Magnetic Field Cycling Research Articles

Frequency stabilization of adiabatic temperature change in Fe50Rh50 alloy in a cyclic magnetic field of 1.2 T

We present the results of direct measurements of the adiabatic temperature change (ΔTad) for the Fe50Rh50 alloy in a cyclic magnetic field (CMF) of 1.2 T. It is shown that increasing the frequency of the CMF from 1 to 30 Hz is accompanied by a shift of the position of temperature dependence ΔTad(T) maximum, Tmax, toward low temperatures. With an increase in the CMF frequency from 1 to 5 Hz, the ΔTmax value decreases by ∼12%. A further increase in frequency leads to stabilization of the effect. In the vicinity of the antiferromagnetic-ferromagnetic phase transition point TC = 370 K, ΔTad exhibits unconventional frequency behavior: while at T well above TC, the value of ΔTad monotonously decreases as frequency increases, at T = 370.4 K; an interval of frequency-independent ΔTad up to 10 Hz is observed, and at 368 K < T < TC, the maximum of ΔTad(f) dependence is found in the interval 1 < f < 10 Hz. Such behavior in the future can be applied in magnetic cooling technology due to large values of ΔTad and the frequency stability of the effect in alternating fields. The specific cooling power reaches giant values of ∼22 W/g at 20 Hz, which is comparable to the values under the same conditions for Gd −21.6 W/g. The unconventional behavior of ΔTad in the CMF is discussed in the context of the role of secondary phase localization, which leads to an enhanced internal local magnetic field and dynamic effects of ΔTad.

Micromechanical analysis of magnetoelectric coupling of composites containing nonlinear magnetostrictive and piezoelectric constituents

This paper is a reformulation of the simplified unit-cell and Mori-Tanaka micromechanics theories in their applications to nonlinear magnetoelectric analysis of two-phase composite materials with 0–3, 1–3, and 2–2 connectivity types, respectively. We elucidate the similarity between the two models insofar as concentration-factor matrices are concerned. The representations of the bulk magnetostrictive and piezoelectric phases are based on nonlinear constitutive equations. Due to material nonlinearity, the mathematical frameworks are accomplished via incremental formulation that provides a system of linear algebraic equations at each increment which is obviously a great advantage over nonlinear one. The derived nonlinear composite constitutive relations that govern the hysteresis behavior of composites are implemented to study the composite composed of Terfenol-D and PZT constituents. The responses of this composite to a complete cycle of magnetic field are shown and the micromechanics predictions are compared in light of existing experimental data.

Parahydrogen-Induced 13C Hyperpolarizer Using a Flow Guide for Magnetic Field Cycling to Evoke 1H-13C Spin Order Transfer Toward Metabolic MRI.

The pair-wise addition of parahydrogen, the singlet form of molecular hydrogen, to unsaturated precursors evokes the hyperpolarization of two parahydrogen-derived 1H nuclear spins through a process known as parahydrogen-induced polarization (PHIP). Subsequent spin order transfer (SOT) from the 1H to the surrounding 13C nuclear spins via magnetic field cycling (MFC) results in substantial signal enhancement in 13C magnetic resonance imaging (MRI). Here, we report the development of a unique PHIP 13C hyperpolarizer system using a flow guide for MFC. The optimal MFC scheme for 1H to 13C spin order transfer was quantum-chemically simulated using the J-coupling values of 13C-labeled metabolic tracers. The flow guide system was three-dimensionally designed based on the simulated MFC scheme and pre-measured magnetic field distribution in a zero-field chamber. The system efficiently transfers the spin order of hyperpolarized 1H to a particular 13C spin when the parahydrogenated tracer passes through the flow guide at a designated flow rate. The 13C MRI signal is enhanced more than 40,000 times in 13C-labeled pyruvate and fumarate, compared to the thermal equilibrium level at 1.5 T, was achieved for conducting in vivo metabolic MRI of mice. A fully automated PHIP-based 13C polarizer was developed using a unique flow guide to conduct the MFC for 1H to 13C SOT. The PHIP hyperpolarizer with a flow guide can conduct efficient 1H-13C SOT without a MFC magnetic field sweep system and offers a cost-effective alternative to conventional dynamic nuclear polarization.

Discriminating between Babcock–Leighton-type Solar Dynamo Models by Torsional Oscillations

The details of the dynamo process in the Sun are an important aspect of research in solar-terrestrial physics and astrophysics. The surface part of the dynamo can be constrained by direct observations, but the subsurface part lacks direct observational constraints. The torsional oscillations, a small periodic variation of the Sun's rotation with the solar cycle, are thought to result from the Lorentz force of the cyclic magnetic field generated by the dynamo. In this study, we aim to discriminate between three Babcock–Leighton dynamo models by comparing the zonal acceleration of the three models with the observed one. The property that the poleward and equatorward branches of the torsional oscillations originate from about ±55° latitudes with their own migration time periods serves as an effective discriminator that could constrain the configuration of the magnetic field in the convection zone. The toroidal field, comprising poleward and equatorward branches separated at about ±55° latitudes, can generate the two branches of the torsional oscillations. The alternating acceleration and deceleration bands in time are the other property of the torsional oscillations that discriminates between the dynamo models. To reproduce this property, the phase difference between the radial (B r ) and toroidal (B ϕ ) components of the magnetic field near the surface should be about π/2.

Structural dynamics of first-order phase transition in giant magnetocaloric La(Fe,Si)13: The free energy landscape

Maximizing the performance of magnetic refrigerators and thermomagnetic energy harvesters is imperative for their successful implementation and can be done by maximizing their operation frequency. One of the features delimiting the frequency and efficiency of such devices is the phase transition kinetics of their magnetocaloric/thermomagnetic active material. While previous studies have described the magnetic component governing the kinetics of the magnetovolume phase transition in La(Fe,Si)13 giant magnetocaloric materials, a comprehensive description of its structural component has yet to be explored. In this study, in situ synchrotron X-ray diffraction is employed to describe the structural changes upon magnetic field application/removal. Long magnetic field dependent relaxation times up to a few hundred seconds are observed after the driving field is paused. The phase transition is found to be highly asymmetric upon magnetic field cycling due to the different Gibbs energy landscapes and the absence of an energy barrier upon field removal. An exponential relationship is found between the energy barriers and the relaxation times, suggesting the process is governed by a non-thermal activation over an energy barrier process. Such fundamental knowledge on first-order phase transition kinetics suggests pathways for materials optimization and smarter design of magnetic field cycling in real-life devices.

13C MRI of hyperpolarized pyruvate at 120 µT

Nuclear spin hyperpolarization increases the sensitivity of magnetic resonance dramatically, enabling many new applications, including real-time metabolic imaging. Parahydrogen-based signal amplification by reversible exchange (SABRE) was employed to hyperpolarize [1-13C]pyruvate and demonstrate 13C imaging in situ at 120 µT, about twice Earth’s magnetic field, with two different signal amplification by reversible exchange variants: SABRE in shield enables alignment transfer to heteronuclei (SABRE-SHEATH), where hyperpolarization is transferred from parahydrogen to [1-13C]pyruvate at a magnetic field below 1 µT, and low-irradiation generates high tesla (LIGHT-SABRE), where hyperpolarization was prepared at 120 µT, avoiding magnetic field cycling. The 3-dimensional images of a phantom were obtained using a superconducting quantum interference device (SQUID) based magnetic field detector with submillimeter resolution. These 13C images demonstrate the feasibility of low-field 13C metabolic magnetic resonance imaging (MRI) of 50 mM [1-13C]pyruvate hyperpolarized by parahydrogen in reversible exchange imaged at about twice Earth’s magnetic field. Using thermal 13C polarization available at 120 µT, the same experiment would have taken about 300 billion years.

Magnetic field dependence of the para-ortho conversion rate of molecular hydrogen in SABRE experiments

The use of parahydrogen – the isomer of molecular hydrogen with zero nuclear spin – is important for promising and actively developing methods for spin hyperpolarization of nuclei called parahydrogen induced polarization (PHIP). However, the dissolved parahydrogen in PHIP experiments quickly loses its spin order, resulting in the formation of orthohydrogen and reduction of the overall nuclear polarization of the substrate. This process is due to the difference of chemical shifts of hydride protons, as well as spin–spin couplings between nuclei, in the intermediate catalytic complexes, and it has not been rigorously explained so far. We proposed a new experimental technique based on magnetic field cycling for measuring the rate of molecular hydrogen para–ortho conversion in solution and applied it for non-hydrogenative PHIP Signal Amplification By Reversible Exchange (SABRE) experiments. The para–ortho conversion rate was measured over a wide range of magnetic field from 0.5 mT to 9.4 T. It was found that the conversion rate strongly depends on the magnetic field in which the reaction occurs, as well as on the concentrations of reactants. The rate decreases with increasing the concentration of pyridine ligand and increases with increasing the concentration of iridium catalyst. The model, which takes into account the reversible exchange of molecular hydrogen with the catalyst, nuclear spin–spin interaction of hydride protons with nuclei of ligands within catalytic complex and nuclear Zeeman interactions, qualitatively describes the experimental data. Two types of complexes with different spin system symmetry contribute to the molecular hydrogen conversion. In asymmetric complexes possessing hydride protons with different chemical shifts due to the presence of chlorine anion ligand the para–ortho conversion rate increases with magnetic field, while for symmetric complexes this mechanism is not operable. In the magnetic field where level anti-crossing occurs the resonant feature for the rate of para–ortho conversion is found. The results of this work can be utilized for finding the optimal conditions for obtaining the maximum hyperpolarization in the experiments employing parahydrogen.

Anomalies in the magnetostrictive modulation of love surface acoustic waves

A magnetic surface acoustic wave (SAW) sensor is built by growing a 100 nm galfenol (Fe72Ga28) film by sputtering between the interdigitated transducers of a SAW delay line. Love waves are produced when the shear waves excited on the piezoelectric substrate are guided by a 3.1 μm layer of amorphous SiO2. Due to the magnetostrictive nature of galfenol deposited on top, the application of magnetic fields modulates the propagation of the mechanical excitations along the sensor by the strain coupling. By introducing the delay line in a feedback loop circuit, these changes are studied as resonant frequency variations. Magnetic field cycles of ±40 mT are applied to the sample and the resonant frequency shift is tracked simultaneously. The sensor exhibited hysteretic frequency behavior that depends on the orientation of the applied magnetic field relative to the direction of Love wave propagation. In the configuration in which the wave vector and the applied field form an angle of 45°, the resonant frequency seems to increase with the magnetization induced by the external field. When the wave vector propagation is parallel to the field, two positive peaks appear close to the coercive field of the film, which has not been reported before. This is probably due to a more complex relationship between the acoustic wave and the magnetic state of the film which could be exploited to give rise to new models of magnetic sensors.

Magnetocapacitance at the Ni/BiInO3 Schottky Interface.

We report the observation of a magnetocapacitance effect at the interface between Ni and epitaxial nonpolar BiInO3 thin films at room temperature. A detailed surface study using X-ray photoelectron spectroscopy (XPS) reveals the formation of an intermetallic Ni-Bi alloy at the Ni/BiInO3 interface and a shift in the Bi 4f and In 3d core levels to higher binding energies with increasing Ni thickness. The latter infers band bending in BiInO3, corresponding to the formation of a p-type Schottky barrier. The current-voltage characteristics of the Ni/BiInO3/(Ba,Sr)RuO3/NdScO3(110) heterostructure show a significant dependence on the applied magnetic field and voltage cycling, which can be attributed to voltage-controlled band bending and spin-polarized charge accumulation in the vicinity of the Ni/BiInO3 interface. The magnetocapacitance effect can be realized at room temperature without involving multiferroic materials.

Analytical 3D model for coupled magneto-mechanical behaviors of ferromagnetic shape memory alloy

Ferromagnetic shape memory alloys (FSMA), a type of smart material, are promising for engineering applications due to their large, high-frequency, and reversible magnetic-field-induced-strain (MFIS). However, the magneto-mechanical behaviors of FSMA are still not well understood due to the intrinsically coupled and cross-scale magneto-mechanical responses, limiting the design and optimization of FSMA-based devices such as sensors and actuators. In this work, a fully-analytical 3D model containing only basic material parameters and incorporating all key mechanisms for the magneto-mechanical performances of FSMA is developed based on a new magneto-mechano-decoupled energy minimization approach. It is shown that the coupled magneto-mechanical responses of FSMA-based sensors (cyclic stress with constant magnetic field) and actuators (cyclic magnetic field with constant stress) predicted by the model are in excellent agreement with existing experimental measurements. Based on these analytical predictions, the optimal ranges for the constant field and demagnetization factor are determined to achieve simultaneous complete strain recovery and considerable magnetization change as required by the FSMA-based sensors. In addition, the dependences of switching and saturating fields of MFIS on the constant stress and demagnetization factor are quantified for the FSMA-based actuators. Finally, a phase diagram is constructed to quantitatively determine the critical magnetic fields and stresses for predicting the strain induction and recovery under various loading conditions. The analytical model provides a simple, reliable, and versatile tool to reveal the comprehensive mechanisms for the coupled magneto-mechanical behaviors of FSMA and to guide the design of FSMA-based sensors and actuators with customized and on-demand performances.

Investigation of the electronic and magnetic properties of bare and oxygen-terminated ordered double transition-metal MXenes for spintronic applications.

MXenes are a large and new family of intrinsically magnetic two-dimensional (2D) transition-metal carbides and nitrides. This family has been adding new members since their first discovery in 2011, and has expanded with the exploring of ordered double transition-metal (DTM) MXenes. In this study, we have investigated the electronic and magnetic properties of thirteen bare and fourteen oxygen-terminated DTM MXene structures (M3C2, M3C2O2, MM'C2 and MM'C2O2, M = Ti, Zr, Cr, and Mo; M' = Ti, V, Nb, and Ta). The Hubbard-U parameter strongly depends on the atom environment and the coordination number in the cell. Therefore, for the first time in the literature, we have calculated the Hubbard-U parameters for each considered MXene structure systematically instead of taking them randomly. The investigated MXene structures have striking properties with respect to their magnetic ground states, and show ferromagnetic to antiferromagnetic or non-magnetic properties, accompanied by semiconductor to metallic or semi-metallic properties, depending on the transition metal(s) or termination by oxygen. We have performed Monte Carlo simulations to obtain the magnetic phase transition temperature of each structure. Additionally, coercivity and remanence values have been calculated for ferromagnetic cases, and we have investigated the hysteresis features of the MXenes of interest by applying a cyclic magnetic field at several temperatures.

Towards understanding time variations of proton to helium ratios in the heliosphere: Implication for the time dependence of the elements of the diffusion tensor

A comprehensive three-dimensional numerical model for the modulation of cosmic rays in the heliosphere is applied to investigate the relative roles of the time dependence of the elements of the diffusion tensor on the proton to total Helium (p/He) and Helium-3 to Helium-4 (3He2/4He2) ratios at rigidities below 3 GV. At these rigidities the ratios have been observed by both PAMELA and AMS-02 detectors to have a time variation in response to changing solar activity. We found that the contribution of the time dependence of the perpendicular diffusion in the radial direction of the heliosphere is the dominant cause of this observed time variation, especially in the A < 0 magnetic field cycle, and not any fundamental difference between the solar modulation of galactic protons and He-isotopes. It follows that neglecting this time dependence from numerical models, both in value and its rigidity dependence, would produce time trends in the mentioned ratios that are incompatible with observed trends at the Earth. Furthermore, we found differences in the computed time trends of p/He and 3He2/4He2 ratios at rigidities below 1.5 GV. This is mainly a consequence of an interplay between perpendicular diffusion in the radial direction and adiabatic energy losses which begin to influence modulated spectra at a higher rigidity for 3He2 than for 4He2, and for total He than for protons.

Enhanced magnetoelectric coupling effect in Mg-doped Y-type hexaferrite BaSrCo2-xMgxFe11.1Al0.9O22 ceramics

The influences of Mg doping on the magnetic order structure and magnetoelectric (ME) effect were investigated in Y-type hexaferrite BaSrCo2-xMgxFe11.1Al0.9O22 (x = 0.00, 0.25, 0.50, 0.75, 1.00) ceramics. The results revealed that the Mg doping could increase the magnetic phase transition temperature. The optimal magnetic-driven electric polarization could be obtained at x = 0.25 ceramic, exhibiting a maximum electric polarization of 16.22 μC/m2 and a ME coefficient of 203 ps/m at 100 K. The stability of reversible electric polarization was demonstrated via the measurement of continuous magnetic field cycles. Moreover, the ME phase diagram was established by measuring the magnetic dielectric properties. Finally, a possible Mg-tune magnetic structure was proposed to explain the enhanced ME effect.

The Magnetocaloric Effect in La(Fe,Mn,Si)&lt;sub&gt;13&lt;/sub&gt;H&lt;sub&gt;&lt;i&gt;x&lt;/i&gt;&lt;/sub&gt; Based Composites: Experiment and Theory

Abstract—Samples of composites with different porosity and surface roughness based on LaFe11.4Mn0.3Si1.3H1.6 (LFMSH) alloy powders were obtained, their magnetocaloric properties were studied by a direct method in cyclic magnetic fields μ0H = 1.2 T at a frequency of 2 Hz. The maximum value of the adiabatic temperature change in pure LFMSH powder was ΔT = 3 K at Т0 = 287 K in the sample cooling mode; for composite samples, this value turned out to be approximately 2 times lower than in the powder. The effect of Mn and H atoms on the electronic structure and local magnetic characteristics of the initial La(Fe,Si)13 alloy has been studied by the methods of the electron density functional theory. Replacing some of the Fe atoms with Mn reduces the total magnetic moment and slightly lowers the Curie temperature. Hydrogenation, on the contrary, leads to an increase in exchange interactions between Fe atoms located at the vertices of the icosahedron and an increase in the Curie temperature.

Simulations of dynamo action in slowly rotating M dwarfs: Dependence on dimensionless parameters

Aims. The aim of this study is to explore the magnetic and flow properties of fully convective M dwarfs as a function of rotation period Prot and magnetic Reynolds ReM and Prandlt numbers PrM. Methods. We performed three-dimensional simulations of fully convective stars using a star-in-a-box set-up. This set-up allows global dynamo simulations in a sphere embedded in a Cartesian cube. The equations of non-ideal magnetohydrodynamics were solved with the PENCIL CODE. We used the stellar parameters of an M5 dwarf with 0.21 M⊙ at three rotation rates corresponding to rotation periods (Prot) of 43, 61, and 90 days, and varied the magnetic Prandtl number in the range from 0.1 to 10. Results. We found systematic differences in the behaviour of the large-scale magnetic field as functions of rotation and PrM. For the simulations with Prot = 43 days and PrM ≤ 2, we found cyclic large-scale magnetic fields. For PrM &gt; 2, the cycles vanish and the field shows irregular reversals. In the simulations with Prot = 61 days for PrM ≤ 2, the cycles are less clear and the reversal are less periodic. In the higher PrM cases, the axisymmetric mean field shows irregular variations. For the slowest rotation case with Prot = 90 days, the field has an important dipolar component for PrM ≤ 5. For the highest PrM the large-scale magnetic field is predominantly irregular at mid-latitudes, with quasi-stationary fields near the poles. For the simulations with cycles, the cycle period length slightly increases with increasing ReM.

Influence of the interstellar magnetic field and 11-year cycle of solar activity on the heliopause nose location

Context. The heliosphere is formed by the interaction between the solar wind (SW) plasma emanating from the Sun and a magnetised component of local interstellar medium (LISM) inflowing on the Sun. A separation surface called the heliopause (HP) forms between the SW and the LISM. Aims. In this article, we define the nose of the HP and investigate the variations in its location. These result from a dependence on the intensity and direction of the interstellar magnetic field (ISMF), which is still not well known but has a significant impact on the movement of the HP nose, as we try to demonstrate in this paper. Methods. We used a parametric study method based on numerical simulations of various forms of the heliosphere using a time-dependent three-dimensional magnetohydrodynamic (3D MHD) model of the heliosphere. Results. The results confirm that the nose of the HP is always in a direction that is perpendicular to the maximum ISMF intensity directly behind the HP. The displacement of the HP nose depends on the direction and intensity of the ISMF, with the structure of the heliosphere and the shape of the HP depending on the 11-year cycle of solar activity. Conclusions. In the context of the planned space mission to send the Interstellar Probe (IP) to a distance of 1000 AU from the Sun, our study may shed light on the question as to which direction the IP should be sent. Further research is needed that introduces elements such as current sheet, reconnection, cosmic rays, instability, or turbulence into the models.

The nature of the frequency dependence of the adiabatic temperature change in Ni50Mn28Ga22-x(Cu, Zn)x Heusler alloys in cyclic magnetic fields

This study presents the results of direct measurements of the adiabatic temperature change (∆Tad) in Ni50Mn28Ga22−x(Cu, Zn)x (x = 0; 1,5) alloys in cyclic magnetic fields of 0.62 and 1.2 T at frequencies f= 1, 5, 10, and 20 Hz. The substitution of zinc and copper for the initial composition resulted in a decrease in ∆Tad and a stronger frequency dependence. The strong frequency dependence of ∆Tad near TC in the Ni50Mn28Ga22−x(Cu, Zn)x system is due to the inhomogeneous microstructure and the coexistence of martensite-austenite phases, which give rise to two simultaneously acting mechanisms. Firstly, the addition of Zn and Cu increases the coercive force HC, resulting in an increase in the viscosity coefficient. Secondly, an increase in the frequency of the cyclic magnetic field (i.e., an increase in the field sweep rate) leads to the same effect, increasing the viscosity coefficient. Which, in our opinion, is the reason for the frequency dependences of ∆Tad near TC. The study found that the specific cooling power (SCP) for the Ni50Mn28Ga22 sample in a cyclic magnetic field of 1.2 T increased with frequency, reaching 4.75 W/g at 20 Hz, which is 14.1 times greater than at 1 Hz. This suggests that, under conditions of sufficient heat exchange, the cooling efficiency of a magnetic refrigerator can be greatly improved by increasing the operating frequency.

Temperature–Frequency Dependence of the Magnetocaloric Effect Near the TC in the Ni50Mn28Ga22 Alloy in Cyclic Magnetic Fields

Temperature–Frequency Dependence of the Magnetocaloric Effect Near the TC in the Ni50Mn28Ga22 Alloy in Cyclic Magnetic Fields

Dynamic nuclear polarization weighted spectroscopy of multispin electronic-nuclear clusters

Nuclear spins and paramagnetic centers in a solid randomly group to form clusters featuring nearly degenerate, hybrid states whose dynamics are central to processes involving nuclear spin-lattice relaxation and diffusion. Their characterization, however, has proven notoriously difficult mostly due to their relative isolation and comparatively low concentration. Here, we combine magnetic field cycling experiments, optical spin pumping, and variable radiofrequency (RF) excitation to probe transitions between hybrid multispin states formed by strongly coupled electronic and nuclear spins in diamond. Leveraging bulk nuclei as a collective time-integrating sensor, we probe the response of these spin clusters as we simultaneously vary the applied magnetic field and RF excitation to reconstruct multidimensional spectra. We uncover complex nuclear polarization patterns of alternating sign that we qualitatively capture through analytical and numerical modeling. Our results unambiguously expose the impact that strongly hyperfine-coupled nuclei can have on the spin dynamics of the crystal, and inform future routes to spin cluster control and detection.

The extended solar cycle and asymmetry of the large-scale magnetic field

ABSTRACT Traditionally, the solar activity cycle is thought as an interplay of the main dipole component of the solar poloidal magnetic field and the toroidal magnetic field. However, the real picture as presented in the extended solar-cycle models is much more complicated. Here, we develop the concept of the extended solar cycle clarifying what zonal harmonics are responsible for the equatorward and polarward propagating features in the surface activity tracers. We arrive at a conclusion that the zonal harmonics with l = 5 play a crucial role in separating the phenomena of both types, which are associated with the odd zonal harmonics. Another objective of our analysis is the role of even zonal harmonics, which prove to be rather associated with the north–south asymmetry of the solar activity than with its 11-yr solar periodicity.