The Ahualulco Volcanic Complex (AVC) is situated in the north-central part of the San Luis Potosí Volcanic Field (SLPVF) that is found in the southern portion of the Mesa Central (MC). The Cúcamo, AVC is mainly composed of mafic and intermediate volcanic rocks. The present study focuses on understanding the evolution, origin, and magmatic processes and petrogenesis of mafic and intermediate rocks in the Cúcamo, AVC. The Quaternary mafic rocks have porphyritic textures with the mineral assemblage of olivine, and clinopyroxene. These volcanic rocks display high K calc-alkaline basaltic compositions with enrichment in light rare earth elements (LREEs) and incompatible elements. Geochemical modeling reveals that mafic magmas were derived through a partial melting process of a spinel lherzolite source at low degrees of melting (~2 to 15 %) in an extensional regime. The intermediate volcanic rocks show porphyritic and glomeroporphyritic textures with matrix formed by randomly oriented microlites. The main mineral assemblage consists of plagioclase, K-feldspar, and clinopyroxene. These volcanic rocks are characterized by calc-alkaline basaltic andesitic and andesite compositions with enrichment in light rare earth elements and incompatible elements. Geochemical modeling suggests that intermediate rocks were derived from high ratios of assimilation and fractional crystallization processes between mafic melts and continental crust in an extensional environment.