Magnetic Measurements Research Articles

Noncollinear Magnetic Structures in the Chiral Antiperovskite β-Fe2SeO.

We present the magnetic properties of the chiral, polar, and possibly magnetoelectric antiperovskite β-Fe2SeO as derived from magnetization and specific-heat measurements as well as from powder neutron diffraction and Mössbauer experiments. Our macroscopic data unambiguously reveal two magnetic phase transitions at TN1 ≈ 103 K and TN2 ≈ 78 K, while Rietveld analysis of neutron powder diffraction data reveals a noncollinear antiferromagnetic structure featuring magnetic moments in the a-b plane of the trigonal structure and a ferromagnetic moment along c. The latter is allowed by symmetry between TN1 and TN2, weakly visible in the magnetization data yet unresolvable microscopically. While the intermediate phase can be expressed in the trigonal magnetic space group P31, the magnetic ground state is modulated by a propagation vector q = (1/2 1/2 0) resulting in triclinic symmetry and an even more complex low-temperature spin arrangement which is also reflected in the Mössbauer hyperfine patterns indicating additional splitting of Fe sites below TN2. The complex noncollinear spin arrangements suggest interesting magnetoelectric properties of this polar magnet.

WMH Contributions to Cognitive Impairment: Rationale and Design of the Diverse VCID Study.

As awareness of dementia increases, more individuals with minor cognitive complaints are requesting clinical assessment. Neuroimaging studies frequently identify incidental white matter hyperintensities, raising patient concerns about their brain health and future risk for dementia. Moreover, current US demographics indicate that ≈50% of these individuals will be from diverse backgrounds by 2060. Racial and ethnic minority populations bear a disproportionate burden of vascular risk factors magnifying dementia risk. Despite established associations between white matter hyperintensities and cognitive impairment, including dementia, no study has comprehensively and prospectively examined the impact of individual and combined magnetic resonance imaging measures of white matter injury, their risk factors, and comorbidities on cognitive performance among a diverse, nondemented, stroke-free population with cognitive complaints over an extended period of observation. The Diverse VCID (Diverse Vascular Cognitive Impairment and Dementia) study is designed to fill this knowledge gap through 3 assessments of clinical, behavioral, and risk factors; neurocognitive and magnetic resonance imaging measures; fluid biomarkers of Alzheimer disease, vascular inflammation, angiogenesis, and endothelial dysfunction; and measures of genetic risk collected prospectively over a minimum of 3 years in a cohort of 2250 individuals evenly distributed among Americans of Black/African, Latino/Hispanic, and non-Hispanic White backgrounds. The goal of this study is to investigate the basic mechanisms of small vessel cerebrovascular injury, emphasizing clinically relevant assessment tools and developing a risk score that will accurately identify at-risk individuals for possible treatment or clinical therapeutic trials, particularly individuals of diverse backgrounds where vascular risk factors and disease are more prevalent.

Analyzing Pulse Compression Performance and Image Quality Metrics of Different Excitations in MAET With Magnetic Field Measurements.

This study investigates the pulse compression technique to improve the performance of magneto-acousto-electrical tomography (MAET) with magnetic field measurements through numerical studies. Emphasizing the effects of specific coil configuration on MAET measurements, the study conducts evaluations using a linear phased array (LPA) transducer and numerical breast models with tumor inclusion. It provides feasibility and a detailed comparative analysis of various excitations, including linear frequency modulated (LFM), Barker code, and Golay code excitations in MAET. To simulate experimental conditions, additive White Gaussian noise is added to the MAET signal detected by the receiver coils. The results obtained from the LPA steering angle at 0° and the reconstructed B-mode MAET images using the pulse compression technique lead to improvements compared with conventional single-cycle excitation. The computed mean signal-to-noise ratio (SNR) improvements for LFM, Barker code, and Golay code excitations in B-mode MAET images for 10,000 iterations are 7.42, 8.36, and 8.44 dB, respectively, compared with single-cycle excitation. Similarly, the mean contrast-to-noise ratio (CNR) improvements for these excitations in B-mode MAET images are 1.43, 1.63, and 1.9 dB, respectively. The results demonstrate that Golay code is superior in CNR and image quality metrics, while Golay and Barker codes have comparable SNR and outperform LFM. The research shows that the coil configuration significantly impacts tumor detection. With Golay code excitation, detecting a tumor as small as 5 mm × 2 mm at a depth of 33 mm with an SNR of 6.38 dB is possible, achieving an axial resolution of 2 mm.

Drastic enhancement of electronic correlations induced by hydrogen insertion in the cerium intermetallic compound CeFeSi.

We report a comparative study of two cerium-based intermetallic compounds: CeFeSi with an anti-PbFCl type structure, and CeFeSiH with a ZrCuSiAs type structure. The latter is obtained from CeFeSi through hydrogen insertion. Our results are based on X-rays, transport, thermodynamic and magnetic measurements. While the tetragonal structure with P4/nmm symmetry remains unchanged after hydrogen insertion, the thermodynamic, magnetic, and transport properties change drastically. On the one hand, CeFeSi behaves as a Pauli paramagnet with a small Sommerfeld coefficient, indicating the absence of 4f electron physics. On the other hand, our study shows that CeFeSiH exhibits strong magnetic fluctuations with a magnetic transition at 3.5 K, and coherent Kondo-lattice heavy-fermion features.

Numerical study of a tapered fiber magnetic field sensor based on the ENZ mode

This study introduces what we believe to be a novel magnetic field sensor that utilizes a tapered optical fiber coated with indium tin oxide (ITO) and titanium dioxide (TiO2), operating on an epsilon-near-zero (ENZ) mode. The evanescent field around the tapered optical fiber can excite the ENZ mode of the ITO film, and the TiO2 layer can ensure the phase matching between the fiber core mode and the ENZ mode. The sensor, immersed in magnetic fluid, leverages the unique properties of ENZ materials to achieve a high sensitivity and resolution in the near-infrared (NIR) region. Through a simulation, the sensor demonstrated a maximum sensitivity of 6900 nm/RIU and a magnetic field sensitivity of 370 pm/Oe. The findings suggest that ENZ mode-based optic sensing presents a promising alternative to traditional plasmonic sensing methods, offering potential applications in various fields requiring precise magnetic field measurements.

A Nanosized {NiII18} Cluster with a 'Flying Saucer' Topology Exhibiting Slow Relaxation of Magnetisation Phenomena at Both 15 K and 1.3 K.

A high-nuclearity {Ni18} complex (1) with a unique 'flying saucer' motif has been prepared from the organic chelate, α-methyl-2-pyridine-methanol (mpmH), in conjunction with bridging azido (N3-) and peroxido (O22-) ligands. Magnetic susceptibility measurements revealed the presence of both ferro- and antiferromagnetic exchange interactions between the metal centres in 1, and the stabilization of spin states with appreciable S values at two different temperature regimes. The end-on bridging azido and alkoxido groups are in all likelyhood the ferromagnetic mediators, while the η3:η3:μ6-bridging peroxides most likely promote the antiparallel alignment of the metals' spin vectors, yielding an overall non-zero spin ground state for the centrosymmetric compound 1. Furthermore, the {Ni18} nanosized cluster behaves as a single-molecule magnet, exhibiting magnetic hysteresis at low temperatures and two relaxation processes at 15 K and 1.3 K, a very rare phenomenon in polynuclear magnetic 3d-metal clusters.

Magnetoelectric Coupling in a Mn4Na-Organic Complex under Pulsed Magnetic Fields up to 73 T.

Research on the magnetoelectric (ME) effect (or spin-electric coupling) in molecule-based magnetic materials is a relatively nascent but promising topic. Molecule-based magnetic materials have diverse magnetic functionalities that can be coupled to electrical properties. Here we investigate a realization of ME coupling that is fundamental but not heavily studied─the coupling of magnetic spin level crossings to changes in electric polarization. A mixed-valence Mn4Na complex with a total ground-state spin S = 5/2 under zero magnetic field and S = 17/2 under high magnetic field undergoes a cascade of ground-state level crossings of the Sz states with increasing magnetic field. Magnetization and electrical polarization measurements under pulsed magnetic fields up to 73 T show that each spin level crossing is accompanied by a significant change in electric polarization that is an even function of the applied magnetic field. A molecular Hamiltonian describing antiferromagnetic exchange in a distorted tetrahedron of three MnIII and one MnII ions matches the data well. We conclude that the ME coupling is caused by magnetostriction within the polar molecule as it distorts to lower its magnetic exchange energy.

Crystal growth and pressure effect on the transport properties in 122-type (La,Na,K)Fe2As2 superconductors

Abstract High-quality single crystals are essential for probing the intrinsic properties of unconventional superconductors. In this work, we report the successful growth of (La,Na,K)Fe2As2 single crystals, a novel 122-type iron-based superconductor, using the self-flux method. The crystal structure and chemical composition were characterized through x-ray diffraction and energy-dispersive x-ray spectroscopy. The (La,Na,K)Fe2As2 single crystals exhibit bulk superconductivity, with a critical transition temperature Tc of approximately 22 K. Magnetization measurements reveal a second peak effect and a critical current density Jc ~ 5×105 A/cm2 at 2 K in a self-field. The upper critical field anisotropy was systematically studied within the framework of the anisotropic Ginzburg–Landau theory, yielding an anisotropy value of approximately 2.6. Furthermore, we employ the diamond anvil cell technique to investigate the pressure effect on (La,Na,K)Fe2As2. Our results demonstrate that superconductivity is gradually suppressed with increasing pressure, while the normal state resistivity at low temperatures evolves from non-Fermi liquid to Fermi liquid behavior. This observation suggests that (La,Na,K)Fe2As2 may be situated on the right of the quantum critical point or, at the very least, within the over-doped region. These findings provide a critical sample platform and experimental insights for advancing the understanding of the physical properties of the newly discovered (La,Na,K)Fe2As2 superconductors.

Trigonal Planar Heteroleptic Lanthanide(III) Bis(silyl)amide Complexes Containing Aminoxyl Radicals and Anions.

Modulation of the crystal field (CF) in lanthanide (Ln) complexes can enhance optical and magnetic properties, and large CF splitting can be achieved with low coordination numbers in specific geometries. We previously reported that the homoleptic near-linear Sm2+ complex [SmII{N(SiiPr3)2}2] (1-Sm) is oxidized by the 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO•) radical to give the heteroleptic, approximately trigonal planar Sm3+ complex, [SmIII{N(SiiPr3)2}2(TEMPO-)] (2-Sm). Here, we report the synthesis of homologous [LnIII{N(SiiPr3)2}2(TEMPO-)] (2-Ln; Ln = Tm, Yb) complexes by the oxidation of the parent [Ln{N(SiiPr3)2}2] (1-Ln; Ln = Tm, Yb) with TEMPO•; complexes 2-Ln all contain TEMPO- anions. The homoleptic bent Ln3+ complexes [LnIII{N(SiiPr3)2}2][B(C6F5)4] (3-Ln; Ln = Sm, Tm, Yb) were also treated with TEMPO• to yield the heteroleptic, approximately trigonal planar Ln3+ complexes [LnIII{N(SiiPr3)2}2(TEMPO•)][B(C6F5)4] (4-Ln; Ln = Sm, Tm, Yb); the cations of 4-Ln all contain TEMPO• radicals. We have compared the electronic structures of the two geometrically similar families of Ln3+ complexes with the TEMPO- anion (2-Ln) or TEMPO• radical (4-Ln) using a combination of UV-vis-NIR and EPR spectroscopy, magnetic measurements, and ab initio calculations. These studies revealed no single-molecule magnet behavior for 2-Yb despite evidence for sizable CF splitting and a high degree of purity of the ground stabilized mJ = |±7/2⟩ state, while the radical TEMPO• in 4-Yb did not significantly improve performance.

Development of an internet-of-things-based controlled-source ultrasonic audio frequency electromagnetic receiver

Abstract. Electromagnetic exploration, characterized by its low cost, wide applicability, and high operational efficiency, finds extensive applications in fields such as oil and gas exploration, mineral prospecting, and engineering geology. Traditional controlled-source electromagnetic detection methods are typically confined to operating frequencies below 250 kHz, resulting in insufficient detection accuracy for applications such as shallow- and intermediate-depth exploration, thereby constraining their performance in high-resolution imaging. To address these challenges, we propose a controlled-source ultrasonic audio frequency electromagnetic receive system based on the internet of things (IoT). We investigate cascaded digital filtering and sampling techniques to extend the receiver's sampling rate range, thereby elevating the operating frequency of controlled-source electromagnetic acquisition from the conventional maximum of 250 kHz to 1 MHz. The receiver achieves a sampling rate of up to 2.5 MHz, comprising three magnetic field measurement channels and two electric field measurement channels. The instrument is compact, lightweight, and capable of real-time data storage locally and real-time data transmission to an upper computer. Additionally, IoT technology is introduced, leading to the design of a cloud-based real-time remote control and data acquisition scheme. Experimental results demonstrate the stability of the instrument, meeting the requirements of field exploration.

From weak- to strong-coupling superconductivity in the AlB2-type solid solution SrGa1−xAlxGe with honeycomb layers

We report on the structure and the superconducting properties of 9-electron 111 compounds with honeycomb layers, namely SrGaGe, SrAlGe, and the SrGa1-xAlxGe solid solution. By means of single-crystal x-ray diffraction we show that, on one hand, SrGaGe crystallizes into the centrosymmetricP6/mmmspace group (a= 4.2555(2) Å,c= 4.7288(2) Å) with statistical disorder in the [GaGe]62-honeycomb layers. On the other hand, we confirm that SrAlGe crystallizes in a non-centrosymmetric space group, namelyP6¯m2(a= 4.2942(1) Å,c= 4.7200(2) Å) with fully ordered [AlGe]62-honeycomb layers. By using magnetization and specific heat measurements, we show that the superconducting properties of SrGaGe and SrAlGe differ significantly from each other. SrGaGe is a superconductor with a critical temperature ofTc= 2.6 K falling into the weak coupling limit, while SrAlGe has aTc= 6.7 K and can be classified in the strong coupling limit. By realizing the SrGa1-xAlxGe solid solution, we were able to investigate the transition between the different crystal structures as well as the evolution of the electronic properties. We show that the transition from the weak-to strong-coupling superconductivity in this system is likely associated with the disorder-to-order transition of the honeycomb layer, along with the loss of the inversion center in the crystal structure.

Non-stoichimometric square sheets in RSe2−x (x ∼ 1/6) (R = Gd and Tb)

The application of optimal electron count has proven effective in predicting the existence of complex structural topologies containing electron-rich polyanionic networks, including linear and zig-zag chains, square planar structures, and simple cubic lattices of main group elements. In this study, we report the successful synthesis of a new family of magnetic compounds, RSe2−x (x ∼ 1/6) (R = Gd and Tb), using KCl flux. The resulting crystal structure of RSe2−x is tetragonal, exhibiting PbFCl-type symmetry with space group P4/nmm. Chemical composition analysis consistently reveals x ∼ 1/6, indicating chalcogen-deficient square sheets. This observation suggests that RSe2−x adheres to the 14-electron rule, as the total valence electrons per RSe2−x (x ∼ 1/6) is 14 e−. In GdSe2−x (x ∼ 1/6), the magnetic susceptibility measurement displays a lambda-shaped peak around 8 K, indicating an antiferromagnetic-type transition. However, the positive Curie–Weiss temperature (θCW) suggests the presence of an additional ferromagnetic interaction, which may result from the large magnetic moment of the Gd atoms. In contrast, TbSe2−x (x ∼ 1/6) exhibits antiferromagnetic ordering. Chemical bonding analysis also indicates that the strong Se–Se antibonding in the square net may be related to Se deficiency. Our work shed light on ellucidating the interplay between chemical rule, defects, and magnetism.

Exploration of quantum oscillation in antiferromagnetic Weyl semimetal GdSiAl.

GdSiAl single crystal has been investigated by means of magnetic and magneto-transport measurements and compared with ab-initio density functional theory (DFT) calculations. Significant non-saturating magnetoresistance reaching ∼ 18% at 12T and 2K was observed, alongside the presence of Shubnikov-de Haas oscillations with the fundamental frequencies 22.09T and 77.33T. Shubnikov-de Haas oscillations provide the information about the nontrivial π Berry phase in GdSiAl with the Fermi surface areas of 0.00211 Å-2and 0.00739 Å-2. Angle-dependent magnetoresistance shows anisotropy with θ, exhibiting a maximum at 180°. The magnetic susceptibility data for H ∥ c and H ⊥ c reveals that the magnetic moments of Gd3+ions orders antiferromagnetically below 32K along with an another transition occurs at ∼ 8K, which is consistent with the heat capacity measurements where a distinct λ-shaped anomaly has been observed near antiferromagnetic ordering temperature 32K. The high value of Debye temperature indicates the contribution of acoustic phonons. Electronic structure calculations suggest the existence of nested Fermi surface pockets characterized by nesting wave vectors that closely align with the observed magnetic ordering wave vector. Furthermore, DFT calculations reveal the presence of Weyl nodes in close proximity to the Fermi surface. Our findings from combined experimental and theoretical techniques indicate GdSiAl to be a potential candidate for an antiferromagnetic topological Weyl semimetal.

Vanadate Inclusion Leading to Red-Ox-Rich Zircon PrCrO4: Synthesis, Magnetic, and Catalytic Properties.

Rare-earth-based ternary compounds with the formula REBO4 (B = V, Cr, P, As) exhibit rich structural chemistry and associated technologically significant properties. Among the rare-earth chromates, realizing PrCrO4 in a single polymorphic modification has been challenging. Herein, we report the successful stabilization of the zircon polymorph of PrCrO4 by introducing 10 mol % of VO43- instead of CrO43- following a solution combustion method. Compositions with progressively higher amounts of vanadate have been synthesized and characterized extensively. XPS analysis of 10 and 50 mol % VO43- substituted PrCrO4 samples ascertained the existence of Pr3+/4+, Cr4+,5+, and V5+ in them, making it a red-ox-rich system. The tetragonal symmetry of PrCr0.50V0.50O4 was confirmed from the HRTEM images and SAED patterns. FTIR and Raman spectral analyses indicated distorted tetrahedral (Cr/VO4) units with a local site symmetry below D2d. Both d-d and f-f transitions of Cr4+ and Pr3+, respectively, were observed in the absorption spectra. Field and temperature-dependent magnetic measurements of PrCr0.50V0.50O4 confirmed its predominant paramagnetic behavior. The samples possessed porous morphology with a reasonable surface area. PrCr1-xVxO4 (x = 0.00-0.50) samples catalyzed the oxidation of phenol. This study demonstrated B-site tuning in ABO4 systems to select a desired polymorph preferentially.

Solubility and magnetic properties of Ag−Co−Si alloy synthesized by mechanical alloying and annealing

AbstractThis present work concerns the effect of ternary addition of non‐metallic and diamagnetic silicon on the metastable solubility of the immiscible silver‐cobalt system during the course of ball milling, annealing of the ball milled samples and the corresponding magnetic properties. It should be noted that silicon has a smaller goldsmidt radius (111 pm) than silver (144 pm) and silicon+4 has more valence electrons than silver+1. Keeping the objectives of the current study in mind, silicon may thus be considered as an option for ternary addition, in contrast to metallic components. An attempt has been made to examine the phase changes that occurred in the 50 silver‐40 cobalt‐10 silicon (atom percent) system during ball milling and the subsequent isothermal annealing of the ball milled product. Phase evolution during mechanical alloying and isothermal annealing is identified by means of x‐ray diffraction, differential thermal analysis, high resolution transmission electron microscopy and magnetic measurements. The addition of silicon facilitates cobalt‘s formation of a metastable alloy with copper after 50 hours of ball milling. Annealing significantly improves the magnetic characteristics of materials that have been ball milled; the optimal combination of magnetic properties was obtained after an hour of annealing at 550 °C.

Inter-site comparability of 4D flow cardiovascular magnetic resonance measurements in healthy traveling volunteers—a multi-site and multi-magnetic field strength study

Inter-site comparability of 4D flow cardiovascular magnetic resonance measurements in healthy traveling volunteers—a multi-site and multi-magnetic field strength study

Frustrated Radical Pairs: From Fleeting Intermediates to Isolable Species.

We present the design and comprehensive investigation of stable para-substituted triarylamine-2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) radical ion pairs (RIPs) generated via single-electron transfer (SET). We quantified the degree of SET in both solution and solid phases, utilising a suite of spectroscopic techniques including IR, EPR, NMR, and single-crystal X-ray diffraction (SC-XRD). Our findings reveal that the extent of SET is significantly influenced by the nature of the substituents (MeO > tBu > Br) and the polarity of the solvent (MeCN > DCM > toluene). The radical ion pair [(pMeOPh)3N]•+[DDQ]•- was unambiguously identified using EPR and UV-vis spectroscopy, and its structure was confirmed by SC-XRD. Detailed analysis indicates an open-shell singlet ground state with a thermally accessible triplet state, as corroborated by EPR, magnetic susceptibility measurements, and DFT calculations. This study offers crucial insights into the mechanistic pathways of RIP formation and tuning both in solution and solid states, laying the groundwork for future exploration of their reactivity and potential applications.

Enhancement of Magnetic Shielding Based on Low-Noise Materials, Magnetization Control, and Active Compensation: A Review

Magnetic-shielding technologies play a crucial role in the field of ultra-sensitive physical measurement, medical imaging, quantum sensing, etc. With the increasing demand for the accuracy of magnetic measurement, the performance requirements of magnetic-shielding devices are also higher, such as the extremely weak magnetic field, gradient, and low-frequency noise. However, the conventional method to improve the shielding performance by adding layers of materials is restricted by complex construction and inherent materials noise. This paper provides a comprehensive review about the enhancement of magnetic shielding in three aspects, including low-noise materials, magnetization control, and active compensation. The generation theorem and theoretical calculation of materials magnetic noise is summarized first, focusing on the development of spinel ferrites, amorphous, and nanocrystalline. Next, the principles and applications of two magnetization control methods, degaussing and magnetic shaking, are introduced. In the review of the active magnetic compensation system, the forward and inverse design methods of coil and the calculation method of the coupling effect under the ferromagnetic boundary of magnetic shield are explained in detail, and their applications, especially in magnetocardiography (MCG) and magnetoencephalogram (MEG), are also mainly described. In conclusion, the unresolved challenges of different enhancement methods in materials preparation, optimization of practical implementation, and future applications are proposed, which provide comprehensive and instructive references for corresponding research.

Spin conduction and interfacial effects in La2/3Sr1/3MnO3/NiO/Pt heterostructures

In this work we report on the generation and transport of pure spin currents in La2/3Sr1/3MnO3(LSMO)/NiO/Pt heterostructures. Pure spin currents, generated by means of spin pumping in the LSMO layer, are transmitted through the NiO layer and detected by measuring the transverse voltage signal generated by the inverse spin Hall effect (ISHE) in the Pt layer. The spin current transmission is studied as a function of the NiO thickness and temperature. NiO layers grown at room temperature are polycrystalline and their microstructural and magnetic features clearly depend on thickness. Scanning transmission electron microscopy techniques revealed that homogeneous conformal coating of the LSMO layer is only achieved for NiO layer thicknesses above about 2 nm. Below this critical thickness the NiO layer is discontinuous and its main role would be to disturb the LSMO/Pt interface causing it to behave as something similar to an insulating barrier. Magnetic measurements indicate that NiO layers are paramagnetic (PM) well below room temperature. In agreement with these observations, the amplitude of the ISHE voltage signal decreases monotonically on lowering temperature and makes evident that there are two spin conduction regimes as a function of the NiO layer thickness with different spin diffusion lengths. For thin discontinuous NiO layers a spin diffusion length of λSDL≈0.8 nm is found, which is slightly larger than typical values found for insulating barriers, but definitely smaller than λSDL≈3.8 nm found for NiO layer thickness above 2 nm. The latter being similar to λSDL previously reported for epitaxial NiO layers. Our findings indicate that inserting a PM NiO insulating layer of optimal thickness improves the spin transparency of the LSMO/Pt interface. Additionally, the results suggest that spin conduction through the NiO layer is likely driven by magnetic correlations and short-range thermal magnons.

Structural Effect of N-7 Alkylation in 6-Chloropurine on Cu (II) Binding: Effect of Anions and Magnetic Studies.

This study investigates the anion-directed assembly of discrete copper (II) complexes. The ligands of choice are two N7-alkyl-purine-based neutral ligands. These ligands facilitate the exclusive coordination through the N3 and N9 positions, preventing polymeric chain formation. Perchlorate ions promoted the formation of discrete paddlewheel-like complexes with the general formula [Cu2(μ-Pur)4(CH3CN)2]4+, while chloride ions yielded chloride-bridged dimers of the form [Cu2(Pur)2(μ-Cl)2Cl2]. Copper-copper bond distances within these complexes ranged from 2.92 to 2.98 Å. Magnetic susceptibility measurement of chloride-bridged complexes exhibited antiferromagnetic coupling, whereas paddlewheel complexes displayed more complex alternating ferromagnetic and antiferromagnetic interactions. Chloride-bridged compounds exhibited strong near-infrared absorption.