Due to their flexibility, self-healing ability, and biocompatibility, conductive hydrogels have become excellent candidates for flexible electronics. However, challenges remain, such as water evaporation when exposed to air, resulting in a loss of flexibility and conductivity. Additionally, traditional hydrogels quickly swell underwater, which causes irreversible damage to their structure and electrical properties. As a promising alternative, organogels have gained attention for overcoming these drawbacks. Here, we report a transparent, multifunctional organogel using ultraviolet-initiated polymerization, which exhibits excellent adhesion, robustness, electrical and interfacial stability, and super stretchability. By adjusting the concentration of the lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), the conductivity of organogel could be easily regulated from non-conductive to conductive, obtaining non-conducting elastomer (NCE, without LiTFSI) and ion-conducting elastomer (ICE, with LiTFSI) with identical mechanical properties and superior adhesion due to the same composing polymer chains. This unique characteristic overcomes the interface mismatch problem of traditional flexible electronic devices. Moreover, a high-performance triboelectric nanogenerator (TENG) was designed (ICE-TENG) to achieve a maximum power density of 151.3 μW cm−2, which was utilized to power small electronics. Additionally, a strain sensor was constructed using the ICE, realizing underwater sensing and communication with high stability. This multifunctional organogel is promising for multi-functional human–machine interaction.
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