Low Loading Rates Research Articles

Experimental research on influence mechanism of loading rates on rock pressure stimulated currents

The study of pressure stimulated current (PSC) changes of rocks is significant to monitor dynamic disasters in mines and rock masses. The existing studies focus on change laws and mechanism of currents generated under the loading of rocks. An electrical and mechanics test system was established in this paper to explore the impacts of loading rates on PSCs. The results indicated that PSC curves of different rocks had different change laws under low/high loading rates. When the loading rate was relatively low, PSC curves firstly changed gently and then increased exponentially. Under high loading rates, PSC curves experienced the rapid increase stage, gentle increase stage and sudden change stage. The compressive strength could greatly affect the peak PSC in case of rock failure. The loading rate was a key factor in average PSC. Under low loading rates, the variations of PSCs conformed to the damage charge model of fracture mechanics, while they did not at the fracture moment. Under high loading rates, the PSCs at low stress didn’t fit the model due to the stress impact effects. The experimental results could provide theoretical basis for the influence of loading rates on PSCs.

Mechanical properties of cellulose-fibre reinforced bituminous mix under various loading rates

This research aims to observe the effect of applying cellulose fibre to the mechanical properties of bituminous mixtures when subjected to various loading speeds that simulate various traffic situations with fibre dosages of 0.3 – 0.5% of mix weight. The semi-circular bending (SCB) test was employed in this project, where the specimens were subjected to loading speeds of 0.25, 0.5, and 1 mm/min. The incorporation of cellulose was reported to enhance the tensile strength of the specimens up to 43.75% at the lowest loading rate and 13.75% at the highest rate, while the critical strain energy was elevated to 24.54% at the lowest rate and 38.2% at the highest rate, signifying better resistance against loading. Meanwhile, the flexibility index (FI) of modified specimens showed a mixed trend compared to the control mix, 30.43% higher at the lowest rate and 28.9% lower at the highest rate. To sum up, the incorporation of cellulose fibre into the bituminous mixture can enhance its strength and resistance against various loading rates, and the fibre dosage of 0.3% is recommended to give the best outcome.

Exploring the effects of organic loading rate and domestic wastewater treatment by algal‐bacterial granules under natural daylight conditions

Algal-bacterial granules or phototrophic granules (PGs) comprising phototrophic microorganisms and bacteria are explored in wastewater treatment for achieving both environmental and economic sustainability. This study describes development of PGs and their use in biological treatment of synthetic and real domestic wastewater (sewage) under natural daylight conditions and low organic loading rate (OLR). Development of PGs was sequentially recorded in a photobioreactor operated in photo-sequencing batch reactor (photo-SBR) mode at a low OLR of 1 kgCOD.m-3 .day-1 and the developed PGs was evaluated for treating synthetic wastewater and real municipal wastewater with 0.14 kg COD m-3 .day-1 . PGs formed in the photo-sequential batch reactor (SBR) were compact and dense and exhibited excellent settling properties. The removal efficiencies were determined to be up to 95%, 93%, 97%, 72%, and 88% for turbidity, COD, TOC, NH4 + -N, and NO2 - -N/NO3 - -N, respectively. Additionally, a reduction in total viable bacterial counts and fecal coliform bacteria up to 1.7 × 103 and 7.8 × 102 cfu.mL-1 , respectively, during treatment of real municipal wastewater was achieved. This study demonstrated cultivation of algal-bacterial granules or PGs and their application for treating real municipal wastewater under natural daylight and tropical climate conditions. Further studies are needed on understanding interactions among phototrophic, autotrophic, and heterotrophic microorganisms of complex algal-bacterial consortium for emerging applications in bioremediation and wastewater treatment. PRACTITIONER POINTS: Phototrophic granules (PGs) were cultivated from algal consortium and activated sludge inoculum in photo sequencing batch reactors. Granular photobioreactor was operated at low OLR of 1 kgCOD.m3 .day-1 for developing well-settling algal-bacterial granules. PGs were stable and showed efficient biological treatment of synthetic wastewater and real sewage. Removals for turbidity, pathogens, and ammonium were at 95%, 3-log, and 72%, respectively, from real sewage.

Stigmasterol Removal by an Aerobic Treatment System.

Stigmasterol is a phytosterol contained in kraft mill effluent that is able to increase over 100% after aerobic biological treatment. This compound can act as an endocrine disrupter as its structure is similar to that of cholesterol. Furthermore, stigmasterol contained in kraft mill effluent shows high toxicity (25-fold more than β-sitosterol) to aquatic organisms such as Daphnia magna. However, the operation of the aerobic treatment and biomass adaptation could be affecting their removal. The performances of activated sludge (AS), aerated lagoon (AL), and moving bed biofilm reactors (MBBR) are compared to remove the stigmasterol contained in kraft mill effluent. The AL operates at a hydraulic retention time of 6h and removes up to 90% of phytosterols. So, a 96% of stigmasterol is removed by AL when the sterol retention load is 0.6mg/L · d. However, stigmasterol concentrations increase from 29% to 37% at a low stigmasterol load rate (0.2mg/L · d). On the other hand, the stigmasterol is removed between 65% and 87% by an AS under a hydraulic retention time of 3h. Moreover, a 100% of stigmasterol can be removed by the MBBR when the hydraulic retention time is 2days.

Influence of the Loading Rate on the Cracking Process of Concrete in Quasi-Static Loading Domain

This study presents analysis of two types of experimental test related to the crack propagation in concrete specimens subjected to high-sustained loading levels and quasi-static loadings. The concept of the equivalent crack length is introduced to perform this analysis. Even though this analysis is partial, it shows the influence of loading rate conditions on the crack process rate. This result shows that, in the domains of low and very low loading rates, the concrete mechanical characteristics linked to the cracking process (for example, tensile strength, post-cracking behaviour, etc.) are dependent on the loading rates applied to the specimens for determining them.

Hardening mechanisms of “cold” rolled tungsten after neutron irradiation: Indentation and finite elements modelling

The mechanical properties of “cold” rolled tungsten sheet after neutron irradiation at high temperature are investigated by instrumented indentation and crystal plasticity finite element modelling (CPFEM). Neutron irradiation to a dose of 0.2 displacements per atom was performed in the temperature range from 600 to 1200 °C in the Belgian material test reactor BR2 at SCK CEN, Mol. The contribution of the irradiation damage in the constitutive laws has been deduced by utilizing the load-depth curves of the indentation measurements and incorporating microstructural information from transmission electron microscopy measurements. The simulated load-depth curves are in very good agreement with the experimental data indicating that the model can characterize the plastic deformation of the irradiated W material. It is found that the irradiation temperature has almost no effect on the load-depth curves and the hardness increase, of around 19% after irradiation, is temperature independent within errors. The formation of voids after irradiation is the main cause of irradiation induced hardening while the dislocation loops have a much lower influence. Indentation tests at low and high loading rates showed that the void dominated microstructure is more sensitive to the increase of the deformation rate.

Fractal characteristics of rocks and mesoscopic fractures at different loading rates

Uniaxial compression tests were conducted on rocks under different loading rates to analyze their effect on rock fragmentation. The fractal dimension of the macroscopic fragmentations of the rocks were then calculated by combining the fractal theory. Based on scanning electron microscopy (SEM), the macroscopic failure characteristics and mesoscopic fracture morphology characteristics of the rocks under different loading rates were compared and analyzed; the mesoscopic fractal dimension of the fracture was calculated using the box dimension method. The results demonstrate that when the loading rate is increased from 0.001 to 0.05 mm/s, the average fragmentation distribution coefficient decreases from 18.99 to 16.37 mm. As the loading rate increases, the fragmentation distribution coefficient gradually decreases, and the rock sample breaks; the degree of failure gradually increases, and the failure mode of the rock transforms from tension to shear failure. The SEM analysis reveals that under low loading rates, an intergranular fracture indicates the primary failure mode. The macroscopic performance primary presents tensile failure; as the loading rate increases, the range of the transgranular fracture gradually increases, and the failure mode evolves from an intergranular to transgranular fracture. The fractal dimension of the mesoscopic structure of the rock fracture tends to increase with an increase in the loading rate, and demonstrates a good positive relationship by fitting with the macrostructure fractal dimension. A larger fractal dimension of the microstructure of a rock fracture indicates more complex structure of the fractured surface. This study provides a better understanding of the meso-rock failure mechanism, and presents significant findings regarding ore rock fragmentation and rockburst prevention.

Ultrasonic-promoted defect activation and structural rejuvenation in a La-based metallic glass

Ultrasonic-assistant rejuvenation in a La-based metallic glass was demonstrated by means of nanoindentation for the first time. A more pronounced nanoindentation creep behavior along with mechanical softening was detected. It is proposed to be associated with the activation of flow defects with long characteristic relaxation time at a low loading rate and short characteristic relaxation time at a high loading rate during anelastic deformation process based on the Maxwell-Voigt model. Such rejuvenation behavior also leads to an unstable plastic flow and a relatively low energy barrier for atomic diffusion during the fast growth process of crystalline phases accompanied with the reduced glass transition and crystallization temperatures. Our studies might provide insights into the microscopic deformation mechanism of glassy materials, which could help in seeking the novel applications of amorphous alloys such as ultrasonic-assistant cold joining or molding.

Deformation-softening behaviors of high-strength and high-toughness steels used for rock bolts

In deep ground engineering, the use of high-strength and high-toughness steels for rock bolt can significantly improve its energy absorption capacity. However, the mechanisms and effects of rock loading conditions on this kind of high energy-absorbing steel for rock bolt remain immature. In this study, taking Muzhailing highway tunnel as the background, physically based crystal plasticity simulations were performed to understand the effect of rock loading rate and pretension on the deformation behaviors of twinning induced plasticity (TWIP) steel used for rock bolt. The material physical connecting to the underlying microscopic mechanisms of dislocation glide and deformation twinning were incorporated in numerical modeling. The rock loading conditions were mimicked by the real-time field monitoring data of the NPR bolt/cable equipment installed on the tunnel surrounding rock surface. The results indicate that the bolt rod exhibits pronounced deformation-softening behavior with decrease of the loading rate. There is also a sound deformation-relaxation phenomenon induced by the dramatic decrease of loading rate after pre-tensioning. The high pretension (>600 MPa or 224 kN) can help bolt rod steel resist deformation-softening behavior, especially at low loading rate (<10−1 MPa/s or 10−2 kN/s). The loading rate was found to be a significant factor affecting deformation-softening behavior while the pretension was found to be the major parameter accounting for the deformation-relaxation scenario. The results provide the theoretical basis and technical support for practical applications.

Construction of pH-responsive polydopamine coated magnetic layered hydroxide nanostructure for intracellular drug delivery

In recent years, using magnetic nanocomposites for controlled release of drugs and target-specific drug delivery has great potential in exploring a new method for cancer chemotherapy. Nevertheless, the low loading rate of insoluble drugs greatly restricts their efficacy and clinical application. Here, an efficient magnetic nanostructure combining Fe3O4 nanoparticles and layered double hydroxide (LDH) was developed and used for tumor cell inhibition. LDH was first deposited on Fe3O4 nanoparticles (Fe3O4@LDH), curcumin (Cur) was then loaded and polydopamine (PDA) eventually formed a PDA-coating on Fe3O4@Cur-LDH via self-polymerization. The Fe3O4@Cur-LDH/PDA nanostructure showed a suitable nano-meter size, excellent magnetic property, and high drug loading rate (up to 38 %). In vitro release results implied that Fe3O4@Cur-LDH/PDA nanostructure had good pH-responsive performance and excellent controlled-release behaviors due to the introduction of PDA. The cellular experiments demonstrated that Fe3O4@Cur-LDH/PDA nanostructure had good biocompatibility. In addition, Fe3O4@Cur-LDH/PDA entered into the cells mainly through endocytosis and had excellent inhibition on HepG2 cell viability in a concentration-dependent manner. Therefore, Fe3O4@Cur-LDH/PDA nanostructure has a prospective application in cancer therapy as a controlled drug delivery system.

A mechanistic insight into the shrinkage and swelling of Ca-montmorillonite upon adsorption of chain-like ranitidine in an aqueous system

Adsorption behavior of ranitidine hydrochloride (RT) on a Ca-montmorillonite (SAz-1) was studied in aqueous system through batch experiments. The adsorption kinetics revealed that the equilibrium reached within 0.25 h and the data fitted well to the pseudo-second order kinetic equation (R2 = 0.98). The maximum RT adsorption capacity of SAz-1 was 369.2 mg/g and the adsorption isotherm data followed the Langmuir model (R2 = 0.99). The adsorption of RT and desorption of exchangeable cations from the clay mineral were linearly correlated, suggesting that cation exchange was the dominant mechanism of RT adsorption. The XRD examination of RT-adsorbed SAz-1 samples (unsaturated/saturated) after heating enabled the calculation of RT occupied area in the interlayer of the clay mineral. The results suggested that adsorbed-RT at low loading rate could lay on the internal surfaces in a free style to reduce the basal spacing (d001 value) of SAz-1. When the RT loading rate was increased, a limited surface space enforced more RT molecules to lay in a tilted style and caused interlayer swelling of SAz-1 increasing the d001 value. The trend of rising decomposition temperature of RT with increasing RT loading rates confirmed intercalation of RT molecules in SAz-1. Infrared spectral analysis revealed the participation of amide and furan groups of RT in binding between RT and SAz-1. Thus, this study indicated that SAz-1 is an efficient adsorbent to remove RT from contaminated water, and the chain-like molecular structure of RT could cause an irregular change in the basal spacing of swelling type clay minerals.

Shear transformation zones and serrated flow dynamics of metallic glasses revealed by nanoindentation

The relationship between shear transformation zones (STZs) and serrated flow dynamics of Co-, Fe-, Zr-, La- and Al-based metallic glasses (MGs) with different plasticity were analyzed by nanoindentation. The serrated flow dynamic behaviors were analyzed using statistical analysis of shear stress drops, Δτ. The STZ size was estimated via the nanoindentation creep method based on the cooperative shear model. Examination of two distinct types of serrated flow dynamics were performed. For MGs (e.g., Al- or Zr-based) where STZs could be easily activated or at low loading rates, shear stress exhibited a decreasing trend and followed a power-law distribution, which was an indicator of a self-organized critical (SOC) state in the dynamics. In contrast, a Gaussian law distribution was found for STZs in hard MGs (e.g., La-, Co-, and Fe-based) or at high loading rate. In the case of Gaussian distribution case, serrated flow dynamics were in a chaotic state, which indicated that STZ aggregation reduced the stresses required for plastic deformation.

Statistical analysis of effects of test conditions on compressive strength of cement solidified radioactive waste

Radioactive waste should be solidified before being disposed of in the repository to eliminate liquidity or dispersibility. Cement is a widely used solidifying media for radioactive waste, and cement solidified waste should satisfy the minimum compressive strength of the waste acceptance criteria of a radioactive repository. Although the compressive strength of waste should be measured by the test method provided by the waste acceptance criteria, the method differs depending on the operating repository of different countries. Considering the measured compressive strength changes depending on test conditions, the effect of test conditions should be analyzed to avoid overestimation or underestimation of the compressive strength during disposal. We selected test conditions such as the height-to-diameter ratio, loading rate, and porosity as the main factors affecting the compressive strength of cement solidified radioactive waste. Owing to the large variance in measured compressive strength, the effects of the test conditions were analyzed via statistical analyses using parametric and nonparametric methods. The results showed that the test condition of the lower loading rate, with a height-to-diameter ratio of two, reflected the actual cement content well, while the porosity showed no correlation. The compressive strength assessment method that reflects the large variance of strengths was suggested.

Experimental investigation of rock–shotcrete interface damage under dynamic splitting using digital image correlation and acoustic emission

AbstractInterface failure is the main type of rock–concrete structure failure, which affects the stability and safety. To study the interface crack propagation and damage characteristics, this article carried out the rock–shotcrete cube interface splitting test under different loading rates. The rock–shotcrete specimens are composed of four material types. Based on the nondestructive monitoring technology, digital image correlation and acoustic emission (AE) were used to monitor the whole process of splitting failure. The results indicate that, both peak load and critical displacement exhibit significant strain rate effects. The main stage of interfacial microcrack development is between 0.8 Pmax and Pmax. And the damage evolution of cracks is more sufficient and stable under low loading rate. The splitting damage at the rock–shotcrete interface shows phased characteristics. When the load is near the peak, the surge of the AE signal indicates that the damage is intensified.

Fracture of dual crosslink gels with permanent and transient crosslinks: Effect of the relaxation time of the transient crosslinks

We investigate the fracture properties of poly(acrylamide-co-1-vinylimidazole) dual crosslink hydrogels [P(AAm-co-VIm)-M2+ gels] containing a small fraction of covalent bonds and a majority of dynamic bonds based on metal coordination bonds (Ni2+ or Zn2+). Unlike a previous study on a different dual crosslink hydrogel system having slower dynamic bonds based on poly(vinylalcohol) and borate ions (PVA-Borax gels), the presence of these faster dynamic coordination bonds has two main effects: They significantly toughen the P(AAm-co-VIm)-M2+ gels even at high stretch rates, where the dynamic bonds should in principle behave as covalent bonds at the crack tip, and they toughen the gels at very low stretch rates, where the dynamic bonds are invisible during the loading stage. We propose two additional molecular mechanisms to rationalize this behavior of P(AAm-co-VIm)-M2+ gels: we hypothesize that fast exchanging dynamic bonds remain slow compared to the characteristic time of bond scission and are, therefore, able to share the load upon covalent bond scission even at low loading rates. We also argue of the existence of longer-lived clusters of dynamic bonds that introduce a stretch rate-dependent strain hardening in uniaxial tension and stabilize and increase the size of the dissipative zone at the crack tip, thereby introducing a strain-dependent dissipative mechanism.

Fracture characteristics of sustainable crumb rubber concrete under a wide range of loading rates

The dynamic mechanical properties of concrete materials significantly influences the safety of construction under impact loads. In this study, a comprehensive experiment on the crack straight-through flattened Brazilian disc specimens of crumb rubber concrete (CRC) is undertaken. Three specific experiments were performed to obtain the wide loading-rate ranges of fracture characteristics, i.e., the quasi-static test, drop-hammer impact test, and split Hopkinson pressure bar test. The measured and calculated results are also discussed. The results reveal that the fracture toughness and energy are both positively correlated with loading rate. Moreover, a transition loading rate (around 1 GPa × m1/2/s) exists between the high and low loading rates, and the enhancing effect of high loading rate on fracture toughness cannot be neglected. The analysis of the dynamic increased factor (DIF) on the fracture toughness (DIFk) and fracture energy (DIFg) of CRC shows that DIFk and DIFg are related to the rubber content. Furthermore, the analysis demonstrates that crumb rubber particles can enhance the crack resistance of concrete under dynamic loads. Accordingly, empirical models for the DIFk and DIFg of CRC are proposed based on the experimental data. In addition, the mechanisms by which the loading-rate affects the fracture characteristics were preliminarily identified by observing the failure modes under various loading-rate loads. This study is intended to help spread the application of crumb rubber in concrete materials.

Evaluation and sizing of proprietary sedimentation devices for decentralised stormwater treatment.

Suspended solids removal is a key performance measure for proprietary stormwater treatment devices. Various technologies are available, with manufacturers claiming hydrodynamic separators offer performance advantages. However, it is important to assess manufacturers' claims. Accordingly, this study seeks to compare the performance of proprietary devices, by applying dimensional analysis to third-party certification data and experimental data from uncertified devices, and to determine the accuracy of a single parameter estimation (Hazen or Péclet number) of removal efficiency. Statistical analysis indicates that device performance is well described by a single parameter estimation transitioning from Hazen (Nash-Sutcliffe coefficient = 0.81 and root mean square error = 5.1%) at low surface loading rates (SLR) in all technology types (high removal efficiency) to Péclet (Nash-Sutcliffe coefficient = 0.5 to 0.61 and root mean square error = 5.9% to 4.3%) at higher SLR (low removal efficiency) for hydrodynamic separators. This indicates that performance at low SLR is well explained by gravity separation in all technology types, whilst in hydrodynamic separators removal at high SLR is better explained by gravity separation plus advection. Consequently, when high (>80%) removal efficiency is required there is no performance advantage between technology types. However, when low (<50%) removal efficiency is required hydrodynamic separators offer a 33% increase in treatment area.

Localization of large intraplate earthquakes along faulted density-contrast boundaries: Insights from the 2017 Mw6.5 Botswana earthquake

The major controls on the localization of deep crustal intraplate earthquakes remain enigmatic due to their deep hypocentral depths and rarity of coseismic surface ruptures. Here, we investigate the 3-D crustal density structure of the 2017 Mw 6.5 Botswana earthquake epicentral region, a strong lower-crustal (∼24–29 km) event which is suspected to have reactivated a Precambrian structure via normal faulting. We perform a 3-D inversion of the gravity data using published geological constraints, then integrate the resulting density model with aftershock hypocenter distribution and use as constraints in a 3-D thermo-mechanical geodynamic model implemented in ASPECT. Our results reveal crustal blocks of density anomalies, with the aftershocks clustering along a prominent NW-trending, NE-dipping density contrast separating a high-density (>2708 kg/m3) footwall and lower-density (2670–2700 kg/m3) hanging wall blocks. Additionally, a secondary density contrast boundary in the hanging wall coincides with a splay of aftershock clusters at depth. Our observations suggest that the 2017 Mw6.5 Botswana earthquake nucleated near a fault intersection in the lower crust and is associated with brittle normal faulting reactivation of a long-lived basement fault that follows a prominent deep-reaching density contrast boundary. Further, as demonstrated by geodynamic modeling results, we argue that in regions of low tectonic loading rates, where stress perturbations are high enough, faulted crustal-scale density contrast boundaries are preferential concentrators of strain that may localize intraplate earthquakes.

Acoustic force spectroscopy reveals subtle differences in cellulose unbinding behavior of carbohydrate-binding modules

Protein adsorption to solid carbohydrate interfaces is critical to many biological processes, particularly in biomass deconstruction. To engineer more-efficient enzymes for biomass deconstruction into sugars, it is necessary to characterize the complex protein-carbohydrate interfacial interactions. A carbohydrate-binding module (CBM) is often associated with microbial surface-tethered cellulosomes or secreted cellulase enzymes to enhance substrate accessibility. However, it is not well known how CBMs recognize, bind, and dissociate from polysaccharides to facilitate efficient cellulolytic activity, due to the lack of mechanistic understanding and a suitable toolkit to study CBM-substrate interactions. Our work outlines a general approach to study the unbinding behavior of CBMs from polysaccharide surfaces using a highly multiplexed single-molecule force spectroscopy assay. Here, we apply acoustic force spectroscopy (AFS) to probe a Clostridium thermocellum cellulosomal scaffoldin protein (CBM3a) and measure its dissociation from nanocellulose surfaces at physiologically relevant, low force loading rates. An automated microfluidic setup and method for uniform deposition of insoluble polysaccharides on the AFS chip surfaces are demonstrated. The rupture forces of wild-type CBM3a, and its Y67A mutant, unbinding from nanocellulose surfaces suggests distinct multimodal CBM binding conformations, with structural mechanisms further explored using molecular dynamics simulations. Applying classical dynamic force spectroscopy theory, the single-molecule unbinding rate at zero force is extrapolated and found to agree with bulk equilibrium unbinding rates estimated independently using quartz crystal microbalance with dissipation monitoring. However, our results also highlight critical limitations of applying classical theory to explain the highly multivalent binding interactions for cellulose-CBM bond rupture forces exceeding 15 pN.

Application of mesenchymal stem cell-derived exosomes from different sources in intervertebral disc degeneration.

Intervertebral disc degeneration (IVDD) is a main cause of lower back pain, leading to psychological and economic burdens to patients. Physical therapy only delays pain in patients but cannot eliminate the cause of IVDD. Surgery is required when the patient cannot tolerate pain or has severe neurological symptoms. Although surgical resection of IVD or decompression of the laminae eliminates the diseased segment, it damages adjacent normal IVD. There is also a risk of re-protrusion after IVD removal. Cell therapy has played a crucial role in the development of regenerative medicine. Cell transplantation promotes regeneration of degenerative tissue. However, owing to the lack of vascular structure in IVD, sufficient nutrients cannot be provided for transplanted mesenchymal stem cells (MSCs). In addition, dead cells release harmful substances that aggravate IVDD. Extracellular vesicles (EVs) have been extensively studied as an emerging therapeutic approach. EVs generated by paracrine MSCs retain the potential of MSCs and serve as carriers to deliver their contents to target cells to regulate target cell activity. Owing to their double-layered membrane structure, EVs have a low immunogenicity and no immune rejection. Therefore, EVs are considered an emerging therapeutic modality in IVDD. However, they are limited by mass production and low loading rates. In this review, the structure of IVD and advantages of EVs are introduced, and the application of MSC-EVs in IVDD is discussed. The current limitations of EVs and future applications are described.