Main Pollution Sources Research Articles

Comparison of active and passive methods for atmospheric particulate matter collection: From case study to a useful biomonitoring tool

In this study we conducted air pollution monitoring using three different methods: active monitoring with the use of high volume aerosol sampler and biomonitoring with the use of lichens and spider webs. All of these monitoring tools were exposed to air pollution in Legnica city, a region of Cu-smelting in the SW Poland, which is well known for exceeding the environmental guidelines. Quantitative analysis was carried out for the particles collected by the three selected methods and concentrations of seven selected elements (Zn, Pb, Cu, Cd, Ni, As, Fe) were obtained. Concentrations found in lichens and in spider webs were directly compared and indicated significant differences between them, with higher amounts noted for spider webs. Then, in order to recognize the main pollution sources the principal component analysis was conducted and obtained results were compared. It resulted that spider webs and aerosol sampler, despite different mechanisms of accumulation, show similar sources of pollution – in this case – copper smelter. Additionally, the HYSPLIT trajectories and the correlations between metals in the aerosol samples also confirmed that this is the most probable source of pollution. This study can be considered innovative as these three air pollution monitoring methods were compared, which has never been conducted before, and their comparison gave satisfying results.

Development and characterization of silver modified novel graphitic-carbon nitride (Ag-ZnO/C3N4) coupled with metal oxide photocatalysts for accelerated degradation of dye-based emerging pollutants

Industrial wastewater undesirably affects aquatic life and the environment. One of the main sources of aquatic pollution is organic dyes, which are discharged into the mainstream water without any treatment. Therefore, organic dyes and their derivatives must be degraded by heterogeneous photocatalysts before discharge into wastewater. In this study, we synthesized three different photocatalysts using a low-cost material, i.e., melamine (as a ground material). The photocatalysts, pristine graphitic-carbon nitride (g-C3N4), coupled with zinc oxide (ZnO/C3N4), and modified with a silver (Ag-ZnO/C3N4), were synthesized by the calcination of melamine, following a hydrothermal process. The novel synthesized photocatalysts were characterized by different electro-analytical techniques such as X-ray diffraction (XRD), Transmission Electron Microscopy (TEM), Fourier Transform Infra-red (FT-IR), and Thermogravimetric analysis (TGA). The XRD results reveal the crystalline nature of the synthesized photocatalysts, which increases further with silver modification. TEM analysis discloses that the average particle sizes of ZnO and Ag NPs were 3–5 nm and 20–22 nm, respectively. Where the g-C3N4 displays a 2-D sheet-like structure. The photocatalysts were deeply investigated to study the degradation of organic dyes under UV light for Bromophenol Blue (BBP) and Methylene Blue (MB). Effects of different parameters such as contact time, Dye dose, photocatalyst dose, and pH were also investigated. In all three photocatalysts, Ag-ZnO/C3N4 was the most effective, showing high degradation for both dyes; BPB showed 99.2 percent degradation, whereas in MB the maximum degradation was 97.3 percent. The maximum degradation observed in the pH study was different for both dyes, BPB shows high degradation at pH-1 with 96.8 percent degradation, whereas in MB the maximum degradation is observed at pH-14 with 99.3 percent. The kinetics of the dyes BPB and MB, which follow pseudo-first-order kinetics, were also calculated. In short, the results revealed that the novel g-C3N4 photocatalysts were extremely active in the degradation of target organic dyes, which encourages more work on the degradation of these pollutants from wastewater.

Amsterdam urban water system as entry point of river plastic pollution

Accumulation of plastic litter in aquatic environments negatively impacts ecosystems and human livelihood. Urban areas are assumed to be the main source of plastic pollution in these environments because of high anthropogenic activity. Yet, the drivers of plastic emissions, abundance, and retention within these systems and subsequent transport to river systems are poorly understood. In this study, we demonstrate that urban water systems function as major contributors to river plastic pollution, and explore the potential driving factors contributing to the transport dynamics. Monthly visual counting of floating litter at six outlets of the Amsterdam water system results in an estimated 2.7 million items entering the closely connected IJ river annually, ranking it among the most polluting systems measured in the Netherlands and Europe. Subsequent analyses of environmental drivers (including rainfall, sunlight, wind speed, and tidal regimes) and litter flux showed very weak and insignificant correlations (r = -0.19–0.16), implying additional investigation of potential drivers is required. High-frequency observations at various locations within the urban water system and advanced monitoring using novel technologies could be explored to harmonize and automate monitoring. Once litter type and abundance are well-defined with a clear origin, communication of the results with local communities and stakeholders could help co-develop solutions and stimulate behavioral change geared to reduce plastic pollution in urban environments.

Linking atmospheric emission and deposition to accumulation of soil cadmium in the Middle-Lower Yangtze Plain, China

Cadmium (Cd) is one of the most toxic heavy metals in the environment. Atmospheric deposition has been found to be the main source of Cd pollution of soil on a large scale in China, and identification of the relationships between anthropogenic emission, atmospheric deposition, and Cd accumulation in soil is important for developing ways to mitigate Cd non-point pollution. In this study, the relationship between atmospheric emission, atmospheric deposition, and soil Cd accumulation in the Middle-Lower Yangtze Plain in China was investigated using datasets of atmospheric emission, deposition, and soil accumulation from the literatures published between 2000 and 2020. The results showed that the soil Cd accumulation rate in the study area exceeded the national average (4.0 μg kg–1 yr–1) and continued to accumulate in recent decades, although the average accumulation rate decreased from 9.45 μg kg–1 yr–1 (2000–2010 period) to 8.86 μg kg–1 yr–1 (2010–2020 period). The contribution of atmospheric deposition flux to Cd increment in the soil was in the range of 22–29%, with the atmospheric deposition flux decreasing from 0.54 mg m–2 yr–1 (2000–2010) to 0.48 mg m–2 yr–1 (2010–2020), both values being greater than the national average. Atmospheric Cd deposition and emission were highly correlated in a provincial administrative region, which is close to a ratio of 1.0. Emission factors may be in a state of dynamic change due to the influences of new Cd emission control technologies and environmental policies. As the main sources of Cd emissions, dust, and smoke emissions per ton of non-ferrous metal production decreased by 64.7% between the 2000–2010 and 2010–2020 periods. Although new environmental policies have been instigated, atmospheric emission of Cd is still excessive. It was hoped that the findings of this work would provide a scientific basis for the rational control of atmospheric emissions and Cd pollution of soil.

Biological Treatment of Naphthol Yellow S and Batik Effluent using Aspergillus tamarii and Aspergillus sclerotiorum

Wastes released from the textile dyeing industry contain different hazardous compounds that are difficult to degrade such as azo dyes which are the main source of environmental pollution. Biological treatment processes are a great solution to prevent the environmental pollution caused by wastes because of their environmental friendliness, low cost and minor sludge-giving properties. Fungi are known as mycoremediation in which dyes are eliminated by fungi through biosorption, detoxification and biodegradation. Two fungal isolates Aspergillus tamarii and A. sclerotiorum were isolated from dye-contaminated soil. The maximum decolourization efficiency against 250 ppm dye concentration of Naphthol Yellow S was 87.62% and 89.99% for A. tamarii and A. sclerotiorum respectively at room temperature after 5 days in shaking conditions. The physicochemical characteristics of batik effluent such as BOD, COD, total dissolved solids and total suspended solids had removal percentages of 42.10%, 37.13%, 36.10% and 21.20% for A. tamarii and 37.44%, 42%, 42% and 31.3% for A. sclerotiorum. The removal percentage indicated the potential application of both isolates for biological treatment.

Mercury Biogeochemical Cycle in Yanwuping Hg Mine and Source Apportionment by Hg Isotopes.

Although mercury (Hg) mining activities in the Wanshan area have ceased, mine wastes remain the primary source of Hg pollution in the local environment. To prevent and control Hg pollution, it is crucial to estimate the contribution of Hg contamination from mine wastes. This study aimed to investigate Hg pollution in the mine wastes, river water, air, and paddy fields around the Yanwuping Mine and to quantify the pollution sources using the Hg isotopes approach. The Hg contamination at the study site was still severe, and the total Hg concentrations in the mine wastes ranged from 1.60 to 358 mg/kg. The binary mixing model showed that, concerning the relative contributions of the mine wastes to the river water, dissolved Hg and particulate Hg were 48.6% and 90.5%, respectively. The mine wastes directly contributed 89.3% to the river water Hg contamination, which was the main Hg pollution source in the surface water. The ternary mixing model showed that the contribution was highest from the river water to paddy soil and that the mean contribution was 46.3%. In addition to mine wastes, paddy soil is also impacted by domestic sources, with a boundary of 5.5 km to the river source. This study demonstrated that Hg isotopes can be used as an effective tool for tracing environmental Hg contamination in typical Hg-polluted areas.

The impact of seasonality and meteorological conditions on PM2.5 carbonaceous fractions coupled with carbon isotope analysis: Advantages, weaknesses and interpretation pitfalls

PM2.5 samples were collected from October 2020 to September 2021 in Legnica in the Lower Silesia Voivodeship (SW Poland), where environmental guidelines are often exceeded. In order to have a better insight into the respective inputs of local and regional sources concentrations of PM2.5, carbonaceous fractions (TC/OC/EC), carbon isotope composition (δ13CTC) and FTIR spectra of PM2.5 were studied in parallel. The objectives of this study were to (i) identify the emission sources controlling the local aerosol budget and to (ii) discuss the potential limits of the approach used. We highlighted a seasonality in the concentrations of PM2.5, TC, OC, and EC, with higher concentrations in winter resulting of an increased activity of local emission sources coupled to the occurrence of specific meteorological conditions. While we identified coal burning as the main source of pollution in winter, a mix of emissions from coal and bio/organic combustion and road traffic explains the pollution levels in summer. Coupling these findings with the study of FTIR spectra, we corroborated that incomplete combustion of fossil fuels is a major source in winter whereas biogenic particles are in summer. Despite the observed seasonal variations in the OC and EC concentrations, the OC/EC ratios did not show significant variations. It suggests that this ratio, if used as a single proxy to infer sources of carbonaceous aerosols, may lead to interpretation pitfalls. Our results strongly suggest that a multi-proxy approach that couples TC/OC/EC and FTIR to carbon isotope geochemistry provides a reliable evaluation tool for air quality and brings strong constraints on the corresponding sources of PM2.5.

Performance of olive mill wastewater treatment using hybrid system combining sand filtration and vertical flow constructed wetlands

Olive mill wastewater (OMWW) is a main source of noxious and recalcitrant organic pollutants of significant concern in environmental engineering. For this purpose, the current study assessed the performance of system combining sand filtration and vertical flow constructed wetlands (VF-CWs) in reducing the organic load of OMWW. Sand filter system wed in this study is composed of 6 plastic columns of 0.50 m in diameter and 120 L of capacity. The irrigation of sand filter columns was assured by 50 % diluted OMWW at flow rate of 5 L/day. VF-CWs system consists of a 1 m3 tank filled with soil and gravel in the bottom and planted of Typha latifolia, Phragmites australis and Arundo donax aquatic plants. The irrigation of VF-CWs system was assured with treated OMWW with a flow rate of 20 L twice in the week. Obtained results showed that sand filtration achieved a high removal rate of 76.42, 75.12, 79.7 and 78.10 %, respectively, for total suspended solid (TSS), dissolved COD (chemical oxygen demand), total COD and phenolic compounds. The usage of the combination of sand filter and VF-CWS improved significantly the elimination efficiency of total COD up to 91.44 %, dissolved COD up to 77.09 % and phenolic compounds up to 79.47 %, but it did not report any performance in the removal of TSS. Despite the high performance of hybrid system (sand filter+VF-CWs) in reducing the organic pollution, final effluent concentrations remained below the permitted limits for discharge into a municipal sewer system.

A yearlong monitoring campaign of polycyclic aromatic compounds and other air pollutants at three sites in Sweden: Source identification, in vitro toxicity and human health risk assessment

Air pollution is a complex mixture of gases and particulate matter (PM) with local and non-local emission sources, resulting in spatiotemporal variability in concentrations and composition, and thus associated health risks. To study this in the greater Stockholm area, a yearlong monitoring campaign with in situ measurements of PM10, PM1, black carbon, NOx, O3, and PM10-sampling was performed. The locations included an Urban and a Rural background site and a Highway site. Chemical analysis of PM10 was performed to quantify monthly levels of polycyclic aromatic compounds (PACs), which together with other air pollution data were used for source apportionment and health risk assessment. Organic extracts from PM10 were tested for oxidative potential in human bronchial epithelial cells. Strong seasonal patterns were found for most air pollutants including PACs, with higher levels during the winter months than summer e.g., highest levels of PM10 were detected in March at the Highway site (33.2 μg/m3) and lowest in May at the Rural site (3.6 μg/m3). In general, air pollutant levels at the sites were in the order Highway > Urban > Rural. Multivariate analysis identified several polar PACs, including 6H-Benzo[cd]pyren-6-one, as possible discriminatory markers for these sites. The main sources of particulate pollution for all sites were vehicle exhaust and biomass burning emissions, although diesel exhaust was an important source at the Highway site. In vitro results agreed with air pollutant levels, with higher oxidative potential from the winter samples. Estimated lung cancer cases were in the order PM10 > NO2 > PACs for all sites, and with less evident seasonal differences than in vitro results. In conclusion, our study presents novel seasonal data for many PACs together with air pollutants more traditionally included in air quality monitoring. Moreover, seasonal differences in air pollutant levels correlated with differences in toxicity in vitro.

Analysis of Heavy Metal Pollution in Soil along the Shuimo River by the Grey Relational Method and Factor Analysis

Soil samples were collected from the upstream, midstream and downstream areas of the Shuimo River in three layers of 0–20, 20–40 and 40–60 cm, and each group of sample points was located 5 m, 1 km and 2 km away from the river bank, respectively. The analysis was carried out. Based on the investigation and research, six indicators, including As, Pb, Zn, Cu, Ni and Cr, were designated as evaluation factors in combination with the results of the sample collection with low or no detectable values of Cd and Hg. The mean values of the samples measured in the upper, middle and downstream layers were taken, and the degree and source of pollution were evaluated and jointly analyzed using the gray correlation analysis and factor analysis methods. By using the gray correlation analysis, it was found that the evaluation results of the upstream and middle reaches of the soil along the Shuimo River were both level 3, with slight pollution, and the evaluation results of the downstream areas were level 2, with good soil quality. There are two main sources of pollution obtained through the factor analysis; source 1 is mainly heavy metals such as Zn, Cu, Cr, Pb and Ni, while source 2 is mainly heavy metals such as As, Pb and Ni. The amount of pollution sources is inferred from the heavy metal types of each source and the soil environment along the Shuimo River as industrial and human sources of pollution. From the analysis results, the combination of the gray correlation analysis model and factor analysis model is convenient and fast and can accurately quantify the source contribution of various pollution sources. Not only can it reflect the actual situation more objectively and realistically in the evaluation of soil heavy metal pollution and pollution sources, but also the calculation is simple and easily applied with low data requirements.

The Relationship Between Air Quality, Health Outcomes, and Socioeconomic Impacts of the COVID-19 Pandemic in the US.

COVID-19 lockdowns caused significant improvements in air quality in US states where traffic emissions are the main pollution source. In this study, we investigate the socioeconomic impacts of the COVID-19-related lockdowns in states which experienced the greatest changes in air quality, especially among different demographic populations and those with contraindications to health. We administered a 47-question survey and collected 1,000 valid responses in these cities. Our results show that 74% of respondents within our survey sample had some level of concern regarding air quality. In agreement with previous literature, perceptions of air quality were not significantly correlated with measured air quality criteria butrather seemed to be influenced by other factors. Respondents in Los Angeles were the most concerned about air quality followed by Miami, San Francisco, and New York City. However, those from Chicago and Tampa Bay expressed the least amount of concern about air quality. Age, education, and ethnicity were all factors affecting peoples' concerns about air quality. Respiratory conditions, living in proximity to industrial areas, and financial impacts from the COVID-19 lockdowns influenced concerns about air quality. About 40% of the survey sample reported greater concern for air quality during the pandemic, while approximately 50% stated that the lockdown didn't affect their perception. Furthermore, respondents seemed concerned about air quality in general, not a specific pollutant, and are willing to adopt additional measures and more stringent policies to improve air quality in all investigated cities.

Occurrence and Distribution of Antibiotics in a Tropical Mariculture Area of Hainan, China: Implications for Risk Assessment and Management.

With the rapid global demand for mariculture products in recent years, the use of antibiotics has increased intensively in the mariculture area. Current research on antibiotic residues in mariculture environments is limited, and less information is available on the presence of antibiotics in tropical waters, limiting a comprehensive understanding of their environmental presence and risk. Therefore, this study investigated the environmental occurrence and distribution of 50 antibiotics in the near-shore aquaculture waters of Fengjia Bay. A total of 21 antibiotics were detected in 12 sampling sites, including 11 quinolones, 5 sulfonamides, 4 tetracyclines, and 1 chloramphenicol; the quinolones pyrimethamine (PIP), delafloxacin (DAN), flurofloxacin (FLE), ciprofloxacin (CIP), norfloxacin (NOR), pefloxacin (PEF), enrofloxacin (ENO), and minocycline (MNO) of the tetracycline class were detected in all sampling points. The total antibiotic residue concentrations in the study area ranged from 153.6 to 1550.8 ng/L, the tetracycline antibiotics were detected in the range of 10 to 1344.7 ng/L, and the chloramphenicol antibiotics were detected in the range of 0 to 106.9 ng/L. The detected concentrations of quinolones ranged from 81.3 to 136.1 ng/L, and the residual concentrations of sulfonamide antibiotics ranged from 0 to 313.7 ng/L. The correlation analysis with environmental factors revealed that pH, temperature, conductivity, salinity, NH3--N, and total phosphorus had a strong correlation with antibiotics. Based on PCA analysis, the main sources of antibiotic pollution in the area were determined to be the discharge of farming wastewater and domestic sewage. The ecological risk assessment indicated that the residual antibiotics in the water environment of the near-shore waters of Fengjiawan had certain risks to the ecosystem. Among them, CIP, NOR, sulfamethoxazole (TMP), ofloxacin (OFL), enrofloxacin (ENO), sulfamethoxazole (SMX), and FLE showed medium to high risk. Therefore, it is recommended to regulate the use of these antibiotics and the discharge and treatment of culturing wastewater, and measures should be taken to reduce the environmental pollution caused by antibiotics and to monitor the long-term ecological risk of antibiotics in the region. Overall, our results provide an important reference for understanding the distribution and ecological risk of antibiotics in Fengjiawan.

Hydrochemical characteristics of groundwater in a plain river network region: Establishing linkages between source and water quality variables

The chemical characteristics of groundwater can indicate water quality condition and provide useful information for pollution source identification. This study aimed to understand the effects of dissolved organic matter (DOM) on ionic composition of groundwater and identify the main ions and sources of pollution. The Lake Taihu is a typical eutrophic lake in China. In this study, the hydrochemical composition of groundwater in the surrounding aquifer of Lake Taihu Basin was analyzed. The results showed that the values of water quality index (WQI) range from 13.29 to 56.26 (good water quality). The dominant hydrochemical type of groundwater was Ca–Mg–HCO3 type, and the rock dominance was the major mechanism controlling the groundwater chemistry. With an increasing concentration in dissolved organic carbon (DOC), the Na+, Mg2+, and HCO3– concentrations all showed a sharp increase followed by a slow increase, while the NO3– concentration showed an opposite trend, indicating the DOM can affect the ions composition. In addition, K+ was positively correlated with NO3–, As, and Cd. Hence, DOM input may directly or indirectly change the hydrochemistry of groundwater. Besides, the NO3– concentration in groundwater was much higher than that in Lake Taihu, indicating that the NO3– in groundwater mainly came from surface soil leaching. The anthropogenic sources are probably the main sources of different ions, including K+, NO3–, As, and Cd. This study can help to better understand the effects of lake eutrophication on groundwater and its pathways.

Microbial source tracking identifies sources of contamination for a river flowing into the Yellow Sea.

The excessive input of nutrients into rivers can lead to contamination and eutrophication, which poses a threat to the health of aquatic ecosystems. It is crucial to identify the sources of contaminants to develop effective management plans for eutrophication. However, traditional methods for identifying pollution sources have been insufficient, making it difficult to manage river health effectively. High-throughput sequencing offers a novel method for microbial community source tracking, which can help identify dominant pollution sources in rivers. The Wanggang River was selected for study, as it has suffered accelerated eutrophication due to considerable nutrient input from riparian pollutants. The present study identified the dominant microbial communities in the Wanggang River basin, including Proteobacteria, Actinobacteria, Bacteroidetes, Cyanobacteria, Verrucomicrobia, and Firmicutes. The Source Tracker machine-learning classification system was used to create source-specific microbial community fingerprints to determine the primary sources of contaminants in the basin, with agricultural fertilizer being identified as the main pollutant source. By identifying the microbial communities of potential pollution sources, the study determined the contributing pollutant sources in several major sections of the Wanggang River, including industry, urban land, pond culture, and livestock land. These findings can be used to improve the identification of pollution sources in specific environments and develop effective pollution management plans for polluted river water.

Low-temperature highly selective water delignification based on geopolymer materials

Delignification pretreatment is the main source of high cost and high pollution in biomass processing. This paper reports on a simple cheap geopolymers-based highly selective and efficient pretreatment process for delignification under low-temperature water-cooking without discharging black liquor. The geopolymer with a SiO2/Al2O3 ratio of 4.4 showed the largest number of acidic sites and highest catalytic activity. Under mild reaction conditions (mGeopolymer/mFiber = 1/4, 90 min and 90 °C), the delignification rates of woody (eucalyptus) and herbaceous (bagasse) biomass increased by up to 38.90% and 62.20%, respectively. Moreover, the low-alkali black liquor produced by the new water delignification process facilitates subsequent water treatment, eliminating the need for alkali recovery. This study confirms the immense application prospects of geopolymers for the highly selective delignification of most biomass fibre. This study will develop a low-temperature water-cooking process for the delignification of papermaking or biomass processing without wastewater discharge.

Environmental contamination characteristics of heavy metals from abandoned lead–zinc mine tailings in China

China holds large-scale lead–zinc mineral resources; however, mining activities often cause severe contamination by heavy metals. This study systemically assessed contamination by eight heavy metals (Cu, Zn, Cd, Pb, Cr, Hg, Ni, and As) in mine tailings, soil, and groundwater from 27 contaminated sites across China. Regarding mine tailings, 1% of the mine tailing samples were hazardous waste and 20% were class II non-hazardous waste. Regarding soil, Zn and Pb showed the highest mean concentrations, at 5574.67 mg/kg and 2034.88 mg/kg, respectively. The indexes of geo-accumulation (Igeo) of eight heavy metals ranged from −3.62 to 7.67, while Zn, Pb, and Cd showed the highest environmental risk levels as the priority pollutants. The contamination levels of these heavy metals in groundwater were generally in the order of Zn>As>Pb>Ni>Cd>Cu>Hg>Cr. In this study, 20% of the soil and 10% of the groundwater samples exceeded the corresponding quality limits. The content of heavy metals in soil, groundwater, and mine tailing were positively correlated, demonstrating the main pollution source and transport paths. The pollution levels of heavy metals in soil and groundwater were listed in the foremost and moderate positions compared with similar sites from other countries, respectively. These results may help determine the pollution levels of lead–zinc mining regions and direct the remediation activities of target sites to support the environmental management of abandoned mining and tailing waste in China.

MONITORING OF GROUNDWATER QUALITY IN LISTVYANKA SETTLEMENT (SOUTHWEST COAST OF LAKE BAIKAL)

A systematic monitoring of the hydrosphere is important and necessary to maintain a good ecological status of Lake Baikal. The article presents the results of a five-year monitoring of the groundwater and surface waters quality in Listvyanka settlement. The goal is to determine the contamination level of drinking water supply system. In the field studies, portable measurement devices were used for monitoring temperature, pH, Eh, electrical water conductivity and water levels in wells, and water samples were taken for a complete chemical analysis. The analysis of the macrocomponent composition of water was carried out by various methods (flame photometry, volumetric titration, weight method, colorimetry) at the Center for Geodynamics and Geochronology of the Institute of the Earth’s Crust SB RAS (Irkutsk); the trace element composition was determined by the ICP MS method on the Element-2 device (Finnigan MAT, Germany) at the Institute of Geochemistry SB RAS (Irkutsk); microbiological analysis of water samples was performed at the Irkutsk Interregional Veterinary Laboratory; the analysis of isotope characteristics (δ 18O and δD) of water samples was performed in the Laboratory of Hydrogeology of the Institute of the Earth’s Crust SB RAS (Irkutsk) on a Picarro L2140-i gas analyzer.The results obtained indicate a change in macrocomponent composition of waters and an uneven distribution of pollutants over the area. The content of 42 trace elements in groundwater and river waters generally does not exceed the regulatory requirements for drinking water; the exceptions are Fe and Mn. Ten wells do not meet the sanitary and epidemiological rules and norms SanPiN 2.1.4.1074-01. The main sources of groundwater pollution are leaking septic tanks of numerous hotel complexes located in the valleys and on the valley slopes. The processes of water pollution and restoration of natural regime of water are of different intensity. For groundwater and river waters, there were determined the relative concentrations of stable isotopes of hydrogen and oxygen (δD and δ18О), and δD=5.5307·δ18 O–31.815 relationship and the deuterium excess values were obtained. Characteristics δD and δ18 O are the bases of the isotope database for the aquatic environment of Listvyanka settlement.

Evaluation of water quality pollution and analysis of vertical distribution characteristics of typical Rivers in the Pearl River Delta, South China

Water quality comprehensive evaluation is an essential technical measure for water environment management and treatment. The previous research methods were often insufficient for studying black-sticking water bodies' formation and transformation mechanisms. In view of this, the single pollution index method and the comprehensive water quality identification index method (Iwq) were used to evaluate the pollution characteristics of rivers; the main pollution factors and sources of the watershed were determined by principal component analysis (PCA), and the vertical stratification characteristics of the water bodies were analyzed. The results showed that the total nitrogen (TN) values of pollutants in typical rivers in the Pearl River Delta were higher than the class V water quality standard, and the ammonia nitrogen (NH3−N) pollution level was the second-highest. TN concentration ranges from 4.27 to 19.83 mg/g, and NH3-N concentration ranges from 2.44 to 15.37 mg/g. In addition, in the monitoring of 15 rivers, 11 of them were the inferior V surface water, including five rivers' comprehensive water quality categories for black-stinking water bodies. This may be related to the process of water self-purification and pollutant transport, and rivers in densely populated areas are often subject to discharge from domestic sewage and industrial sewage. The results of the PCA extracted three principal components (PC), accounting for 88.825% of the total variance, with the first and third PCs controlled by human activities and the second PC influenced by natural sources. There is a more apparent vertical stratification of water bodies here in the typical rivers of the Pearl River Delta, and DO was an important factor affecting the vertical distribution of chemical oxygen demand (COD), NH3-N, TN, total phosphorus (TP), sulfide, Ferrum (Fe), and manganese (Mn). The severe lack of DO in deep water bodies led to elevated levels of NH3-N, Fe, and Mn, and gases such as hydrogen sulfide was released under anaerobic conditions, resulting in eutrophication and black-sticking levels in water bodies.

On the effectiveness of tributyltin ban part II: Temporal and spatial trends of organotin pollution in intense sediment accumulation areas and dumping sites of the Baltic Sea

Based on the knowledge gained from our previous study, our aim is to observe the current levels of butyltin (BTs) pollution, changes during different seasons, and the factors that affect these trends in the areas of highest concern. These areas include semi-enclosed bays in the Port that were previously affected by large tributyltin (TBT) inputs, as well as the dumping sites of dredged sediment in the Baltic Sea. Compared to previous studies, there has been a significant decrease in the levels of BTs in the Klaipeda Port. However, the sediment in the semi-enclosed bays still contained BTs, ranging from less than 0.5 ng Sn g−1 dw to as high as 728.5 ng Sn g−1 dw. Some BTs were also detected in the currently exploited dumping sites of the Baltic Sea. Moreover, butyltin degradation index (BDI) revealed occasional fresh TBT input or slow degradation both in the Port and in the Sea. Some trends in butyltin concentrations were indicative of the impact of climate change in Lithuania, which are consistent with global trends. We also found that variations in BTs concentrations were closely related to dredging and cleaning activities taking place in the Klaipeda Port. Correlation, principal component, and cluster analysis revealed close relationship between TBT and its degradation products, as well as between TBT and Zn, Pb, Cu. Ship cleaning/maintenance activities were identified as the main source of pollution in the study area. Despite the gradually decreasing BTs concentration in the Klaipeda Port, the problem is not yet completely solved.

Microplastics discharged from urban drainage system: Prominent contribution of sewer overflow pollution

Urban drainage system is an important channel for terrigenous microplastics (<5 mm in size) to migrate to urban water bodies, especially the input load caused by overflow pollution in wet weather. Investigating how they transport and discharge is essential to better understand the occurrence and variability of microplastics in different water ecosystems. This study evaluated the abundance and distribution characteristics of microplastics in the drainage systems of typical coastal cities in China. The impacts of meteorological conditions and land use were explored. In particular, the prominent contribution of drainage sewer overflow pollution during storm events were investigated. The results showed that the microplastics abundance in daily sewage discharge from different drainage plots ranged between 13.6 and 30.8 items/L, with fibers as the dominant type of microplastics. Sewer overflow discharge can greatly aggravate microplastic abundance to 83.1 ± 40.2 items/L. Road runoff and sewer sediment scouring were the main pollution sources. Systematic estimates based on detailed data showed that the average microplastics emitted per capita per day in household wastewater was 3461.5 items. A quantitative estimation method was proposed to show that the annual emissions load of microplastics via urban drainage system in this research area was 5.83×1010 items/km2, of which the proportion of emissions in wet weather accounted for about 60%. This research provides the first full-process of assessment and source apportionment of the microplastic distribution characteristics in old drainage system. The occurrence of storm events is an important marker of increased microplastic abundance in urban rivers, with a view to urgent need for interception of surface runoff and purification of sewer overflow pollution.