

The Western Liaoning area, where a large number of Jurassic-Cretaceous volcanic rocks are exposed, is one of the typical areas for studying the Mesozoic Paleo-Pacific and Mongolia-Okhotsk subduction process, and lithospheric destruction of North China Craton. The identification and investigation of Early Jurassic adakitic volcanic rocks in the Xintaimen area of Western Liaoning is of particular significance for exploring the volcanic magma source and its composition evolution, tracking the crust-mantle interaction, and revealing the craton destruction and the subduction of oceanic plates. Detailed petrography, zircon U–Pb dating, geochemistry, and zircon Hf isotope studies indicate that the Early Jurassic intermediate-acidic volcanic rocks are mainly composed of trachydacites and a few rhyolites with the formation ages of 178.6–181.9 Ma. Geochemical characteristics show that they have a high content of SiO2, MgO, Al2O3, and total-alkali, typical of the high-K calc-alkaline series. They also show enrichment of light rare earth elements (LREEs) and large ion lithophile elements (LILEs), depletion of heavy rare earth elements (HREEs) and high field strength elements (HFSEs), and have a high content of Sr and low content of Y and Yb, suggesting that they were derived from the partial melting of the lower crust. The εHf(t) values of dated zircons and two-stage model ages (TDM2) vary from −11.6 to −7.4 and from 1692 to 1958 Ma, respectively. During the Early Jurassic, the study area was under long-range tectonic effects with the closure of the Mongolia-Okhotsk Ocean and the subduction of the Paleo-Pacific plate, which caused the basaltic magma to invade the lower crust of the North China Craton. The mantle-derived magma was separated and crystallized while heating the Proterozoic lower crust, and part of the thickened crust melted to form these intermediate-acidic adakitic volcanic rocks.

Highly siderophile element and osmium isotope systematics of basaltic volcanics: A different approach to petrological processes

The highly siderophile element (HSE) or platinum group element (PGE) and Os isotope systematics of basaltic volcanics have recently received a significant attention because of their potential to constrain the petrological processes on magma generation and evolution. The HSE and Os isotope data, which are generally observed at very low concentrations in basalts and obtained by modern enrichment and analytical techniques, are frequently used in petrological studies. The HSE contents and ratios from whole-rock analysis of basalts, and combined evaluation with the theoretical knowledge and modelling of HSE behaviour during the partial melting of mantle and the differentiation of basaltic magma would provide opportunity for geochemical modelling on mantle melting. Besides, HSE contents and Pd-PGE/Ir-PGE ratios are important indicators for the nature of mantle sulfides, the sulfur saturation conditions of the mantle source, sulfide segregation, fractional crystallization, crustal assimilation and partial melting degrees in the origin and evolution of mantle-derived magmas. Therefore, in addition to the traditional whole-rock geochemical data obtained from Cenozoic aged basalts observed widely in Turkey, HSE and Os isotope systematics of these basalts can contribute to define the geochemical features of the mantle source, and to model petrological processes which are effective in the magma evolution.

Geochemical characteristics of the early Neoarchean komatiite from the North China Craton: Evidence for plume–craton interaction

Komatiite is characterized by extremely high MgO contents and H2O-poor nature and plays an important role in understanding the early mantle-derived magma processes, crust–mantle differentiation of the Archean earth, but it is sparse in the North China Craton. Although komatiitic rocks have ever been discovered in the Mengyin area, their formation ages and types are still in debate. Here, we firstly report a new komatiite outcrop near Nanbaita village (Jinan city) of the western Shandong Province and present new major and trace element contents, as well as Sr–Nd and Re–Os isotopic compositions. The rocks show spinifex texture with primary olivine and pyroxene skeletal needles have been transformed into secondary minerals (e.g., serpentine, tremolite). The komatiites display extremely high MgO, but low TiO2 and Na2O + K2O. Their chondritic Al2O3/TiO2 and GdN/YbN ratios suggest they are Aluminium-undepleted komatiites which are generated by larger degrees of melting (~50%) in relatively lower pressure (ca. 5–7 GPa) with garnet absence than Aluminium-depleted komatiites. The formation age of these komatiites was no later than 2.69 Ga constrained by the Re depletion age. Flat heavy rare earth element patterns and low 187Re/188Os and Th/Yb ratios show the primary komatiitic magma was not contaminated by substantial crustal material. The γOs value of sample 18LH51 is 0.09, which is adjacent with chondrite and other contemporaneous komatiites in the world, indicating that the Nanbaita komatiites were originated from a chondritic mantle. Furthermore, the widely distribution of ~2.7 Ga ultramafic–mafic rocks in the western Shandong Province might be the reflection of a contemporaneous worldwide superplume event.

Trace Element Contents of Mantle-Derived Magmas Through Time

Abstract A large compilation of quality-curated major and trace element data has been assembled to investigate how trace element patterns of mafic and ultramafic magmas have varied with time through particular settings from the Archean to the Phanerozoic, the primary objective being to recognise at what times particular patterns of variation emerge, and how similar these are to baseline data sets representing tectonic settings in the modern Earth. The most informative element combinations involve Nb, Th and the REE, where REE are represented by ‘lambda’ parameters describing slope and shape of patterns. Combinations of the ratios of Th, Nb, La and lambda values from Archean and early Proterozoic basalts and komatiites reveal a distinctive pattern that is common in most well-sampled terranes, defining a roughly linear trend in multi-dimensional space from compositions intermediate between modern n-MORB and primitive mantle at one end, towards compositions approximating middle-to-upper continental crust at the other. We ascribe this ‘Variable Th/Nb’ trend in most instances to varying degrees of crustal contamination of magmas with similar compositions to modern oceanic plateau basalts. Komatiites had slightly more depleted sources than basalts, consistent with the hypothesis of derivation from plume tails and heads, respectively. The most significant difference between Precambrian and Phanerozoic plume-derived basalts is that the distinctive OIB-like enriched source component appears to be largely missing from the Archean and Proterozoic geologic record, although isolated examples of OIB-like trace element characteristics are evident in datasets from even the oldest preserved greenstones. Phanerozoic intra-cratonic LIPs, such as the 260 Ma Emeishan LIP in China, have fundamentally different geochemical characteristics to Archean and Paleoproterozoic assemblages; the oldest Proterozoic LIP we have identified that has this type of ‘modern’ signal is the Midcontinent Rift at 1100 Ma. The data are consistent with plume tail sources having changed from being dominantly depleted in the Archean Earth to dominantly enriched in the Phanerozoic Earth, while plume head sources have hardly changed at all. Trace element patterns considered to be diagnostic of subduction are locally present but rare in Archean terranes and become more prevalent through the Proterozoic, although this conclusion is tempered by the large degree of overlap in compositional space between continental arc magmas and continental flood basalts. This overlap reflects the difficulty of distinguishing the effects of supra-subduction metasomatizm and flux melting from those of crustal contamination. Additional factors must also be borne in mind, particularly that trace element partitioning systematics may have been different in all environments in a hotter planet, and large-scale asthenospheric overturns might have been predominant over modern-style plumes in the Archean Earth. Some basaltic suites in particular Archean terranes, notably the western parts of both the Yilgarn and Pilbara cratons in Western Australia and parts of the Superior Craton, have restricted, but locally predominant, suites of basalts with characteristics akin to modern oceanic arcs, suggesting that some process similar to modern subduction was preserved in these particular belts. Ferropicrite magmas with distinctive characteristics typical of modern OIBs and some continental LIPs (notably Emeishan) are rare but locally predominant in some Archean and early Proterozoic terranes, implying that plume sources were beginning to be fertilised by enriched, probably subducted, components as far back as the Mesoarchean. We see no evidence for discontinuous secular changes in mantle-derived magmatism with time that could be ascribed to major mantle reorganisation events. The Archean–Proterozoic transition appears to be entirely gradational from this standpoint. The transition from Archean-style to Phanerozoic-style plume magmatism took place somewhere between 1900 Ma (age of the Circum-Superior komatiitic basalt suites) and 1100 Ma (the age of the Midcontinent Rift LIP).

Late Eocene post-collisional magmatic rocks from the southern Qiangtang terrane record the melting of pre-collisional enriched lithospheric mantle

Abstract Diverse rock types and contrasting geochemical compositions of post-collisional mafic rocks across the Tibetan Plateau indicate that the underlying enriched lithospheric mantle is heterogeneous; however, how these enriched mantle sources were formed is still debated. The accreted terranes within the Tibetan Plateau experienced multiple stages of evolution. To track the geochemical characteristics of their associated lithospheric mantle through time, we can use mantle-derived magmas to constrain the mechanism of mantle enrichment. We report zircon U-Pb ages, major and trace element contents, and Sr-Nd isotopic compositions for Early Cretaceous and late Eocene mafic rocks in the southern Qiangtang terrane. The Early Cretaceous Baishagang basalts (107.3 Ma) are characterized by low K2O/Na2O (&amp;lt;1.0) ratios, arc-like trace element patterns, and uniform Sr-Nd isotopic compositions [(87Sr/86Sr)i = 0.7067–0.7073, εNd(t) = −0.4 to −0.2]. We suggest that the Baishagang basalts were derived from partial melting of enriched lithospheric mantle that was metasomatized by subducted Bangong–Nujiang oceanic material. We establish the geochemistry of the pre-collisional enriched lithospheric mantle under the southern Qiangtang terrane by combining our data with those from other Early Cretaceous mafic rocks in the region. The late Eocene (ca. 35 Ma) post-collisional rocks in the southern Qiangtang terrane have low K2O/Na2O (&amp;lt;1.0) ratios, and their major element, trace element, and Sr-Nd isotopic compositions [(87Sr/86Sr)i = 0.7042–0.7072, εNd(t) = −4.5 to +1.5] are similar to those of the Early Cretaceous mafic rocks. Based on the distribution, melting depths, and whole-rock geochemical compositions of the Early Cretaceous and late Eocene mafic rocks, we argue that the primitive late Eocene post-collisional rocks were derived from pre-collisional enriched lithospheric mantle, and the evolved samples were produced by assimilation and fractional crystallization of primary basaltic magma. Asthenosphere upwelling in response to the removal of lithospheric mantle induced the partial melting of enriched lithospheric mantle at ca. 35 Ma.

Petrogenesis of Early Cretaceous granitoids and mafic microgranular enclaves from the giant Tonglushan Cu–Au–Fe skarn orefield, Eastern China

Late Mesozoic high-K calc-alkaline and high Sr/Y granitoids related to the skarn–porphyry–stratabound Cu–Au polymetallic deposits are widespread in the Middle–Lower Yangtze River Belt (MLYRB), Eastern China. However, the role of mantle-derived magmas in the petrogenesis of these granitoids remains controversial. In this study, we present new zircon U–Pb–Hf isotopes, and whole-rock geochemical and Sr–Nd isotopes data for quartz monzodiorites (porphyry), their hosting mafic microgranular enclaves (MMEs) and associated dykes from Tonglushan orefield in the MLYRB. Field relationships and geochronological data show that these intrusive rocks cluster around 141–139 Ma, indicating a short duration of magmatism, rather than a prolonged magmatism (~30 My) as previously thought. Crystallization age of the MMEs is identical to that of their quartz monzodiorite host. Petrographical and geochemical observations suggest that the MMEs represent mafic melts that injected into the quartz monzodioritic magmas, and magma mixing and (previously) fractional crystallization were involved in producing their compositional diversity. All the Tonglushan granitoids and MMEs show trace element geochemical and Sr–Nd–Hf isotope compositions similar to the coeval K-rich mafic rocks in the MLYRB. This indicates that these granitoids and MMEs were mainly sourced from the enriched subcontinental lithospheric mantle (SCLM) that metasomatized by slab derived fluids/melts, and had experienced significant fractional crystallization. The high oxygen fugacity and water content of the early Tonglushan quartz monzodiorite (porphyry) indicate melting of metasomatized SCLM and subsequently fractional crystallization and recharging/mixing in magmatic system have the potential to Cu–Au polymetallic mineralization. This study also highlights that the SCLM beneath the eastern Yangtze plate is one of the likely sources for Late Mesozoic magmatic rocks in the MLYRB.

Contrasting Neoproterozoic and Mesozoic granitoids in Zaranda complex (Nigeria): insights into the distinct origins, tectonic settings and mineralization potential

Combined whole-rock geochemistry, zircon U–Pb dating, and Sr–Nd–Pb isotopic analyses were carried out to constrain the petrogenesis and tectonic implications of the “Zaranda Older Granites” (ZOG) and “Younger Granites” (ZYG) in north-central Nigeria. Zircon U–Pb dating yielded 633 ± 3 Ma for the ZOG and 203 ± 1 Ma for the ZYG, corresponding to Late Neoproterozoic and Late Triassic, respectively. The ZOG consists dominantly of biotite granite, which displays a whole-rock ɛNd(t) values of − 3.48 to − 5.00 and Nd model ages of 1620–1720 Ma. Most ZOG samples exhibit elevated Sr/Y (107–128) and La/Yb ratios (36–40), with a positive Eu anomaly (Eu/Eu* = 2.2–2.58), interpreted to reflect magma derivation through partial melting of a thickened lower crust. The ZOG is geochemically and geochronologically similar to the Pan-African granites from Togo–Benin (West Africa) and Northeast Borborema, Sao Paulo (Brazil), suggesting that their emplacement probably marked the initial phase of the Pan-African orogeny during which the Gondwana was amalgamated. The ZYG consists of compositionally diverse alkaline granitoids including aegirine syenites, quartz syenite, and fayalite granite porphyry. These rocks are strongly ferroan, alkalic and show petrographic and geochemical features of classical A-type granites. Substantial depletion in Ba, Sr, P, Ti, and Eu signifies fractionation of felsic and mafic minerals such as feldspar, biotite, amphibole, and Ti-rich augite. The low Y/Nb and Yb/Ta ratios (≤ 2) indicate that the ZYG samples display geochemical features typical of OIB-derived A-type granites. The ɛNd(t) values in the ZYG range from + 4.16 to − 2.76 and the Nd model ages range from 0.6 to 1.2 Ga. Based on these results, we propose that the ZYG samples and by extension, other alkaline granitoids from the Nigerian Younger Granite (NYG) province with similar geochemical compositions were likely generated through extensive differentiation of OIB-type mantle-derived magma. The concentrations of Nb and other HFSEs are much higher in ZYG than ZOG, indicating that the former has higher rare metal mineralization potential.