Magmatic Contribution Research Articles

Enrichment of massive sulfdes from the Semenov hydrothermal cluster (Mid-Atlantic ridge) in barite: a result of E-MORB involvement and magmatic contribution

The paper reviews and compares the barite fndings in hydrothermal felds of the mid-oceanic ridges. The genetic signifcance of barite is considered for the Semenov hydrothermal sulfde cluster associated with an oceanic core complex (OCC) at 13°30? N of the Mid-Atlantic Ridge. Massive sulfdes of the Semenov-1, -3, and -4 felds are enriched in barite (up to 20 vol. %) and therefore Ba (up to 4.12 wt. %). The presence of a signifcant amount of barite and a high Ba content of massive sulfdes of the OCC-related felds link their formation with E-MORBs. Magmartic contribution for the formation of massive sulfdes from some Semenov felds is supported by negative values of S isotopic composition of sulfdes associated with barite, the presence of magmatic gases (CO2 and SO2) in Raman spectra of fuid inclusions in barite and the results of physicochemical modeling, which indicate the formation of barite-sulfde assemblage upon the interaction of E-MORBs, seawater, and magmatic gas. The results of modeling of the system with felsic rocks show that oceanic plagiogranites from OCC structure could be an additional supplier of Ba.

Ilei fluorite-phenakite ore phenomenon (Eastern Sayan): contribution of Devonian riftogenic magmatism to formation of Eastern Sayan rare metal metallogenic zone

Within the Altai-Sayan fold region, covering the territory of the East Tuva Highlands and Eastern Sayan, one of the richest rare metal provinces of Russia is concentrated. Deposits of rare metals, elements and lands formed within its limits have different ages and arose in different geotectonic environments and in different metallogenic eras. They are associated with the introduction of alkaline rock masses that are common along the fault system between the caledonids of the Altai-Sayan fold region and the Tuvino-Mongolian Precambrian superterrane. Their distribution range is also defined as the East Sayan rare metal metallogenic zone (VSMZ), which arose due to the impact of mantle plumes on the southwestern framing of the Siberian platform. Geochemical and geochronological studies were carried out at the Ilei fluorite-phenakite ore show. Ore development resulted from the introduction of Ognite complex granitoids into the limestones of the Mongoshin formation, which became a geochemical barrier to the igneous fluid enriched with fluorine and Be. Geochronological Rb-Sr and Ar-Ar studies have shown that subalkaline granites, as well as acidic volcanites of the Ilean sequence, are of Middle Devonian age ~ 390 million years, which is consistent with age estimates for the rocks of the Ognite complex. Thus, the same age of magmatism and ore formation at the Ilei ore phenomenon indicates the contribution of Devonian magmatism to the formation of rare metal mineralization within the VSMZ.

Assessing magmatic contributions to rift-related geothermal systems in collisional orogens: Insights from the Sangri-Cona rift, southern Tibetan Plateau

Fault-controlled geothermal systems in the Himalayan-Tibetan orogen could receive heat and material from deep-seated magmas due to crustal anatexis in orogenic settings. The near N-S trending rifts in southern Tibetan Plateau host abundant geothermal systems but potential role of residual magmas remains less constrained. Here, we evaluate magmatic contributions to geothermal systems in Sangri-Cona rift (SCR), the youngest rift in southern Tibetan Plateau, based on chemical and isotopic compositions of thermal waters from a south-to-north sampling profile. Our results show that the thermal springs in the central SCR have significant inputs from magmatic fluids, which account for high B concentrations and positive shift in δ18OH2O, while those in the southern and northern SCR are dominated by recharge of meteoric water. Water-rock interaction constrained by 87Sr/86Sr, hydrochemistry, and geothermometry results, suggests a hotter or deeper groundwater circulation path beneath central SCR than that of the southern and northern SCR. The identified magmatic fluid inputs, higher reservoir temperature, and higher degrees of water–rock interaction in the central SCR agree well with the presence of high conductivity anomalies at crustal depths of ∼ 10–30 km revealed by magnetotelluric surveys. Our findings provide geochemical evidence for the impact of lithospheric extension and associated geological and geophysical expressions (e.g., extension-induced exhumation of genesis domes that recorded crustal anatexis and upwelling of partially molten crustal channel flows) on modern geothermal systems in collisional orogens.

Origins and nature of large explosive eruptions in the lower East Rift Zone of Kīlauea volcano, Hawaii: Insights from ash characterization and geochemistry

Several powerful explosive eruptions have taken place in the populated lower East Rift Zone of Kīlauea within the past ∼750 years. These have created distinctive landforms, including a tephra rim enclosing Puʻulena Crater immediately south of the Puna Geothermal Venture power station, a tuff cone at Kapoho Crater near the eastern cape of the Island of Hawaiʻi, and a set of littoral cones, the Sand Hill in Nānāwale, where the 1840 lava flow poured into the ocean. Kapoho Crater tuff cone is the largest of these recent pyroclastic features. Mineral, glass, and melt inclusion analyses of tuff cone ash and later fissure-related scoriaceous materials also found within the crater indicate slightly evolved basaltic magmas (1120–1130 °C) that are compositionally similar to parts of the effusive lower East Rift Zone eruptions in 1955 and 2018. Tuff cone magmas were stored at depths of ∼2.5–3.5 km and had pre-eruptive volatile contents (0.5–0.8 wt% H2O, 280–340 ppm CO2, 1400–1800 ppm S) similar to other Kīlauea eruptions (e.g., 1959, 1960), suggesting that internal magma properties were unlikely to account for the unusual explosiveness of this eruption. Tephra componentry, grain-size analyses, and field observations confirm that the cone grew during a phreatomagmatic eruption mostly of vitric ash, probably where a fissure opened across the coastline or shallow ocean floor nearby. Supporting this hypothesis is the identification of at least two genera of marine diatoms within tuff cone strata. Sand Hill littoral cone ash is also vitric like that of Kapoho Crater, but distinctly coarser with abundant fluidal ejecta represented. In contrast, the Puʻulena Crater eruption deposited lithic ash and related blocks with minor juvenile magmatic contribution; a phreatomagmatic eruption that was dominantly phreatic. Differences in eruption styles are related to unique mechanics that tephra analyses help us interpret. While powerful explosive eruptions in the lower East Rift Zone are rare, they present a definite future hazard for inhabitants in this part of Hawaii.

New data on the geological structure and zonality of the Vorontsovka gold field in the Northern Urals

Spatial distribution of gold, copper, and iron ore deposits in the Northern Urals with the largest Turya-Auerbakh ore region is controlled by north-west trending linear zones of a probably fault nature. The influence has been demonstrated of regional factors (including the tectonic, magmatic, and geochemical ones) favoring formation of the large Au-As-Sb-Hg-Tl Vorontsovka deposit located within a volcanogenicsedimentary, substantially carbonate rock sequence. Closely spaced swarms of Devonian pre-ore and Carboniferous post-ore mafic dykes have been identified within the deposit. The primary geochemical halos of the Vorontsovka deposit have a multielement composition and, coupled with the ores, form a thick ore-halo zone confined to the gentle tectonic contact of sandstone-siltstone and limestone units. The main halo-forming elements are zonally distributed in the section. The footwall side of the gold deposit (rear zone) is dominated by Zn, Cd, Cu, Pb, Ag, and Bi; the axial zone, by Sb, Hg, Tl, and As; and the hanging side (frontal zone), by
 As, Zn, Hg, Pb, Ag, (Cu). In the east (closer to the Auerbakh granitoid massif), Ag, Zn, Pb, Mn, Y, Mo, and W relatively accumulate, while in the west (most remotely from the intrusive), Sb, Ba, As, Hg, Co, Ni, and Sn dominate. The 40Ar/39Ar age of ~391.1 million years, obtained for hydromica of the gold-arsenic ores, corresponds to the period of emplacement of granodiorite of the final Auerbakh massif intrusive phase. The conclusion is made on the crucial magmatic contribution to the formation of gold ores of the deposit.

A stable isotope (S, C and O) study of metamorphosed polymetallic sulphide deposits in the Bergslagen district, Sweden: The Stollberg example

Abstract The Paleoproterozoic Stollberg Zn-Pb-Ag plus magnetite ore field contains SVALS-type stratabound, limestone-skarn hosted sulphide deposits within volcanic (bimodal felsic and mafic rocks)/volcaniclastic rocks metamorphosed to the amphibolite facies. The sulphide ores consist of semi-massive to disseminated to vein-network sphalerite-galena and pyrrhotite (with subordinate pyrite, chalcopyrite, arsenopyrite and magnetite). Thermochemical considerations and stabilities of minerals in the systems K-Al-Si-O-H and Fe-S-O and sulphur isotope values for sulphides of δ34SVCDT = +1.12 to +5.71 ‰ suggest that sulphur most likely formed by inorganic reduction of seawater sulphate that was carried in hydrothermally modified seawater fluid under the following approximate physicochemical conditions: T = 250o–350 oC, δ34SΣS = +3 ‰, I = ∼1 m NaCl and a total dissolved S content of ∼0.01 to 0.1 moles/kg H2O. However, a magmatic contribution of sulphur cannot be discounted. Carbon and oxygen isotope compositions of calcite in altered rocks spatially associated with mineralisation show values of δ13CVPDB = −2.3 to −0.8 ‰ and δ18OVSMOW = +9.5 to +11.2 ‰, with one anomalous sample exhibiting values of δ13CVPDB = −0.1 ‰ and δ18OVSMOW = +10.9 ‰. Most carbonates in ore show lighter C and O isotope values than those of Proterozoic (Orosirian) limestones and are likely the result of premetamorphic hydrothermal alteration involving modified seawater followed by decarbonation during regional metamorphism. The isotopically light C and O isotope values are consistent with those for carbonates spatially associated with other SVALS-type deposits in the Bergslagen ore district and suggest that such values may be used for exploration purposes.

The magmatic origin of the Columbia River Gorge, USA.

Along subduction zones, high-relief topography is associated with sustained volcanism parallel to the plate margin. However, the relationship between magmatism and mountain building in arcs is poorly understood. Here, we study patterns of surface deformation and correlated fluvial knickpoints in the Columbia River Gorge to link long-term magmatism to the uplift and ensuing topographic development of the Cascade Range. An upwarped paleochannel exposed in the walls of the Gorge constrains unsteady deep magma flux, the ratio of intrusive to extrusive magmatic contributions to topography, and the impact of magmatism on Columbia River incision since 3.5 million years ago. Geophysical data indicate that deep magma influx beneath the arc axis is ongoing and not aligned with the current locations of volcanic edifices, representing a broad regional influence on arc construction.

The Ilee Fluorite–Phenakite Ore Occurrence, East Sayan: Contribution of Rift Devonian Magmatism to the Formation of the East Sayan Rare Metal Metallogenic Zone

The Ilee Fluorite–Phenakite Ore Occurrence, East Sayan: Contribution of Rift Devonian Magmatism to the Formation of the East Sayan Rare Metal Metallogenic Zone

Superimposed Gold Mineralization Events in the Tuanshanbei Orogenic Gold Deposit, Central Jiangnan Orogen, South China

Abstract The Jiangnan orogen, one of the largest gold-producing areas in China, has experienced multiple orogenic events with complex structural overprinting that is marked by multiple stages of magmatism, deformation, metamorphism, and orogenic gold mineralization. Different orogenic events have been recognized in the Neoproterozoic, mid-Paleozoic, Triassic, and Early Cretaceous, reflecting collisions and intracontinental orogenic episodes. The age of gold deposition in the Jiangnan orogen, however, has been poorly constrained owing to the absence of suitable dating minerals. Field studies in the orogen indicate the Tuanshanbei gold deposit includes two generations of auriferous quartz-ankerite-pyrite-arsenopyrite veins (Q2 and Q3), with the latter of the two notable for containing more abundant ankerite and base metal sulfides. The Q2 veins were formed throughout the near S-N–directed shortening associated with D1 deformation and along resulting subhorizontal to low-angle-dipping EW- to WNW-striking transpressive faults. The Q3 veins, containing about 70% of the total gold resource, were primarily localized in moderately to steeply dipping NW-striking tensional/tensional shear faults and moderately dipping NE- to NNE-striking transpressive faults that were products of NW-SE–directed shortening during D2 deformation. Both vein generations are temporally younger than the 437.2 ± 4.2 Ma Tuanshanbei granodiorite host, and both are crosscut by postgold ca. 225 Ma diabase dikes. Hydrothermal monazite coexists with native gold and gold-bearing metal sulfides in the Q2 and Q3 veins. The Q2 monazite yielded a Tera-Wasserburg lower intercept age of 415.1 ± 2.1 Ma, consistent within error with an ankerite Sm-Nd isochron age of 410 ± 15 Ma and a laser ablation-inductively coupled plasma-mass spectrometry hydrothermal zircon 206Pb/238U age of 411.2 ± 4.0 Ma. The Q3 monazite yielded a Tera-Wasserburg lower intercept age of 234.3 ± 1.1 Ma. These new ages suggest that the Early Devonian gold event was overprinted by hydrothermal activity along the same structural system almost 200 m.y. later such that the gold resource must be a product of two temporally distinct events. Geologic and structural evidence, coupled with existing published geochemical data, suggests both ore-forming events were related to crustal metamorphism typical of most orogenic gold deposits. Fluids would have been derived from Neoproterozoic metasedimentary basement rocks, most likely from metamorphic devolatilization of the Neoproterozoic Cangxiyan Group greenschist-amphibolite facies metasediments. There is no evidence suggesting any type of magmatic contribution to the ore-forming process at either time. The data are best interpreted to suggest that various parts of the basement were metamorphosed near the greenschist-amphibolite boundary at different times, but during both times, the gold-bearing metamorphic fluids eventually migrated into the same structural conduits.

Boiling-induced extreme Cu isotope fractionation in sulfide minerals forming by active hydrothermal diffusers at the Aegean Kolumbo volcano: Evidence from in situ isotope analysis

Abstract We analyzed the first Cu isotopes in primary cupreous pyrite and orpiment, from modern CO2-degassing, seafloor massive sulfide diffuser vents (“KCO2Ds”), from the Kolumbo submarine volcano, Hellenic volcanic arc. Samples came from six KCO2Ds that are actively boiling. Pyrite comprises colloform pyrite-I and euhedral pyrite-II, which occur erratically distributed within the KCO2Ds and are contemporaneous with barite and spatially concurrent with the chalcopyrite that is lining narrow internal conduits, respectively. Orpiment occurs on the outer walls of the KCO2Ds with barite and stibnite. The δ65Cupyrite-I values show high variability, ranging from +2.93‰ to +6.38‰, whereas the δ65Cupyrite-II and δ65Cuchalcopyrite values vary from −0.94‰ to +0.25‰ and −0.45‰ to –0.09‰, respectively. The range of δ65Cuorpiment between +1.90‰ and +25.73‰ is the most extreme ever reported from any geological setting. Pyrite-I is concentrically layered, with a core comprising random crystallites, whereas the mantle crystallites have grain-size, shape, and orientation variability between layers. Pyrite-II forms aggregates of uniform euhedral pyrite crystals. Pyrite-I has higher concentrations of Cu (≤21,960 ppm) compared to pyrite-II (≤4963 ppm), and both have incompatible and volatile metal(loid)-rich composition and low Sb/Pb (<0.5) and Tl/Pb (<0.03) ratios. When combined with evidence for significant magmatic contributions at Kolumbo and geochemical and micro-textural evidence for recurrent intense boiling and/or flashing or gentle and/or non-boiling, the measured extreme δ65Cu values are consistent with transport of Cu by vapor that is preferentially enriched by heavy 65Cu and controlled by continuous Rayleigh distillation–type Cu fractionation. Boiling-induced Cu vapor transport can generate extreme Cu isotope fractionation.

Pre-eruptive water content and volatile degassing processes in the southern Okinawa Trough magma: Implications for subduction zone water recycling and magmatic contributions to hydrothermal systems

Pre-eruptive water content and volatile degassing processes in the southern Okinawa Trough magma: Implications for subduction zone water recycling and magmatic contributions to hydrothermal systems

Quantifying the influence of magmatism and tectonism on ultraslow-spreading-ridge hydrothermal activity: Evidence from the Southwest Indian Ridge

Hydrothermal activity in mid-ocean ridges (MORs) is an important intermediary for the mass and heat exchange between the ocean and lithosphere. The development of hydrothermal activity on MORs is primarily controlled by coupled magmatic and tectonic activities. In ultraslow-spreading ridges, deep-dipping low-angle normal faults with large offsets, typically detachment faults in the inside corners of ridge offsets, favor the formation of tectonic-related hydrothermal activities, whereas volcanic-related hydrothermal fields are typically developed in neovolcanic zones in this category of the ridge system. However, whether tectonic or magmatic activity is dominant and to what extent they control the formation of hydrothermal activities on ultraslow-spreading ridges remain unclear. Segments in the west and east of the Gallieni transform fault (TF) located in the ultraslow-spreading Southwest Indian Ridge (SWIR), namely, western area (WA) and eastern area (EA), exhibit distinct magma-supply conditions that provide favorable conditions for examining the influence of magmatic and tectonic activities. We generated prediction models for these areas using the spatial analysis of the water depth, minor faults, large faults, ridge axis, nontransform discontinuity (NTD) inside corners, TF inside corners, Bouguer gravity anomaly, magnetic anomalies, and seismic activities. By employing the weights of evidence method, we reported that the formation of seafloor hydrothermal systems in SWIR was primarily correlated to the NTD inside corner, ridge axis, and minor fault (i.e., contrast values (C) of 4.186, 3.727, and 3.482 in WA and 4.278, 3.769, and 3.135 in EA). Furthermore, EA was significantly affected by the TF inside corner (C = 3.501), whereas WA was influenced by large faults (C = 4.062). Our results demonstrated that tectonism was the primary controlling factor in the development of hydrothermal activities in the study area, and the contribution of magmatism was secondary, even in WA, which has a relatively robust magma supply. We delimited prominent prospecting areas at each side based on posterior probability. Our results provided insights into the formation mechanisms of hydrothermal activities and support prospecting in MORs.

Deep magma degassing and volatile fluxes through volcanic hydrothermal systems: Insights from the Askja and Kverkfjöll volcanoes, Iceland

Mantle volatiles are transported to Earth's crust and surface by basaltic volcanism. During subaerial eruptions, vast amounts of carbon, sulfur and halogens can be released to the atmosphere during a short time-interval, with impacts ranging in scale from the local environment to the global climate. By contrast, passive volatile release at the surface originating from magmatic intrusions is characterized by much lower flux, yet may outsize eruptive volatile quantities over long timescales. Volcanic hydrothermal systems (VHSs) act as conduits for such volatile release from degassing intrusions and can be used to gauge the contribution of intrusive magmatism to global volatile cycles. Here, we present new compositional and isotopic (δD and δ18O-H2O, 3He/4He, δ13C-CO2, Δ33S-δ34S-H2S and SO4) data for thermal waters and fumarole gases from the Askja and Kverkfjöll volcanoes in central Iceland. We use the data together with magma degassing modelling and mass balance calculations to constrain the sources of volatiles in VHSs and to assess the role of intrusive magmatism to the volcanic volatile emission budgets in Iceland.The CO2/ΣS (10−30), 3He/4He (8.3–10.5 RA; 3He/4He relative to air), δ13C-CO2 (−4.1 to −0.2 ‰) and Δ33S-δ34S-H2S (−0.031 to 0.003 ‰ and −1.5 to +3.6‰) values in high-gas flux fumaroles (CO2 > 10 mmol/mol) are consistent with an intrusive magmatic origin for CO2 and S at Askja and Kverkfjöll. We demonstrate that deep (0.5–5 kbar, equivalent to ∼2–18 km crustal depth) decompression degassing of basaltic intrusions in Iceland results in CO2 and S fluxes of 330–5060 and 6–210 kt/yr, respectively, which is sufficient to account for the estimated CO2 flux of Icelandic VHSs (3365–6730 kt/yr), but not the VHS S flux (220–440 kt/yr). Secondary, crystallization-driven degassing from maturing intrusions and leaching of crustal rocks are suggested as additional sources of S. Only a minor proportion of the mantle flux of Cl is channeled via VHSs whereas the H2O flux remains poorly constrained, because magmatic signals in Icelandic VHSs are masked by a dominant shallow groundwater component of meteoric water origin. These results suggest that the bulk of the mantle CO2 and S flux to the atmosphere in Iceland is supplied by intrusive, not eruptive magmatism, and is largely vented via hydrothermal fields.

Chemical vectoring in continental geothermal systems: Composition of altered rocks and illite as guides to magmatic degassing

The Taupō Volcanic Zone, New Zealand, is one of the most voluminous volcanic regions on Earth. Over the last 1.8 Myr, bimodal volcanism in this rifted-arc setting has been dominated by voluminous rhyolite ignimbrite eruptions (>6000 km3 cumulative) and minor arc-type andesite and dacite, underpinned by basaltic intrusions. The combination of the magmatism and extensionally thinned arc crust with high heat flow has resulted in more than 23 active geothermal fields in the region. The fluids sampled in the geothermal systems are dominated by dilute meteoric fluids that are low in components such as acids, alkalis, and some trace metals commonly ascribed to magmatic sources but can contain large amounts of deep sourced magmatic volatiles such as CO2.This study was designed to assess the long-term (>20,000yr) fluid and metal input into two Taupō geothermal systems, and the amount and proportion of magmatic-derived components in these fluids. We collected major and trace element compositions of hydrothermal altered whole rocks and clay minerals from two active geothermal systems and compared them with hydrothermally altered rocks of the fossil (0.6 Ma) Ngatamariki magmatic-hydrothermal system, which has a demonstrated large magmatic contribution. The Ohaaki and Rotokawa geothermal systems have both been drilled to a depth of 3000 m, with sampled reservoir fluids containing low concentrations of chloride (∼1000 mg/kg) but high levels of gas (CO2, N2) that have previously been interpreted to reflect subduction components derived from arc-type magmas. Whole-rock samples lack enrichment in chloride-transported metals such as Cu, Pb or Zn but have minor anomalies of bisulfide-complexed Au, Sb, and As in the uppermost 1500 m of the geothermal reservoirs. Hydrothermal water-rock interactions in the deep reservoirs of both geothermal systems at temperatures between 220 and 300 °C produced assemblages of illite + albite + adularia + calcite + pyrite that are in equilibrium with the observed neutral to slightly acidic pH (6 ± 1) of the present-day fluids. In the lower temperature end of this range, Mg and Fe increasingly enter the illite crystal lattice via Tschermak-type (phengite) substitution, whereas a few high-temperature (>300 °C) samples contain scarce muscovite compositions. The illites commonly have low contents of most trace metals, although minor amounts of Cs, Li, Cu, Sb and Sn occur in near-surface samples. Based on these data, over the >20,000-year lifetime of the Ohaaki and Rotokawa geothermal systems, fluids were dominated by chloride-poor meteoric water and contained little magmatic contributions other than conducted heat, some gases (CO2 - N2 ± H2S), and a small fraction of the total H2O of geothermal waters. Therefore, the inferred magma bodies of intermediate to silicic composition that lie at shallow depth beneath these geothermal systems currently are not, and likely have not been for >20,000 years, degassing significant water and chloride despite the high water and chloride contents of the magmas. By inference, the intermediate to silicic magmas at depth have not transferred large amounts of volatiles to the geothermal systems over this period, and rather are storing them in the magmatic bodies to be released in volcanic eruptions that are commonly explosive and pyroclastic in nature and highly hazardous.

U-Pb Dating, Lead Isotopes, and Trace Element Composition of Pyrite Hosted in Black Shale and Magmatic Rocks, Malaysia: Implications for Orogenic Gold Mineralization and Exploration

Several orogenic/sediment-hosted gold deposits are widely distributed in the Central Belt of Peninsular Malaysia. This study combines U-Pb dating with the isotope composition of lead as well as gold content in ore and magmatic rock-hosted pyrite. It aims to investigate the age of gold mineralization and possibly establish a link between gold mineralization and magmatic intrusion in the district. The results show that the S-type magmatic rocks yield crystallisation ages ranging from 204.1 ± 4.7 Ma to 223 ± 3.2 Ma with low magnetic susceptibility measurements below 3 × 10−3 SI unit. These ages fit within the 200–250 Ma Pb-Pb model age of the Pb isotopic composition of K-feldspars. Pyrite trace element mapping has shown that gold and lead show zoning patterns occurring at the same time in pyrite. The Pb isotope composition of the cores of pyrite grains indicate that the approximate model age of gold mineralization is 200 Ma. This age is close to 197–199 Ma (Early Jurassic), previously determined by K-Ar dating of sericite which was interpreted to be the age of gold mineralization. In this study, gold content varies up to 793 ppb in the analysed magmatic rock-hosted pyrites, indicative of a likely magmatic contribution to gold mineralization.

Genesis and Evolution of Hydrothermal Fluids in the Formation of the High-Grade Hishikari Gold Deposit: Carbon, Oxygen, and Sulfur Isotopic Evidence

The Hishikari low-sulfidation epithermal gold (Au) deposit in Kyushu, Japan, is world-famous for its premium ore. It has been hypothesized that magmatic contributions to the hydrothermal fluid during early stages of mineralization is possible, even if the hydrothermal fluids for many Au occurrences near the Hishikari deposit are of meteoric origin and are influenced by basement sedimentary rocks. The purpose of this study is to obtain constraints on the genesis and evolution of hydrothermal fluids in the formation of the high-grade Hishikari Au deposit by carbon and oxygen isotope ratios of calcite-bearing samples. Since the microanalysis of carbon and oxygen isotope ratios in every 12 μm of the calcite-bearing sample along the growth direction (corresponding to 10 years of the Hishikari mineralization) scatter in a particular range, the fluid evolution might not be a gradual change from a magmatic to a meteoric origin. Alternatively, a rapid turnover of two fluids might be happening locally. The average sulfur isotope ratio of hydrothermal pyrite is similar to that of the adjacent magma. However, according to the secondary ion mass spectrometry (SIMS) microanalysis, local pyrite with extremely low sulfur isotope ratios may interact with basement sedimentary rocks. Unlike other epithermal Au deposits in the vicinity, rapid local mixing of the magmatic-origin deep fluid and meteoric-origin fluid reacted with organic matter containing basement sedimentary rocks might cause gold precipitation at the Hishikari deposit.

The mobilization of boron and lithium in the hydrothermal system of the ∼3.48 Ga Dresser caldera: A stable isotope perspective

Voluminous hydrothermal circulation in the ∼3.48 Ga Dresser caldera produced zoned alteration haloes around major fluid pathways. Specifically, in the North Star Basalt (the footwall) hydrothermal alteration decreases with increasing distance from the margins of hydrothermal silica±barite veins, changing from argillic (i.e., kaolinite-quartz) to phyllic (i.e., illite-quartz), and then to either propylitic (i.e., chlorite-albite-epidote) or actinolitic (i.e., actinolite-albite-chlorite-epidote) assemblages at distal positions. This alteration series developed through hydrolysis reactions at decreasing acidic conditions, which promoted variable degrees of mobilization of major and trace elements in the hydrothermal fluids.In this study, we characterize the B and Li concentrations and the relative stable isotope ratios of the altered North Star Basalt to provide new insights into the hydrothermal processes that generated these complex alteration patterns. In particular, we focus on the magnitude and timing of the inputs from different fluid reservoirs, the mobilization of B and Li in the hydrothermal system of the Dresser caldera and their influence on the near-surface environment where ancient stromatolites were forming.Actinolitic and propylitic samples have homogeneous δ11B and δ7Li values (−17 to −15‰ and +1 to +3‰, respectively) that are associated with lower B and Li concentrations in actinolitic (4 to 11 ppm and 46 to 128 ppm, respectively) relative to propylitic samples (9 to 25 ppm and 176 to 305 ppm for B and Li, respectively). This pattern suggests that at least the propylitic assemblage interacted with alteration fluids of largely magmatic origin, thus excluding the possibility of an early seawater contributions to the hydrothermal system. Conversely, phyllic samples have distinctly higher B contents (57 to 99 ppm) and δ7Li values (+7 to +8‰), but have much lower δ11B values (−19 to −28‰) and Li contents (5 to 6 ppm) relative to actinolitic and propylitic samples. We argue that these striking differences are attributable to mineralogical and temperature controls that promoted the preferential removal of 6Li during chlorite dissolution and incorporation of 10B into illite. Furthermore, the highly negative δ11B values in phyllic samples suggest that the additional B incorporated into the altered North Star Basalt originated from the magma chamber underlying the Dresser caldera rather than from seawater or other crustal sources. The most intensely altered (argillic) samples have moderate B and Li contents (2 to 43 ppm and 41 to 71 ppm, respectively) and highly variable δ11B and δ7Li values (−24 to −0.4‰ and −10 to +11‰, respectively). These signatures are interpreted to represent the input of ‘external’ fluids into the upper portions of the hydrothermal system during periodic crack-seal events that allowed the influx of restricted amounts of seawater and, possibly, meteoric fluids.Overall, this study provides a novel non-traditional stable isotope perspective on the evolution of the hydrothermal system of the Dresser caldera that adds richness to our understanding of this complex environment. Both B and Li stable isotopes support a prominent magmatic contribution to the hydrothermal fluid budget, reinforcing the interpretation of a hot-spring origin of the tourmaline-bearing layers associated with the stromatolites of the North Pole Chert.

A Review on Mineralogical and Geochemical Characteristics of Seafloor Massive Sulfide Deposits in Mid-Ocean Ridge and Volcanic Arc Settings: Water-Rock Interaction and Magmatic Contribution

A Review on Mineralogical and Geochemical Characteristics of Seafloor Massive Sulfide Deposits in Mid-Ocean Ridge and Volcanic Arc Settings: Water-Rock Interaction and Magmatic Contribution

Trace-element distribution and ore-forming processes in Au–Ag-rich hydrothermal chimneys and mounds in the TA25 West vent field of the Tonga Arc

We report detailed mineralogy and geochemistry of hydrothermal mounds and chimneys in the TA25 West vent field (TA25 WVF), a newly discovered magmatic–hydrothermal system in the Tonga (Tofua) arc. Chimney samples are classified as sulfate- or sulfide-rich, based on major sulfide, sulfosalt, and sulfate minerals. The former type represents a simple mineral assemblage of predominance of anhydrite/gypsum + barite + pyrite, whereas the sulfide-rich chimneys show three different stages of mineralization with decreasing fluid temperature: sphalerite–pyrite dominated stage I, sphalerite–sulfosalts dominated stage II, and stage III is dominated by seawater alteration. Mound samples are characterized by sulfide assemblages and paragenesis similar to those of sulfide-rich samples, but abundant chalcopyrite indicates a relatively high-temperature mineralization. The chimney and mound samples are enriched in Au (average 9.2 ppm), Ag (297 ppm), As (1897 ppm), Sb (689 ppm), Hg (157 ppm), and Se (34.6 ppm). LA–ICP–MS and FE–TEM studies indicate that most of these elements occur in sulfides or sulfosalts in solid solution, although some occur as nanoparticles. This is mainly controlled by the combined effects of fluid conditions (temperature and redox state) and influx of ambient seawater. Petrography and trace-element compositions of sulfides and/or sulfosalts suggest that most concentrations of Au and Ag in the TA25 WVF result from the precipitation and/or adsorption of Au–Ag-bearing nanoparticles on rapidly crystallized sulfides, the substitution of Au and Ag in sulfide and/or sulfosalt minerals, and the saturation of Ag in hydrothermal fluids during late, relatively low-temperature mineralization (< 150 °C). The maximum measured temperature (242 °C) of venting fluids and calculated formation temperatures of sphalerite (229–267 ℃) are below the boiling temperature of seawater at the depths (966–1096 m) of the TA25 WVF, suggesting fluid boiling had little effect on Au–Ag-rich mineralization in the TA25 WVF. The presence of enargite–tetrahedrite–tennantite assemblages, high concentrations of magma-derived elements (e.g., Au, Ag, As, Sb, Hg, and Se), low δ34S values (2.1 to 4.3‰) of sulfide minerals relative to the host rocks, and the distribution of CO2-rich hydrothermal plumes (500 to 1000 ppm) suggest that the TA25 WVF is a submarine hydrothermal system influenced by a magmatic contribution in an arc setting. Our results indicate that the magmatic contribution is most likely to play an important role in supplying various metals, including Au and Ag, to the TA25 WVF. Subsequently, the rapid crystallization of sulfides induced by abundant fluid-seawater mixing significantly contributes to the precipitation of Au–Ag-rich mineralization.

Hydrogeochemistry characterization of an overexploited municipal, agricultural, and industrial aquifer, central Mexico

The Valley of Celaya aquifer, located in one of the most important agricultural and industrial areas in central Mexico, has been extremely overexploited for several decades for agricultural, industrial, and municipal uses. The Celaya aquifer is a multilayer, composed of an open upper alluvial (sedimentary deposit) aquifer with inter-layers of late tertiary acid tuffs and basalts (medium semi-confined aquifer) and a downward recharge from River La Laja. The groundwater follows a natural hydrogeochemical evolution, producing low total dissolved solids (TDS) carbonate-type to medium TDS Na-enriched carbonate-type water. The average water temperature is 33 °C, with three thermal groups (low temperature: 16–29 °C, medium temperature: 30–30 °C, and high temperature: 46–60 °C). The electrical conductivity ranges from 645 to 805 μS/cm. Isotopic data (δ2H and δ18O) indicates an evaporation and mixing line with a regression equation of δ2H = 5.48 xδ18O-20.67; R2 = 0.9827. Saturation index geothermometric calculations for the bottom of the well indicate temperatures ranging from 98 to 135 °C. The Cl vs. B relationships indicate the water chemistry is mostly due to local water-rock interaction with a minor magmatic contribution (deep igneous rock). The arsenic and fluoride concentrations are above the limits of the standard on the eastern part of the study area (As = 0.54 mg/L and F = 3.2 mg/L). The arsenic concentration may be due to groundwater residence time, while the fluoride concentration is generally associated with acid and intermediate volcanic rocks. Inverse geochemical modeling indicates a normal evolution of groundwater from meteoric water with some influence from meteoric water to rock-water interactions with sediments and volcanic rock to a deep regional aquifer. This aquifer is considered a low-temperature system (≤150 °C), conductive, and non-magmatic with extensional dominance where local faults produced by overexploitation play an important role in transporting water, and potentially toxic elements to the surface. The hydrogeochemical characterization in this study will help improve the sustainable management of groundwater resource.