In order to study the mechanism of critical heat flux of pool boiling, measurement of heat flux fluctuation and high speed photographic observation were carried out simultaneously on a constant temperature surface heated by electrically controlled Joule heating, in the vicinity of a critical heat flux point. They revealed the following : (1) when the surface is covered by a coalesced bubble, heat flux begins to increase because evaporation is enhanced ; (2) heat flux begins to decrease either while the surface is covered by a coalesced bubble due to dryout of the liquid on the surface, or just after nucleation begins under the rising bubble due to a relatively low heat transfer rate of nucleation ; and (3) heat applied from the time the surface is covered by a bubble until the time heat flux begins to ducrease does not vary widely and corresponds to latent heat of liquid about 11 -μm thick.