Magnetic Polymer Research Articles

Performance enhancement of magnetoactive elastomer soft robots through a coupled magnetoelastic topology optimization scheme

Abstract We have found that considering local magnetic fields, large deformations, and magnetoelastic coupling simultaneously significantly affect the resulting shape in magnetoelastic topology optimization in a uniaxial actuator case. In contrast to the work presented here, other works incorporate magnetoelastic formulations that include simplifying assumptions on the local field, and subsequent effects on the magnetization response of the material, or the absence of large deformation mechanics, or both. These assumptions were shown to produce solutions that differ substantively from cases where local fields and large deformations are addressed concurrently. Magnetoelastic topology optimization schemes are needed to optimize magnetoactive elastomer (MAE) devices. MAE devices are magnetic particle-filled polymer matrices designed for specific actuations and controlled remotely by an external magnetic field. They garner considerable research interest as an emerging technology for actuators in soft robots or in applications requiring untethered actuation. The material properties of MAEs are dependent on the volume fraction of particles in the elastomer matrix, where a high-volume fraction increases relative permeability (for soft magnetic particles) but also increases elastic modulus. For optimal actuation, a tradeoff between low stiffness and high magnetic response must be made by adjusting volume fraction and controlling material placement. Using a topology optimization scheme that considers both the magnetic and mechanical properties of the material, the shape and material composition of the device can be tuned to best achieve the desired actuation displacement. In this work, a density-based magnetoelastic multimaterial topology optimization scheme for soft magnetic material is developed in COMSOL Multiphysics. The optimization scheme uses multiphysics coupling that considers local magnetic fields and large deformations at each iteration through a Maxwell stress tensor formulation. A simulated example is then considered to demonstrate the effectiveness and necessity of a coupled optimization. The effect of considering large deformations during optimization is also investigated. It was found that a coupled topology optimization scheme with large deformations produced shapes with modes of actuation not captured by schemes with simplifying assumptions, leading to better performance at lower material cost. Considering large deformations in the coupled scheme offered significantly better performance, with an increase of 81.3% in a side-by-side performance simulation when compared to uncoupled cases.

Preparation and Characterization of Magnetic Polymeric Micro- and Nanocomposites for Industrial Applications

ABSTRACT To optimize cost and weight and streamline the manufacturing process of existing soft magnetic components, which currently rely on metallic soft magnetic particles, an innovative approach involving the preparation of high-performance magnetic polymeric composites is proposed. These composites are based on soft magnetic ferrite particles with high Curie temperature and magnetic saturation, along with low coercivity and remanent magnetization, and are used as fillers in thermoplastic polymers. To achieve these goals, cobalt ferrite (CoFe2O4) micro- and nanoparticles were synthesized by two different methos: solid-state reaction and coprecipitation. The as-obtained particles were used to fabricate soft magnetic polymer composites by extrusion and injection molding methods. The successful synthesis of cobalt ferrite was confirmed by X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), and Raman spectroscopy. The magnetic behavior of cobalt ferrites and polymer composites was also investigated by vibrating sample magnetometry (VSM). This study shows that these new high-performance soft magnetic polymer composites can be used as alternative materials for the manufacture of magnetic components such as inductors and transformers and that their low cost and lightweight make them suitable for the manufacture of magnetic components.

Stimulus-responsive magnetic enzyme-encapsulated coordination polymer for the potential field monitoring of alkaline phosphatase using personal glucometer

Stimulus-responsive magnetic enzyme-encapsulated coordination polymer for the potential field monitoring of alkaline phosphatase using personal glucometer

Porous polymeric materials prepared via pickering emulsion templating targeted as a bronsted acid catalyst in room-temperature biodiesel production

The present work is about preparing a set of magnetic macroporous polymers using the Pickering high internal phase w/o emulsions (HIPEs) templating method. The octyl-modified core-shell magnetic nanoparticles (Fe3O4@SiO2-Octyl) were used as a solid stabilizer and Span 80 surfactant to stabilize the HIPEs. The effect of Fe3O4@SiO2-Octyl content, Span 80 content, and molar ratio of styrene/divinylbenzene (St/DVB) on physical properties, morphology, pore size, and void size of the macroporous polyHIPEs was precisely evaluated. The optimized polyHIPE prepared by 2 wt% of Fe3O4@SiO2-Octyl nanoparticles, 9 wt% of Span 80, and St/DVB molar ratio of 8 with the porosity of 86±1.1 % and an average pore size of 4.1 µm was selected as catalyst support to functionalize with sulfonic acid groups. The resulting catalyst (polyHIPE–SO3H) showed excellent performance in reacting long-chain free fatty acids (FFA) with methanol to give fatty acid monoalkyl esters (FAMEs) at room temperature. In this way, the polyHIPE–SO3H was found to be very active and reusable in the mentioned process, giving high yields (∼92–98 %) of various biodiesel compounds under very mild reaction conditions and recycling in the next subsequent runs without significant loss of activity.

Leveraging anchoring ligands for efficient one-pot solvothermal synthesis of PDMS functionalized iron oxide polymer nanocomposites (PNC’s)

Producing substantial quantities of high purity, narrow size distribution, magnetic polymer nanocomposites (PNC’s) has been a challenge for the nanoparticle synthesis community. In this study, we introduce a novel one-pot solvothermal synthesis technique to produce a type of PNC known as a ferrofluid. By employing a polymer (polydimethylsiloxane (PDMS)) modified with anchoring ligands as the surfactant, we eliminate the need for a post-synthesis ligand exchange, resulting in high yield and purity of the final product. This approach offers greater flexibility in polymer selection and simplifies the synthetic process. Electron microscopy, magnetic characterization, infrared spectroscopy, and thermal analysis were employed to investigate particle size, crystallinity, magnetic behavior, and surface environment. Our findings suggest that this new synthetic technique could significantly advance the development of magnetic nanoparticle-based theranostics.

Regulating the N-functional hydrogen bond donors over magnetic nanoparticles supported imidazole tribromide zinc ionic liquid for CO2 cycloaddition

The design of catalysts for the mile production of cyclic carbonates by CO2 cycloaddition is of value. Magnetic polymer nanoparticles-supported imidazole tribromide zinc ionic liquid catalysts, incorporating N-functional hydrogen bond donors (HBD), was successfully accomplished. The correlation between the N-functional HBD and catalytic activity was thoroughly investigated through experimental studies and DFT calculations. The catalyst featuring a secondary amine group (NHM) demonstrated remarkable catalytic performance in CO2 cycloaddition reactions. Under optimized conditions, including 0.12 mol% catalyst dose, 100 °C, and nPO:nCO2 = 1:1.2 for 3 h, a complete conversion was achieved. The exceptional performance of the catalyst was attributed to the multicenter synergistic effect, arising from the appropriate electronegativity, minimal spatial site resistance, a balanced distance between the NHM and imidazolium ion, and the presence of multiple active centers (NHM, Zn2+, and Br−). The integration of a magnetic component enabled swift separation and exceptional recovery stability over 8 consecutive cycles.

Simultaneous Removal of Eriochrome Black T and Chromate Anions from Aqueous Solution Using Functionalized Hybrid Magnetic Polymers

Simultaneous Removal of Eriochrome Black T and Chromate Anions from Aqueous Solution Using Functionalized Hybrid Magnetic Polymers

β-Cyclodextrin based magnetic hyper-crosslinked polymer: A recyclable adsorbent for effective preconcentration of triazine herbicides in complex sample matrices

High efficiency enrichment and trace analysis of triazine herbicide residues are crucial for ensuring environmental and food safety. Herein, a series of magnetic hyper-crosslinked polymers (CD-gs-MHCPs) were synthesized with different crosslinkers, which might possess different pore structure and surface area, so they might dispay variable adsorption performance. CD-gs-MHCP2 with dichloroxylene as crosslinker delivered superior adsorption ability for triazine herbicides (THs). The synergistic effect of hydrogen bonds, hydrophobic interaction, π-π stacking interaction and pore adsorption were proved to be the main adsorption mechanism. Combined CD-gs-MHCP2 based magnetic solid-phase extraction (MSPE) with high-performance liquid chromatography, the quantitative analysis of THs in river water and vegetable samples (zucchini, pakchoi) was achieved. Under the optimal conditions, the enrichment factors for three different samples ranged from 94 to 244 and low detection limit (S/N = 3) of the four THs were obtained from 0.05 to 0.15 ng mL−1 for river water and 0.31–3.10 ng g−1 for vegetable samples. The method recoveries were in the range of 86.2 %–120 % with relative standard deviations lower than 7.4 %. This work not only offers a new strategy for fabrication β-CD-based HCPs, but also provided a practical and effective method for efficient isolation and sensitive detection of trace THs residues in complex samples.

Simulation and experimental study of tool passivation based on magnetic elastic abrasive particles

The presence of micro-cracks and serrations on the tool often leads to its premature failure. However, these microscopic defects can be mitigated through passivation treatment of the tool. Magnetoelastic abrasive particles are new composite particles formed by using abrasive phase particles, magnetic media phase particles and polymer matrix according to a certain ratio, the abrasive particles have both viscoelasticity and magnetic conductivity. The introduction of magnetoelastic abrasive grains into the dual-disk tool passivation equipment can effectively improve the surface quality of the tool and increase the passivation efficiency. At the outset, a model for tool passivation was crafted employing the ABAQUS simulation software. This model aimed to evaluate the effects of diverse passivation variables on the stress levels, the shape of the impact, and the depth of the impact experienced by the tool. Subsequently, by applying statistical theory combined with fitting function techniques, a mathematical model was constructed to determine the passivation volume of the tool subjected to multiple magnetic elastic abrasive particles. This model was then used to examine the impact count and passivation volume associated with each passivation factor. Finally, a tool passivation experiment was conducted using a dual-disk magnetic tool passivation device. The results showed that the smaller the impact velocity of magnetic elastic abrasive particles, the stress and impact depth of the cutting tool are decreasing, and the deformation of the cutting edge is caused by compressive stress. The error of impact depth calculated by simulation and mathematical model is within 20 %, which proves that the mathematical model can better calculate the impact depth of magnetic elastic abrasive particles on the cutting edge of the tool.

Selective solid phase extraction of folic acid from tomato as a biological source with a magnetic molecularly imprinted polymer measured by fluorescence spectroscopy

AbstractA novel magnetic molecular-imprinted polymer (MMIP) was used to selectively extract folic acid directly from real samples. Folic acid was used as template molecule, Fe3O4/SiO2-3-triethoxysilyl-propyl-acrylamide as functional monomer, azobisisobutyronitrile as initiation, ethylene glycol dimethacrylate as crosslinker agent, and acrylamide as the secondary monomer in a mixed ethanol-water solvent. The effect of different parameters on the extraction efficiency was studied, and the optimum conditions were established as follows: the concentrations of crosslinking and template were fixed at 0.05 and 0.06 g, absorption percentage was 96.5, pH was adjusted to 8, and extraction time was 8 h with a temperature of 25 °C. By examining the effect of pH, we tried to investigate the effect of the amide groups that present in MMIP and its intermolecular hydrogen interaction with folic acid. After optimising the effective parameters in polymer synthesis and adsorption rate, a magnetic imprinting dispersive solid-phase extraction method combined with fluorescence spectrophotometry at λem = 367 nm (MMIP-DSPE-FL) was constructed for sensitive determination of folic acid in tomato samples. The limit of quantification (LOQ) and limit of detection (LOD) values were 30.00 ± 0.01 μg L−1 and 10.00 ± 0.03 μg L−1, respectively, after the MMIP-DSPE preconcentration. Three tomato samples were analysed to give recoveries in the range of 80.2–81.6%, with relative standard deviation values below 0.6% (n = 3). The prepared MMIP-DSPE showed high selectivity toward folic acid, which could be used six times without changing adsorption capacity. The adsorption isotherm of the folic acid-imprinted polymer pursued the Langmuir model (RL = 0.029), and the kinetics model followed pseudo-first-order (R2 = 0.9974).

Magnetically-Actuated Endoluminal Soft Robot With Electroactive Polymer Actuation for Enhanced Gait Performance

Abstract Endoluminal devices are indispensable in medical procedures in the natural lumina of the body, such as the circulatory system and gastrointestinal tract. In current clinical practice, there is a need for increased control and capabilities of endoluminal devices with less discomfort and risk to the patient. This paper describes the detailed modeling and experimental validation of a magneto-electroactive endoluminal soft (MEESo) robot concept that combines magnetic and electroactive polymer (EAP) actuation to improve the utility of the device. The proposed capsule-like device comprises two permanent magnets with alternating polarity connected by a soft, low-power ionic polymer-metal composite (IPMC) EAP body. A detailed model of the MEESo robot is developed to explore quantitatively the effects of dual magneto-electroactive actuation on the robot’s performance. It is shown that the robot’s gait is enhanced, during the magnetically-driven gait cycle, with IPMC body deformation. The concept is further validated by creating a physical prototype MEESo robot. Experimental results show that the robot’s performance increases up to 68% compared to no IPMC body actuation. These results strongly suggest that integrating EAP into the magnetically-driven system extends the efficacy for traversing tract environments.

DFT Modeling of Polyethylene Chains Cross-linked by Selected ns1 and ns2 Metal Atoms.

We analyze the structures, stabilities, and thermochemical properties of polyethylene (PE) oligomer chains cross-linked by metal (M) atoms through C-M-C bonds. Representative PEn-Mm-PEn complexes contain between 7 and 15 carbon atoms in each oligomer and one to three Li, Be, Mg, Zn, Ag, or Au cross-linking metal elements. PEn-Mm-PEn complexes are quasiplanar with nearly parallel PE chains. Their stability is determined by covalent C-M-C bonds accompanied by noncovalent dispersion interactions between PEn chains. Using the CAM-B3LYP+D3BJ+ABC functional, the binding energies of PE15-M-PE15 with respect to two PE15 radicals and metal fragments are -225, -230, -322, -551, -289, and -303 kJ/mol for Li, Ag, Au, Be, Mg, and Zn atoms, respectively. Entropy contributions (109 to 121 kJ/mol at 298.15 K) destabilize all complexes significantly. With two cross-linking metal elements in PE15-M2-PE15 complexes, binding energies are about double. Complexes with several open-shell Li, Ag, or Au doublet atoms have spins located on separated C-M-C bonds. High-spin PE15-Mm1-PE15-Mm2-PE15 complexes of three PE oligomers cross-linked by up to five doublet metal atoms create parallel PE tubes, which are suggested as elementary cells for modeling magnetic polymer tubes.

Interpreting the removal behaviours of aniline and 3,4-diaminotoluene on aromatic carbon-rich magnetic polymer: Statistical modelling, DFT quantitative calculations and new perspectives

The widespread presence of harmful and stubborn amine organic contaminants in aquatic environments motivated the exploration of efficient technologies for alleviating their serious environmental crisis. Herein, the recyclable magnetic Schiff base polymer (Fe3O4-TENE) with satisfactory and promising capacity in treating aniline and 3,4-diaminotoluene as representative amine organic contaminants was fabricated via a simple in-situ polymerization method, which combined the magnetic separability advantage of magnetic oxides with the abundant aromatic carbon content properties of Schiff base polymer. Multiple characterization methods verified the effectiveness of the in-situ polycondensation coating reaction and analyzed the physicochemical properties of Fe3O4-TENE. The Fe3O4-TENE possessed abundant homogeneous reaction sites and excellent regeneration performance, multiple diffusion driving forces and micro-mechanisms co-participated in the removal reaction. The adsorption pathway, underlying reaction mechanism and the most probable bonding system were identified based on the statistical modelling and DFT quantitative calculations. Especially, the visible electrostatic potential molecular and molecular orbitals verified the π-π interaction and electrostatic forces greatly contributed to the removal reaction. The Driving forces – Challenges – Breakthrough – Application framework was proposed for comprehensively assessing the possible environmental application of Fe3O4-TENE. Overall, this work not only provides important insights into the utilization of magnetic polymer composite to alleviate ecological and environmental risks caused by amine organic pollutants, but also contributes to an in-depth excavation of the bonding types and removal mechanisms from both micro and macro perspectives.

Preparation of Magnetic Spongy Porous Carbon Skeleton Materials for Efficient Removal of BTEX.

Magnetic polymer microspheres have been extensively utilized as separable and highly efficient adsorbents in wastewater treatment. In this study, a series of novel magnetic spongy porous carbon skeleton materials (Mag-SPCS) have been designed and synthesized by acetonitrile suspension precipitation polymerization, which combines the advantages of the acetonitrile precipitation method and the suspension polymerization method. It was demonstrated that the transformation of the material morphology from microspheres to a porous sponge was achieved by a gradual decrease in the usage amount of ethylene glycol. After N,N-dimethyloctadecylamine (C18) was grafted onto the Mag-SPCS materials, the C18-Mag-SPCS materials with a superhigh saturation adsorption capacity and superfast adsorption efficiency were used for the removal of BTEX (toluene, benzene, and para-xylene) in wastewater. Subsequently, the adsorption properties of the composites with different morphologies were evaluated, and the effect of the usage amount of C18 on the adsorption properties of the C18-Mag-SPCS was further investigated. The maximum adsorption capacities of C18-Mag-SPCS for benzene, toluene, and para-xylene were 714.84, 564.32, and 394.48 mg/g, respectively. The adsorption process was conducted in accordance with the proposed secondary and Langmuir models. Finally, the FTIR, XPS, and XRD characterization results before and after adsorption demonstrated that the adsorption mechanism of toluene onto C18-Mag-SPCS was primarily hydrogen bonding, π-π stacking, and van der Waals forces. These findings of the study indicate that the composite material exhibits an ultrahigh saturation adsorption capacity and ultrafast adsorption efficiency, thereby confirming its considerable potential for application in wastewater treatment.

Molecular dynamics simulations of microscopic structural transition and macroscopic mechanical properties of magnetic gels.

Magnetic gels with embedded micro-/nano-sized magnetic particles in cross-linked polymer networks can be actuated by external magnetic fields, with changes in their internal microscopic structures and macroscopic mechanical properties. We investigate the responses of such magnetic gels to an external magnetic field, by means of coarse-grained molecular dynamics simulations. We find that the dynamics of magnetic particles are determined by the interplay of magnetic dipole-dipole interactions, polymer elasticity, and thermal fluctuations. The corresponding microscopic structures formed by the magnetic particles, such as elongated chains, can be controlled by the external magnetic field. Furthermore, the magnetic gels can exhibit reinforced macroscopic mechanical properties, where the elastic modulus increases algebraically with the magnetic moments of the particles in the form of ∝(m-mc)2 when magnetic chains are formed. This simulation work can not only serve as a tool for studying the microscopic and the macroscopic responses of the magnetic gels, but also facilitate future fabrications and practical controls of magnetic composites with desired physical properties.

Development of Magnetic Porous Polymer Composite for Magnetic Solid Phase Extraction of Three Fluoroquinolones in Milk.

In this study, a magnetic porous polymer composite with both hydrophilic and hydrophobic groups was synthesized for magnetic solid phase extraction (MSPE) of milk substrates. Optimization was conducted on various parameters, including adsorption dose, solution pH, adsorption time, and some elution conditions. Coupled with a high-performance liquid chromatography fluorescence detector, a novel MSPE method for determination of norfloxacin (NFX), ciprofloxacin (CIP), and enrofloxacin (ENR) in milk was developed based on magnetic metal organic framework polystyrene polymer (Fe3O4@MOF@PLS) as adsorbent. The Fe3O4@MOF@PLS exhibited significantly improved adsorption performance compared to MOF and PLS. Under optimized experimental conditions, the method exhibited good linearity for the three fluoroquinolones (FQs) in the range of 0.5-1000 μg/kg, with limit of detections (LODs) ranging from 0.21 to 1.33 μg/kg, and limit of quantitations (LOQs) from 0.71 to 4.42 μg/kg. The relative standard deviation (RSD) for the three FQs were 3.4-8.8%. The recoveries of three FQs in milk samples ranged from 84.2% to 106.2%. This method was successfully applied to the detection of three FQs in 20 types of milk, demonstrating its simplicity, speed, and effectiveness in analyte enrichment and separation. The method presented advantages in adsorbent dosage, adsorption time, LODs, and LOQs, making it valuable for the analysis and detection of FQs in milk.

Fabrication of Novel Carbon-based Polymers by On-surface Cycloaromatization of Isopropyl Substituents

Surface-catalyzed reactions have been employed for the synthesis of carbon nanomaterials featuring precisely defined atomic structures. A recent breakthrough involves the gold surface-catalyzed [3 + 3] cycloaromatization of isopropyl-substituted arenes, allowing for on-surface synthesis of novel carbon-based polymers[1-3]. In this process, the surface plays a crucial role in activating the isopropyl substituents, facilitating the formation of phenylene rings through intermolecular coupling. For instance, such investigations might open new avenues in the field of carbon magnetism, which has gained an increased attention in view of the recent progress made in the synthesis and characterization of open-shell polycyclic aromatic hydrocarbons[2]. Under this scenario, the comprehensive fabrication of magnetic polymers emerges as a highly appealing field of research.Here, we introduce exemplary approaches toward the bottom-up fabrication of different carbon-based polymers homocoupled via surface-catalyzed [3 + 3] cycloaromatization of isopropyl substituents studied on Au(111) under ultra-high vacuum (UHV) conditions. The chemical structures of the polymers have been clearly elucidated by non-contact atomic force microscopy (nc-AFM). Scanning tunneling spectroscopy (STS), complemented by computational investigations reveals their ground state. Our approach can be a highly relevant step towards the on-surface synthesis of covalently linked 1D organic polymers with prospects in sensing, catalysis and nanoscale spintronic devices.

Fast Determination of Eleven Food Additives in River Water Using C18 Functionalized Magnetic Organic Polymer Nanocomposite Followed by High-Performance Liquid Chromatography.

A novel magnetic nanomaterial with Fe3O4 as the core, PS-DVB as the shell layer, and the surface modified with C18 (C18-PS-DVB-Fe3O4) had been synthesized by seeded emulsion polymerization. C18-PS-DVB-Fe3O4 retains the advantages of the chemical stability, large porosity, and uniform morphology of organic polymers and has the magnetic properties of Fe3O4. A simple, flexible, and efficient magnetic dispersive solid phase extraction (Mag-dSPE) method for the extraction of preservatives, sweeteners, and colorants in river water was established. C18-PS-DVB-Fe3O4 was used as an adsorbent for Mag-dSPE and was coupled with high-performance liquid chromatography (HPLC) to detect 11 food additives: acesulfame, amaranth, benzoic acid, tartrazine, saccharin sodium, sorbic acid, dehydroacetic acid, sunset yellow, allura red, brilliant blue, and erythrosine. Under the optimum extraction conditions, combined with ChromCoreTMAQC18 (5 μm, 4.6 × 250 mm), 20 mmol/L ammonium acetate aqueous solution and methanol were used as mobile phases, and the detection wavelengths were 240 nm and 410 nm. The limits of detection (LODs) of 11 food additives were 0.6-3.1 μg/L with satisfactory recoveries ranging from 86.53% to 106.32%. And the material could be reused for five cycles without much sacrifice of extraction efficiency. The proposed method has been used to determine food additives in river water samples, and results demonstrate the applicability of the proposed C18-PS-DVB-Fe3O4 Mag-dSPE coupled with the HPLC method to environment monitoring analysis.

Core-shell magnetic covalent organic polymer nanocomposites as an adsorbent for the extraction of flavonoids.

A novel 3D magnetic nanocompositematerialbased on covalent organic polymers was successfully synthesized and utilized as an efficient sorbent for magnetic solid-phase extraction. It exhibited a regular core-shell structure, large specific surface area, superior stability, and paramagnetism. To evaluate its extraction efficiency, six flavonoids were tested, demonstrating maximum adsorption capacities ranging from 90 to 218mg/g. Additionally, the material exhibited remarkable reusability and mechanical stability, maintaining its original state over eight cycles with consistent recovery. An analytical strategy combining magnetic solid-phase extraction with high performance liquid chromatography and tandem mass spectrometry was developed for the determination of flavonoids in orange, honey, soybean, and Dioscorea bulbifera L. samples. The low limits of detection (0.01-0.1ng/mL) and limits ofquantification (0.05-0.5ng/mL), as well as satisfactory recovery (80.4-114.8%), were obtained. The linear range started from the limits of quantification to 500ng/mL with R2 ≥ 0.9929. These results suggest that the prepared adsorbent possesses excellent adsorption capabilities for flavonoids, highlighting its significant potential for detecting these compounds in complex sample matrices.

Recent Advances in Synthesising and Applying Magnetic Ion-Imprinted Polymers to Detect, Pre-Concentrate, and Remove Heavy Metals in Various Matrices

Magnetic ion-imprinted polymers (MIIPs) are an innovative material that combines the selectivity of ion imprinting with the ease of separation provided by magnetic properties. Recent advancements in MIIPs have shown that they have higher selectivity coefficients compared to non-imprinted materials. The synthesis of MIIPs involves creating specific recognition sites for target ions in magnetic nanomaterials. Various nanomaterials, such as graphene oxide, carbon nanotubes, and silica, have been incorporated into the IIPs to improve their analytical performance for different environmental applications, including metal extraction, monitoring, detection, and quantification. This review stresses the need to develop new monomers with a high affinity for the target analyte and to find supporting materials with groups that facilitate the effective removal of the target analyte. It also explores the influence of experimental parameters on metal determination.