Magnesium and its alloys are expected to be used in various engineering fields, such as automobiles, trains, and electronic product enclosures due to their lightness and mechanical properties. Electropolishing of magnesium surfaces is an important technique for fundamental research works and industrial applications, and perchloric acid or nitric acid is typically used for electropolishing. However, these acids are highly reactive and hazardous, thus the usage should be avoided in the industrial application processes. In this study, we demonstrated a highly safe electropolishing process of magnesium using a novel sodium chloride/glycol solution.High-purity magnesium plates (99.95 wt%, 1 mm thick) were used as the starting materials. The specimens were ultrasonically degreased in ethanol for 10 min. The magnesium specimen as the anode and a platinum plate as the cathode were immersed in four types of glycol solutions including 0.5 M NaCl/ethylene glycol (EG), diethylene glycol (DEG), triethylene glycol (TrEG), and tetraethylene glycol (TeEG) solutions at 278-308 K, and linear sweep voltammetry (0.1 Vs-1) and constant voltage electrolysis (25-100 V) were carried out. After electrolysis, the surface of the specimens was examined by stereo microscopy (SM), scanning electron microscopy (SEM), and atomic force microscopy (AFM). The regular reflectance from the magnesium surfaces was measured using a spectrophotometer. Two types of industrial magnesium alloys including Mg-Al alloy, AZ31, and Mg-Li alloy, LZ91, were also used for electrolysis.As the voltage-current curves were measured by linear sweep voltammetry of the pure magnesium specimen in four types of glycol solutions, clear diffusion limiting currents were obtained after the initial current increases. We found that the unevenness of the magnesium specimens decreased by constant voltage electrolysis at appropriate applied voltages in NaCl/DEG and NaCl/TeEG solutions. Figure 1a shows the surface appearances of pure magnesium, LZ91, and AZ31 after constant voltage electrolysis at 50 V in NaCl/DEG solution for 60 min. The pure magnesium specimen and LZ91 alloy were successfully electropolished by constant voltage electrolysis and mirror-finished surfaces were obtained. On the other hand, the AZ31 alloy exhibited a nonuniform appearance with the coexisting of metallic luster and brownish regions, although a mirror-finished surface was obtained. The difference of the electropolishing behaviors between LZ91 and AZ31 alloys may be due to the metallographic structure such as the solid solution and intermetallic compound. Three-dimensional magnesium specimens possessing the curved and spiral structures could also be electropolished by constant voltage electrolysis in NaCl/DEG (Fig. 1b). Figure 1
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