Lunar Regolith Simulant Research Articles

Preparation and evaluation of GCD-1 lunar regolith simulant based geopolymer activated by solid sodium silicate

In this study, a new lunar regolith simulant, named "GCD-1", was formulated by combining various minerals, such as anorthite, albite, pyroxene, ilmenite, slag, and fly ash. Through X-ray fluorescence spectroscopy (XRF) and X-ray diffraction (XRD) analysis, it was verified that the main mineral composition of GCD-1 was basically the same as that of the lunar soil at the Apollo 14 landing site, in which the deviation in the main compound (i.e., SiO2 and Al2O3) was within 0.5%. Furthermore, GCD-1 based geopolymer was prepared by the one-part method, which was a mixture of solid GCD-1 precursor, solid sodium silicate (SS) activator, and water. The average daytime temperature at the lunar equator, which was calculated to be 60°C, was set as the curing temperature for the GCD-1 based geopolymer. The strength development of the GCD-1 based geopolymer was then characterized by unconfined compressive strength (UCS) for 3, 7, and 12 curing days to consider the effectiveness of the factors (solid SS to lunar regolith simulant [S/L] and water to binder ratio [W/B]). The micro-analysis tests including scanning electron microscope-energy dispersive spectrometer (SEM-EDS), mercury intrusion porosimetry (MIP), and brunner-emmet-teller (BET), were further conducted to investigate the microstructural development of the GCD-1 based geopolymer. Results showed that the increase of the W/B ratio in the GCD-1 based geopolymer tended to increase the total porosity of the sample, thereby inducing a lower UCS. At the same time, for a fixed W/B ratio, the higher S/L ratio had a certain inhibition effect on the hydration reaction, which caused the reduction in the UCS of the sample. The highest UCS of the GCD-1 based geopolymer reaching 30.54 MPa, was achieved under the simulated lunar equatorial daytime temperature for 12 days with W/B and S/L ratios set at 0.25 and 0.18, respectively. Microstructure and mineralogy analyses indicated that the hydrated sodium aluminosilicate (N-A-S-H) gels contributed to reducing the sample's porosity, thereby enhancing the UCS. The relationship between the UCS and total porosity of GCD-1 based geopolymer was then derived. The results of the current study are crucial for lunar base construction with in-situ resources.

Macro- and micro-mechanical behavior of CSU-LRS-1 lunar soil simulant under true triaxial loading path

Macro- and micro-mechanical behavior of CSU-LRS-1 lunar soil simulant under true triaxial loading path

Cocopeat supplementation negates lunar soil simulant-induced baneful phenotypic and biochemical changes in crop seedlings

Lunar exploration has captivated significant attention in recent times through programs such as Artemis. To establish long-term sustenance on the moon, astronauts have to grow their food on-site. While a key substrate for plant production – lunar regolith can induce baneful effects, supplementation with organic amendments could alleviate this inherent toxicity and significantly improve plant growth. In the present study, we examined the suitability of cocopeat (CP) as an amendment to ISRO's lunar soil simulant (LSS), LSS-ISAC-1. We assessed the germination and seedling growth response of four crops—wheat, tomato, groundnut, and cotton to LSS and Cocopeat supplementation. As anticipated, all four crops grew very well on earth soil (ES) and CP per se compared to the LSS. However, due to acidic pH, low electric conductivity (EC), and severe nutrient deficiency in LSS, we observed significantly low germination, stunted seedling growth, and altered associated oxidative stress indicators. To mitigate these pernicious effects, LSS supplemented with varied CP proportions – 3.125, 6.25, 12.50, 25, 50, and 100 %. The resultant data revealed that LSS supplemented with 6.25 % CP in wheat and tomato; 3.125 % CP in groundnut, and 25 % CP in cotton significantly improved phenotypic and biochemical traits in seedlings. Collectively, this study suggests the utility of CP as a novel augmenting agent to boost ISRU strategy for crop growth in moon regolith.

Velocity Measurements of Powdered Rock at Low Confining Pressures and Comparison to Lunar Shallow Seismic Velocity

AbstractSeismic methods will be useful for future lunar near‐surface characterization, and high‐fidelity elastic models will be required to aid interpretation of seismic observations. To develop an elastic lunar near‐surface model, we performed ultrasonic velocity measurements of lunar regolith simulant at low confining pressure and developed a rock physics model calibrated to these measurements. Grain contact models based on Hertz‐Mindlin theory produce accurate results at high confining pressure (i.e., several hundred meters or more burial depth) but historically fail to predict observed velocities in unconsolidated media at low pressure. Therefore, we heuristically modified existing models to fit our measured data over a range of porosities and confining pressures. To compare with Apollo 14 and 16 active seismic experiments, we used our new heuristic rock physics model to produce lunar subsurface velocity profiles. We performed ray tracing through our velocity profiles to calculate seismic traveltime, which results in good agreement with first arrivals interpreted from the Apollo experiments. Our model suggests a slightly higher velocity‐pressure dependence than inferred from in situ measurements, which may be due to porosity reduction in the lunar regolith from impact‐induced and natural vibrations.

Lunar highlands simulant — Geotechnical characterization, 3D discrete element modeling, and cone penetration simulations

Lunar regolith on the surface of the Moon has gained great attention as a resource for many proposed lunar exploration projects. Not only is it serving as the ground support for construction projects on the Moon, but it is also the most accessible construction material for building the human habitat and a key component in in-situ resource utilization efforts. Therefore, gaining a fundamental understanding of the characteristics of lunar regolith is a critical step in the success of lunar exploration projects. However, it is challenging and expensive to obtain samples of lunar regolith directly, or conduct physical experiments on lunar regolith samples in situ. Hence, investigative alternatives, such as laboratory experiments and numerical simulation tools are very important means of investigating the properties of lunar regolith. This paper presents a comprehensive study on lunar highlands simulant (LHS-1), using both laboratory experimentation and discrete element method (DEM) simulations. In the laboratory experiment, triaxial tests were conducted on samples of LHS-1 to explore the stress–strain behaviors of the lunar regolith simulant. Correspondingly, 3D DEM simulations of the triaxial tests were conducted to generate the initial model parameters and the Taguchi method was performed to obtain the optimal calibrated input parameters of the DEM model. With the calibrated parameters, 3D DEM model of the cone penetration into LHS-1 was then built to study the responses of the regolith simulant during the penetration process. The effects of porosity and vertical stress on the tip resistance and sleeve friction profiles were investigated for both terrestrial and lunar environments to study the correlation between the in-situ state of the regolith simulants with the force reactions during the penetration.

An elastoplastic constitutive model of lunar soil simulant considering shear dilatancy and softening characteristics

The study of the constitutive relationship of lunar soil is the key to a deep understanding of the mechanical properties of lunar soil and the subsequent construction of lunar bases. Previous models mostly focused on the strengthening behavior before the peak, while rarely reflected the post-peak softening and residual deformation stages during shear deformation. A new elastoplastic constitutive relation is derived with combining kinematic hardening model and initial shear stress, which effectively compensates for the shortcomings of existing constitutive models, and the validity of the model is verified by comparing with existed laboratory test results. The developed constitutive model not only effectively captures the shear dilatancy and softening characteristics of lunar soil simulant, but also requires fewer parameters to be easily determined by simple initial loading curves from direct shear tests, Furthermore, the influences of some key parameters on shear strength and softening behavior of lunar soil simulant can be easily obtained based on this constitutive model.

A Study of Lunar Regolith Obtained during the Apollo and Luna Space Programs Based on Principal Component Analysis

In this study, a modern principal component analysis (PCA) of the chemical properties of lunar soils was conducted. American and Soviet results acquired during the Apollo and Luna missions, respectively, were analyzed and compared. The chemical composition of the lunar soil was the focus of our analysis, the main aim of which was to assess any possible differences between the results provided by the missions in question. The results were visualized in two- and three-dimensional spaces. The use of PCA virtual variables enabled the chemical composition of the lunar soil to be fully visualized—something impossible to achieve using traditional techniques—and key similarities and differences among the properties of the lunar soil samples were determined. The sources of any differences were then conceptualized. The work reported in this paper offers new directions for future studies, especially research into the design of new lunar soil simulants for lunar construction and civil engineering programs.

Characterisation of different types of power plant ashes as potential lunar regolith simulants

Ashes from various Polish coal-fired power plants were analysed in this investigation as the source material for preparing simulants of lunar regolith. The chemical and phase constituents were the most important parameters used to describe these ashes. The second parameter was particle size and morphology, specifically characterising technological properties such as flowability or density. The final element of the investigation was related to the characterisation of thermal properties. Differential thermal analysis yields information on phase transitions, melting temperatures and other characteristic temperatures of stimulants. Thermogravimetry with Fourier transform infrared analysis provides information on evolved gas species and their evolution temperature profiles.

Near Room Temperature Production of Segregated Network Composites of Carbon Nanotubes and Regolith as Multifunctional, Extra-Terrestrial Building Materials.

Constructing a semi-permanent base on the moon or Mars will require maximal use of materials found in situ and minimization of materials and equipment transported from Earth. This will mean a heavy reliance on regolith (Lunar or Marian soil) and water, supplemented by small quantities of additives fabricated on Earth. Here it is shown that SiO2-based powders, as well as Lunar and Martian regolith simulants, can be fabricated into building materials at near-ambient temperatures using only a few weight-percent of carbon nanotubes as a binder. These composites have compressive strength and toughness up to 100 MPa and 3 MPa respectively, higher than the best terrestrial concretes. They are electrically conductive (>20Sm-1) and display an extremely large piezoresistive response (gauge factor >600), allowing these composites to be used as internal sensors to monitor the structural health of extra-terrestrial buildings.

Temperature Dependence of the Dielectric Constant on the Lunar Surface Based on Mini-RF and Diviner Observations

Radar observation is an effective way to understand subsurface structures in terms of the dielectric constant, whose controlling factors include chemical composition, packing density, and water/ice content. Recently, laboratory measurements have shown that the dielectric constant of lunar regolith simulants also depends on the temperature, which has never been evaluated from remote sensing data. In this study, we estimated the dielectric constant from the Miniature Radio Frequency (Mini-RF) data on a lunar crater floor in the north polar region at two different local times (i.e., different surface temperatures). We calculated the dielectric constant using the inversion method and obtained the bolometric surface temperature from the Diviner Lunar Radiometer Experiment (Diviner) data. The histograms of the estimated dielectric constant values are different between the two local times. This could be interpreted as a result of the temperature dependence of the dielectric constant, while further evaluation of the influence of topography on the incidence angle and small surface roughness is needed. Nevertheless, our result suggests that the temperature dependence of the dielectric constant should be considered when interpreting S-band radar observations of the Moon and other celestial bodies with large surface temperature differences.

YOLO-ET: A Machine Learning model for detecting, localising and classifying anthropogenic contaminants and extraterrestrial microparticles optimised for mobile processing systems

Imminent robotic and human activities on the Moon and other planetary bodies would benefit from advanced in situ Computer Vision and Machine Learning capabilities to identify and quantify microparticle terrestrial contaminants, lunar regolith disturbances, the flux of interplanetary dust particles, possible interstellar dust, β-meteoroids, and secondary impact ejecta. The YOLO-ET (ExtraTerrestrial) algorithm, an innovation in this field, fine-tunes Tiny-YOLO to specifically address these challenges. Designed for coreML model transference to mobile devices, the algorithm facilitates edge computing in space environment conditions. YOLO-ET is deployable as an app on an iPhone with LabCam® optical enhancement, ready for space application ruggedisation. Training on images from the Tanpopo aerogel panels returned from Japan’s Kibo module of the International Space Station, YOLO-ET demonstrates a 90% detection rate for surface contaminant microparticles on the aerogels, and shows promising early results for detection of both microparticle contaminants on the Moon and for evaluating asteroid return samples. YOLO-ET’s application to identifying spacecraft-derived microparticles in lunar regolith simulant samples and SEM images of asteroid Ryugu samples returned by Hayabusa2 and curated by JAXA’s Institute of Space and Astronautical Sciences indicate strong model performance and transfer learning capabilities for future extraterrestrial applications.

Optimized manufacturing process of homogeneous microwave-sintered blocks of KLS-1 lunar regolith simulant

The use of materials from the Moon's surface based on In-Situ Resource Utilization (ISRU) is gaining considerable attention as a means of constructing infrastructure to sustain a human presence there. In particular, the sintering of lunar regolith appears a promising way to fabricate infrastructure on the lunar surface. This study presents a method to manufacture homogeneous blocks using a lunar regolith simulant. The tested simulant, KLS-1, was sintered under diverse conditions in a multi-mode microwave sintering furnace. Successful sintering requires the sample to be heated throughout, without generating a temperature gradient. This was achieved by testing various heating rates and sample sizes. X-ray computed tomography was used to assess the pore structure of sintered samples. While the optimized sintering conditions resulted in the formation of internal cracks by outgassing, preheating the KLS-1 in a vacuum oven at 250 °C effectively prevented the formation of internal cracks. The homogeneity of the blocks was confirmed by coring and measurements of true density, bulk density, porosity, and unconfined compressive strength. The robust reproducibility and similarity in physical and mechanical properties validate the viability of microwave sintering in manufacturing large and uniform blocks suitable for application as construction materials on the Moon.

Ultraviolet and thermal dual-curing assisted extrusion-based additive manufacturing of lunar regolith simulant for in-site construction on the Moon

The establishment of a lunar base is crucial for lunar studies, resource extraction, and advancement in deep space exploration. Considering the limitations of rocket capacity and Earth-Moon transportation costs, lunar regolith is regarded as the most practical material for lunar base construction. Consequently, the in-situ additive manufacturing technology for simulated lunar regolith has been widely studied in recent years. This paper proposes a novel additive manufacturing approach for lunar regolith simulants. The simulants and several resins were mixed into a paste with high simulant content of 86 wt%, which was suitable for extrusion-based additive manufacturing process. To fully leverage the lunar environment, the feasibility of the ultraviolet (UV) and thermal curing of the resins was first verified, which was followed by the validation of the lunar regolith paste with the solid content of 86 wt%. After the characterization of the ultraviolet and heat curing properties, the paste was further 3D printed via the extrusion-based device. The extruded paste underwent preliminary curing in a UV environment and was then heated to approximate the daytime lunar conditions, achieving complete curing of the printed component. The cured parts exhibited a compressive strength of 9.83 ± 1.07 MPa, meeting the requirements for infrastructure construction in the low-gravity lunar environment. This work offers significant implications for future in-situ construction on the Moon using extrusion-based additive manufacturing of lunar regolith.

Additive manufacturing of hydrogel-based lunar regolith pastes: A pathway toward in-situ resource utilization and in-space manufacturing

Additive Manufacturing (AM), combined with efficient in-situ resource utilization, has the potential to enable sustained presence on the Moon through in-situ production and replacement of construction blocks, engineered parts, and devices in the lunar terrain. As an initial step toward realizing this vision, this work proposes a new material formulation utilizing lunar regolith simulants (LHS-1), water, and a hydrophilic hydrogel-forming polymer (Pluronic F127) to produce a hydrogel-based lunar regolith paste suitable for material extrusion AM. This formulation enables the use of water as another potential lunar in-situ resource for the first time in the literature, considering the recent confirmation of large quantities of water-ice in the shadowed craters around the lunar poles and the presence of water on the sunlit surface of the Moon. To systematically investigate the viability of the proposed hydrogel-based lunar regolith material feedstock and the application of material extrusion AM, this work introduces a three-stage design of experiment (DOE) framework to achieve two fundamental objectives. First, the viable range of lunar regolith simulant in the hydrogel-based material formulation is identified using a categorical quality evaluation of single and multi-layer material depositions. Second, the material printability window is established in terms of printing speed and extrusion rate for different viable material compositions through hierarchically designed experiments. The observed porosity of the sintered parts decreased with increasing regolith content in the material composition, while the density and compressive strength increased with higher regolith content. For material compositions consisting of 25–40 vol% regolith simulants, the observed porosity of the sintered parts decreased from 6.4 to 2.18 %, their density increased from 0.78 to 0.89 g/cm3, and their average compressive strength ranged between 0.68 and 1.32 MPa. Finally, the printability of the material was demonstrated by producing various prototype hand tools and lab-scale construction blocks with varying geometrical complexities. This work represents a crucial step toward in situ resource utilization and sustainable in-space manufacturing, sets the stage for future investigations, and the introduced DOE driven framework offers a pathway toward systematically identifying the optimal material compositions and the corresponding process parameters to enable high-quality prints.

DEM analysis of the dynamic characteristics of QH-E lunar soil simulant under cyclic triaxial tests

In this paper, cyclic triaxial tests are performed by using discrete element method (DEM) to investigate the dynamic behaviors of QH-E lunar soil simulant. The influences of number of cycles, loading frequency, waveform, cyclic stress ratio (CSR) and confining pressure on the dynamic behaviors of lunar soil simulant are discussed. The results indicate that the axial strain and dynamic modulus first increase and then tend to be stable with increasing number of cycles. The dynamic modulus increases with increasing the loading frequency, while the axial strain decreases. The damping ratio is not particularly sensitive to the confining pressure and CSR, it only decreases slightly with increasing confining pressure or decreasing CSR. Under the same conditions, rectangular wave dynamic load can produce a larger axial strain and a smaller dynamic modulus than those of sine and triangular waves, and a higher loading frequency will lead to a higher dynamic modulus and a lower axial strain, these characteristics are consistent with other lunar soil simulants and sandy soils tested in the experiment. However, the effect of confining pressure on the dynamic modulus depends on the magnitude of the CSR. For the lower CSR (CSR<0.6), the dynamic modulus increases with increasing confining pressure. While for the higher CSR(CSR>0.6), the dynamic modulus decreases significantly with increasing confining pressure, which demonstrates the unique dynamic characteristics that differs from other lunar soil simulants and sandy soils, and shows the importance of considering the magnitude of the CSR under cyclic triaxial tests.

Experimental Study on Geopolymerization of Lunar Soil Simulant under Dry Curing and Sealed Curing.

The construction of lunar surface roads is conducive to improving the efficiency of lunar space transportation. The use of lunar in situ resources is the key to the construction of lunar bases. In order to explore the strength development of a simulated lunar soil geopolymer at lunar temperature, geopolymers with different sodium hydroxide (NaOH) contents were prepared by using simulated lunar regolith materials. The temperature of the high-temperature section of the moon was simulated as the curing condition, and the difference in compressive strength between dry curing and sealed curing was studied. The results show that the high-temperature range of lunar temperature from 52.7 °C to 76.3 °C was the suitable curing period for the geopolymers, and the maximum strength of 72 h was 6.31 MPa when the NaOH content was 8% in the sealed-curing mode. The 72 h strength had a maximum value of 6.87 MPa when the NaOH content was 12% under dry curing. Choosing a suitable solution can reduce the consumption of activators required for geopolymers to obtain unit strength, effectively reduce the quality of materials transported from the Earth for lunar infrastructure construction, and save transportation costs. The microscopic results show that the simulated lunar soil generated gel substances and needle-like crystals under the alkali excitation of NaOH, forming a cluster and network structure to improve the compressive strength of the geopolymer.

Sintering kinetics and microstructure development of synthetic lunar highlands and mare regolith

Kinetics and microstructure development during pressureless sintering of two Lunar regolith simulants are reported and discussed. Dry-pressed cylindrical specimens of either a Highlands simulant or a Mare simulant were heated at 80 K min−1 to a prescribed sintering temperature and held for ten hours while dimensional changes were tracked in situ by optical dilatometry. The axial and volumetric strains and densification rates were calculated as a function of time and temperature. Possible phase transformations were evaluated by quantitative X-ray powder diffraction. The relative density increased with the logarithm of time at any temperature, and densification rates decreased continuously and sharply with increasing density. Sintered microstructures and compositional characteristics were observed by scanning electron microscopy and X-ray microprobe analysis of polished surfaces. The microstructures of both materials show evidence of heterogeneous densification, with large but isolated high-density domains surrounded by lower-density regions with interconnected porosity. No significant compositional differences were detected between the higher- and lower-density regions, meaning that the heterogeneous local densities are caused by gradients in particle size or packing that induce locally varying thermodynamic driving forces for densification. The apparent activation enthalpy for densification was measured as 445 kJ mol−1 and 440 kJ mol−1 for the Highlands and Mare simulants, respectively, values that were observed to be independent of temperature and sintered density to within the measurement uncertainty.

Pore-scale physics of ice melting within unconsolidated porous media revealed by non-destructive magnetic resonance characterization

Melting of ice in porous media widely exists in energy and environment applications as well as extraterrestrial water resource utilization. In order to characterize the ice-water phase transition within complicated opaque porous media, we employ the nuclear magnetic resonance (NMR) and imaging (MRI) approaches. Transient distributions of transverse relaxation time T2 from NMR enable us to reveal the substantial role of inherent throat and pore confinements in ice melting among porous media. More importantly, the increase in minimum T2 provides new findings on how the confinement between ice crystal and particle surface evolves inside the pore. For porous media with negligible gravity effect, both the changes in NMR-determined melting rate and our theoretical analysis of melting front confirm that conduction is the dominant heat transfer mode. The evolution of mushy melting front and 3D spatial distribution of water content are directly visualized by a stack of temporal cross-section images from MRI, in consistency with the corresponding NMR results. For heterogeneous porous media like lunar regolith simulant, the T2 distribution shows two distinct pore size distributions with different pore-scale melting dynamics, and its maximum T2 keeps increasing till the end of melting process instead of reaching steady in homogeneous porous media.

Experimental Evaluation of Lunar Regolith Settlement Caused by Ice Extraction

Water resources are essential to human exploration in deep space or the establishment of long-term lunar habitation. Ice discovered on the Moon may be useful in future missions to the lunar surface, necessitating the consideration of in situ resource utilization if it is present in sufficient amounts. Extraction of ice can cause the regolith to settle, which can lead to unintended structural damage. Therefore, any settlement resulting from ice extraction should be understood from a geotechnical perspective. This work reports on experimental investigation of the potential settlement caused by the extraction of ice from lunar regolith simulant containing different textures of ice. The KLS-1 simulant was prepared with different water contents and ice textures. Significant settlement occurred in simulant–ice mixtures with initial water contents of 5–10%.

A study of high-velocity penetration on icy lunar regolith simulants

Understanding the mechanical response of a high-speed penetrator penetrating icy lunar regolith (ILR) is essential for designing penetrators in lunar permanently shadowed regions and interpreting the detection data from the device. Experimental research on the penetrators is limited in engineering due to the difficulties in preparing large-scale icy lunar regolith simulants (ILRS). Such limitation urges the need to construct a theoretical model and verify a numerical simulation model based on the scaled-down penetration experimental results, which provide insights into the mechanical response of penetrator penetrating ILR. Projectile penetration experiments were conducted on ILRS targets with four typical water content levels in a cryogenic chamber at 110 K. The experimental results show that the ILRS with higher water content exhibits greater brittleness and a faster crack growth rate. Consequently, the diameters of cratering and scabbing areas are augmented on the target surface upon projectile penetration. Moreover, increased mechanical strength decreases the plugging height on the ILRS targets. Based on the projectile residual velocities, the equivalent target strength parameter R were calculated and fitted to a functional relationship with the uniaxial compressive strength. RHT model parameters were calibrated using the test results of the dynamic and static mechanical properties of the simulants. Numerical simulation of projectile penetration into semi-infinite and thick targets were conducted using the calibrated model. The simulation results demonstrate high consistency with the experimental and theoretical calculations, indicating the effectiveness of the constitutive model in describing the mechanical response of the ILRS under projectile penetration.