Lubrication Interactions Research Articles

Fabrication of AFM-Compatible Hydrogel Probe to Achieve Hydration Superlubrication in Salt Solutions.

Hydrogels demonstrate effective lubricating properties, but the underlying mechanisms at the nanoscale remain elucidated. In this study, a novel strategy is proposed by fabricating the hydrogel probes compatible with atomic force microscopy (AFM) to establish a superlubrication system based on the hydration interactions. The probe is made of polyethylene glycol diacrylate (PEGDA)-based hydrogel microspheres, which can achieve an extremely low friction coefficient of 0.0014 when sliding on the mica surface in NaCl solution. The friction coefficients in salt solutions sequence μ(NaCl) <0.01 < μ(KCl) < μ(LiCl), which contradicts the sequence based on the ion hydration capacity (K+ < Na+ < Li+), suggesting that the hydrogel-based lubrication systems are governed by the interplay between ion hydration lubrication and ions-polymer interactions simultaneously. The observed superlubrication in NaCl solution is ascribed to the superior hydration capacity of Na+ ions, which forms a stable and smooth hydration layer within the contact zone. This work provides new avenues for AFM-based hydrogel studies, and also significantly advances the comprehension of hydrogel lubrication mechanisms at the nanoscale.

The confined stresslet for suspensions in a spherical cavity. Part 1. Traceless elements

The confined Stokesian dynamics (CSD) algorithm recently reported equilibrium properties but was missing hydrodynamic functions required for suspension stress and non-equilibrium properties. In this first of a two-part series, we expand the CSD algorithm to model the traceless part of the stress tensor. To obtain quantities needed to solve the integral expressions for the stress, we developed a general method to solve Stokes’ equations in bispherical coordinates. We calculate the traceless stress tensor for arbitrary particle-to-enclosure size ratio. We next compute rheology of a confined suspension by implementing the stresslet hydrodynamic coefficients into CSD, yielding the deviatoric part of the many-body hydrodynamic stresslet. We employed energy methods to relate this stresslet to the high-frequency viscosity of the confined suspension, finding an increase in viscous dissipation with crowding and confinement well beyond the unconfined value. We show that confinement effects on viscosity are dominated by near-field interactions between the particles that reside very near the cavity wall (rather than particle–wall interactions). Surprisingly, this near-field effect is stronger than the viscosity of an unconfined suspension, showing that entropic exclusion driven by the wall sets up many lubrication interactions that then generate strong viscous dissipation. The limiting case of a particle near a flat wall reveals a correction to prior literature. The theory presented in this work can be expanded to study the Brownian contribution to the viscosity of confined suspensions in and away from equilibrium. In part 2, we report the osmotic pressure, via the trace of the stress tensor.

Effect of Shot‐Peening Process and Nanoparticle‐Added Lubricant on the Tribological Performance of Aluminium‐Based Sliding Bearing Material

ABSTRACTIn this study, it is aimed to increase the wear and fatigue performance of aluminium‐based sliding bearing material by using silver nanoparticles (AgNPs) added lubricant and shot‐peening process. The main purpose is to minimise the wear of the bearing material by penetrating AgNPs added lubricants into the rough surfaces formed by shot peening. Almen intensity, coverage and shot size parameters in the shot‐peening process were analysed in terms of hardness, surface roughness and fatigue strength. The shot‐peened aluminium bronze was subjected to wear experiments under dry, pure water and AgNPs added lubricant conditions. The wear test results were analysed in terms of friction coefficient, wear volume and surface roughness parameters, and the interaction of lubricant and shot‐peening parameters was evaluated. According to the results of the shot‐peening experiments, the Almen intensity was the most effective parameter in terms of hardness and surface roughness (91.62%). It was concluded that the hardness value was 8% higher at high Almen (12–14A) intensity compared with low Almen intensities, and the shot‐peening process could increase the fatigue strength by ~21 times. According to the wear tests, the most effective parameters were 4–6 Almen intensity and AgNP‐added lubricant.

Optimal lubricating protection and interfacial behavior for titanium alloy surface from phosphorus-based ionic liquids

The poor wear resistance of titanium alloy makes it challenging to develop high-performance lubricating materials. For the characteristic of highly designable structure, ionic liquids (ILs) are the potential lubricants with excellent physicochemical properties and lubricating performance. Herein, three protic phosphorus-based ionic liquids (PPILs) were designed and synthesized with the exploration of their interfacial lubrication behavior and interaction mechanism on the titanium substrate. The as-synthesized IL lubricants exhibit optimal tribological properties on steel-titanium friction pairs even at high load and temperature. The surface analysis showed that IL can form the lubricating protective film on the titanium-based metal surface, effectively reducing the adhesive wear. Combined with surface analysis techniques (SEM, XPS, FIB-TEM and TOF-SIMS), the lubrication mechanism was discussed systematically.

Visualization of vane chattering in rotary compressor

In this study, the impacts of various factors on the chattering phenomenon in sliding vane compressors, which is a crucial aspect that influences their performance and efficiency were explored. The analysis focused on the compressor rotational speed, pressure ratio, and operating temperature, considering both ambient and heated conditions. The aim was to provide a comprehensive understanding of the relationship between these factors and the occurrence of chattering at different operational intervals, as well as the vane sealing performance and adherence to the chamber wall.The methodology involved examining vane behavior and the chattering occurrence across three intervals under various conditions, specifically looking at oil films formation and sealing performance degradation. The experimental results provided notable insights into the chattering phenomenon. It was shown that as the pressure ratio increased and the compressor rotational speed decreased, the sealing performance deteriorated. Moreover, when operating under heated conditions, a decrease in oil viscosity leads to reduced friction between the vane and bearing, improving vane adherence compared to ambient conditions.The methodology and findings of this study provide insights into the chattering phenomenon in vane compressors by considering the interplay between various factors. The results emphasize the importance of optimizing the compressor oil refueling flow, rotational speed, pressure ratio, and operating temperature, to ensure proper lubrication and efficient interaction between the vanes and compression chamber walls for improved compressor performance and reduced operational challenges.

Effects of confinement-induced non-Newtonian lubrication forces on the rheology of a dense suspension

In this work, we propose a functionalised bi-viscous lubrication model to study the material properties of concentrated non-Brownian suspensions and explore the possible confinement-induced non-Newtonian effects of the lubricant in the rheological response of this type of suspensions. From tribological studies, it is well-known that even macroscopically Newtonian liquids under strong confinement might exhibit properties which deviate significantly from their bulk behaviour. When two surfaces separated by an extremely small gap (still large compared to the molecular size) are sheared, strong shear-thinning of the lubricant viscosity at low shear-rates is observed, in spite of its Newtonian-like bulk response. This is connected to a significant increase of the zero-shear-rate viscosity under extreme confinement. We start from an effective lubrication algorithm recently proposed and develop a new gap-size-dependent interparticle bi-viscous lubrication model, able to capture qualitatively the main phenomenology of confined lubricants. We solve the lubrication interaction between particles iteratively via a semi-implicit splitting scheme. Since the handling of lubrication is made implicitly here, the method copes efficiently with large increases of the inter-particle effective viscosities, which would otherwise lead to simulation blow-up or the use of vanishing time-steps in standard explicit schemes. We analyse the rheological response of the suspension systematically in terms of model parameters. In contrast to pure Newtonian lubrication interactions, distinct shear-thinning and shear-thickening regimes in the relative suspension viscosity are observed, which are discussed in terms of particle microstructure coupled with the complex rheology of the confined lubricant. In addition, normal-stress response is negative in both N1 and N2, which is difficult to achieve with standard contact frictional models.

Superior tribological and anti-corrosion performance of corrosion inhibitors intercalated LDH-MAO coating on AZ31 Mg alloys

Sodium dodecyl sulfate (SDS) and 8-Hydroxyquinoline (8-HQ) intercalated layered double hydroxides (LDH) sheets were in-situ formed in MAO layer to prepare a composite coating (CI@LDH-MAO) on AZ31 magnesium alloy. This composite coating demonstrates commendable anti-corrosion performance, primarily attributed to the formation of LDH sheets and insoluble Mg(HQ)2 compounds. The electrochemical impedance modulus of the composite coating surpasses that of the MAO coating by three orders of magnitude after immersion of 360 h. Concurrently, the CI@LDH-MAO composite coating exhibits exemplary tribological properties, characterized by a friction coefficient of approximately 0.19 and a wear rate of (11.5 ± 1.5)× 10−6 mm3/(N·m). This outstanding tribological performance can be ascribed to enhanced interaction of lubricants with the friction interface by 8-HQ and SDS anions.

Collision efficiency of like-charged spheres settling in a quiescent environment

We study the gravity-induced collisions of charged spheres of dielectric materials dispersed in a gaseous medium. When the gap thickness between the surfaces of two spheres is shorter than the mean free path of the surrounding fluid medium, continuum assumptions for the hydrodynamics interactions are no longer valid, and the non-continuum lubrication interactions result in surface-to-surface contact in finite time. Two like-charged dielectric spheres attract each other at close separations for a wide range of size and charge ratio values. We use trajectory analysis to calculate the collision rate and, thus, explore the role of electrostatic interactions in the collision dynamics of a pair of like-charged dielectric spheres. We present the modifications of pair trajectories due to electrostatic forces and show how collision efficiencies vary with the non-dimensional parameter capturing the relative strength of the electrostatic force to gravity as well as the charge ratio and size ratio.

Collision Statistics of Droplets in Turbulence Considering Lubrication Interactions, Mobility of Interfaces, and Non-continuum Molecular Effects

Collision statistics of same-size aerodynamically interacting droplets in homogeneous isotropic turbulence is examined via hybrid direct numerical simulations combined with Lagrangian particle tracking under a point-particle assumption and a one-way momentum coupling. The simulations are performed both in the absence and presence of gravity for various droplet Stokes numbers (0.1–2) over a wide range of liquid water contents (LWCs = 1–30 g/m3\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ ext {g/m}^3$$\\end{document}). Also, the effects of using different representations of the lubrication forces, i.e. a continuum and a non-continuum one, have been investigated. The results have highlighted the importance of considering the aerodynamic interaction, especially in the presence of gravity for the systems that have high LWCs. Likewise, taking the lubrication force into account shows a notable change in statistics, but a non-continuum representation yields results that are close to the continuum one. In addition, the impact of modeling droplets as fluid drops instead of rigid particles has been examined. Obtaining quite close statistics under both cases demonstrates that a rigid particle assumption for water droplets in air is sufficiently accurate owing to the high water-to-air viscosity ratio. Moreover, the collision efficiency is shown to be in the range 60–100% in the absence of gravity, which approaches 100% as the LWC is enlarged. In the presence of gravity, however, the efficiency grows, with both the Stokes number and the LWC, to values as high as 300%. Finally, for settling droplet systems, the enhancement factor due to turbulence is quantified, exhibiting a growth with the LWC and a reduction with the Stokes number.

Hydrodynamic interactions between squirmers near walls: far-field dynamics and near-field cluster stability

Confinement increases contacts between microswimmers in dilute suspensions and affects their interactions. In particular, boundaries have been shown experimentally to lead to the formation of clusters that would not occur in bulk fluids. To what extent does hydrodynamics govern these boundary-driven encounters between microswimmers? We consider theoretically the symmetric boundary-mediated encounters of model microswimmers under gravity through far-field interaction of a pair of weak squirmers, as well as the lubrication interactions occurring after contact between two or more squirmers. In the far field, the orientation of microswimmers is controlled by the wall and the squirming parameter. The presence of a second swimmer influences the orientation of the original squirmer, but for weak squirmers, most of the interaction occurs after contact. We thus analyse next the near-field reorientation of circular groups of squirmers. We show that a large number of swimmers and the presence of gravity can stabilize clusters of pullers, while the opposite is true for pushers; to be stable, clusters of pushers thus need to be governed by other interactions (e.g. phoretic). This simplified approach to the phenomenon of active clustering enables us to highlight the hydrodynamic contribution, which can be hard to isolate in experimental realizations.

Characterization of the Tribological Behavior of Different Tool Coatings and Dry Lubricant for High‐Strength Aluminum Alloys at Elevated Temperatures

The use of high‐strength aluminum components in automotive manufacturing offers the opportunity to reduce vehicle weight significantly and provide new lightweight potentials. In the past, the so‐called hot forming and quench process (HFQ) successfully demonstrates the potential for the production of complex‐shaped components made out of age‐hardenable high‐strength aluminum alloys. Currently, no method permits wear‐free quench forming without the use of lubricants. To fulfill the increasing ecological and economic requirements, it is necessary to identify wear‐reducing techniques to promote this forming technology in the future. This contribution investigates the interaction of lubricant and tool coatings on the tribological performance during quench forming of the high‐strength aluminum alloy AA7075 at elevated temperatures. For this purpose, the tribological behavior is investigated using both, flat strip drawing tests and deep drawing operations. Subsequently, the component quality is compared and discussed. The results demonstrate that tool coatings are effective for the production of high‐strength components in the HFQ process with minimal or even no lubrication and thus provide ecological as well as economic advantages.

Collision efficiency of cloud droplets in quiescent air considering lubrication interactions, mobility of interfaces, and noncontinuum molecular effects

The gravitational collision efficiency of a pair of cloud droplets settling in quiescent air is computed using various models for the aerodynamic interaction forces. The employed models consider (i) the effect of spherical fluid drops with mobile interfaces, and (ii) the noncontinuum molecular effect which changes short-range lubrication forces when the gap size between a pair is comparable to the air mean free path. These cases are compared with the widely used case that considers the droplets to be spherical rigid particles. We find that assuming rigid particles is accurate for water droplets interacting in air, but noncontinuum lubrication has to be taken into account.

Hydrodynamic lubrication in colloidal gels.

Colloidal gels are elasto-plastic materials composed of an out-of-equilibrium, self-assembled network of micron-sized (solid) particles suspended in a fluid. Recent work has shown that far-field hydrodynamic interactions do not change gel structure, only the rate at which the network forms and ages. However, during gel formation, the interplay between short-ranged attractions leading to gelation and equally short-ranged hydrodynamic lubrication interactions remains poorly understood. Here, we therefore study gelation using a range of hydrodynamic descriptions: from single-body (Brownian Dynamics), to pairwise (Rotne-Prager-Yamakawa), to (non-)lubrication-corrected many-body (Stokesian Dynamics). We confirm the current understanding informed by simulations accurate in the far-field. Yet, we find that accounting for lubrication can strongly impact structure at low colloid volume fraction. Counterintuitively, strongly dissipative lubrication interactions also accelerate the aging of a gel, irrespective of colloid volume fraction. Both elements can be explained by lubrication forces facilitating collective dynamics and therefore phase-separation. Our findings indicate that despite the computational cost, lubricated hydrodynamic modeling with many-body far-field interactions is needed to accurately capture the evolution of the gel structure.

Implementation of Sustainable Vegetable-Oil-Based Minimum Quantity Cooling Lubrication (MQCL) Machining of Titanium Alloy with Coated Tools

The lubrication capacity and penetration ability of the minimum quantity cooling lubrication-based strategy is linked with lubrication specific parameters (oil flow rates and air pressure), cutting conditions, and chip formation. It points out the complex selection involved in the MQCL-assisted strategy to attain optimal machining performance. Lubrication during metal cutting operations is a complex phenomenon, as it is a strong function of the cutting conditions. In addition, it also depends on the physical properties of the lubricant and chemical interactions. Minimum Quantity Lubrication (MQL) has been criticized due to the absence of cooling parts; MQCL is a modified version where a cooling part in the form of sub-zero temperatures is provided. The aim of this paper was to investigate the influence of different lubrication flow parameters under minimum quantity cooling lubrication (MQCL) when machining aeronautic titanium alloy (Ti6Al4V) using Titanium Aluminum Nitride—Physical Vapor Deposition (TiAlN-PVD) coated cutting inserts. The machining experiments on the MQCL system were performed with different levels of oil flow rates (70, 90, and 100 mL/h) and the performance was compared with the conventional dry cutting and flood cooling settings. A generic trend was observed that increasing the oil flow rate from 70—mL/h to 100 h/h improved the surface finish and reduced thermal softening at a low feed of 0.1 mm/rev. The results revealed that many tool-wear mechanisms such as adhesion, micro-abrasion, edge chipping, notch wear, built-up edge (BUE), and built-up layer (BUL) existed.

Assessing compatibility of excipients selected for a sustained release formulation of bilberry leaf extract

The study is aimed to assess the compatibility of bilberry leaf powder extract (BLPE) with six excipients selected for sustained-release (SR) tablet formulation. The BLPE was obtained with the addition of L-arginine and Myo-inositol as the carriers. Thermogravimetric (TG-DTG) analysis and Fourier-transform infrared spectroscopy (FTIR), supported by Pearson correlation analysis, were applied to detect possible interactions in the binary mixtures (1:1) of the BLPE with each excipient. The TG-DTG showed some deviations in the thermal behavior of the BLPE / excipient mixtures. However, only the thermal behavior of magnesium stearate in the mixture significantly differed from individual samples, which suggested chemical interaction for this excipient. The FTIR analysis confirmed that the BLPE is compatible with Eudragit L100, Methocel K4M, Methocel K100LV, Avicel PH-101, and Plasdone S-630. Whereas it undergoes solid-state chemical interaction in the binary mixture with magnesium stearate. According to the FTIR-spectra, it is suggested that this interaction results in the formation of stearic acid and alkalization of the medium. These findings evidence for the possibility of using TG-DTG analysis as an independent thermal technique for compatibility studies and also confirm the earlier reported interaction of basic lubricants, e.g., stearic salts, with active ingredients containing amino groups.

Investigation of interaction of extreme pressure additive, load and sliding speed parameters with silver nano-particles in wear environment

This study aims to minimize the wear of brass-based sliding bearing materials by using extreme-pressure and nano-silver added lubricants. The nano-fluids used in the experiments were characterized by the Zeta test, size measurement, absorbance graphs, wettability analyses and TEM imaging. The effect of extreme-pressure (5%, 10% and 15%) and nano-silver (1%, 5% and 9%) concentration ratios and the interaction of lubricants with load and speed parameters were analyzed with ball-on-plate wear experiments. The results were analyzed by evaluating the friction coefficient and wear volume values, as well as SEM and 3D topography images. It has been found that 5% extreme pressure lubricant reduces friction coefficient by 32.82% and volume loss by 89.51% compared to base lubricant. According to the results, the lowest friction coefficient (0.0276), volume loss (0.042 mm3) values and the best surface images were obtained at 1% concentration. Furthermore, the tribological performance decreased as the concentration of extreme-pressure and nano-silver increased, and optimum extreme-pressure and nano-silver concentrations were obtained as 5% and 1%, respectively. Using additives, different load (10N, 20N and 30N) and speed (10 rpm, 25 rpm, 40 rpm) parameters, Taguchi’s L9 fractional factorial experimental design was created for interaction analyses. With the Taguchi analysis of the design, 5% extreme pressure added lubricant, 10N load and 40 rpm speed parameter combination was determined as the optimum test condition and base lubricant, 30N load and 25 rpm speed parameters were determined as the worst test condition. According to the variance analyses results, it was determined that the lubricant condition was the most effective parameter on the coefficient of friction (67.79%), volume loss (51.07%) and surface roughness (45.43%).

Cyclic force driven colloidal self-assembly near a solid surface

HypothesisSelf-assembled colloidal mobility out of a non-equilibrium system can depend on many external and interparticle forces including hydrodynamic forces. While the driving forces guiding colloidal suspension, translation and self-assembly are different and unique, hydrodynamic forces are always present and can significantly influence particle motion. Unfortunately, these interparticle hydrodynamic interactions are typically overlooked. ExperimentsHere, we studied the collective behavior of colloidal particles (4.0 µm PMMA), located near the solid surface in a fluid medium confined in a cylindrical cell (3.0 mm diameter, 0.25 mm height) which was rotated vertically at a low rotational speed (20 rpm). The observed colloidal behavior was then validated through a Stokesian dynamics simulation where the concept of hydrodynamic contact force or lubrication interactions are avoided which is not physically intuitive and mathematically cumbersome. Rather, we adopted hard-sphere like colloidal collision or mobility model, while adopting other useful simplification and approximations. FindingsUpon particles settling in a circular orbit, they hydrodynamically interact with each other and evolve in different structures depending on the pattern of gravity forces. Their agglomeration is a function of the applied rotation scheme, either forming colloidal clusters or lanes. While evolving into dynamic structures, colloids also laterally migrate away from the surface.

Fuel-Lubricant Interactions: Critical Review of Recent Work

A critical review of recent work on fuel lubricant interactions is undertaken. The work focusses on liquid fuels used in diesel and gasoline vehicles. The amount of fuel that contaminates the lubricant depends on driving conditions, engine design, fuel type, and lubricant type. When fuel contaminates a lubricant, the viscosity of the lubricant will change (it will usually decrease), the sump oil level may increase, there may be a tendency for more sludge formation, there may be an impact on friction and wear, and low speed pre-ignition could occur. The increased use of biofuels (particularly biodiesel) may require a reduction in oil drain intervals, and fuel borne additives could contaminate the lubricant. The move towards the active regeneration of particulate filters by delayed fuel post-injection and the move towards hybrid electric vehicles and vehicles equipped with stop-start systems will lead to increased fuel dilution. This will be of more concern in diesel engines, since significant fuel dilution could persist at sump oil temperatures in the range of 100–150 °C (whereas in gasoline engines the more volatile gasoline fuel will have substantially evaporated at these temperatures). It is anticipated that more research into fuel lubricant interactions, particularly for diesel engines, will be needed in the near future.

Impact of polydispersity and confinement on diffusion in hydrodynamically interacting colloidal suspensions

We present a computational study of the equilibrium dynamics of a polydisperse hard-sphere colloidal dispersion confined in a spherical cavity. We account for many-body hydrodynamic and lubrication interactions between particles and with the confining cavity utilizing our confined Stokesian dynamics model, expanded here for size polydispersity. We find that, even though the tendency of polydispersity to homogenize structure in a suspension is still present in confinement, strong correlations induced by the cavity resist homogenization. Although seemingly opposite, these two effects have a common driver, which is to maximize configurational entropy of particles in the cavity interior. These structural effects couple with the hydrodynamics to change the particle dynamics: polydispersity weakens lubrication effects near the cavity wall, allowing small (large) particles to diffuse faster (slower) than in a monodisperse suspension. As a small (large) particle gets farther from the wall, polydispersity weakens many-body hydrodynamic couplings, driving diffusivity up (down). While the local cage dynamics dominates short-time self-diffusion, long-time dynamics is also affected. In the concentrated regime, polydispersity and confinement combine to induce radial de-mixing into size-segregated populations. The cavity becomes the most influential ‘nearest neighbour’, setting the length scale of and dynamics within these radial domains. This intermediate length-scale caging makes the angular dynamics insensitive to polydispersity but leads to radial long-time mean-square displacement that changes qualitatively with volume composition. These results hold promise for explaining colloidal-scale physics implicated in the functioning of biological cells, and the engineering of non-living confined colloids where size de-mixing could be useful in the design of encapsulated micro-reactors and therapeutic vesicles.

Interacting Brownian particles exhibiting enhanced rectification in an asymmetric channel

Rectification of interacting Brownian particles is investigated in a two-dimensional asymmetric channel in the presence of an external periodic driving force. The periodic driving force can break the thermodynamic equilibrium and induces rectification of particles (or finite average velocity). The spatial variation in the shape of the channel leads to entropic barriers, which indeed control the rectification of particles. We find that by simply tuning the driving frequency, driving amplitude, and shape of the asymmetric channel, the average velocity can be reversed. Moreover, a short range interaction force between the particles further enhances the rectification of particles greatly. This interaction force is modeled as the lubrication interaction. Interestingly, it is observed that there exists a characteristic critical frequency Ωc below which the rectification of particles greatly enhances in the positive direction with increasing the interaction strength; whereas, for the frequency above this critical value, it greatly enhances in the negative direction with increasing the interaction strength. Further, there exists an optimal value of the asymmetric parameter of the channel for which the rectification of interacting particles is maximum. These findings are useful in sorting out the particles and understanding the diffusive behavior of small particles or molecules in microfluidic channels, membrane pores, etc.