Fractionation Of Magma Research Articles

Role of metasomatism in formation of the Yichun rare-metal deposit, China

What role post-magmatic processes have played in the development and mineralization of rare-metal peraluminous granites and how important that role can be, are questions that researchers have been wrestling with for decades. The Yichun Li-Ta-Nb deposit is an example that has been the subject of such a debate. The granitic appearance of rocks, the inert nature of tantalum, and the scarcity of mineralization in country rocks have been taken to suggest that fluid overprints were limited to within the granites and were unimportant in rock- and ore-forming processes. In this study, the identification of two types of abundant Li- and Cs-rich pseudomorphs in both the topaz-lepidolite granite and overlying pegmatite, the only two mineralized units at Yichun, suggests that extensive metasomatism was involved in rock and ore formation. The textural and chemical similarities of lepidolite in comparable mineral assemblages from a variety of occurrences, including lepidolite in pseudomorphs, veins, and miarolitic cavities from both the topaz-lepidolite granite and pegmatite, suggest that all lepidolite at Yichun is metasomatic and largely inherited its chemical signatures from a magmatic-hydrothermal transitional fluid, rich in Li, Cs, and Ta, derived possibly from the Li-muscovite granite that lies beneath the topaz-lepidolite granite. We propose that this transitional liquid, composition of which lies between a silicate melt and aqueous fluid, was not in equilibrium with the original igneous mineralogy, thus bringing about significant metasomatism along its infiltration and evolution upwards. Variations in the trace-element composition of lepidolite likely reflect the influence on mineral compositions by precursor minerals. The ambiguous boundary between the topaz-lepidolite and Li-muscovite granites, combined with the intensely metasomatized nature of the former, is most consistent with the topaz-lepidolite granite being the extensively altered upper portion of the Li-muscovite granite, which is itself somewhat metasomatized. Although magmatic fractionation played a key role in the initial concentration of Nb, Li, and Ta in both granite and pegmatite formation, the Li-Ta-Nb-Cs mineralization and its host rocks were largely formed through magmatic-hydrothermal rejuvenation and re-enrichment.

Age and petrogenesis of the Madi intrusion in the Huashi area, northern margin of the North China Craton: Implications for magma evolution and Nb–Ta mineralization

Although the mineralization of rare earth elements (REEs) and rare metals is intimately associated with the extreme fractionation of granitic magmas, the metallogenic intrusions of many granite-hosted Nb–Ta deposits have undergone fluid–melt interaction. Nevertheless, the precise mechanisms by which fluid–melt interaction influences mineralization remain poorly understood. The present investigation examines the issues of the fluid–melt interaction in highly fractionated granites with Nb–Ta mineralization, utilizing data from the newfound Huashi deposit in the northern margin of the North China Craton (NNCC). The Huashi Nb–Ta–Rb–Li deposit hosted in the Madi intrusion consists of two lithologies that have evolved continuously, namely medium–fine grained granite (MGG) in the lower section and alkali-feldspar granite (AG) at the top. The ages of the MGG and AG were determined using LA–ICP–MS columbite U–Pb dating, yielding values of 182.9 ± 1.7 Ma and 184.7 ± 1.3 Ma, respectively. The Madi intrusion has high SiO2, Al2O3, and total alkali contents, along with low CaO, MgO, MnO, and TFe2O3 contents and high Al2O3 / (CaO + Na2O + K2O) (A/CNK) values, classifying it as highly peraluminous granite with a high-K calc-alkaline affinity. Additionally, the intrusion also exhibits enrichment in Rb, U, Th, and Nb alongside significant depletion in Sr, Ba, Ti, Eu, and P, with a noticeable tetrad effect of REEs. The investigation of mica and feldspar minerals in the Madi intrusion using electron probe microanalysis (EPMA) indicates that the mica is mainly zinnwaldite, while the plagioclase belongs to albite. In summary, the Madi intrusion exhibits a highly I-type fractionated granite affinity. The extreme fractionation, intense fluid–melt interaction, and hydrothermal alteration of the intrusion contribute to the formation of the Huashi deposit.

Transcrustal magmatic systems in NE China: Insights from Early Cretaceous metaluminous–peraluminous–peralkaline rock associations in the southern Great Xing’an Range

The generation and evolution of crustal-scale magmatic systems are important in revealing the continental crust differentiation. In the Bayangeer-Aliwula area of Inner Mongolia, metaluminous–peraluminous–peralkaline rock assemblages provide a rare opportunity to evaluate Early Cretaceous magmatic systems. This study presents new geochemical data, including whole-rock and zircon geochemistry, zircon U–Pb dating, and Hf–O isotopic analysis of rocks formed between 132 and 121 Ma. The metaluminous rocks exhibit low SiO2 (55.35–65.65 wt%), low Rb/Sr (0.08–0.24) and (La/Yb)N (4.88–7.58) ratios, and positive εHf(t) values (+4.9 to +8.7). These features, along with enrichment in large-ion lithophile elements and depletion in Nb and Ta, suggest formation via partial melting of fluid-metasomatised lithospheric mantle. By contrast, peraluminous rocks have high SiO2 (69.37–80.58 wt%), a high differentiation index (DI = 88–95), and Fe-index (0.84–0.95), resembling highly fractionated I-type granites. They show high Rb/Sr (0.77–3.35) and (La/Yb)N (5.79–22.75) ratios, and positive εHf(t) values (+6.7 to +10.8), combined with the modelling results, indicating origin from partial melting of K-rich mafic lower crust followed by magma fractionation. Peralkaline rocks display typical ferroan A-type granite characteristics (Zr + Nb + Ce + Y = 906–4292 ppm; Fe-index = 0.96–0.99), with high SiO2 (74.02–77.50 wt%), high Rb/Sr (6.17–121.38), and (La/Yb)N ratios (2.19–17.72), and positive εHf(t) values (+3.1 to +9.6). Zircon geochemistry characteristics suggest that peralkaline and peraluminous felsic melts are different batches extracted from the same magma reservoir. Further analysis, including hyperbola diagrams and zircon oxygen isotope compositions, suggests peralkaline magma formation through the mixing of altered oceanic crust fluids and peraluminous melts after melt extraction. During Early Cretaceous, the transcrustal magmatic system provides a reasonable explanation for the petrogenesis of various contemporaneous rocks in the study area in southern Great Xing’an Range.

Geodynamic Evolution of the Proto-Tethys Ocean in the West Kunlun Orogenic Belt, northwest Tibetan Plateau: Implications from the Subarc Crust and Lithospheric Mantle Modification

Abstract Radiogenic isotopes serve as a crucial tool for investigating crustal evolution, playing a pivotal role in revealing magma sources and petrogenesis. However, they can be ineffective in distinguishing between distinct magmatic sources with similar radiogenic isotopic compositions, a common occurrence in nature. Here we addresse this challenge in the Ordovician igneous rocks from the West Kunlun orogenic belt (WKOB), aiming to distinguish between two potential magmatic sources (i.e. the Tarim Craton and the Tianshuihai terrane) with similar isotopic compositions using appropriate thermodynamic and geochemical modeling based on mineral and whole-rock geochemistry. Zircon U–Pb dating yields ages of 483 ± 3 Ma for the Pushou gabbros and 469 ± 2 Ma and 461 ± 2 Ma for the Datong monzogranites and syenites, respectively. The Pushou gabbros exhibit low SiO2 (47.4–49.1 wt %), high MgO (5.5–6.9 wt %), high large-ion lithophile elements (LILEs, e.g. Rb, Ba, Th, and K), and low high field-strength elements (HFSEs, e.g. Nb, Ta, Zr, Hf, P, and Ti), suggesting an origin in subduction-modified mantle. They display high whole-rock (87Sr/86Sr)i ratios (0.7156 to 0.7192), negative whole-rock εNd(t) values (−7.1 to −7.8), as well as high zircon δ18O values (7.6–7.9‰) and enriched zircon Hf isotopic compositions (εHf(t) = −5.3 to −7.7), which are consistent with 1–5% subducted sediments in an enriched mantle source. Trace element models further confirm that the gabbros are most likely derived from low-degree (~15%) partial melting of subduction-modified Tarim mantle in the spinel–garnet facies rather than from the Tianshuihai mantle. The Datong syenites belong to the shoshonitic series and are characterized by medium SiO2 (59.5–61.4 wt %), relatively low MgO (0.9–1.2 wt %) and Mg# (37–42), enrichment in LILEs and depletion in HFSEs. They have high whole-rock (87Sr/86Sr)i ratios (0.7103 to 0.7105) and negative whole-rock εNd(t) values (−3.8 to −4.3), along with negative to slightly positive zircon εHf(t) values (−3.8 to +2.6), similar to coeval mafic rocks. Thermodynamic and geochemical modeling suggest that the Datong shoshonitic rocks likely originated via crystal fractionation of shoshonitic basaltic magmas in the SW Tarim Craton. The Datong monzogranites have high SiO2 (69.7–72.6 wt %), low MgO (0.6–0.7 wt %), and a typical enrichment in alkalis, Zr, and Nb, with depletion in Sr, P, and Ti, consistent with A-type granites. They are characterized by high whole-rock (87Sr/86Sr)i ratios (0.7321 to 0.7323), negative whole-rock εNd(t) values (−11.3 to −11.8), negative zircon εHf(t) values (−11.0 to −16.5), and high zircon δ18O values (7.2–8.0‰), indicating derivation from the remelting of an ancient crustal source. Thermodynamic, major, and trace element modeling indicate that their parent magma may have been generated by water-deficient (~2 wt %) partial melting of ancient crustal material beneath the SW Tarim Craton rather than that of the Tianshuihai terrane, under high-temperature (T > ~950°C) and low-pressure (P = 5–8 kbar) conditions. Based on the tectonic framework of the WKOB, we propose that the original mantle and crust beneath the southern Kunlun terrane may have been modified or partially replaced by that beneath the SW Tarim Craton during the Ordovician. Therefore, this evidence for Tarim-derived magmatism, when combined with regional sedimentary and structural records, indicates that Ordovician magmatism in the southern Kunlun terrane is most consistent with episodic northward subduction of the Proto-Tethys Ocean, commencing at ~485 Ma. Middle Ordovician slab break-off can explain the formation of the A-type granites, but reinstated northward subduction is required for the generation of late Ordovician Datong syenites.

Anatomy of a Lunar Silicic Construct—The Wolf Crater Complex, Mare Nubium and Implications for Early Silicic Magmatism on the Moon

AbstractSilicic lithologies on planetary surfaces indicate magmatic evolutionary processes in their interiors. The Wolf crater complex within Mare Nubium on the Moon is one such silicic construct associated with a high thorium anomaly. This study integrates morphological, compositional, chronological and gravity anomaly analyses of high‐resolution data from various lunar missions to establish this construct as a silicic volcanic caldera. Lobate flows with steeply sloping fronts indicate that the crater rims comprise high‐viscosity silicic lavas, while the structurally controlled inner crater walls suggest caldera collapse triggered by magma depletion. In the crater rims, low Christiansen Feature position values reaffirm the presence of silicic lithologies, consistent with the low gravity anomaly signature beneath the complex, while spectroscopic data reveal low mafic mineral abundances and negligible hydration features. Chronological analyses yield silicic volcanism ages coeval with surrounding mare basalts (3.8–3.6 Ga), while intra‐caldera basalts have 2.36–2.02 Ga ages, indicating prolonged magmatism in this region. Melting of suitable crustal protoliths like alkali gabbronorite/monzogabbro/troctolite by basaltic underplating is inferred to have generated silicic magmas that formed the Wolf volcanic complex, instead of basaltic magma fractionation or silicate‐liquid immiscibility processes. Large impacts during the Late Heavy Bombardment may have enhanced partial melting of the mantle and created crustal fractures that facilitated the ascent of viscous silicic melts through the lunar crust. Contemporaneous existence of suitable protoliths and adequate crustal pathways for magma ascent may have controlled silicic volcanism on the Moon, and can explain the sporadic occurrence and overlapping ages of the lunar silicic constructs.

In-situ geochemical and isotopic analyses of multiple pyrite generations: Insights for the giant Beiya Au polymetallic ore genesis in southwestern China

The Beiya giant Au polymetallic deposit is located in the Sanjiang Tethyan Orogen, northwestern Yunnan (SW China). The ores occur as disseminations or veinlets in granite porphyry. To unravel the ore genesis at Beiya, we analyzed the ore-related sulfide trace elements and sulfur isotopes. Py-1 is mainly euhedral-subhedral medium-/coarse-grained (size: > 100 μm), with relatively smooth surface and some pores. Py-2 is mostly coarse grained (size: 50–200 μm), with well-developed pores and inclusions. The pyrite is usually Co-Cu rich and V-Ti-Sb poor, resembling typical magmatic-hydrothermal pyrite. In addition, the Co/Ni ratios decrease from pyrite-1 (Py-1) to pyrite-2b (Py-2b), suggesting that their chemical compositions are controlled by magma fractionation. We found that Co, Ni, As, and Se occurred as solid solution in the pyrite lattice, while Pb, Bi, Ag, and Mn occurred mainly in inclusions in the pyrite. Pb and Bi display good positive correlation, suggesting that they occurred as inclusions or nano-particles in pyrite lattice. The pyrite samples have sulfur isotope value (δ34S) of 0.62–3.45 ‰ (avg. 2.35 ‰) for Py-1, 0.18–3.12 ‰ (avg. 1.85 ‰) for Py-2a, and 0.62–4.18 ‰ (avg. 2.51 ‰) for Py-2b. These characteristics may have played a vital role in the initial enrichment of Cu, Mo, Au, and ultimately formed the complex polymetallic system at Beiya.

Late Palaeozoic high-K calc-alkaline to shoshonitic series magmatism and related W(–Mo–Cu–Au) metallogeny of the Kyrgyz Tien Shan, Central Asia

In the Kyrgyz Tien Shan, numerous high-K calc-alkaline to shoshonitic series intrusions are associated with the large fault system known as the ‘Major structural line of Tien Shan’, or ‘Nikolaev Line’. During the Carboniferous, this lineament represented a zone of intracontinental, possibly back-arc rifting associated with a north-dipping subduction, whereas in the Late Carboniferous to Permian it was part of a larger continental collision structure. These Late Paleozoic high-potassic intrusions comprise numerous intrusive phases that vary in composition from the early mafic (monzogabbro, monzodiorite) through intermediate (monzonite, syenite, quartz syenite) to late stage and more evolved (quartz monzonite, granodiorite, monzogranite, leucogranite–alaskite) members locally intersected by monzodiorite–porphyry and lamprophyre dykes. They can be related to low degrees (from ∼1–2 to 2–2.5 vol%) of partial melting of metasomatically enriched upper mantle followed by magma fractionation and emplacement at shallower crustal levels. In summary, the high-K magmas formed in continental- and post-collisional arc settings with a progressive input of crustal material. From the west to the east, the potassic intrusions contain progressively higher Nb and Y concentrations, reflecting their derivation in a post-collisional setting. The A-type granite signatures also become more distinct in this direction. This is consistent with the tectonic model implying the ‘scissor-like’ closure of the Late Paleozoic Turkestan palaeo-ocean from east to west. These high-potassic intrusions are accompanied by W–Mo–Cu–Au skarn/porphyry to Au(–W) replacement-style deposits, which are part of the extended Au (Au–W–Mo–Cu) metallogenic belt of Tien Shan. The association of skarn and porphyry-style W–Mo to Mo–Cu–Au–W mineralization defines these ‘porphyry–skarn’ systems as a distinct group containing strongly oxidized andradite-dominant skarns. An early W partitioning into magmatic–hydrothermal fluid, together with Mo and Cu, is typical of this magmatic–hydrothermal system and can be explained by an early H 2 O saturation of the parental magma. The late-stage mafic dykes including lamprophyres probably reflect the presence of another, but concealed, mafic intrusion releasing CO 2 and metals, such as Au, As, Sb, Bi and Te, into the hydrothermal mineral system.

Magmatic-hydrothermal evolution of the Dangba rare-metal granitic pegmatites in the Songpan–Ganzê orogenic belt, Eastern Tibet: Insights from muscovite and columbite-group minerals

Rare-metal granitic pegmatites are commonly considered to be the results of a combination of magmatic and hydrothermal processes. Although magmatic crystallization and fractionation, and magmatic-hydrothermal transition have been extensively investigated, the processes related economically valuable mineralization of rare-metals and strong fractionation of geochemical twins remain controversial. This study presents a comprehensive analysis of the geochemical evolution of rare-metal mineralized pegmatites, focusing on the mineral chemistry of muscovite and columbite-group minerals (CGM) from the Dangba rare-metal granitic pegmatites in the Songpan–Ganzê orogenic belt. Our findings suggest that the random orientation growth of spodumene crystals and widespread distribution of disordered columbite-group minerals crystals are indicative of lithium saturation in the initial melt at the Dangba No. VII dike. Magmatic fractionation is indicated by gradually increasing ratios of alkali metals (K/Rb ratios) and Ta# (Ta/(Ta + Nb)) in muscovite and CGM, and is proposed to be an important factor for enrichment of rare-metals. During the magmatic-hydrothermal transition, muscovite from metasomatism of spodumene exhibits similar or slightly higher levels of Li, Rb, and Cs, compared to primary muscovite, but shows strong depletion of Ta, Nb, Sn, and W. Alteration of primary minerals (e.g., spodumene, alkali feldspar, and columbite-group minerals) results in the release of these elements into the reactive media (melt/fluid) during the metasomatism. This process ultimately leads to the depletion of rare metals in the early crystallized minerals. However, this process is advantageous for the subsequent mineralization of Ta and Nb, as well as their fractionation. The chemical compositions of exsolved aqueous fluid are influenced by the mineralogy of pegmatites and the partitioning behavior between melt and fluid. Furthermore, pervasive albitization serves as an exploration criterion for Li–Ta–Nb in the Ke'eryin Orefield.

Geochemical and Isotopic Constraints on the Origin of Rare-Metal Enriched Alkaline A-Type Granites from the Nubian Shield: Role of Mantle Metasomatism

Abstract The U-Pb zircon TIMS age of 637.47 ± 0.23 Ma identifies the oldest anorogenic complex in the northern Nubian Shield as that at Mount Hamr, emplaced as elongated plutons along deep-seated faults, intruding the Pan-African shield rocks. The hypersolvus peralkaline granites of Mount Hamr are dominated by perthite, quartz, and arfvedsonite, along with accessory zircon, chevkinite-(Ce), monazite, aenigmatite, apatite, fluorite, and opaque ilmenite. The rocks are depleted in Al, Ca, and Sr and enriched in Rb, high field strength elements (Zr, 528–1115 ppm), and rare earth elements (ΣREE, 416–1648 ppm), showing fractionated, light rare earth element-enriched patterns [(La/Yb)N = 17]. The rocks are classified as ferroan, reduced A-type granites (A1-subtype) and exhibit age-corrected (143Nd/144Nd)(i) ratios ranging from 0.5115 to 0.5117, with [ϵNd(t) = +5.0 to +5.9] similar to HIMU-OIB, and have lower age-corrected (87Sr/86Sr)(i) ratios (avg. Sr(i) = 0.702). The data yield Nd-TDM2 model ages of 860–929 Ma. High Zr/Hf, (Ce/Pb)N and low Y/Nb, (Th/Nb)N in these rocks reflect OIB-geochemical-signatures. The rocks crystallized at high temperature (TZr = 900–1185 °C) from H2O–depleted melt via extensive low-pressure fractionation of OIB-type parent magma, initially developed from a Na-F-rich metasomatized mantle source. The latter may have led to the formation of similar rare-metal-enriched alkaline intrusions within the vast Arabian-Nubian Shield and possibly within some magmatic provinces occurring in other shields.

The giant Baerzhe rare-earth-element–Nb–Zr–Be deposit, Inner Mongolia, China, an Early Cretaceous analogue of the Strange Lake rare-metal deposit, Quebec

The Baerzhe deposit represents world-class mineralization of rare metals, in particular rare earth elements (REEs) and Nb, and shares mineralogical and geochemical similarities with the Strange Lake deposit in Canada. However, the mechanisms responsible for the rare-metal enrichment at Baerzhe are still under debate. Mineralization at Baerzhe is characterized by multiple stages of dissolution, re-precipitation and enrichment of rare-metal elements, as with the Strange Lake deposit. Zirconium was concentrated during magmatic fractionation of elpidite in a transsolvus agpaitic granite (Stage I), and was redistributed into zircon–quartz pseudomorphs during Na-metasomatism (Stage II). Rare earth elements, Nb and Be occur as a variety of mineral assemblages, mainly as pseudomorphs after complete replacement of unknown precursor minerals that are disseminated through the hematized transsolvus granites and were precipitated in three sequential stages (Stages III–V): Stage III is characterized by the mineralization of hingganite, aeschynite-(Y), columbite-(Fe) and euxenite-group minerals, accompanied by hematite alteration; the following Stage IV is defined mainly by monazite-(Ce) crystallization, and Stage V by the preceding REE minerals being replaced by light REE minerals (i.e. bastnäsite-(Ce) and fluocerite-(Ce)). The formation of various pseudomorphs as replacement for precursor minerals is also a common feature documented at Strange Lake. Our results call for a re-evaluation of the timing and role of meteoric waters at Baerzhe, which were suggested by previous researchers to have entered the ore-forming system prior to the mineralization of zircon. New in situ O isotopic analyses on pseudomorph-hosted mineral pairs and investigation of silicate melt–fluoride melt immiscibility through observations and analyses of melt inclusions could provide further insights into the nature of the Baerzhe system.

Understanding the links between volcanic systems and epithermal ore formation: A case study from Conical Seamount, Papua New Guinea

The Tabar-Lihir-Tanga-Feni (TLTF) island chain in northeastern Papua New Guinea formed by tectonic and alkaline to shoshonitic magmatic activity since the Pliocene. Several volcanic centers are CuAu mineralized including the world-class Ladolam Au deposit and Conical Seamount south of Lihir. The latter has been recognized as a juvenile analogue to the Ladolam deposit located on-shore. Whereas the mineralization at Conical Seamount is reasonably well studied, the specific magmatic processes that promote epithermal mineralization at this seamount but not at others are poorly understood. Here, we present new petrological and geochemical data from Conical Seamount, and compare them with those from the barren (unmineralized) Edison, Tubaf and New World seamounts nearby. We focus on whole rock compositions and major and trace element analysis of melt inclusions and minerals including clinopyroxene, sulfide and magnetite. We combine our observations with modelled constraints on mantle source composition and partial melting as well as magma evolution. A first-stage melting leaves a residual mantle source enriched in Au. Second-stage melting of a previously subduction-metasomatized mantle generally promotes the transfer and concentration of metals and volatiles in the ascending melts. These magmas are unlikely to control ore formation as all seamounts show evidence for similar mantle sources and parental melt composition. However, the presence of a shallow crustal magma chamber is unique to Conical Seamount. It is characterized by frequent melt replenishments and extensive magma fractionation leading to sulfide and magmatic volatile saturation. These specific magma chamber processes lead to the pre-enrichment of the magma in chalcophile elements including Au, while sulfide saturation coeval with magmatic volatile exsolution provide the way for an effective Au transfer from the magmatic to the epithermal system.

Mesozoic crustal growth and recycling along the Southern margin of Eurasia: Magmatic rocks from the Sanandaj-Sirjan Zone of Iran

The Sanandaj-Sirjan Zone of western Iran is characterized by significant Mesozoic magmatic activity (from the early Jurassic to the late Cretaceous), with Cenozoic rocks being less common. Granitoids are prevalent in this zone, displaying A-, I-, and S-type geochemical characteristics. Despite several studies on these granitoids, there are still some questions regarding their sources– especially the S- and A-type granitoids – and the crustal growth and recycling in this zone, which require further studies using isotopes. This study focuses on the Aligoodarz, Kolah-Ghazi, and Golpayegan granitoids from the central SaSZ to better understand crustal growth and recycling in the Sanandaj-Sirjan Zone. The Aligoodarz and Kolah-Ghazi granitoids are identified as S-type granites, showing strong peraluminous signatures. Geochemical evidence suggests a mixture of melts from sub-crustal metasedimentary and meta-igneous sources, with factors such as source diversity and disequilibrium melting contributing to their formation. in contrast, the Golpayegan granitoids exhibit high total alkali (Na2O + K2O) contents and high field strength elements, indicating alkaline magmatic affinity. Their geochemical signatures suggest derivation from an enriched portion of an Indian MORB-like protolith. Golpayegan syenites share similarities with within-plate A1 granites, suggesting they are related to anorogenic silica-oversaturated granitoids. Golpayegan A-type granites probably originated from high-degree fractionation of alkali basic magmas. Golpayegan gabbros may be derived from a MORB or OIB-like mantle source, with characteristics indicating the presence of garnet in the mantle source and potentially deep melting from a mantle plume. Newly compiled zircon UPb data from the Sanandaj-Sirjan Zone show a complex magmatic chronology spanning from approximately 180 million years ago to the Eocene epoch, revealing peaks of magmatic activity at various intervals. Distinct phases of A-, I-, and S-type magmatism are identified, and synthesis of zircon UPb ages and HfO isotope data reveals the simultaneous occurrence of S-type and I-type magmas during specific periods. Furthermore, our study explores the tectonic settings underlying these magmatic processes and proposes scenarios involving subduction, continental rifting, and asthenospheric upwelling to elucidate the geological dynamics of the SaSZ.

Genesis of the Jiada pegmatite lithium deposit in the Ke’eryin ore field, western Sichuan, China: Evidence from whole-rock trace element and Li isotope

The origin and petrogenesis of pegmatite-type lithium deposits within the Songpan-Garze Fold Belt (SGFB) of western China remain subjects of debate. To provide further insight on this subject, this study investigated the whole-rock trace elements and whole-rock Li isotopic compositions of the two-mica monzogranite (TMG) from the Ke’eryin composite pluton, the Jiada albite pegmatite (AP) and albite-spodumene pegmatite (ASP) and their metasedimentary wall rocks within the Ke’eryin ore field in the eastern SGFB. Modeling of muscovite-dehydration melting based on the whole-rock trace elements (e.g., Li, Rb, and Sr) and Rayleigh dehydration modeling related to the whole-rock Li isotopes suggest that the Jiada pegmatites are unlikely to have originated from the low-degree partial melting of metasandstone (MS) of the Zhuwo Formation. Variations in the whole-rock trace elements and Li isotope between the TMG and the Jiada pegmatites are consistent with the evolution trend of magmatic fractionation. However, the whole-rock Li isotopic compositions of the AP and ASP display inverse variation characteristics with the muscovite Li isotopic compositions, with the AP exhibiting lower Li concentrations and higher whole-rock δ7Li values than ASP. Furthermore, the variation patterns of whole-rock trace elements do not align perfectly with the Rayleigh-type fractional crystallization processes, implying other geological processes would be also involved in the formation of the Jiada pegmatites. Collectively considering the Li isotope behavior during various geological processes, the observed variations in whole-rock Li isotopic compositions between AP and ASP can be explained by aqueous fluid enrichment during the pegmatitic melt evolution. This suggests that fractional crystallization and fluid exsolution jointly contributed to pegmatite formation and Li mineralization in the Jiada deposit. Moreover, the whole-rock δ7Li values of the wall rock of ASP (MS2) are lower than those of MS and the wall rock of ASP (MS1), primarily due to metasomatism by 6Li-enriched fluids expelled from ASP and the kinetic diffusion of Li isotopes. The high concentrations of highly mobile elements, especially Li and Cs, combined with the low whole-rock δ7Li value of the metasandstone, could serve as effective tracers for locating concealed orebodies and evaluating the metallogenic potential of Li mineralization.

Petrogenesis and zircon U-Pb ages of the Late Paleozoic high-potassic Sonkul and Kokturpak plutons in Kyrgyz Tien Shan, with implications for related skarn-porphyry W-Au(-Cu-Mo) mineralization

ABSTRACT The Sonkul and adjacent Kokturpak multiphase plutons are situated along the ‘Major Structural Line of Tien Shan’ (known also as the ‘Nikolaev Line’) that extends for over 500 km and divides the terranes of the Middle and Northern Tien Shan. The plutons comprise a broad variety of high-potassic igneous rocks including the early olivine gabbro, intermediate monzonite to quartz monzonite, and later granodiorite, monzogranite, and leucogranite-alaskite, in turn followed by the late mafic dikes. U-Pb dating of zircon grains yields ages of 299 ± 2 Ma (olivine gabbro), 300 ± 3 Ma to 298 ± 3 Ma (monzonite to quartz monzonite), 299 ± 3 Ma to 298 ± 4 Ma to 297 ± 4 Ma (granodiorite), and 289 ± 4 Ma to 285 ± 2 Ma (monzogranite). These consecutive intrusive phases appear to have been produced by partial re-melting of a partially crystallized (mush) magma batch at deeper levels, which is evident by the presence of zircon antecrysts dated at some 306–311 Ma (up to 323 Ma?). Geochemical signatures of the igneous rocks correspond to high-K calc-alkaline to shoshonitic series intrusions emplaced in a transitional subduction-related to post-collisional setting. A low-degree partial melting of the metasomatically enriched upper mantle can be envisioned as the leading process of shoshonitic magma generation; this was followed by amphibole fractionation in a deep (lower crustal ?) magma chamber and possibly a mantle-induced generation of granitic magmas in the crustal protolith. Further mixing/mingling of the mafic magma and crustal granitic magma was followed by the magma fractionation and emplacement at shallow crustal levels. Assimilation of the old continental crust is consistent with the presence of ancient xenocrystic zircons (dated at ca. 1.5 to 2.5 Ga) in the studied rocks. The Late Carboniferous to Early Permian age and high-K calc-alkaline to shoshonitic composition are similar to those of highly mineralized intrusions of the other segments of the Middle Tien Shan. In this regard, several magmatic pulses of high-potassic intrusions and corresponding metallogenic pulses can be suggested in this region. Whereas the early (ca. 337 to 315 Ma) igneous suites accompanied by dominantly porphyry Cu-Au-Mo mineralization, the later (ca. 305 to 285 Ma) suites including the Sonkul and Kokturpak plutons are accompanied by W- and/or Au-dominant mineralization. This mineralization appears to pre-date more substantial intrusion-related to orogenic-type Au mineralization.

The mafic–ultramafic roots of a Mesoarchean microblock in southern India: Insights from petrochemistry and isotope geochronology of the Coorg Block

The Coorg Block in southern India is an archive of Paleo-Mesoarchean arc magmatism and continental building in the early Earth. Here we investigate a suite of mafic and ultramafic rocks and associated lithologies to characterize the roots of this microcontinent. We present petrologic, geochemical, as well as U-Pb and Lu-Hf data on zircon and U-Pb data on monazite from these rocks which provide insights into the petrogenesis of the rocks as well as the timings of magmatism and subsequent metamorphism. The geochemical features of the mafic granulites indicate that the rock suite was derived from the fractionation of a sub-alkaline tholeiite magma. Most of the rocks correspond to arc setting in a subduction-related tectonic regime. The rocks exhibit relative enrichment in LILE, Pb, and LREE with depletion in HFSE such as Nb and Ta suggesting partial melting of a metasomatized mantle wedge. Their high LILE/HFSE and LREE/HFSE ratios indicate slab dehydration and mantle wedge melting in typical island arc settings. The overall trace element and REE patterns of the rocks indicate that the source magma of the ultramafic and mafic rocks might have been derived from a refractory mantle source followed by the metasomatic enrichment of lithospheric mantle wedge by incompatible elements through the influx of subduction-derived fluids/melts. We present comprehensive zircon U-Pb data and Lu-Hf data on a suite of mafic granulite, garnet-bearing granulite, tremolite actinolite schist, charnockite, and anorthositic gabbro as well as monazite U-Pb data from a charnockite sample. Most zircon grains show cores with magmatic crystallization features and many grains are mantled by metamorphic rims. The age data show a prominent peak at 3.1 Ga for most of the rocks suggesting that the major crustal building in the Coorg Block occurred during the Mesoarchean. Rocks on the margins of the block were affected by the younger (Neoarchean) tectonothermal event in the surrounding blocks. The Lu-Hf isotopic data on zircon grains with ca. 3.1 Ga ages show εHf(t) values ranging from −4.4 to + 3.7 (average + 0.3). In the εHf(t) versus 207Pb/206Pb age diagram, the plots are distributed close to the CHUR line suggesting Paleo-Eoarchean juvenile magma sources. The voluminous mafic lower crust at the root of the Coorg Block is consistent with addition of mafic magmas through slab melting induced by high mantle potential temperatures in the Archean, as well as the interaction of fluids/melts with the mantle wedge.

A mantle origin for Pliocene SiO2-rich ignimbrites in the modern Colombian magmatic arc

The generation of voluminous SiO2-rich magmas has been extensively investigated due to their petrologic implications and because they pose a significant natural hazard. Two main petrogenetic models have been proposed to explain these volcanic products: partial melting of the continental crust and fractional crystallization and assimilation of mantle-derived magmas. In the central segment of the modern Colombian magmatic arc, the northernmost Andean magmatic arc, the eruption of voluminous rhyolitic pyroclastic rocks occurred at 2.6 Ma, covering an area of ∼3000 km2. This contribution presents Hf-Nd-Sr-Pb whole-rock isotopes, zircon UPb geochronology, and major/trace-element data from Pliocene rhyolitic ignimbrites and Quaternary andesitic lava flows from the modern Colombian magmatic arc to understand the mechanisms responsible for the formation of high-silica magmas.The whole-rock and zircon geochemistry and Nd-Sr-Pb-Hf isotopic signatures indicate that this high-silica magmatism is mantle-derived and underwent extensive crystal fractionation and limited assimilation of the continental crust. Extreme magma fractionation at low temperatures and crustal thicknesses above 45 km could have favored the production of cumulates and fast (< 5 Ma) crustal thickening. These results highlight the major role of the mantle in generating high-silica magmatism and the associated crustal thickening, a process that has been poorly understood in the Northern Andes.

Unravelling the effects of magmatic fractionation, fluid phase separation and dilution on the composition of magmatic-hydrothermal fluids of the Cornubian Batholith (SW England)

The compositional evolution of magmatic-hydrothermal fluids from the SnW mineralized Cornubian batholith was investigated via in situ fluid inclusion LA-ICP-MS microanalysis and reveals a large degree of variation between intrusive stages and at the sample scale, with complexities due to superposition of several mechanisms affecting fluids chemistry during the protracted evolution of the batholith. Despite large ranges of salinities (from <1 wt% to 48 wt% NaCleq.), the effects of individual processes such as magmatic differentiation, fluid saturation and boiling, fluid mixing and dilution can all be discerned on the basis of fluid inclusion trace element geochemistry combined with detailed petrography and microthermometry.In all samples, different fluid types (aqueous liquid-rich, vapor-rich and brine inclusions) were identified in variable proportions and microthermometry revealed complex temporal trends. Granite-related samples from the G5 intrusive stage are characterized by intermediate density fluids undergoing magmatic fractionation under pressure conditions above 1.5 kbar, indicated by successively decreasing fluid salinities with concomitant increases in Li, B, Rb and Cs concentrations. The latter two elements later strongly partitioned in the brine phase upon boiling, together with most of the other Cl-complexing elements (e.g., Fe, Mn, Pb, Zn). Those brines subsequently underwent progressive dilution with meteoric waters that caused a decrease in the concentration of all elements (besides B) and homogenization temperatures. In G3 granite from Dartmoor, on the other hand, brine inclusions represent the earliest fluid type while intermediate density fluids are absent, and a large salinity range in the fluid inclusion record associated with a decrease in homogenization temperatures represents their progressive dilution with meteoric fluid. The lack of intermediate density fluids at Dartmoor indicates fluid exsolution at relatively low pressures resulting in immediate phase separation into brine and vapor.All studied samples associated with ore mineralization display only the trend of dilution of high-salinity magmatic fluids. Their transition metal contents (e.g. Fe, Mn, Pb and Zn) show the expected positive correlation with salinity of the fluids. Conversely, the compositional trends observed for Sn and particularly W are more enigmatic, as they do not appear to significantly fractionate during most of the physicochemical processes outlined above and appear to be unrelated to fluid salinity, opposite of what would be expected for Sn as it is dominantly transported in Cl-complexes.This study highlights the key advantages of high-resolution geochemical fluid inclusion studies in discerning a variety of magmatic and post-magmatic processes in fluids in comparison to bulk fluid inclusion techniques or more simplistic fluid inclusions studies which might overlook important aspects of the typically complex history of fluids evolution in magmatic-hydrothermal systems.

The Geology and Mineral Chemistry of Beryl Mineralization, South Eastern Desert, Egypt: A Deeper Insight into Genesis and Distribution

Beryl mineralization in the Nugrus-Sikait domain in the South Eastern Desert (SED) of Egypt occurs as disseminated crystals in granitic pegmatite and quartz, as well as pegmatite veins crosscutting mélange schist and ophiolitic rocks. When granitic pegmatite comes into contact with the ophiolitic rocks, phlogopite and amphibole schists are formed due to K metasomatism. The ophiolitic mélange is intruded by leucogranite and related pegmatite along the NNW to NW Nugrus shear zone. Beryl samples have been collected from Um Sleimat, Madinat Nugrus, Wadi Abu Rusheid, and Wadi Sikait. Major oxides and in situ trace and rare earth elements (REEs) of beryl and associated minerals were analyzed through EPMA and LA-ICP-MS, respectively. The investigated beryl, based on its color and chemical compositions, can be classified into the two following types: pegmatitic beryl (type I) and schist-related beryl (type II). The former is colorless to pale green, and is mainly restricted in pegmatite veins; it is poor in Cr2O3 (up to 0.03 wt%) and MgO (Nil). The latter, deep green in color, is rich in Cr2O3 (up to 0.27 wt%) and MgO (up to 2.71 wt%), and occurs within quartz veins, phlogopite schists, and tremolite schists. The abundant beryl mineralization in phlogopite schists and their related quartz veins suggests that granite and associated pegmatite are the source rocks for the Be-bearing fluids that migrate along the NW-SE trending deep-seated tectonic zone, such as the Nugrus shear zone. Therefore, the formation of beryl in schists is attributed to the interaction of granitic/pegmatitic-derived Be-bearing fluids with serpentinite and gabbro interlayered with mélange schists. Variations in the trace and REE contents of both beryl types (I and II) indicate their two-stage formation from different compositions of Be-rich fluids, where light REEs, Zr, Nb, Ba, and Th decrease from type I beryl to type II. These two phases of beryl could be attributed to the magmatic/hydrothermal fluids associated with the pegmatite emplacement. The early phase of the late-stage magmatic-derived fluids was closely related to magma evolution and pegmatite formation, forming euhedral type I beryl. The late phase of pegmatite-derived fluids was mixed with serpentinite/schist-derived fluids that cause high V and Cr content in type II beryl. The composition of parent magmas of felsic rocks, the high degree of magma fractionation or the late stage melts, fluid compositions (rich in Be, Li, Cs, Rb, K), and alkali metasomatism, as well as the linear NW-SE trending deep-seated shear zone, are all factors possibly influencing beryl mineralization in the SED of Egypt.

Significant variations in the structure and composition of the crust beneath northwestern India: Imprints of magmatism

Northwestern India was affected by the Neoproterozoic Malani and Erinpura magmatism, Cretaceous rifting, and magmatism associated with the Deccan precursors. Receiver function analysis was done using 1704 RFs from 18 stations to image and decipher the imprints of the magmatic events and comprehend the crustal modifications in terms of variations in structure and composition. The H-κ grid search and neighbourhood inversion techniques are used to retrieve the crustal structure and Vp/Vs ratios (κ). The study reveals significant variations in the crustal thickness (H = 34 km to 43 km), composition (κ=1.74 to 1.92) and shear wave velocity structure across northwestern India. The terrains encompassing the Erinpura granite and the Malani igneous suite in the vicinity of the Barmer rift are characterized by a thick (H ≥ 41 km) crust with felsic to intermediate composition (κ ≤ 1.81). The crust beneath the southern part of the Marwar basin is ≈ 38–40 km thick with mafic composition (κ> 1.81). The region around the Barmer rift has a thin crust (H = 34–36 km) with intermediate to mafic composition. The region hosting the Early Cretaceous to Paleogene alkaline complexes exhibits a high Vp/Vs ratio (κ= 1.91) that may be associated with mafic cumulates emplaced by magmatic events that overprint the signatures of the Malani event. The crust is heterogeneous with low/high velocity intracrustal layers that reflect the fractionation of magma at different depths. The mafic residue, together with magmatic intrusions, results in a mafic lowermost crust with high shear velocities of 3.9–4.0 km/s beneath most stations. Overall, northwestern India is characterized by a thick crust with intermediate crustal composition and intracrustal layering resulting from large scale magmatic events linked to the Neoproterozoic reorganization of plates and younger magmatic events.

An enhanced chemical maturation of juvenile arc crust recorded by the Urad Houqi intrusive suite in Langshan arc, Central Asia

Continental arc magmatism is crucial in producing juvenile continental crust of andesitic to dacitic composition, yet its impact on the formation of the modern mature continental crust, which is more enriched in potassic and granitic components, remains poorly understood. We examined a suite comprised of norite gabbro, gabbroic diorite, high-Mg diorite, dioritic enclave, and medium-K to high-K granites (the Urad Houqi suite) from the Langshan arc in the southern Central Asian Orogenic Belt (CAOB). Zircon U-Pb geochronology indicates that the Urad Houqi suite was formed ca. 278−268 Ma by a continuous magmatic event, marking the final episode of the late Paleozoic continental arc magmatism in the southern CAOB induced by the subduction of the Paleo-Asian Ocean. The suite exhibits a more potassic and fertile composition compared to typical continental arc magmas, and shows a continuous increasing K2O/Na2O ratio and incompatible element concentrations, including K, Rb, Th, and U, with increasing SiO2 content. The geochemical evolution of the suite offers valuable insights into the maturation process of the juvenile arc crust. By combining zircon Hf and bulk-rock Sr-Nd-Pb isotope studies, we demonstrated that the various lithologies within the Urad Houqi suite recorded a three-stage enhancement of the geochemical fertility of the juvenile Langshan arc crust: (1) generation of the initially fertile primary melt from the mantle wedge metasomatized by the recycled subducted sediments; (2) trans-crustal open-system hybridization processes, including peritectic reaction and magma mixing, that further fertilized the derived melts in addition to fractional crystallization; and (3) diverse petrogenetic processes that contributed to the fertility of the granitic magmas, including polybaric fractionation of the primary magma, anatexis of ancient crust, and extraction of high-silica melts from the shallow mush system. The three-stage maturation of the juvenile Langshan arc crust was typically coupled with the accelerated subduction of the Paleo-Asian Ocean since the earliest Permian. Our study finds that the Urad Houqi suite can serve as an example of modern continental crust maturation at continental arc settings.