The mineral baddeleyite (ZrO 2) occurs in many terrestrial and lunar samples and some achondrite meteorites as a trace constituent that most often crystallizes in the late-stage, most chemically fractionated portions of mafic magmas together with apatite, ilmenite, ± zircon, ± zirconolite. In terrestrial mafic rocks these interstitial regions commonly contain K-feldspar, Cl-rich mica, amphibole and a small amount of quartz. In addition, baddeleyite occurs in tektites as a dissociation product of zircon during meteorite impact and as rims on mantle zircon megacrysts recovered from kimberlites. Baddeleyite is a major carrier of Hf, Ti, Fe and U and strongly fractionates Hf from Zr as it can have very high Zr/Hf (> 50). The baddeleyite rims on mantle zircon xenocrysts have a unique chemical composition with significantly higher TiO 2 and lower FeO contents. Baddeleyite is an ideal mineral for U-Pb dating because it has abundant U (up to 3000 ppm), negligible initial common Pb, rarely occurs as xenocrysts, and, in unmetamorphosed samples, experiences negligible Pb loss. As an example of the reproducibility of conventional U-Pb-baddeleyite dating, several individual fragments from a large crystal obtained from the Phalaborwa carbonatite, South Africa, yielded remarkable consistency with a mean 207 Pb 206 Pb age of 2059.8 ± 0.8 Ma (2σ), interpreted as the age of carbonatite emplacement. Perhaps the best example of the geological reproducibility of U-Pb-baddeleyite dating is the example of the Mackenzie dyke swarm in North America where eight dyke and sill samples, collected over distances of > 2000 km, all have consistent 207 Pb 206 Pb ages of 1267 and 1268 Ma. The ability to obtain very precise (± 1−2 Ma) and accurate U-Pb-baddeleyite ages for mafic magmatic outbursts on Earth, such as the Mackenzie event, is of paramount importance in attempting to make supercontinent reconstructions and in the global correlation of ancient mafic magmatic activity worldwide. In metamorphosed mafic rocks, baddeleyite can also survive very high grades of metamorphism but often develops a rim of polycrystalline metamorphic zircon. The width of the zircon rims and the grain size of the zircon aggregate increase when baddeleyite is subjected to progressively higher grades of metamorphism. A particularly interesting example is the variably metamorphosed Hurwitz gabbro sill, Northwest Territories, Canada. In a relatively unmetamorphosed sample, the mean 207 Pb 206 Pb age of 2111.2 ± 0.6 Ma (2σ) for four baddeleyite fractions with negligible zircon growth preserves the age of gabbro crystallization while baddeleyite from a middle to upper greenschist-facies sample collected along strike, and likely from within the same sill, contains significant metamorphic zircon rim development with corresponding discordance of between 12% and 31% depending on the size of the zircon rims. It is also noteworthy that both the primary age of crystallization and the age of metamorphism can be obtained from some metamorphosed gabbroic rocks. In an upper amphibolite- to granulite-facies coronitic gabbro from the Grenville Province, Ontario, Canada, magmatic baddeleyite and zircon retain a primary crystallization age of 1152 ± 2 Ma while polycrystalline metamorphic zircon pseudomorphs after baddeleyite record the age of metamorphism at ∼ 1050 Ma.
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