Magnesium Silicide Research Articles

Proposal and evaluation of Mg2Si-based vertical tunnel field effect transistor for enhanced performance

This work investigates the performance of silicon-on-insulator (SOI) based vertical heterojunction tunnel FET with magnesium silicide (Mg2Si) as source material (Mg2Si-VTFET) with silicon-based counterpart (Si-VTFET). The investigation utilizes SILVACO TCAD tool to analyse various metrics including electrical characteristics, radio-frequency performance, linearity, and distortion. Incorporation of low bandgap material at source forms hetero-junction at source-channel interface, thereby reducing the tunneling path and enhancing the tunneling rate of charge carriers. ON-state current (ION) and current switching ratio (ION/IOFF) for Mg2Si-VTFET improves by factor of approximately ∼ 105 and 102 times. Mg2Si-VTFET outperforms Si-VTFET in terms of ION current for low biasing voltages, transconductance (gm), gain-bandwidth-product (GBP), cut-off frequency (fT) and transit-time. However, Mg2Si-VTFET has better linearity and reduced distortions in terms of VIP2 and HD2 metrics. HD2 suppresses by 53.8 % for Mg2Si-VTFET over Si-VTFET. This suggests that Mg2Si-VTFET is better suited for applications requiring low distortion, such as in audio amplifiers or communication systems. Therefore, Mg2Si-VTFET shows strong candidacy over Si based counterpart for low power circuits.

Hydrogen Attenuates Cognitive Impairment in Rat Models of Vascular Dementia by Inhibiting Oxidative Stress and NLRP3 Inflammasome Activation.

Vascular dementia (VaD) is the second most common form of dementia worldwide. Oxidative stress and neuroinflammation are important factors contributing to cognitive dysfunction in patients with VaD. The antioxidant and anti-inflammatory properties of hydrogen are increasingly being utilized in neurological disorders, but conventional hydrogen delivery has the disadvantage of inefficiency. Therefore, magnesium silicide nanosheets (MSNs) are used to release hydrogen in vivo in larger quantities and for longer periods of time to explore the appropriate dosage and regimen. In this study, it is observed that hydrogen improved learning and working memory in VaD rats in the Morris water maze and Y-maze, which elicits improved cognitive function. Nissl staining of neurons shows that hydrogen treatment significantly improves edema in neuronal cells. The expression and activation of reactive oxygen species (ROS), Thioredoxin-interacting protein (TXNIP), NOD-like receptor protein 3 (NLRP3), caspase-1, and IL-1β in the hippocampus are measured via ELISA, Western blotting, real-time qPCR, and immunofluorescence. The results show that oxidative stress indicators and inflammasome-related factors are significantly decreased after 7dMSN treatment. Therefore, it is concluded that hydrogen can ameliorate neurological damage and cognitive dysfunction in VaD rats by inhibiting ROS/NLRP3/IL-1β-related oxidative stress and inflammation.

Silane Gas Production Through Hydrolysis of Magnesium Silicide by Hydrochloric Acid

Monosilane (SiH4) is a common precursor for the production of high-purity silicon for solar PV applications. As an alternative to carbothermic reduction of silica to produce metallurgical grade silicon with subsequent conversion to silane, an alternative route over magnesiothermic reduction of silica to Mg2Si has been explored in our earlier work. In the current work, silane gas production through hydrolysis of Mg2Si in HCl acid solution was studied. Two sources of Mg2Si were chosen: a commercial Mg2Si source and a Mg2Si source produced through magnesiothermic reduction of high-purity natural quartz. Effects of various parameters on the hydrolysis of Mg2Si, including different experimental setups, temperature of the acid solution, acid concentration, reaction time, and relative amounts of reactants were studied. The evolution of produced gases was determined by two different methods: firstly, by passing the produced gas through a KOH solution to capture Si with subsequent analysis of the Si content in the KOH solution by inductively coupled plasma mass spectrometry and secondly, on-line gas analysis by GC–MS. The silane distribution between different silane species with reaction time was evaluated and the activation energy of silane formation was calculated. The results indicated comparable silane yields obtained from the on-line GC–MS method and KOH solution analysis method, as well as for commercial Mg2Si and the Mg2Si–MgO mixture produced through magnesiothermic reduction. Furthermore, adding HCl acid to Mg2Si in water led to higher SiH4 formation yield than adding Mg2Si to acid. However, the total silane yield for the two methods was similar at approximately 32%.Graphical

CHANGES IN THE STRUCTURE AND PROPERTIES OF ALUMINIUM ALLOYS WHEN MODIFIED WITH POWDER COMPOSITIONS

Purpose. To determine the effect of modification with powder compositions on the structure and mechanical properties of cast and deformed aluminium alloys. Research methods. Metallographic analysis, stereometric metallography, testing of strength and plastic properties of cast alloys AL4, AL4C of the Al-Si system and deformed alloys 1545 of the Al-Mg-Sc system, 2219 of the Al-Cu-Mn system in their original and modified state. Results. Meltings of AL4, AL4C, 1545, 2219 alloys were carried out in the initial state and with melt treatment with a complex nano-disperse modifier of magnesium silicide Mg2Si and silicon carbide SiC with a particle size of 50...100 nm. The optimal content of Mg2Si+SiC (0.10%) for increasing σ0.2 of aluminium alloys was determined. A 1.6-fold reduction in the grain structure of cast alloys was achieved. The dependence of the particle size and the amount of the modifier on the mechanical properties of the alloys was established. In industrial experiments, the most effective particle size of Mg2Si+SiC was established for increasing σ0.2 of AL4, AL4C alloy from 115 to 260 MPa in the as-cast state. The increase in the strength properties of the modified alloys is 44 % compared to the original state. Scientific novelty. Further development, insight into the influence of melt modification on the parameters of the structure and properties of aluminium alloys was obtained. The use of nanodispersed complex modifier Mg2Si+SiС with a particle size of 50...100 nm is proposed. It has been confirmed that the use of complex nanodisperse modifiers allows you to actively influence the structure and mechanical properties of aluminium alloys. Practical value. It has been experimentally proven that the rational amount of the introduced complex modifier is 0.10% of the mass of the melt. A significant grinding of the grain structure and an increase in the strength properties of cast and deformed aluminium alloys were achieved as a result of the modification.

A study of concave shoulder angle on the mechanical properties and fractography of friction stir welded AA6061-T651 joints

AA6061-T651 material joints produced by friction stir welding (FSW) were analysed in this study. The analysis was conducted to determine the effect of the concave shoulder angle (CSA) of the tool on mechanical and fractographic properties. The mechanical properties studied included impact strength (IS) and hardness (HS), while the fractography included impact fracture and microstructure. The experiments used a Taguchi L16 (44) orthogonal array and were done thrice. The best parameters were then used four times for confirmation. The research findings confirmed that the change in CSA significantly impacts the IS of welded joints. Combining both artificial neural network (ANN) and genetic algorithm (GA), it was found that 9° is the best CSA for IS. The mechanical properties test results showed an IS of 0.806 J/mm2. The HS of the weld nugget zone (WNZ) decreased by 25.49 % compared to the parent material zone (PMZ). This decrease in HS is due to the phase change of magnesium silicide (Mg2Si), resulting in finer grains in the WNZ than in the PMZ. Meanwhile, the fracture angle of the impact test specimens was 81.7°, indicating moderate toughness characteristics.

On the Growth, Structure, and Optical Reflection of Magnesium Silicide Films Grown on Porous Silicon under High-Vacuum Conditions

On the Growth, Structure, and Optical Reflection of Magnesium Silicide Films Grown on Porous Silicon under High-Vacuum Conditions

Inhibition of free heme-catalyzed Fenton-like reaction prevents non-alcoholic fatty liver disease by hepatocyte-targeted hydrogen delivery

The metabolic disorder of hepatocytes in non-alcoholic fatty liver disease (NAFLD) leads to the formation of an iron pool which induces the Fenton reaction-derived ferroptosis and the deterioration of liver disease. The elimination of the iron pool for the removal of Fenton reactions is vitally important to prevent the evolution of NAFLD, but quite challenging. In this work, we discover that free heme in the iron pool of NAFLD can catalyze the hydrogenation of H2O2/‧OH to block the heme-based Fenton reaction for the first time, and therefore develop a novel hepatocyte-targeted hydrogen delivery system (MSN-Glu) by modifying magnesium silicide nanosheets (MSN) with N-(3-triethoxysilylpropyl) gluconamide to block the heme-catalyzed vicious circle of liver disease. The developed MSN-Glu nanomedicine exhibits a high hydrogen delivery capacity as well as sustained hydrogen release and hepatocyte-targeting behaviors, and remarkably improves the metabolic function of the liver in a NAFLD mouse model by the relief of oxidative stress and the prevention of ferroptosis in hepatocytes, accelerating the removal of the iron pool in fundamental support of NAFLD prevention. The proposed prevention strategy based on the mechanisms of NAFLD disease and hydrogen medicine will provide an inspiration for inflammation-related disease prevention.

Growth, Structure, and Optical Reflection of Magnesium Silicide Films Grown on Porous Silicon under High Vacuum Conditions

Growth, Structure, and Optical Reflection of Magnesium Silicide Films Grown on Porous Silicon under High Vacuum Conditions

Design and investigation of doping-less gate-all-around TFET with Mg2Si source material for low power and enhanced performance applications

Metal–oxide–semiconductor field-effect transistor (MOSFET) faces the major problem of being unable to achieve a subthreshold swing (SS) below 60 mV/dec. As device dimensions continue to reduce and the demand for high switching ratios for low power consumption increases, the tunnel field-effect transistor (TFET) appears to be a viable device, displaying promising characteristic as an answer to the shortcomings of the traditional MOSFET. So far, TFET designing has been a task of sacrificing higher ON state current for low subthreshold swing (and vice versa), and a device that displays both while maintaining structural integrity and operational stability lies in the nascent stages of popular research. This work presents a comprehensive analysis of a heterojunction plasma doped gate-all-around TFET (HPD-GAA-TFET) by making a comparison between Mg2Si and Si which serve as source materials. Charge plasma technique is employed to implement doping in an intrinsic silicon wafer with the help of suitable electrodes. A low-energy bandgap material, i.e. magnesium silicide is incorporated as source material to form a heterojunction between source and silicon-based channel. A rigorous comparison of performance between Si-based GAA-TFET and HPD-GAA-TFET is conducted in terms of electrical, radio frequency (RF), linearity, and distortion parameters. It is observable that HPD-GAA-TFET outperforms conventional Si-based GAA-TFET with an ON-state current (I ON), subthreshold swing (SS), threshold voltage (V th), and current switching ratio being 0.377 mA, 12.660 mV/dec, 0.214 V, and 2.985 × 1012, respectively. Moreover, HPD-GAA-TFET holds faster switching and is more reliable than Si-based device. Therefore, HPD-GAA-TFET is suitable for low-power applications.

New Chemical Synthesis Strategy To Construct a Silicon/Carbon Nanotubes/Carbon-Integrated Composite with Outstanding Lithium Storage Capability

The Si/C anode is one of the most promising candidate materials for the next-generation lithium-ion batteries (LIBs). Herein, a silicon/carbon nanotubes/carbon (Si/CNTs/C) composite is in situ synthesized by a one-step reaction of magnesium silicide, calcium carbonate, and ferrocene. Transmission electron microscopy reveals that the growth of CNTs is attributed to the catalysis of iron atoms derived from the decomposition of ferrocene. In comparison to a Si/C composite, the cycle stability of the Si/CNTs/C composite can obviously be improved as an anode for LIBs. The enhanced performance is mainly attributed to the following factors: (i) the perfect combination of Si nanoparticles and in situ grown CNTs achieves high mechanical integrity and good electrical contact; (ii) Si nanoparticles are entangled in the CNT cage, effectively reducing the volume expansion upon cycling; and (iii) in situ grown CNTs can improve the conductivity of composites and provide lithium ion transport channels. Moreover, the full cell constructed by a LiFePO4 cathode and Si/CNTs/C anode exhibits excellent cycling stability (137 mAh g-1 after 300 cycles at 0.5 C with a capacity retention rate of 91.2%). This work provides a new way for the synthesis of a Si/C anode for high-performance LIBs.

Design and Investigation of High Performance Magnesium Silicide Based Face Tunnel Field Effect Transistor

Design and Investigation of High Performance Magnesium Silicide Based Face Tunnel Field Effect Transistor

First-Principles Investigation of Electronic and Related Properties of Cubic Magnesium Silicide (Mg2Si)

We present results from ab initio, self-consistent calculations of electronic, transport, and bulk properties of cubic magnesium silicide (Mg2Si). We employed a local density approximation (LDA) potential to perform the computation, following the Bagayoko, Zhao, and Williams (BZW) method, as improved by Ekuma and Franklin (BZW-EF). The BZW-EF method guarantees the attainment of the ground state as well as the avoidance of over-complete basis sets. The ground state electronic energies, total and partial densities of states, effective masses, and the bulk modulus are investigated. As per the calculated band structures, cubic Mg2Si has an indirect band gap of 0.896 eV, from Γ to X, for the room temperature experimental lattice constant of 6.338 Å. This is in reasonable agreement with the experimental value of 0.8 eV, unlike previous ab initio DFT results of 0.5 eV or less. The predicted zero temperature band gap of 0.965 eV, from Γ to X, is obtained for the computationally determined equilibrium lattice constant of 6.218 Å. The calculated value of the bulk modulus of Mg2Si is 58.58 GPa, in excellent agreement with the experimental value of 57.03 ± 2 GPa.

Wear characteristics of Al-Mg<SUB align="right">2Si alloys of various weight fractions

Industrial applications such as aerospace and defence can benefit from its high strength-to-weight ratio, low thermal expansion coefficient, and good wear resistance. Because of its light weight and simplicity of machining, it has become a popular choice for manufacturing. It is also worth noting that the finish is excellent. These changes necessitate further investigation of Al-Mg2Si alloys. The wear properties of the alloys were examined in this study. Casting was used to develop magnesium-silicide aluminium alloys. Microstructural analysis revealed the existence of a hitherto unidentified magnesium silicide proeutectic. Disc wear behaviour and life span were determined using a computerised pin-on-disc testing procedure. As the sliding distance and time grew, the alloy began to show signs of wear.

Effect of chromium content on microstructure and properties of casting Al‐7Si‐0.35Mg‐0.02Sr alloy

AbstractThe effect of the addition of chromium between 0.1 % and 0.3 % on the structure and properties of Al‐7Si‐0.35Mg‐0.02Sr alloy was studied. The results show that as the chromium content increases, the alloy grains are refined, and the grains appear fine equiaxed after 0.2 % chromium addition. At the same time, chromium combines with iron to form AlCrFeSi phase, which significantly improves the iron phase morphology, making it change from needle shape to fish bone shape. In the aging stage, the Al13Cr4Si4 phase is dispersed in the alloy, and its phase relationship with the matrix is semi‐coherent and non‐coherent. When the chromium content continues to increase, the degree of dispersion of the Al13Cr4Si4 phase is higher, but the performance of the alloy decreases, because the chromium containing precipitate phase consumes magnesium and silicon solute atoms from the nearby melt, making the amount of magnesium silicide decrease. The Al‐7Si‐0.35Mg‐0.02Sr alloy with 0.2 % chromium showed the best mechanical properties (ultimate tensile strength, yield strength, elongation and hardness).

Textured Stainless Steel as a Platform for Black Mg2Si/Si Heterojunction Solar Cells with Advanced Photovoltaic Performance.

This paper reports on a facile bottom-up method for the direct integration of a silicon (Si)-magnesium silicide (Mg2Si) heterojunction solar cell (HSC) with a textured rear reflector made of stainless steel (SS). Modified wet chemical etching and post processing of SS substrates resulted in the formation of both a rough surface texture and diffusion barrier layer, consisting of magnetite (Fe3O4) with reduced optical reflection. Then, Si, Mg2Si and CaSi2 layers were stepwise thermally evaporated onto the textured SS surface. No traces of Fe and Cr silicide phases were detected by Raman spectroscopy, confirming effective suppression of impurity diffusion from the SS to the upper layers at least at temperatures required for Si deposition, as well as Mg2Si and CaSi2 formation. The obtained black-SS/Fe3O4/Si/Mg2Si/CaSi2 sample preserved, to some extent, its underlying textured morphology and demonstrated an averaged reflection of 15% over the spectral range of 200–1800 nm, while its prototype HSC possessed a wideband photoresponse with a photoelectric conversion efficiency of 7.5% under AM1.5 illumination. Moreover, Si layers deposited alone onto a black-SS substrate demonstrated competitive antireflection properties compared with black Si (b-Si) obtained by traditional top-down etching approaches, and hybrid b-Si/textured-SS structures with a glue-bonded interlayer.

High quality Mg(0001) films grown on Si(111)[formula omitted]-B surface at room temperature

Rotational epitaxy of Mg(0001) film on the Si(111) surface has been demonstrated at room temperature using a Si(111)3×3-B surface reconstruction as a template. The 3×3-B reconstruction, which spontaneously forms on the surface of a heavily-doped Si(111) substrate upon annealing, prevents the formation of magnesium silicide and provides the proper orientation of the film at which the lattice mismatch is lowered down. The film has excellent crystal quality as revealed by diffraction, scanning tunneling microscopy at low temperature (60 K) and photoelectron spectroscopy methods. Density functional theory calculations prove the hexagonal close-packed structure typical for the bulk Mg. The film demonstrates a pronounced quantum-well states effect. The energy position of the surface state is close to the relaxed bulk-like position at early stages of growth, which indicates the smaller interaction of the film with the substrate compared to growth on the bare Si(111).

Equations of state of α-SiC (6H) and βʹ-Mg2Si1.1 from single-crystal X-ray diffraction data and novel high-pressure magnesium silicide Mg2Si7

SiC and (Fe, Mg)-silicide are candidate phases forming under reducing conditions in the Earth and planetary interiors. However, structural studies of SiC and Mg2Si at high pressure and their thermal stability are presently lacking. In this work, we applied single-crystal X-ray diffraction in a diamond anvil cell at high pressure and determined the equations of state of α-SiC (6H) and βʹ-Mg2Si1.1 up to 60 and 40 GPa, respectively, yielding bulk moduli of 226.0(4) and 56(1) GPa. We also report the formation of a novel orthorhombic Mg2Si7 phase upon laser heating βʹ-Mg2Si1.1 at ~ 45 GPa and 2000 °C [Pbam, a = 7.16(1) Å, b = 12.490(3) Å, c = 2.6545(3) Å, V = 237.5(3) Å3]. The structure of this compound contains layers formed by irregular 12-member silicon rings, which are arranged in channels filled with both Mg and Si atoms. No signs of the Mg2Si7 phase were detected upon releasing the pressure in the DAC, which suggests that this phase is unstable under ambient conditions.

Thermoelectric properties of bismuth-doped magnesium silicide obtained by the self-propagating high-temperature synthesis

Thermoelectric properties of bismuth-doped magnesium silicide obtained by the self-propagating high-temperature synthesis

Mg2SiO4/Si-Coated Disproportionated SiO Composite Anodes with High Initial Coulombic Efficiency for Lithium Ion Batteries.

Silicon monoxide (SiO) is considered as one of the most promising anode material candidates for next-generation high-energy-density lithium ion batteries (LIBs) due to its high specific capacity and relatively lower volume expansion than that of Si. However, a large number of irreversible products are formed during the first charging and discharging process, resulting in a low initial Coulombic efficiency (ICE) of SiO. Herein, we report an economical and convenient method to increase the ICE of SiO without sacrificing its specific capacity by a solid reaction between magnesium silicide (Mg2Si) and micron-sized SiO. The reaction product (named MSO) exhibits a unique core-shell structure with uniformly distributed Mg2SiO4 and Si as the shell and disproportionated SiO as the core. MSO exhibits a superior ICE and a high reversible capacity of 81.7% and 1306.1 mAh g-1, respectively, which can be further increased to 88.7% and 1446.4 mAh g-1 after carbon coating, and improved cyclic stability compared to bare SiO. This work provides a simple yet effective strategy to address the low ICE issue of SiO anode materials to promote the practical application of SiO.

A Carbon-Free Way for Obtaining Nanoscale Silicon

The nanosized silicon powder has been produced by reduction of silica with magnesium in an argon medium using both the mechanically activated self-propagating high-temperature synthesis and the direct mechanochemical synthesis and has been investigated by X-ray phase analysis, Infrared spectroscopy, electron scanning microscopy, and energy dispersive X-ray spectroscopy. The optimal Mg:SiO2 ratio has been found to provide the minimum content of contaminant impurities of magnesium silicide and silicate in mechanically activated self-propagating high-temperature synthesis. For the first time, direct mechanochemical synthesis of Si via reduction of silica with magnesium has been implemented. Optimal component ratio and mechanical activation parameters have been determined, yielding Si/MgO composites without impurity phases (magnesium silicide and silicate). A purification procedure has been proposed for separating silicon obtained from magnesium oxide and other impurity phases. The ratio of initial components has been determined, at which purified silicon has the least amount of impurities. The particle size of silicon powder obtained was 50–80 nm for the mechanically activated self-propagating high-temperature synthesis, and 30–50 nm for the direct mechanochemical synthesis.