We review aspects of electrical transport in metallic single wall carbon nanotubes (SWCNT) related to the spin of the conductance electrons. For large contact resistances, R ≫ h/2e2, a SWCNT exhibits Coulomb blockade, and transmission can only occur, when a gate voltage leads to an energy degeneracy for two different numbers of electrons in the SWCNT. The Coulomb blockade gate voltage change is directly proportional to the addition energy for single electron tunnelling. In certain ideal cases every second of the populated electronic states has a higher addition energy, indicating that two spindegenerate electrons are roomed at each orbital state. A low addition energy therefore corresponds to approaching an even number of electrons. The odd-even alternation can be checked in a magnetic field, since then the odd additional electron may enter in one of two Zeeman states. If the high resistance contact is a tunnel junction, the transmission reflects the density of states. This leads to a direct detection of the so-called Luttinger liquid state of the electrons. Ferromagnetic contacts to the SWCNT leads to a conductance which depends on the orientation of the magnetic domains in the contacts. The magnetoresistance effect can be much larger than expected from a simple spin-valve phenomenon. For any intermediate normal metal (Au) contact resistances, R ∼ h/2e2, the Coulomb blockade may still separate the single electron states in the SWCNT with odd and even numbers of electrons. However, at the lowest temperatures the transmission only shows Coulomb blockade for even number of electrons. In the situations with odd number of electrons a coherent tunnelling process dominates. This shortage of the blockade is rooted in the Kondo states formed in the two Au electrodes by exchange interaction due to the spin state in the SWCNT. This tunnelling process is a result of a net spin on the SWCNT and consequently a spin degeneracy. A triplet state is forced into degeneracy with the singlet state in a suitable magnetic field. The situation in a magnetic field is particularly simple in a SWCNT, in contrast to conventional quantum dots, because the tiny diameter of the SWCNT practically speaking precludes orbital effects.
Read full abstract