AbstractTo tolerate high processing temperature during the fabrication of low‐temperature polycrystalline silicon thin‐film transistors (LTPS–TFT) in flexible OLED devices, the polyimide (PI) films, which are used as substrate, should have ultra‐high glass transition temperature (Tg > 450°C) and ultra‐low coefficient of thermal expansion (CTE at 0–5 ppm K−1). In this paper, two novel heterocyclic monomers, namely, N,N'‐(xanthone‐2,7‐diyl)bis(4‐aminobenzamide) (p‐DAXBA) and N,N'‐(xanthone‐2,7‐diyl)bis(3‐aminobenzamide) (m‐DAXBA), which contain a xanthone moiety, are prepared and polycondensed with pyromellitic dianhydride (PMDA), respectively. PI films (PIa and PIb) with intrinsic highTgand low CTE are designed from the perspective of rigid conjugate xanthone structure and hydrogen bonding interaction. It is found that the PIa films prepared byp‐DAXBA have better linear structure of molecular chains and show relatively higherTgand lower CTE. TheTgof PIa‐40 is greater than 450°C, and CTE can reach as low as 2.7 ppm K−1, tensile strength of 179 MPa, modulus of 5.67 GPa, indicating potential application prospect as a flexible OLED substrate.
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