Magnetostriction measurements, between ≈5 and 300 K, of powder magnetically aligned samples of the hexagonal compound NdCo 5, in strong pulsed magnetic fields up to 15 T are reported. The measurement have been performed parallel, perpendicular and at 45° to the alignment c-axis, for the field also applied in those directions. This set of measurements allows us to determine the six irreducible magnetoelastic modes: λ α 11, λ α 21, related to the strain dependence of the isotropic exchange, and λ α 12, λ α 22, λ γ, λ ϵ, related to the strain dependence of the crystalline field anisotropy energy. Anomalies on the strains, associated with the spin reorientation (SR) regime are observed, in particular at the temperatures of beginning, T SR1, and end, T SR2, of the SR. The thermal variation of the strains is explained by the standard magnetostriction model, including an ingredients: exchange striction (varying as m 2 Nd), single-ion anisotropy (varying as m 3 Nd), (where m Nd is the reduc ed Nd sublattice magnetization), as well as an angular dependence of the form {sin 2θ( H, T)−sin 2θ(0, T)}, where θ( H, T) and θ(0, T), respectively, are the SR angles under field and spontaneous. The irreducible magnetoelastic coupling constants at 0 K have been estimated, although the point charge model is far from agreement with those results.
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