Mafic Material Research Articles

Chandrayaan-3 APXS elemental abundance measurements at lunar high latitude.

The elemental composition of the lunar surface provides insights into mechanisms of the formation and evolution of the Moon1,2. The chemical composition of lunar regolith have so far been precisely measured using the samples collected by the Apollo, Luna and Chang'e 5 missions, which are from equatorial to mid-latitude regions3,4; lunar meteorites, whose location of origin on the Moon is unknown5,6; and the in situ measurement from the Chang'e 3 and Chang'e 4 missions7-9, which are from the mid-latitude regions of the Moon. Here we report the first in situ measurements of the elemental abundances in the lunar southern high-latitude regions by the Alpha Particle X-ray Spectrometer (APXS) experiment10 aboard the Pragyan rover of India's Chandrayaan-3 mission. The 23 measurements in the vicinity of the Chandrayaan-3 landing site show that the local lunar terrain in this region is fairly uniform and primarily composed of ferroan anorthosite (FAN), a product of the lunar magma ocean (LMO) crystallization. However, observation of relatively higher magnesium abundance with respect to calcium in APXS measurements suggests the mixing of further mafic material. The compositional uniformity over a few tens of metres around the Chandrayaan-3 landing site provides an excellent ground truth for remote-sensing observations.

Zircon U[sbnd]Pb geochronology and geochemistry of hot subduction volcanic suite in the deep bore-hole well-core KBH-5: Evidence of Neoarchean Shimoga greenstone belt beneath the Cretaceous Deccan Traps, India

The continents across Earth have grown through accretion and amalgamation of plume-generated oceanic plateaux and subduction-originated magmatic arcs. The evidence of such evolutionary processes is well preserved in the greenstone belts of Canada, South Africa, China, Australia and India. Unlike accretion that leads to lateral growth of the continents, flood basalt volcanism results in the superposition of large volumes of dense mafic material above relatively less dense sialic upper continental crust. The resulting density inversion is liable to generate tectonic stresses resulting in faulting of under burden along weak planes. The nature of the crust obscured beneath flood basalt provinces that have accumulated over the past 500 My in Large Igneous Provinces (LIPs) has remained enigmatic, largely because of the voluminous lava pile that deters access to the concealed basement, unless otherwise retrieved through deep continental drilling. Here, we present in situ zircon UPb geochronology and bulk-rock geochemistry of a volcanic sequence discovered at −400 m m.s.l in the deep bore-hole well-core KBH-5 of the southwestern Deccan Traps, India. The ∼300 m thick metavolcanic succession includes a basalt – Nb-enriched basalt – andesite – Mg-andesite – dacite – adakite suite. The zircons yielded a 2.58 Ga U-Pb age for the suite, which also incorporates entrained zircon xenocrysts of 2.7 Ga age from a preexisting juvenile material during its emplacement. The bore-hole KBH-5 is located on an NNW-SSE trending normal fault, paralleling a series of major faults west of the Western Ghat Escarpment. Although the crustal block plummeted ∼1000 m downward along the fault plane, the geochemical attributes of the metavolcanic rocks are thoroughly comparable to those reported in the Medur Formation of the Shimoga greenstone belt, ∼300 km south of KBH-5 in the western Dharwar craton. Our study provides the first physical evidence of Dharwar greenstone belt(s) extending further beneath the Deccan Traps, which was previously only speculative based on short-wavelength gravity highs. The metavolcanic sequence evolved in a subduction-related back-arc tectonic regime and accreted to the active continental margin of India in the Neoarchean. Unveiling of potentially similar scenarios in cratons elsewhere entrapped beneath the vast canopy of continental flood basalts, would reveal new crustal growth events during the Archean -Proterozoic transition across the Earth.

Igneous Diversity of the Early Martian Crust

Mars missions and Martian meteorites revealed how complex the Martian crust is. The occurrence of both alkaline and sub-alkaline igneous rocks of Noachian age (>3.7 Ga) in Gale crater indicates diverse magmatic processes, with sub-alkaline rocks likely formed through the partial melting of hydrous mafic rocks, as commonly observed on Earth. The orbital discovery of excavated evolved igneous rocks scattered in Noachian terrains raise questions about the petrology of the ancient Martian crust, long thought to be basaltic. A possibly evolved crust beneath a mafic cover is supported by geophysical and seismic measurements from the Insight lander that indicate the bulk crust has a lower density than expected if it were homogeneously basaltic. If localized magmatic processes could form evolved terrains, the detection of abundant intermediate to felsic Noachian crustal exposures through remote sensing suggest regional- to global-scale processes that produced evolved crustal component(s) that are now buried below mafic materials. Due to the lack of centimetric to millimetric textural imaging and compositional measurements, the petrology of such crust is ambiguous. Future orbiter, rover, and aerial missions should focus on Noachian exposed regions exhibiting evolved crustal characteristics to unfold the petrology of the Martian crust and its formation.

Impact of Ancient Tectonics on Intracontinental Deformation Partitioning: Insights From Crustal Structures of the East Junggar‐Altai Area

AbstractCompressive stress generated at collision fronts can propagate over long distances, inducing deformation within the continent's interior. Nevertheless, the factors governing the partitioning of intracontinental deformation remain enigmatic. The Altai Mountains serve as a type‐example of ongoing intracontinental deformation. Here, we investigate the crustal architecture of the Chinese Altai Mountains, using receiver functions obtained from newly deployed dense seismic nodal arrays. The new seismic results reveal distinct crustal features, including (a) a negative polarity discontinuity beneath Chinese Altai Mountains, suggesting a low‐velocity layer; (b) a north‐dipping mid‐crustal structure beneath the suture zone between East Junggar and Chinese Altai, indicating underthrusting of East Junggar's lower crust beneath the Chinese Altai Mountains; (c) a double Moho structure beneath East Junggar, revealing a high‐velocity lower crustal layer. In conjunction with constraints from previous multi‐disciplinary regional studies, the double Moho structures are interpreted as mafic restite from Late Paleozoic magma underplating. The addition of mafic materials can significantly enhance the rheological strength of East Junggar's crust, causing it to function as an indenter that thrust beneath the Chinese Altai Mountains during the subsequent convergence process. As a consequence, significant deformation occurs in the Chinese Altai region, resulting in the emergence of decollements, as evident by the negative polarity discontinuity. The presence of pre‐existing decollements makes the Altai Mountains region more susceptible to deformation, thereby facilitating the concentration of intracontinental deformation. These findings illuminate the evolution history of the Chinese Altai Mountains and highlight the great impacts of ancient tectonics on intracontinental deformation partitioning.

Science and Science‐Enabling Activities of the SHERLOC and WATSON Imaging Systems in Jezero Crater, Mars

AbstractDuring its first year of operation, the Perseverance rover explored the cratered and fractured floor of Jezero crater on Mars. Here, we report the use of the Scanning Habitability Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC) imaging system that includes two high‐resolution cameras, the Autofocus and Contextual Imager (ACI) and Wide Angle Topographic Sensor for Operations and eNgineering (WATSON). ACI is a fixed focus gray scale imager with a resolution of 10.1 μm/pixel whereas WATSON is a variable field of view, variable focus imager capable of resolution down to 14 μm/pixel. WATSON is a reflight of the MArs Hand Lens Imager (MAHLI) imager and has similar capabilities. During first‐time activities, WATSON was used to support both science and engineering operations related to sample and abrasion patch assessment and sample collection and caching. WATSON also documented the deployment of the Ingenuity helicopter. The Crater Floor Campaign identified two primary rock units, the Máaz formation and the Séítah formation, which have been interpreted as lava flows and an olivine cumulate, respectively. Interpretation of rock textures with WATSON and ACI images was limited to abraded surfaces because unmodified outcrop surfaces (herein termed “natural surfaces”) show high degrees of dust covering, wind abrasion, and coating by secondary mineral products. WATSON and ACI images support the hypothesis that the material of both the Máaz and Séítah formations consists of largely aqueously altered mafic materials with varying igneous origins.

The Singhbhum Craton (India) records a billion year of continental crust formation and modification

The petrogenesis of continental crust from its ultimate mantle source can be reconstructed from the element abundances and radiogenic isotope compositions of ideally pristine igneous rocks. The initial isotope compositions of igneous rocks provide geochemical constraints on the age, composition and evolution of their source(s). Determining initial isotope ratios for rock samples can be challenging, especially in rocks with a long and protracted thermal history. The Rb-Sr system is highly sensitive to parent-daughter element fractionation during magma differentiation. This makes the Rb-Sr isotope systematics ideal to trace the precursor composition of Archean felsic crust and constrain the time of element fractionation during the formation and subsequent modification of continental crust. Initial isotope compositions can be obtained directly from minerals that strongly prefer the daughter element and effectively exclude the parent element of the radio-isotope system of interest. Apatite, having a near zero Rb/Sr ratio, is ideal for preserving its initial 87Sr/86Sr and zircon records initial 176Hf/177Hf compositions. Combined modelling of Sr and Hf isotope data from granitoids of the Archean Singhbhum Craton, indicates that the older Paleoarchean granitoids, emplaced between 3.53 Ga and 3.44 Ga, were derived from a mafic precursor (∼52–54 wt% SiO2) sourced from a depleted mantle at ∼3.71 Ga. Initial 87Sr/86Sr isotope signatures of matrix apatite and apatite inclusions in zircon from the younger Paleoarchean granitoids (3.4–3.2 Ga) of the Singhbhum Craton indicate these younger granitoids were produced by mixing of magma generated from an older mafic source and partial melts derived from the older granitoids. The combined Sr-Hf isotope modelling links the timing of mantle extraction of the precursor material for Paleoarchean Singhbhum granitoids with a known mafic crust extraction event at ∼3.71 Ga. In combination, the new Sr isotope data from apatite combined with whole rock and zircon Hf isotope data from the literature reveal a ∼1 Ga protracted crustal growth and differentiation history of the nucleus of the Singhbhum Craton. By combining radio-isotope systems like 87Rb-87Sr and 176Lu-176Hf, the petrogenesis of Archean felsic crust from the extraction of mafic material from the mantle to reworking in an orogenic cycle to emplacement can be reconstructed. This approach can be applied to other greenstone-gneiss terranes to quantify the spatio-temporal and compositional evolution of voluminous felsic crust and the formation of cratons in the Archean.

Carbonated eclogitic component beneath eastern China revealed by olivine phenocrysts in nephelinites

Carbonates subducted into the mantle alongside mafic material play a critical role in the deep cycling of carbon. This recycled oxidized carbon strongly affects the physical properties of the mantle, changes the local mantle oxidation state, and enhances its ability to melt. Olivine phenocrysts, which are the first to crystallize from mantle-derived magma, record the lithology of the mantle source and provide a new perspective on CO2-rich mantle domains. Here we present data for olivine phenocrysts from Cenozoic nephelinites from eastern China, which have extremely high Ca (1108–6575 ppm) and Mn (1595–5065 ppm) and low Fo (71–85) contents and differ from olivine crystallized from CO2-poor mantle-derived melts (e.g., peridotitic or pyroxenitic mantle-derived melts; Ca < 3000 ppm, Mn < 2500 ppm). This can be explained if the olivine phenocrysts are in equilibrium with melts derived from a carbonated eclogite source, because melts produced experimentally from carbonated eclogite have high Ca and Mn and low MgO contents. The nephelinites have lower δ26Mg (−0.46‰ to −0.37‰) and higher δ66Zn (0.40‰ to 0.56‰) values compared with normal (MORB-source) mantle, lending further support to the influence of carbonated components during the formation of the nephelinites. Decreases in the Ca and Mn contents of the olivine phenocrysts with increasing Fo contents are due to mixing between the initial melt and a reacted melt produced by melt–peridotite interaction during ascent. Our findings demonstrate that the signature of carbonated eclogite in the mantle can be recorded by olivine compositions. This highlights the importance of olivine phenocrysts for tracing CO2-rich lithologies in the mantle and that high Ca and Mn contents of olivine phenocrysts suggest a carbonated eclogite source.

Progressive underplating of mafic material at mid-crustal depth beneath Ischia volcano, Italy

The destructive (Mw 3.9) earthquake of 21 August 2017 re-opened the question on where magma resides at the Ischia island volcano. The peculiar complexity of the seismic source initiated the debate on the involvement of fluid-related processes, but the magmatic origin of the event remains uncertain. Here we use ground displacement and broadband seismic data to investigate the magmatic system of Ischia volcano, where progressive underplating of mafic material at mid-crustal depth feeds the deep structures, which are characterized by exceptionally high seismic velocity and are connected with a shallow crystal mush. Although no direct evidence of large molten volumes was found, strong anisotropy suggests that the crystal mush is pervaded by magma-intruded dykes. We propose that the 2017 event was due to a negative tensile deformation caused by depressurization of supercritical fluids along a shallow southwest (SW-)-dipping fault defined by receiver functions (RFs) data, which acted as a valve regulating the overpressure of deep magmatic fluids.

Crustal and upper mantle structure beneath SE China from joint analysis of receiver functions and Rayleigh-wave dispersion

SUMMARY Various geodynamic models, such as a mantle plume, lithospheric delamination and the subduction of palaeo-Pacific Plate, have been proposed to account for the Mesozoic magmatic activity and related mineralization in SE China. However, previous seismic velocity models are insufficient in resolution to constrain the accompanying crust–mantle interactions, which limits our understanding of the deep geodynamic processes responsible for the Mesozoic magmatism in SE China. In this study, we construct a new 3-D shear wave velocity model of the crust and upper mantle beneath SE China using joint inversion of receiver functions and Rayleigh-wave dispersion. We also determine the crustal thicknesses and Vp/Vs ratios by H–k stacking of receiver functions. Compared to the western Cathaysia Block, the coastal volcanic-intrusive belt (CVIB) southeast of the Zhenghe-Dapu Fault shows relatively high-velocity anomalies in the lower crust and high Vp/Vs ratios, indicating significant underplating of mafic material beneath the CVIB. Furthermore, it is noticeable that the asthenospheric low-velocity anomalies are stronger beneath the CVIB than beneath the interior of SE China, suggesting a southeastward increase in the intensity of asthenospheric upwelling and partial melting, which was likely responsible for the strong volcanism and the inferred mafic underplating beneath the CVIB. Our observations provide new evidence and more details for the northwestward subduction and subsequent rollback of the palaeo-Pacific Plate causing the Late Mesozoic magmatism in SE China.

Geochemistry of Upper Cretaceous bauxite deposits, Zagros Fold Thrust Belt, SW Iran: Paleoenvironment and provenance constraints

Iranian's karst bauxites, as part of the Irano-Himalayan bauxite belt, are related to four structural zones, including the Zagros Fold-Thrust Belt (ZFTB). The ZFTB consists of 7–12 km of the Paleozoic to Pliocene carbonate sediments deposited on the Precambrian basement and Arabian continental margin. In the ZFTB occur several karst bauxite deposits between the Cenomanian-Turonian shallow-marine argillaceous of the Sarvak Formation and the Santonian-Campanian carbonates of the Ilam Formation. Compositional data of karst bauxite deposits may address paleogeographic restoration and record paleoclimate, and here we discuss a dataset including the Mombi, Bidgol, Tang-e Pirzal, and Bagoushi bauxite deposits in the ZFTB. Although the ZFTB karst bauxites show similar texture, they are different in composition, reflecting different paleoenvironmental formation conditions. In most of the studied bauxites, the composition of ooidal concretions indicates the occurrence of long periods of humid tropical climate followed by short and intermittent dry-to-wet conditions. In the Bidgol deposit, a different pattern is recognized, reflecting the predominance of dry climates and characterized by low aqueous silica activity and low water activity. The formation of iron oxyhydroxide minerals is likely due to a multistage process involving the circulation of Fe-rich solutions in micro-cracks or veins due to pyrite and chamosite dissolution and Fe2+ oxidization. In the ZFTB bauxites, two main trends of Ce/Ce* distribution with depth, a proxy of paleo-redox evolution during bauxitization, are recognized. In the Bidgol and Mombi deposits, Ce/Ce* is negative in the basal portion and increases upward. The positive Ce-anomalies in the upper parts of these deposits are due to ceranite formation under oxidizing environment near the surface. In the Bagoushi and Tang-e Pirzal deposits, Ce/Ce* is close to the unit with the notable exceptions of a few samples characterized by significant and positive Ce/Ce* anomalies. This feature suggests that cerianite, originally ubiquitous in these deposits, was affected by congruent dissolution through cerium reduction with Ce3+ transportation by acidic downward percolating solutions as fluoride complexes (REEF2+ and REEF2+), carbonate complexes (REECO3+) and carbonate–fluoride complexes (REECO3F) followed by fluorocarbonate minerals' precipitation. This process has been repeated several times with maximum distribution throughout the profile due to environmental changes, including periodic fluctuations in the groundwater level. Finally, the Sm/Nd, Nb/Ta, and Eu/Eu* provenance proxies indicate that the protolith(s) from which the ZFTB bauxite deposits are derived is UCC-like, thus excluding supply of mafic material and pointing toward a source material primarily derived from the bedrock argillaceous sediments. In addition, several samples record provenance from siliciclastic craton-derived sediment, suggesting that the ZFTB was connected with a continental margin during the Jurassic-early Cretaceous.

RIMFAX Ground Penetrating Radar Reveals Dielectric Permittivity and Rock Density of Shallow Martian Subsurface

AbstractThe Mars 2020 Perseverance Rover is equipped with the RIMFAX ground penetrating radar instrument which has been continuously surveying the shallow subsurface during the rover's journey. Within the first 379 mission days, we identify hyperbolic patterns in the data, which are thought to be caused by objects such as buried boulders or cavities located in the upper 5 m of the subsurface. To obtain the first detailed estimates of radar wave propagation velocity, we match these scatterer‐generated patterns with theoretical traveltime hyperbolas, which take into account the refraction at the surface. We employ these estimates to derive the average dielectric permittivity and bulk rock density of the volume above the scatterer source. The parameters compare well with those obtained through orbital radar measurements and those measured by other instruments onboard the Perseverance Rover. Our findings are consistent with a subsurface dominated by solid rock and mafic material.

Petrogenesis and Tectonic Implications of the Cryogenian I-Type Granodiorites from Gabgaba Terrane (NE Sudan)

The widely distributed granitic intrusions in the Nubian Shield can provide comprehensive data for understanding its crustal evolution. We present new bulk-rock geochemistry and isotopic (zircon U-Pb and Lu-Hf) data from the Haweit granodiorites in the Gabgaba Terrane (NE Sudan). The dated zircons presented a 206Pb/238U Concordia age of 718.5 ± 2.2 Ma, indicating that they crystallized during the Cryogenian. The granodiorites contain both biotite and amphibole as the main mafic constituents. The samples exhibit metaluminous (A/CNK = 0.84–0.94) and calc-alkaline signatures. Their mineralogical composition and remarkable low P2O5, Zr, Ce, and Nb concentrations confirm that they belong to I-type granites. They exhibit subduction-related magma geochemical characters such as enrichment in LILEs and LREEs and depletion in HFSEs and HREEs, with a low (La/Yb)N ratio (3.0–5.9) and apparent negative Nb anomaly. The positive Hf(t) values (+7.34 to +11.21) and young crustal model age (TDMC = 734–985 Ma) indicates a juvenile composition of the granodiorites. The data suggest that the Haweit granodiorites may have formed from partially melting a juvenile low-K mafic source. During subduction, the ascending asthenosphere melts might heat and partially melt the pre-existing lower crust mafic materials to generate the Haweit granodiorites in the middle segment of the Nubian Shield.

Formation of Paleo- to Meso-Archean continental crust in the western Dharwar Craton, India: Constraints from U[sbnd]Pb zircon ages and Hf-Pb-Sr isotopes of granitoids and sedimentary rocks

The combination of UPb zircon ages with Hf-Sr-Pb isotopes of different intrusive and extrusive felsic and sedimentary rocks provides constraints on the petrogenetic evolution of the continental crust in the western Dharwar Craton, India. The oldest detrital zircon preserved formed at ∼3.6 Ga and represents a relic of the oldest felsic crustal material in the region. The dominant granitoid units of the western Dharwar Craton contain zircon grains with magmatic ages between 3.4 Ga and 3.0 Ga that indicate the formation of major felsic continental crust during this interval.Trace element abundances of the granitoids indicate that the oldest members of the intermediate to felsic suite derived by partial melting of mafic material at ∼3.6–3.4 Ga. The initial bulk rock Hf isotope compositions of these granitoids are consistent with their formation by melting of even older mafic material that was slightly enriched relative to the depleted mantle composition. This mafic and slightly enriched material formed by mantle melting at ∼ < 3.8 Ga. The Hf isotope compositions of individual zircon grains, obtained by two different analytical techniques (in-situ and complete dissolution followed by chromatographic separation) give evidence for the presence of such older mafic material (<3.8 Ga) that formed the immediate precursor of their granitoid host rocks. Such a mafic source for the granitoids is consistent with PbSr isotope systematics of these that shows no indication of Eoarchean enriched/evolved material in the western Dharwar Craton. The mafic source material of the granitoids thus represents an intermediate stage of crust formation that started after 3.8 Ga with the formation of mafic crust by mantle melting. The combined geochronological and isotopic constraints suggest that the Mesoarchean felsic crust of the Dharwar Craton formed by differentiation of melts derived from an amphibolite/eclogite source rock and included increasing contributions of reprocessed crustal material with time from ∼3.6 to 3.0 Ga. The major interval of growth of felsic continental crust was from 3.4 to 3.0 Ga. The younger generation of granitoids formed mostly by reworking of older intermediate to felsic crust. These different felsic magmatic bodies with distinct petrogeneses and sources, that include the depleted mantle, older mafic crust and the evolved continental crust, became essential elements of the stable continental crust of the western Dharwar Craton, the majority of which was generated from 3.4 to 3.0 Ga.

Spectrophotometric properties of materials from the Mars Science Laboratory at Gale crater: 1. Bradbury Landing to Cooperstown

During the first 443 martian days (sols) of the Mars Science Laboratory (MSL) Curiosity rover mission, visible/near-infrared (445–1012 nm) multispectral observations were acquired at different times of sol by the Mast Camera (Mastcam) and Navigation Camera (Navcam) at five locations along the traverse. Measurements of soil, dust, and rock units spanned sufficient incidence, emission, and phase angles to enable radiative transfer models to constrain the surface scattering functions, single-scattering albedo ( w ), and microphysical properties of the units at each site. Although the model results were mainly consistent with previous results from other landing sites, there were some notable exceptions. For example, the less dusty “Blue rocks” units were modeled as more backscattering compared to ostensibly dustier “Red rocks” units, which was opposite to results from other landed missions. Relations between the peak phase angle of phase curve ratios, w values, and macroscopic roughness ( θ ¯ ) suggested that unlike most of the materials observed by the Spirit and Opportunity rovers, the effects of particle-scale roughness and internal scattering were a greater influence on MSL units than surface scattering. Also noteworthy were unique photometric signatures modeled from data acquired at the landing site on Sol 20 as part of the first in situ spectrophotometric analyses of materials subjected to erosion and/or surface dust removal from spacecraft descent engines. Modeled w spectra were relatively flat and dark for the Sol 20 Blue rocks unit and were positively correlated with average θ ¯ values, similar to some laboratory studies of coarse-grained and/or glassy mafic materials. While low w values and backscattering behaviors were modeled for the Sol 20 “Regolith” unit, the more heavily scoured, lighter-toned regions included soils with extremely forward scattering behaviors, large w values, and that lacked ferric absorption features. The absence of phase reddening effects in all the Sol 20 units likely also was caused by surface disruptions during the landing. Future analyses of additional spectrophotometric data sets from both Curiosity and the Mars 2020 Perseverance rover will continue to yield important comparisons among the variable scattering properties of martian geologic units. • Five sites imaged by MSL Mastcam/Navcam at multiple times-of-sol during Sols 20- 443. • Less dusty rocks modeled as more backscattering compared to redder, dustier rocks. • Small-scale roughness, internal scattering stronger influence than surface scattering. • Unique photometric signatures at landing site due to effects of lander descent plumes.

Polycyclic soils with Bt and Bw developed on mafic rocks in a forest cerrado transition environment in Roraima, northern Amazon, Brazil

In the extreme north of Brazil, in Roraima, there is an important set of mafic, volcanic or plutonic rocks, associated with the Juro-Cretaceous magmatism, and one of the most extensive areas is the Colônia do Taiano region, the first agricultural colony of Roraima. In addition to basalts, many diabases and diorites occur, forming an extensive patch of soils with good agricultural suitability, in the cerrado-forest transition. Two soil profiles developed from diabase were studied, after selecting the most representative pedons of the area. P1, an Argissolo Vermelho Eutrófico latossólico (Ultisol) and P2 an Argissolo Vermelho Eutrófico típico (Ultisol), were described and collected. Morphological, physical, chemical, mineralogical analyses, and extraction of Fe, Al, Ti and Si oxides by sulfuric attack were carried out; Fe2O3, Al2O3, TiO2, and SiO2, by plasma emission spectrometry; and Fe-DBC (dithionite-citrate-bicarbonate) and Fe ammonium oxalate. The soils presented a typical latosolic morphology at the base of the profile, with the top of the B horizon showing waxiness varying from moderate to abundant, thus revealing a polycyclic genesis of Bt superimposed on Bw, formed in a previous cycle. The SiO2 contents indicated a desilication process, and the low contents of trace elements and TiO2 showed mafic materials poor in magnetite, and reworking of the parent material by pediment in a drier climate. The Feo/Fed ratio proved to be atypical for the Amazon region, consistent with the mafic lithology.

Climatic controls on soil clay mineral distributions in humid volcanic regions of Sumatra and Java, Indonesia

Climate and parent material are considered the primary factors determining the distributions of soil clay (secondary) minerals, but their influence has not been rigorously elucidated for tropical volcanic soils. Herein, we investigated soil secondary mineral distributions in volcanic regions of Java and Sumatra islands representing large variations in climatic (mean annual temperature (MAT): 13 to 27°C; precipitation: 1910 to 3950 mm) and parent material conditions (rhyolitic-to-basaltic tephra). Soil secondary minerals were assessed by selective extractions, X-ray diffraction analysis, and differential thermal analysis. Moreover, the thermodynamic stabilities of minerals were evaluated based on the ion activities of equilibrated soil–water suspensions. Factor analysis of climate and soil geochemical (e.g., total Si, Fe and K) properties identified temperature, dry season intensity, and parent material as the primary factors regulating secondary mineral distributions. A negative correlation between oxalate extractable Al and Fe (Alo and Feo) and the temperature factor indicates low temperature promoted the formation and preservation of short-range-order (SRO) minerals and organo-Al/Fe complexes, which resulted in Alo + 1/2Feo ≥ 20 g kg−1 (andic property criterion) at MAT <21°C. Desiccation in the dry season, represented by excess precipitation for the driest quarter of the year, was related to soil H4SiO40 activity of soil–water suspensions. High H4SiO40 activity resulting from intense seasonal desiccation coincided with a higher Si/Al ratio of SRO aluminosilicates (Si-rich allophane) and smectite. In contrast, low H4SiO40 activity enhanced the formation of SRO aluminosilicates with a low Si/Al ratio (Al-rich allophane) and gibbsite. The influence of parent materials was evident in high free Fe(hydr) oxide content in soils derived from mafic materials and the occurrence of mica, which altered to hydroxy-Al interlayered vermiculite under continuous leaching conditions, in soils from felsic materials. Overall, we demonstrated strong temperature and seasonal desiccation controls on secondary mineral distributions in the humid, tropical volcanic soils of Java and Sumatra islands.

Provenance Discrimination of Siliciclastic Sediments in the Western Sea of Japan over the Past 30 kyr: Evidence from Major, Trace Elements, and Pb Isotopes

Abstract The Sea of Japan (JS), a unique marginal sea without any large river influxes in the western Pacific, provides ample information about the evolution of sea level, East Asian monsoons (EAM), sea ice activity, and ocean currents in geological time. However, insufficient investigation in the western JS limits our knowledge of East Asian climate change. This study utilizes major and trace elements and Pb isotopes of fine siliciclastic components (&amp;lt;63 μm) of core LV53-18-2 and determines the provenances using statistical methods and discrimination diagrams. The results show that the terrigenous debris of LV53-18-2 was mainly composed of aeolian dust from northeast China, ice-rafted debris (IRD), and volcanic materials from the Far East coast over the last 30 kyr. During the late last glacial period, sea ice activity carried weakly weathered IRD to the study area. Meanwhile, the strengthened East Asian winter monsoon (EAWM) brought dust from northeast China to the study site owing to the cold climate and enlarged sandy land. During the late last deglacial period to early Holocene (15-8 kyr), ascending boreal summer insolation drove the intense melting of sea ice. This led to the deposition of large amounts of weakly weathered IRD and remarkably influenced the chemical composition of the core. After 8 kyr, the global sea level rose to -15 m below the modern sea level and opened the Tatar Strait. Consequently, freshwater supplied by the Amur River entered the JS and gave birth to the Liman Cold Current (LCC), which transported more mafic materials from the Kema terrane upstream.

Thermodynamic constraints on the composition of orogenically thickened lower crust

Orogenically thickened lower crust is the key site of crustal differentiation, crustal deformation, and Moho modification. However, the composition of thickened lower crust is still highly debated. Here, we calculate a set of pseudosections with mafic lower crust compositions in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 (NCKFMASHTO) system. Our modeling results show that the maximum thickness of the mafic lower crust increases with the Moho temperature (TMoho). In addition, the lithologies of stable mafic crust are characterized by medium-pressure (MP) to high-pressure (HP) granulites at 40–50 km, HP granulites and garnet-omphacite granulites at 50–60 km, and garnet-omphacite granulites at 60–70 km. Under the Pamir geothermal conditions, mafic rocks with high SiO2 (>50.2 wt%), XMg (>0.70), XCa (>0.49), or low XAl (<0.11) could be stable at 70 km; however, only ~10% of global mafic granulite xenoliths lie within this compositional range. Further modeling indicates that if TMoho reaches 900–1000 °C, neither the lower crust nor the upper mantle has significant strength relative to the upper crust, and that only ~5–37% of mafic materials are gravitationally stable at 70 km. This implies that the base of doubly thickened (70 km) crust is dominated by intermediate-felsic rocks, consistent with the low Vp and Vp/Vs values seismically observed in young orogenic crustal roots. Thus, most mafic materials at >70 km could delaminate into the deep mantle. Our results provide insights on the formation of extremely thick crust with a predominantly intermediate-felsic base and the crustal thickness variation in continental collision zones.

Role of seafloor production versus continental basalt weathering in Middle to Late Ordovician seawater 87Sr/86Sr and climate

The global climate of the Ordovician Period (486.9 to 443.1 Ma) is characterized by cooling that culminated in the Hirnantian glaciation. Chemical weathering of Ca- and Mg-bearing silicate minerals and the subsequent trapping of carbon in marine carbonates act as a sink for atmospheric CO2 on multi-million-year time scales, with basaltic rocks consuming CO2 at a greater rate than rocks of granitic composition. The oceanic Sr isotope ratio (87Sr/86Sr) can act as a geochemical proxy for the relative proportion of basaltic versus granitic weathering. Oxygen isotopes (δ18O) act as a proxy for paleotemperature and ice volume, providing a useful complement to 87Sr/86Sr in studies of ancient climate. Previous studies have reported stepwise cooling (increasing δ18O) during the Middle to Late Ordovician. Combined with Sr and C cycle models, this has led to the hypothesis that continental silicate weathering of mafic material drove Ordovician cooling (e.g., the Taconic Orogeny). However, Sr and C cycle models have not accounted for an apparent rise in sea level and seafloor production in the Middle Ordovician (Darriwilian), which would increase the hydrothermal Sr flux as well as degassing along continental volcanic arcs. Furthermore, some Ordovician studies contain temporal uncertainty between 87Sr/86Sr and δ18O curves if they are not based on paired analyses, which can obscure the relationship between silicate weathering and cooling. Here, we present new paired 87Sr/86Sr and δ18O data from conodont apatite and integrate this with both a deterministic (forward) and stochastic (reverse) modeling approach to argue that increased hydrothermal weathering played a role in driving marine 87Sr/86Sr, specifically an inflection occurring in the Pygoda serra conodont zone of the mid-Darriwilian Stage (∼ 460.9 Ma ± 1 My). This 87Sr/86Sr inflection is accompanied by an increase in δ18O, consistent with climate cooling. Clarifying the role of seafloor production for marine 87Sr/86Sr and the implications for Ordovician cooling allows for a more nuanced understanding of the factors that drive multi-million-year shifts in climate.

Closure of the Eastern Paleo-Asian Ocean: Constraints from the Age and Geochemistry of Early Permian Zhaojinggou Pluton in Inner Mongolia (North China)

The closing time of the Paleo-Asian Ocean and the tectonic evolution of the northern margin of the North China Craton are still controversial. The geochronology and geochemistry of the Zhaojinggou monzogranite pluton provide new constraints on the late Paleozoic tectonic evolution and the closure time of the Paleo-Asian Ocean in the southern Central Asian Orogenic Belt (CAOB). The monzogranite yielded a zircon U-Pb age of 286.7 ± 1.2 Ma. Due to the characteristics of low–moderate Mg# values (25.87–39.21), low Fe2O3T values (1.13–1.72), and A/CNK &gt; 1, we show that the pluton is weak peraluminous, high in potassium calc–alkaline series, and displays the feature of S-type granite. The total REE content is low, the distribution curve is right dipping, and the LREE is enriched; the δEu average value is 1.32 (1.11–1.54). The granite presents relatively high (87Sr/86Sr)i values of 0.712345–0.713723, low εNd(t) values of −8.89–−8.21 (an average value of −8.56), and a TDM2 of 1718–1773 Ma. Furthermore, the zircon in situ Hf isotopic analysis shows 176Hf/177Hf ratios of 0.282342 to 0.282614, low εHf(t) values of −9.27–0.38 (mean −4.74), and a TDM2 of 1275–1887 Ma. Additionally, high field strength elements such as Nb, Ta, and Ti are depleted, and large ion lithophile elements, e.g., Rb, Ba, K, and Sr, are enriched. The above features of the Zhaojinggou monzogranite indicate that the pluton was derived from late Paleoproterozoic to Mesoproterozoic lower crustal mafic materials. By discussing the genesis and tectonic implications of the pluton massif, we propose that the Zhaojinggou monzogranite represents a magmatic event caused by the crustal–mantle interaction during the southward subduction of the eastern Paleo-Asian Ocean in the northern margin of the North China Craton during the Early Permian.