Abstract The early-stage subduction records of the Paleo-Asian ocean are poorly preserved in the eastern segment of the Central Asian Orogenic Belt (CAOB), which hinders constraints on the evolution of the whole CAOB. This study presents new age data and zircon Hf-O isotopes as well as bulk-rock geochemistry of the Wuxing mafic-ultramafic complex in the Xingkai massif in northeastern China, which has been identified as Alaskan-type complex with aspects of field occurrence, petrological and mineral assemblages, and mineral chemistry in our recently published work. The results indicate that the complex formed mainly between 517 Ma and 510 Ma with a lithological sequence of Sanying clinopyroxenite (517 Ma), then Sanying gabbro (514 Ma), and Erying hornblendite (513 Ma), and finally Erying hornblende clinopyroxenite (510 Ma). The lithological formation sequence is consistent with the intrusive relations between lithological phases and their irrelevant major element compositions and variable trace element patterns of the bulk rocks. The εHf(t) values of zircon in two samples in this study vary from from +4.45 to +7.61 and from −11.8 to +4.42, respectively and tend to be more depleted with age. These features suggest that the Wuxing complex was a product of long-term arc magmatism and experienced significant ancient crustal assimilation in early-stage magmas and negligible contamination in later ones. The presence of 1222 Ma and 706 Ma inherited zircon grains implies existence of Proterozoic basement in the Xingkai massif and its continental arc setting in Cambrian. The Wuxing complex is the oldest Alaskan-type complex found so far in the entire CAOB and is a good witness of the Paleo-Asian oceanic subduction in the easternmost CAOB. The older age of the Wuxing complex compared to the regional Hongqiling intrusion is also compatible with its Alaskan-type nature and platinum-group element mineralization, which are distinct to the Permian-Triassic Ni-Cu sulfide deposit-hosting maficultramafic intrusions in the southern CAOB.