Magneto-optical Spectra Research Articles

Manipulation of anisotropic Zhang-Rice exciton in NiPS3 by magnetic field

The effect of external magnetic fields on the behavior of the Zhang-Rice exciton in NiPS3, which captures the physics of spin-orbital entanglement in 2D XY-type antiferromagnets, remains unclear. This study presents systematic study of angle-resolved and polarization-resolved magneto-optical photoluminescence spectra of NiPS3 in the Voigt geometry. We observed highly anisotropic, non-linear Zeeman splitting and polarization rotation of the Zhang-Rice exciton, which depends on the direction and intensity of the magnetic field and can be attributed to the spin-orbital coupling and field-induced spin reorientation. Furthermore, above the critical magnetic field, we detected additional splitting of the exciton peaks, indicating the coexistence of various orientations of Néel vector. This study characterizes orbital change of Zhang-Rice exciton and field-induced spin-reorientation phase transitions in a 2D hexagonal XY-type antiferromagnet, and it further demonstrates the continuous manipulation of the spin and polarization of the Zhang-Rice exciton.

MAGNETO-OPTICAL KERR SPECTROSCOPY OF (СD 3 AS 2)100-X (MNAS) X COMPOSITES

Composite Films (Сd3As2)100-X(MnAs)X on silicon and sitall substrates with a concentration of Mn 5.8-16.4 at.% were obtained by vacuum-thermal evaporation. The structural properties of the films were investigated by X-ray phase analysis and scanning electron microscopy. Magneto-optical properties were studied by the method of the equatorial Kerr e ect (EEC) in the energy range of 0.5-4.0 eV in magnetic elds with a strength of up to 3 kE at a temperature of 20-300 K. In the geometry of the equatorial Kerr effect, spectral, field and temperature dependences of the EEC are obtained. The analysis of experimental data showed that with a Mn content of more than 12.9 at.% of the films contain the α′′-phase of the topological Dirac semimetal Cd3As2 in the form of large granules, as well as ferromagnetic MNAs granules. The Curie temperature of lms depends on the Mn content in them and is less than the temperature of bulk samples ofMPas. When the Mp content in the lm is 5.8 at.% and 6.4 at.%, the magneto-optical response is not detected, which indicates the formation of a superparamagnetic state or a spin glass state at low concentrations of Mn. With a film content of Mn 9.9 at%. A signi cant change in magneto-optical spectra was detected, which indicates the formation of MNAs nanoclusters and partial dissolution of Mn in the Cd3As2 matrix.

Magnitoopticheskaya kerr-spektroskopiya nanokompozitov

Magnetooptical spectroscopy is an effective method for studying the magnetic microstructure of homogeneous and heterogeneous magnets. This review is devoted to analysis of numerous factors affecting the intensity and spectral dependence of a magnetooptical signal of the equatorial Kerr effect in nanocomposites “ferromagnetic metal–dielectric” in the visible and near infrared spectral regions. Examples of the influence of the metal concentration, nanoparticle size and shape, the substrate, the material of the dielectric, the amorphization of grains, the deposition method, and other factors on the magnetooptical spectrum are considered. The differences in the magnetooptical spectra for the superparamagnetic, superferromagnetic, and ferromagnetic states are demonstrated. It is noted that in the presence of fractions with different field dependences of the magnetization in a nanocomposite, the magnetooptical signal is not proportional to the total magnetization. Examples of enhancement and sign inversion of the magnetooptical signal in nanocomposites are considered. The possibility of the description of magnetooptical spectra using the methods of the effective medium (the Bruggeman method and the Maxwell–Garnett symmetrized approximation) is discussed.

Effect of granule sizes on magneto-optical spectra of nanocomposites

The magneto-optical transverse Kerr effect (TKE) spectroscopy allows non-contact investigation of nanostructures, giving valuable information about the microstructure of samples. In this paper, within the framework of effective medium approach we analyze the effect of granule size on the magneto-optical spectra of magnetic nanocomposites. We consider the influence of various microscopic parameters such as plasma frequency, relaxation time, the coefficient of the anomalous Hall effect inside the granule and on its surface on the amplitude and profile of the TKE spectrum. Three main mechanisms are considered: the quasi-classical size effect, spin–orbit interaction enhancement at the granule surface and change of the percolation threshold.

Structural, Magnetic, and Magneto-Optical Properties of Thin Films of BaM Hexaferrite Grown by Laser Molecular Beam Epitaxy.

Thin films of BaM hexaferrite (BaFe12O19) were grown on α-Al2O3(0001) substrates by laser molecular beam epitaxy. Structural, magnetic, and magneto-optical properties were studied using medium-energy ion scattering, energy dispersive X-ray spectroscopy, atomic force microscopy, X-ray diffraction, magneto-optical spectroscopy, and magnetometric techniques, and the dynamics of magnetization by ferromagnetic resonance method. It was shown that even a short time annealing drastically changes the structural and magnetic properties of films. Only annealed films demonstrate magnetic hysteresis loops in PMOKE and VSM experiments. The shape of hysteresis loops depends on thickness of films showing practically rectangular loops and high value of remnant magnetization (Mr/Ms~99%) for thin films (50 nm) and much broader and sloped loops in thick (350-500 nm) films. The magnitude of magnetization 4πMs ≈ 4.3 kG in thin films corresponds to that in bulk BaM hexaferrite. Photon energy and sign of bands in magneto-optical spectra of thin films correspond to ones observed earlier in bulk samples and films of BaM hexaferrite. FMR spectra of 50 nm films at 50 GHz consist of a number of narrow lines. The width of main line ΔH~20 Oe is lower than has been reported up to now.

Transient magneto-optical spectrum of photoexcited electrons in the van der Waals ferromagnet Cr2Ge2Te6

Femtosecond optical control of magnetic materials shows promise for future ultrafast data storage devices. To date, most studies in this area have relied on quasimonochromatic light in magneto-optical pump-probe experiments, which limited their ability to probe semiconducting and molecule-based materials with structured optical spectra. Here, we demonstrate the possibility of extracting the magneto-optical spectrum of the electrons in the conduction band in the two-dimensional van der Waals ferromagnet ${\mathrm{Cr}}_{2}{\mathrm{Ge}}_{2}{\mathrm{Te}}_{6}$ (CGT), which is made possible due to broadband probing in the visible spectrum. The magneto-optical signal is a sum of contributions from electrons in the conduction and valence bands, which are of opposite sign for CGT. Depending on the probe wavelength used, this difference could lead to an erroneous interpretation that the magnetization direction is reversed after excitation, which has important consequences for understanding spin toggle switching phenomena.

Field-induced chiral transitions in the Weyl semimetal TaP

The chiral anomaly effect has been regarded as a hallmark of Weyl semimetals. While most research focuses on the change of electrical conductivity due to the chiral charge-pumping effect, these transport measurements are accompanied by other effects such as weak antilocalization which are difficult to exclude. Also, the magnetic field intensity at which the energy dispersion of the Landau level starts to display the chiral anomaly effect is hard to identify. Here, we report the evolutionary process of the energy dispersion of the zeroth Landau level under increasing magnetic fields, and we elucidate the relationship between the chiral Landau level and the Fermi level via magneto-optical measurements in Weyl semimetal TaP. Two series of Landau-level transitions have been extracted and fitted well to a massless Weyl fermion model and a classical semiconductor model, respectively. The field-induced chiral Landau-level transition is obtained from a comparison between the spectra under Voigt geometry and Faraday geometry in an increasing magnetic field. The chiral nature of the zeroth Landau level is found to enhance with the increase of magnetic field and clearly manifests in the magneto-optical spectrum above 13 T. The state transition of the zeroth Landau level can be explained by the strength of the field-induced chiral anomaly effect and the position of the Fermi level. These magneto-optical results unveil the chiral Landau-level transitions in TaP, which serves as an ideal material platform to analyze the chiral anomaly effect.

Magneto-optical spectroscopy of GaSb–MnSb composites

Polycrystalline samples of (GaSb)100 – x(MnSb)x composites with x = 69.2, 52.0 and 31.7 mol %, MnSb, Mn2Sb compounds were synthesized and their magneto-optical properties in the equatorial (transverse) Kerr effect geometry were studied. The difference of magneto-optical spectra for related compounds MnSb and Mn2Sb is shown. The anomalous temperature behavior of the magneto-optical signal in the composites and MnSb with decreasing temperature is associated with a redistribution of the population of d-states with the opposite spin index.

Magneto-Optical Spectroscopy of Nanocomposites (CoFeB)x(LiNbO3)100 – x with Concentrations up to the Percolation Threshold: From Superparamagnetism and Superferromagnetism to Ferromagnetism

Nanocomposites (CoFeB)x(LiNbO3)100 – x with x = 17–48 at % have been synthesized by ion beam sputtering of a composite target comprised of Co40Fe40B20 and LiNbO3 onto silicon substrates, and the tran-sitions from the superparamagnetic state to the superferromagnetic and ferromagnetic states with an increase in the concentration of the magnetic component are studied by magneto-optical methods. The magneto-optical properties have been investigated in the geometry of the equatorial (transverse) Kerr effect (TKE). Magneto-optical spectra are recorded in the range of 0.5–4.0 eV in fields up to 2.5 kOe at 20–300 K, field and temperature dependences of the TKE at certain wavelengths are obtained, and the domain structure during magnetization reversal is visualized using a magneto-optical Kerr microscope. It is shown that the sample with x = 17 at % is superparamagnetic at temperatures above the blocking temperature (about 30 K). The interaction between the granules is considerable already at x = 20 at %, the transition to the superferro-magnetic state occurs at x ≈ 32–36 at %, and the transition to the ferromagnetic state occurs at x ≈ 44 at %near the metal–dielectric transition, i.e., at a concentration below the percolation transport threshold.

Magneto-Optical Spectroscopy of Nanocomposites (CoFeB)x(LiNbO3)100 –x with Concentrations up to the Percolation Threshold: From Superparamagnetism and Superferromagnetism to Ferromagnetism

Nanocomposites (CoFeB)x(LiNbO3)100 –x with x = 17–48 at % have been synthesized by ion beam sputtering of a composite target comprised of Co40Fe40B20 and LiNbO3 onto silicon substrates, and the transitions from the superparamagnetic state to the superferromagnetic and ferromagnetic states with an increase in the concentration of the magnetic component are studied by magneto-optical methods. The magneto-optical properties have been investigated in the geometry of the equatorial (transverse) Kerr effect (TKE). Magneto-optical spectra are recorded in the range of 0.5–4.0 eV in fields up to 2.5 kOe at 20–300 K, field and temperature dependences of the TKE at certain wavelengths are obtained, and the domain structure during magnetization reversal is visualized using a magneto-optical Kerr microscope. It is shown that the sample with x = 17 at % is superparamagnetic at temperatures above the blocking temperature (about 30 K). The interaction between the granules is considerable already at x = 20 at %, the transition to the superferromagnetic state occurs at x ≈ 32–36 at %, and the transition to the ferromagnetic state occurs at x ≈ 44 at % near the metal–dielectric transition, i.e., at a concentration below the percolation transport threshold.

Electro- and magneto- optical properties of edge states in bilayer black phosphorene quantum dots

We theoretically investigate the electronic and optical properties of stacked bilayer black phosphorus (BBPs) quantum dots (QDs) with three typical BBPs configurations and two AB-stacking with different edge structures, using the tight-binding (TB) method. Our calculation results show that the energy levels can be affected by the different stacking configurations of BBPs. Unlike the monolayer black phosphorus (MBP), the strong inter-layer coupling in AC-stacked BBP and unsymmetrical distribution in AB-stacked BBP will enhance the optical transitions and realize a dark-to-bright transition in the electro and magneto-optical absorption spectra. The coupling strength of the edge states of different configurations is different, resulting in the difference of the properties of the three stacking configurations, which provides a feasible idea for modulating the electronic and optical properties of BBPs.

Anisotropic magneto-optical transport properties in black phosphorus induced by in-plane magnetic field

We study the Landau levels and magneto-optical properties of bulk black phosphorus (BP) subjected to an in-plane magnetic field along the armchair direction based on an effective Hamiltonian. We analytically obtain the Landau levels by the perturbation method, which agrees well with the results of numerical diagonalization. By using the Kubo formula, we find the magneto-optical transition selection rules and conductance spectra for inter-band transitions are highly anisotropic. In particular, for linearly polarized light along the armchair direction, the magneto-optical transition selection rule is = 0, where n is the Landau level index. However, for linearly polarized light along the zigzag and stacking direction, the magneto-optical transition selection rules become = ±1. The magneto-optical conductance excited by linearly polarized light along the armchair direction is two order of magnitude larger than those excited by linearly polarized light along the zigzag and stacking direction because the inter-band coupling only exists in the armchair direction. Our results are useful to detect the band parameters of BP and design magnetically controlled optical devices based on it.

Effects of tilted Dirac cones and in-plane electric field on the valley-dependent magneto-optical absorption spectra in monolayer 8–Pmmn borophene

We investigate the optical absorption properties in a 8-Pmmn borophene monolayer with anisotropic tilted Dirac cones, subjected to a perpendicular magnetic field and in-plane dc electric field (EF). Numerical results for the magneto-optical absorption coefficient (MOAC) show that the tilt of the Dirac cones causes the redshift of absorption peaks. More interestingly, there appears minor absorption peaks corresponding to the transitions between the Landau levels (LLs) n and n±2 beside the principal maxima corresponding to the transitions between LLs n and n±1. These minor peaks are absent in other two-dimensional Dirac materials with non-titled Dirac cones. The simultaneous presence of in-plane EF and the tilt parameter in 8–Pmmn borophene lifts the valley degeneracy in the LLs and causes the valley polarization in the MOAC, that do not occur in the absence of in-plane EF and/or the tilt parameter. The valley-polarized MOAC opens up potential applications in valleytronics.

Tunable broadband transmittance and Faraday effect in a magnetophotonic nanostructure with gradient thickness.

We propose a magnetic photonic crystal (MPC) nanostructure with a gradient thickness of the magnetic layer. Such a nanostructure exhibits on-the-fly adjustment of optical and magneto-optical (MO) properties. Spatial displacement of the input beam allows tuning of the spectral position of the defect mode resonance in the bandgap of both transmission and magneto-optical spectra. Meanwhile, by varying the diameter of the input beam or its focus one can control the resonance width in both optical and magneto-optical spectra.

Magneto-optical Kerr spectra of gold induced by spin accumulation

We report the magneto optic Kerr effect (MOKE) angle of Au magnetically excited by spin accumulation. We perform time resolved polar MOKE measurements on Au/Co heterostructures. In our experiment, the ultrafast optical excitation of the Co drives spin accumulation into an adjacent Au layer. The spin accumulation, together with spin-orbit coupling, leads to non-zero terms in the off-diagonal conductivity tensor of Au, which we measure by recording the polarization and ellipticity of light reflected from the Au surface for photon energies between 1.3 and 3.1 eV. At energies near the interband transition threshold of Au, the Kerr rotation per A/m exceeds 1 urad. Typical values for Kerr rotation per moment in transition ferromagnetic metals like Ni are < 10 nrad per A/m, while predicted values for heavy metals like Pt or W are < 13 nrad per A/m. The exceptional sensitivity of the optical properties of Au to spin magnetic moments make Au to be an exceptionally sensitive optical magnetometer, with potential applications in the development of optospintronic technologies.

Anomalous Magneto-Optical Response and Chiral Interface of Dipolar Excitons at Twisted Valleys.

An anomalous magneto-optical spectrum is discovered for dipolar valley excitons in twisted double-layer transition metal dichalcogenides, where the in-plane magnetic field induces a sizable multiplet splitting of exciton states inside the light cone. Chiral dispersions of the split branches make possible an efficient optical injection of the unidirectional exciton current. We also find an analog effect with a modest heterostrain replacing the magnetic field for introducing large splitting and chiral dispersions in the light cone. Angular orientation of the photoinjected exciton flow can be controlled by strain, with left-right unidirectionality selected by circular polarization.

Geometry tailored magneto-optical absorption spectra of elliptically deformed double quantum rings

ABSTRACT We theoretically investigated the effect of the geometry change on the electronic and magneto-optical absorption spectra of GaAs/Ga0.7Al0.3As double quantum rings. The inner ring shape was changed continuously from circular to elliptic. Our numerical results revealed the decrement of the levels energies with the augments of the eccentricity of the internal/external ellipses that limit the inner ring, leading to a blue shift of the maxima in the absorption spectra in the magnetic field absence. Analysing separately the electronic spectra of the inner/outer single rings and of the double quantum rings structure in the magnetic field, we have found that, in the electronic spectra of the double ring, only the energies and the Aharonov–Bohm periodicity of the outer ring are altered by interference, while the Aharonov–Bohm oscillations of the inner ring levels propagate unchanged in the spectra. The magneto-optical spectra of elliptically deformed double quantum rings cover a wider range of energies than those of circular double ring and, at higher magnetic fields, present new peaks corresponding to transitions to higher states. Also, they show superposed peaks of increased absorption for a particular elliptic geometry and a red-shift of low energy maxima at the augment of the magnetic field which is the more pronounced the eccentricity increases. Moreover, the influence of the temperature is stronger than for the symmetrical structure.

Unconventional Landau level transitions in Weyl semimetal NbP

Weyl semimetals were experimentally discovered as a new quantum phase of matter that exhibits topologically protected states characterized by separated Weyl points. Similar to other topological materials, the research of Landau level transitions can provide abundant information on Fermi surfaces. Extensive experimental efforts on low-temperature transport and optical properties have been dedicated to investigating the nontrivial topology structure. However, there are some theoretically predicted unconventional Landau level transitions in Weyl semimetals that have not been observed experimentally. And, their contribution to the electromagnetic response of Weyl semimetal remains elusive. Here, we report the magneto-optical study of Landau quantization and selection rules in Weyl semimetal NbP under Voigt geometry. By changing the direction of the electric vector of the incoming light under Voigt and Faraday geometry, abundant Landau level transition modes which contain $\mathrm{\ensuremath{\Delta}}=0$, \ifmmode\pm\else\textpm\fi{}1, \ifmmode\pm\else\textpm\fi{}2 selection rules are obtained. The richness of the optical spectra, particularly the ones from the Voigt geometry, allows us to determine the location of Fermi energy and its evolution with magnetic fields. We further extract the transitions between Landau levels and Fermi energy and deduce the Landau index. Our results reveal the track of Fermi energy under varying magnetic fields based on the Landau level transitions under Voigt geometry and suggest that a combination of the magneto-optical spectra under Voigt and Faraday geometry can effectively determine the key properties of topological materials that are otherwise inaccessible.

Observation of optical gyromagnetic properties in a magneto-plasmonic metamaterial

Metamaterials with artificial optical properties have attracted significant research interest. In particular, artificial magnetic resonances with non-unity permeability tensor at optical frequencies in metamaterials have been reported. However, only non-unity diagonal elements of the permeability tensor have been demonstrated to date. A gyromagnetic permeability tensor with non-zero off-diagonal elements has not been observed at the optical frequencies. Here we report the observation of gyromagnetic properties in the near-infrared wavelength range in a magneto-plasmonic metamaterial. The non-zero off-diagonal permeability tensor element causes the transverse magneto-optical Kerr effect under s-polarized incidence that otherwise vanishes if the permeability tensor is not gyromagnetic. By retrieving the permeability tensor elements from reflection, transmission, and transverse magneto-optical Kerr effect spectra, we show that the effective off-diagonal permeability tensor elements reach 10−3 level at the resonance wavelength (~900 nm) of the split-ring resonators, which is at least two orders of magnitude higher than magneto-optical materials at the same wavelength. The artificial gyromagnetic permeability is attributed to the change in the local electric field direction modulated by the split-ring resonators. Our study demonstrates the possibility of engineering the permeability and permittivity tensors in metamaterials at arbitrary frequencies, thereby promising a variety of applications of next-generation nonreciprocal photonic devices, magneto-plasmonic sensors, and active metamaterials.

First-principles insight into all-optical spin switching in the half-metallic Heusler ferrimagnet Mn2RuGa

All-optical spin switching (AOS) represents a new frontier in magnetic storage technology -- spin manipulation without a magnetic field, -- but its underlying working principle is not well understood. Many AOS ferrimagnets such as GdFeCo are amorphous and renders the high-level first-principles study unfeasible. The crystalline half-metallic Heusler Mn$_2$RuGa presents an opportunity. Here we carry out hitherto the comprehensive density functional investigation into the material properties of Mn$_2$RuGa, and introduce two concepts - the spin anchor site and the optical active site - as two pillars for AOS in ferrimagnets. In Mn$_2$RuGa, Mn$(4a)$ serves as the spin anchor site, whose band structure is below the Fermi level and has a strong spin moment, while Mn$(4c)$ is the optical active site whose band crosses the Fermi level. Our magneto-optical Kerr spectrum and band structure calculation jointly reveal that the delicate competition between the Ru-$4d$ and Ga-$4p$ states is responsible for the creation of these two sites. These two sites found here not only present a unified picture for both Mn$_2$RuGa and GdFeCo, but also open the door for the future applications. Specifically, we propose a Mn$_2$Ru$_x$Ga-based magnetic tunnel junction where a single laser pulse can control magnetoresistance.