Low-grade Metamorphic Conditions Research Articles

Structural and metamorphic evolution of a subducted passive margin: insights from the Briançonnais nappes of the Western Alps (Ubaye–Maira valleys, France–Italy)

This contribution analyses the structural architecture and tectono-metamorphic evolution of Briançonnais units in the southern French-Italian Western Alps. The studied area extends from a virtually non-metamorphic area adjacent to the Helvetic-Dauphinois External Domain in the west to the Monviso-Queyras ocean-derived units in the east, where metamorphism increases up to eclogite-facies. Mapping at the scale 1:10.000 of a mountainous part of the Ubaye-Maira transect was performed, which portrays in detail the Briançonnais units over ~ 100 km2. The lithologies include meta-andesite, meta-siliciclastics, marbles, turbiditic calcschists and flysch whose age spans from Late Carboniferous to Eocene. Metamorphism is low-grade greenschist-facies in the west but reaches the blueschist-facies to the east. Structures related to four phases of deformation are identified. The first two generations of structures (D1–D2), related to the original top-to-the-west nappe stacking, are associated with conditions close to the peak of Alpine metamorphism. Previous tectonic surfaces are transposed by the dominant deformation structures (D3), developed under retrograde/decompression conditions. This D3 corresponds to a backfolding and back-thrusting event with a top-to-the-E transport. A fourth phase (D4) developed during late low-grade metamorphic conditions and deforms the previous surfaces by locally developing a crenulation cleavage, followed by brittle tectonics. An updated metamorphic map is presented, backed on published estimates and new thermometric data obtained by Raman Spectroscopy of Carbonaceous Material (RSCM). The TRSCM values range from ~ 295 °C to > 350 °C, moving from the most external Briançonnais unit to the internal Queyras “Schistes Lustrés” units. Suspected Upper Cretaceous palaeofaults have been documented, allowing us to group the classic Aiguille de Mary and Ceillac (sub-) units into a single tectonic unit, here referred to as Maurin unit. The palaeogeographical reconstruction of the evolution of the studied transect highlights the importance of the Marinet and Maurin axial units in the feeding of the Late Cretaceous-Eocene breccias deposited on the more internal Acceglio-type units.

CAI and microtextures of low-grade metamorphosed conodonts related to lithological and geological controls

Textures, microtextures, and CAI of early Permian conodonts recovered from three sections of the La Cueva Limestone and the Mina México Formation from Sonora, northwestern Mexico, are herein reported. Nearly uniform values of CAI 5 (a few at CAI 5.5) indicate low-grade metamorphic conditions in the study area. Metamorphic effects in conodonts are demonstrated by the development of the granular microtexture (recrystallization). It is documented herein that facies of reduced porosity and permeability due to compaction and cementation yielded the most recrystallized conodonts. Observations have revealed a correlation between the external cast microtexture and the micrite crystals found in mudstone to packstone lithologies, with no exceptional requirements for sorting, porosity, and permeability for its development. Furthermore, it has been noted that the development of small and large apatite crystal microtextures primarily occurs in highly porous and permeable lithologies, such as packstone and grainstone. Additionally, most of the sparry calcite cements appear to precipitate after the formation of the apatite overgrowths microtextures during intermediate and deep burial diagenesis. These results on conodont microtextures are useful in the recognition of regional tectonothermal events.

Ti-Bearing Minerals: from the Ocean Floor to Subduction and Back

Abstract Rutile, titanite, and ilmenite are the most common Ti-bearing minerals in metamorphic rocks. Experimental constraints have shown that titanite is stable at low-grade metamorphic conditions, rutile at high pressure (HP), and ilmenite at high temperature, low pressure (HT-LP) conditions. Yet, petrological evidence suggests that titanite can also be stable at low temperature, HP (LT-HP). This implies that both titanite and rutile can be used to develop proxies to track HP metamorphism, which can have interesting applications. In this study, we have investigated the natural occurrence and chemistry of Ti-bearing minerals in gabbroic rocks and basalts that record different degrees of metamorphism, including LP amphibole-bearing gabbros from the ocean floor (Mid-Atlantic and Indian ridge IODP LEGs) and from an obducted ophiolite (Chenaillet) and HP Alpine metagabbros and metabasalts, including blueschist and eclogite facies rocks from the Western Alps and Corsica. We have performed detailed petrography, Raman spectroscopy and analyzed major and trace elements mineral chemistry using EPMA and LA-ICPMS. We found that rutile is stable at low pressure (< 2 kbar) in ocean-floor amphibole-bearing gabbros, lower than experimental constraints had previously suggested. Rutile is also found in eclogitic metagabbros from the Western Alps and can be chemically distinguished from LP rutile. Blueschist metagabbros from the Western Alps and eclogitic metabasalts from Corsica have titanite stable instead of rutile. While the titanite to rutile transition is pressure- and temperature-dependent, we demonstrate how small variations in bulk-rock Ti/Ca and Ca/Al values within the NCKFMASHTO chemical system may shift their stabilities. High-pressure titanite from these metamafic rocks exhibits La depletion and low La/SmN values in comparison to titanite from amphibolite-facies mafic rocks. La/SmN or Nb together with Yb and V can be used to distinguish HP titanite from titanite formed under other P–T settings. These new systematics can be useful in studies using detrital Ti-bearing minerals to probe the HP metamorphic record through time.

Polyorogenic structure of the San Rafael Block, Mendoza, Argentina: New data for the interpretation of the Chanic Orogen

The Paleozoic pre-Carboniferous rocks of the San Rafael Block, located to the east of the Los Reyunos Gondwanan Thrust, show Chanic structures (Late Devonian–early Carboniferous) with east vergence, which were generated in the absence of metamorphism. This Paleozoic succession is unconformably located on the basement of Cuyania. The rocks, located to the west of the Los Reyunos Thrust, were deformed by two fold episodes, the first and main (D1) west verging, developed under low to very low-grade metamorphic conditions, and the second (D2) east verging and mainly developed near Los Reyunos Reservoir. Therefore, the Los Reyunos Thrust must be considered a reactivation of a Chanic structure during the Gondwanan Orogeny (late Carboniferous–early Permian). The ancient Chanic thrust could be responsible for the overlay of the hinterland of the western branch of the Chanic Orogen on the foreland of its eastern branch, at the end of the collision between the Cuyania and Chilenia subplates. The results of this work have been related to those of nearby areas located to the north and west, which has allowed the elaboration of a model that explains the characteristics of the Chanic Orogen in this area. During the Carboniferous, the Los Reyunos Thrust was reactivated as a normal fault, facilitating the sedimentation of carboniferous rocks thousands of meters thick in its hanging wall and later, during the Gondwanan deformation, it underwent a tectonic inversion. During the Andean cycle, the Permian–Triassic beds of the Choiyoi Group were deposited in relation to NW–SE trending normal faults, giving rise to rollover structures. Finally, during the Cenozoic, Andean compression gave rise to the formation of an open antiform, in whose core is the Mesoproterozoic–Paleozoic basement of the San Rafael Block.

The poly-orogenic Paleozoic rocks of Cuesta del Rahue area (Precordillera Neuquina, Argentina) and their significance in marking the southern end of the Chanic orogenic belt

In the Cuesta del Rahue area, located in the Precordillera Neuquina (northern Argentine Patagonia), late Paleozoic turbiditic rocks with maximum depositional age of ca. 389 Ma were affected by three orogenic events. The oldest orogenic event is the Chanic orogeny (Late Devonian–early Carboniferous) that is characterized by folds with NNE vergence. This deformation is developed in low-grade to very low-grade metamorphic conditions, which allowed the development of a slaty/rough cleavage. The main Chanic structure is an asymmetric fold with a large normal limb tilted by the more recent orogenic events. The characteristics of the deformation and metamorphism allows us to assign the Cuesta del Rahue outcrop to the external hinterland of the western wedge of the Chanic orogen. Early to late Carboniferous igneous rocks intruded the Paleozoic rocks of the Cuesta del Rahue area and crosscut the Chanic structures. After the Chanic orogeny, the Gondwanan orogeny (late Carboniferous–early Permian) took place. The main structures of the Gondwanan orogen are thrust and related folds with SSW vergence that fold the large Chanic normal limb and also affect Carboniferous igneous rocks. The Gondwanan deformation was developed under non-metamorphic conditions, and Permian igneous rocks crosscut the Gondwanan structures. Mesozoic regional extension related to the beginning of the Andean cycle and the formation of the Neuquén Basin gave rise to normal faults and small-scale extensional folds. Finally, the Andean orogeny, developed during the Cenozoic in the study area, also affected the Cuesta del Rahue Paleozoic rocks, with the development of compressional structures related to the Aluminé thrust and fold belt. The main Andean structure in the study area is the NW–SE Rahue fault, which links the E–W Piedra Santa tear fault with the NNE–SSW Catán Lil reverse fault. The Rahue fault has a SW tectonic transport direction. It uplifted the Cuesta del Rahue area and placed Paleozoic rocks on top of Mesozoic and Cenozoic rocks. The Piedra Santa fault partially reactivated the Huincul right-lateral and left-lateral Chanic transverse faults that define the southern end of the doubly vergent Chanic orogen, giving rise to the current Huincul lineament.

Structural Analysis and Paleostress Evolution in the Imiter Silver Mining Region, Eastern Anti Atlas, Morocco: Implications for Mineral Exploration

Development and concentration of many ore deposits at the regional and district scales closely depend on structural geology, especially in polydeformed basements. The superposition of many deformation periods highlights the complexity of the structural context and expected potential location of mineralization zones. The formation and concentration of hydrothermal ore deposits is highly dependent on structural controls. On the NE flank of the Saghro massif (Eastern Anti-Atlas, Morocco), the Imiter silver mining region has been affected by multiple tectonic events since the Precambrian and throughout the Phanerozoic. In this investigation, a structural analysis of the different geological units revealed multi-stage deformation, beginning with the late Pan-African-Cadomian event, and ending with the last Cenozoic exhumation of the area. At least eight tectonic regimes have been identified. The Imiter basement, formed by the Cryogenian-early Ediacaran “flysch-like” Saghro Group, has been folded in low-grade metamorphic conditions, followed by an ENE-WSW brittle compressive event. These deformations occurred before to the early Ediacaran during the compressional and/or transpressional late Pan-African-Cadomian events (600–580 Ma). The unconformably overlaying deposition of the late Ediacaran Ouarzazate Group takes place in a WNW-ESE extensional setting and then involved in a NNW-SSE compressional event that occurred concurrently with a regional exhumation and erosion stages. A similar extensional event appears to have controlled the middle Cambrian sedimentation, the oldest Paleozoic deposits in this area. During the late Carboniferous, Variscan shortening was recorded by NW-SE transpressional deformation responsible for combined dextral strike-slip and southward thrusts. The Imiter silver mining region is part of the Moroccan Sub-Meseta Zone along with Paleozoic inliers of the Skoura and Tamlelt on the southern side of the High Atlas. The Mesozoic evolution began with the Late Triassic NNW-SSW transtensional tectonic regime with a northeast trending CAMP (Central Atlantic Magmatic Province) dyke during the Pangea breakup. Ultimately, the Imiter silver mining region experienced NNW-SSE Atlasic shortening during the uplift of the adjacent High Atlas. Over time, the direction of implemented tectonic stress and its effect on various geological units can elucidate the relationship between tectonism and hydrothermal silver mineralization in the Imiter region. In conclusion, structural analysis and investigation of paleostress development can be one of the most important factors for successful exploration plan and resource recovery in the Imiter region. An analysis of geological structures in determining feasible mineralization zones is crucial for future safe mining operation in the study area and can be extrapolated to other ore mining regions.

Geology of the contact area between the Internal and External Nappe Zone of the Sardinian Variscan Belt (Italy): new insights on the complex polyphase deformation occurring in the hinterland-foreland transition zone of collisional belts

ABSTRACT This study aims to decipher the structural evolution of a sector of the Nappe Zone in the Sardinian Variscan Belt. We investigated the Barbagia Thrust between the Meana Sardo Unit (belonging to the External Nappe Zone) in the footwall and the Barbagia Unit (belonging to the Internal Nappe Zone) in the hanging wall. Combining the geological survey with meso- and microstructural analysis, we realized a 1:10.000 scale geological map highlighting the polyphasic evolution developed under low-grade metamorphic conditions during the Variscan orogeny. Both units preserve (i) an early phase generally observed far from the tectonic contact and mainly in the Meana Sardo Unit (D1), (ii) a syn-nappe ductile deformation linked to the Barbagia Thrust activity and a top-to-the S-SW sense of shear (D2) and (iii) a large-scale nappe refolding (D3). A late extensional stage (D4), with the development of collapse folds, marks the end of the orogenic cycle.

1.80–1.75 Ga granite suites in the west Troms Basement Complex, northern Norway: Palaeoproterozoic magma emplacement during advancing accretionary orogeny, from field observations

The Ersfjord Granite is part of a suite of c.1.80–1.75 Ga syeno-granites in the West Troms Basement Complex, northern Norway, presumed to belong to the Transscandinavian Igneous Belt (TIB-1) in the Fennoscandian Shield. Previous data suggest the granite formed post-collisional and ascended as a batholith pluton from a source generated by delamination of mafic-intermediate lower crust. We argue that the Ersfjord Granite was emplaced initially (c. 1.80 Ga) as multiple tabular sills in an extensional setting, then as successive melt injections (c. 1.78–1.75 Ga) in an evolving Andean/Cordilleran type accretionary orogen at the waning stages of the Svecofennian orogen. Field observations indicate melt ascent initiated as successive sills (EG-I) into well-foliated Meso/Neoarchaean TTG gneisses. Some sills preserved a magmatic layering, others injected and assimilated the host rock gneisses leaving pendants of mafic gneiss/migmatite residuum in between the granite sills. The first tectonic patches of melts (EG-II) ascended into the middle/upper crust along regional shear zones and injected into ductile imbricate thrust stacks (D1 event) during NE-SW directed crustal shortening and medium grade P-T conditions, using the sills and ancestor migmatite pendants as melt pathways. Then the tabular EG-I and II granite sheets and adjacent gneisses were coaxially folded by upright macro-folds (D2 event) and steep, granitic pegmatite dyke swarms (EG-III) intruded parallel to the fold axial surface and in related D2 thrusts, at low grade metamorphic conditions. The final melt emplacement (D3 event) included granite pegmatite dykes and sills (EG-IV) along subvertical D3 fold limbs and steep strike-slip shear zones. Our provisional extension, and successive advancing accretionary orogenic emplacement model for the Ersfjord Granite may explain ascent of many other TIB-1 magmas in the Fennoscandian Shield.

Tracing wedge-internal deformation by means of strontium isotope systematics of vein carbonates

AbstractRadiogenic strontium isotopes (87Sr/86Sr) of vein carbonates play a central role in the tectonometamorphic study of fold-and-thrust belts and accretionary wedges and have been used to document fluid sources and fluxes, for example, along major fault zones. In addition, the 87Sr/86Sr ratios of vein carbonates can trace the diagenetic to metamorphic evolution of pore fluids in accreted sediments. Here we present 87Sr/86Sr ratios of vein carbonates from the Infrahelvetic flysch units of the central European Alps (Glarus Alps, Switzerland), which were accreted to the North Alpine fold-and-thrust belt during the early stages of continental collision. We show that the vein carbonates trace the Sr isotopic evolution of pore fluids from an initial seawater-like signature towards the Sr isotopic composition of the host rock with increasing metamorphic grade. This relationship reflects the progressive equilibration of the pore fluid with the host rock and allows us to constrain the diagenetic to low-grade metamorphic conditions of deformation events, including bedding-parallel shearing, imbricate thrusting, folding, cleavage development, tectonic mélange formation and extension. The strontium isotope systematics of vein carbonates provides new insights into the prograde to early retrograde tectonic evolution of the Alpine fold-and-thrust belt and helps to understand the relative timing of deformation events.

Deciphering large-scale superposed fold systems at shallow crustal levels in collision zones: insights from the Marguareis Massif (southwestern Alps)

ABSTRACT We present and discuss the results of a field-based approach including accurate geological mapping and micro- to map-scale structural analysis to highlight the finite strain pattern recorded in Marguareis Unit, a massif deformed at shallow crustal levels at the boundary between Maritime and Ligurian Alps. We describe superposed tectonic structures developed under low-grade metamorphic conditions during the Alpine collision and nowadays exceptionally well recorded in the area of interest. We demonstrate that the structural frame of the Marguareis Unit results from superposition of fourfold systems, later segmented, but without significant displacements, by brittle faults.

The low-grade basement at Península La Carmela, Chilean Patagonia: new data for unraveling the pre-Permian basin nature of the Eastern Andean Metamorphic Complex

The Eastern Andean Metamorphic Complex at Península La Carmela (48°50’S) consists of quartz-rich metaturbiditic sequences with tectonic slices of pillow metabasalt bodies deformed under low-grade metamorphic conditions. Previous and new detrital zircon U–Pb geochronological data from metasandstones indicate a preferred early Carboniferous maximum depositional age of the protolith, interpreted from the youngest single zircon grains of several metasedimentary rocks in the area. The wide spectrum of zircon ages from Península La Carmela, includes Neoproterozoic-early Paleozoic components and subordinate ancient zircon grains (> 2200 Ma). They were sourced from cratonic regions and/or reworked material from older metasedimentary successions and plutonic belts in southwestern Gondwana (e.g., North Patagonian and Deseado massifs or from the Tierra del Fuego Igneous and Metamorphic Complex). The pillow metabasalts have geochemical affinities of normal mid-oceanic ridge basalts and island-arc tholeiites with Nb–Ta negative anomalies, derived from a depleted mantle source (εNdt of + 6 and + 7.5). In consideration that pillow metabasalts with ocean island basalt affinities are reported, we propose that metaturbiditic successions and metabasalts were tectonically juxtaposed within a pre-Permian accretionary wedge of an active continental margin, after the development of island arcs and back-arc marginal basins.

Strain localization during burial and exhumation of the continental upper crust: A case study from the Northern Sporades (Pelagonian thrust sheet, Greece)

Abstract Extension is a key process controlling the post-orogenic exhumation of metamorphic rocks in subduction and collision zones. Previous studies have largely focused on the mechanics of localized core-complex style post-orogenic extension and the large-scale effects of various internal (e.g. rheology) and external (e.g. plate motions) parameters on the mode of extension. However, many regions on earth underwent rock exhumation during post-orogenic extension, which is characterized by distributed rather than localized deformation. We explore conditions of distributed deformation as illustrated by the Pelagonian unit in the Aegean subduction system. In particular, we explore the influence of structural inheritance related to the pre-extension shortening and mechanical stratigraphy on the localization of extension on the scale of the upper crust through detailed structural analysis on the islands of Skiathos and Skopelos. Additionally, the time frame of deformation has been established by 40Ar/39Ar dating of key shear zones. Shortening on the islands predominantly took place by ductile top-SW thrusting under low-grade metamorphic conditions, localized in weak calcite marble layers within the Upper Cretaceous and Upper Triassic carbonates at ~55 Ma. We show that the presence of shallow decoupling levels in the upper crust resulted in the formation of thin (several 100 m thick) thrust sheets that are defined for the first time on Skiathos. The Early Paleogene accretion of the Pelagonian upper crust to the upper plate (Eurasia/Rhodopia) was followed by the extensional inversion of the nappe stack. Extension was accommodated by opposite-sense, generally top-NE, ductile to brittle shearing, which localized at inherited heterogeneities such as reverse-sense shear zones and stratigraphic contacts at around 35 Ma, as suggested by our 40Ar/39Ar age spectra. The dense network of such northerly-dipping, inherited weakness zones resulted in a highly distributed pattern of extensional deformation dominated by layer-parallel shearing. We argue that the distribution of crustal heterogeneities substantially influences the style of post-orogenic extension.

Tectonic Evolution of the Eastern Moroccan Meseta: From Late Devonian Forearc Sedimentation to Early Carboniferous Collision of an Avalonian Promontory

AbstractThe deformed Paleozoic succession of the Eastern Moroccan Meseta crops out in relatively small and isolated inliers surrounded by Mesozoic and Cenozoic rocks. Two of the largest inliers (Mekkam and Debdou) are characterized by a monotonous succession of slates and greywackes affected by polyphasic folding that occurred at low‐ to very low grade metamorphic conditions. New U‐Pb ages on detrital zircon grains from the Debdou‐Mekkam metasediments constrain the maximal depositional age as Late Devonian, interpreted to be close to the true sedimentation age. Furthermore, the εHf values of the Devonian detrital zircons, together with the presence of a series of scattered zircon grains with ages between c. 0.9 and c. 1.9 Ga, suggest provenance from a subduction‐related magmatic arc located on the Avalonian margin. The Debdou‐Mekkam massif is characterized by an Early Carboniferous first deformational event (D1), which gave way to a pervasive cleavage (S1) associated with plurikilometric‐scale, tight to isoclinal, overturned to recumbent folds. Later events (Dc) occurred at Late Carboniferous time and generated variably developed crenulation cleavages (Sc) associated with variously oriented metric‐ to kilometric‐scale folds, which complicate the pattern of both D1 intersection lineations (L1) and axial traces. The restoration of this pronounced curved pattern yields originally SW‐NE‐oriented D1 fold axes with regional SE‐vergence. This important Early Carboniferous shortening and SE‐directed tectonic transport can be explained by closure of the Rheic Ocean and the first phases of the collision between the northern passive margin of Gondwana and an Avalonian promontory.

In situ Th/Pb dating of monazite in fibrous veins: Direct dating of veins and deformation in the shallow upper crust of the Mexican Orogen

Few methods exist for directly dating orogenic events in the upper crust. Here we report in-situ dates from (∼10 μm diameter) monazite grown in quartz-calcite fibrous veins, which precipitated at very low-grade metamorphic conditions (about 250 °C) in volcaniclastic and calcareous rocks of the Early Cretaceous Trancas Fm. in the Zimapán Basin, Central Mexico. Our integrated study includes regional and local structural and kinematic analysis of vein and folds, detailed textural and mineralogical characterization of vein-bearing minerals, and texturally-controlled Th/Pb geochronologic analysis of monazite by LA-MC-ICPMS. We find that monazite in the veins preferentially crystallized at the interface between vein-forming calcite and quartz fibers, as well as at the vein-host rock interface. Monazite ages range from 154 to 68 Ma, with the youngest sub-population yielding a weighted mean age of 76.8 ± 0.8 Ma, coincident with the age of basin-wide folding as earlier constrained by Ar/Ar illite dating. The oldest monazite ages coincide with the timing of deposition of the volcaniclastic host-rock. Given that veins are ubiquitous in shallow crustal rocks, this approach to dating of veins with enclosed monazite has great potential to improve the constraints on temporal resolution of fluid-rock interaction during of deformation.

Discriminating Tectonic and Magmatic Fabrics in the Remal Granite Gneiss: Implications for Terrane Amalgamation Processes in Southeastern Singhbhum, India

The Remal granite gneiss body in the southeastern part of the Singhbhum Craton, near its contact with the Rengali Province, preserves two orthogonal penetrative foliations. The subhorizontal foliation defines cross and trough bedding structures, and is characterized by (i) systematic grain-size variation between the layers, (ii) the presence of feldspar laths and (iii) graphic intergrowth textures, confirming that it is primary and of igneous origin (Sign). Sign has a non-planar geometry and shows a spread in orientations, while a later foliation of tectonic origin is defined by alternating biotite-rich and biotite poor bands that define a consistently oriented gneissic foliation (S1). S1 gneissic layering is associated with the alignment of biotite flakes and myrmekite formation, and operated under low grade metamorphic conditions. S1 shows a remarkable similarity in orientation with the shear fabric along the amalgamation front of the Rengali Province with the Eastern Ghats Province further to the south, indicating that strain related to this regional strike-slip event can be identified even in southeastern Singhbhum.

Radiolarian and U–Pb zircon dating of Late Cretaceous and Paleogene Shimanto accretionary complexes, Southwest Japan: Temporal variations in provenance and offset across an out-of-sequence thrust

In this study, we describe radiolarian fossils, analyze sandstone petrography and geochemistry, and perform detrital zircon U–Pb dating on the Late Cretaceous and Paleogene Shimanto accretionary complexes. These data are used to constrain temporal variations in provenance, which are related to volcanic arc activity. We also determine the behavior of the Aki Tectonic Line, which represents an out-of-sequence thrust. Based on lithology and radiolarian assemblages, we subdivide the Late Cretaceous to early Paleocene Mugi Unit into the Mg1, Mg2, and Mg 3 subunits, and the Eocene Naharigawa Unit into the Nh1 and Nh2 subunits. Detrital zircon U–Pb ages indicate that sandstones of the Mugi Unit were sourced mainly from Late Cretaceous to Paleocene igneous rocks. Nh1 sandstone records a single peak age in the Late Cretaceous, whereas Nh2 sandstone preserves multiple peaks from the pre-Jurassic to early Paleocene. The Naharigawa Unit lacks syn-depositional detrital zircons; however, felsic tuff within Nh1 records an age of 48.7 Ma, which is consistent with radiolarian ages. The Nh1 and Nh2 sandstones contain slightly higher Ba and Rb concentrations than those of the Mugi Unit, suggesting that basement had been uplifted and eroded in the source region, prior to deposition. We conclude that temporal variations in sandstone composition within the Late Cretaceous to early Paleocene Shimanto accretionary complex resulted from tectonic events that occurred in response to syn-depositional igneous activity. We infer that the evolution of the Eocene Shimanto accretionary complex was influenced by uplift and erosion of pre-Jurassic basement. Late Cretaceous radiolarians were identified in subunit Mg3 that forms the footwall of the Aki Tectonic Line, which was previously interpreted as a boundary fault between the Late Cretaceous and Paleogene Shimanto accretionary complexes. The Aki Tectonic Line is re-interpreted as an out-of-sequence thrust (OST) that was active under low-grade metamorphic conditions. We classify several OSTs close to the Late Cretaceous and Paleogene Shimanto accretionary complexes, based on contrasts in metamorphic grades across the faults. Within the study area, the Aki Tectonic Line is classified as a Type-2 OST, indicating that it developed within the Cretaceous Shimanto accretionary complex at temperatures of 250–270 °C.

MnO|SiO2,Al2O3,FeO,MgO] balanced log-ratio in chlorites: a tool for chemo-stratigraphic mapping and proxy for the depositional environment

ABSTRACTThe [MnO|SiO2,Al2O3,FeO,MgO] balanced ratio (i.e. the isometric log-ratio of the MnO concentration relative to the concentration of SiO2, Al2O3, FeO and MgO) of chlorite and of whole-rock composition is an effective discriminant between Mesozoic stratigraphic formations in the Magallanes Basin (Chile). The MnO content in chlorite is only controlled by the host rock chemistry and is dependent on the geological environment. The MnO content in chlorite remains unchanged at low-grade metamorphic conditions. Single-grain chlorite analysis (n = 1042, electron microprobe) and whole-rock analysis (n = 40, X-ray fluorescence) were used to discriminate stratigraphic formations and to decipher differences in the depositional environment in the Magallanes Basin. The samples are from one Upper Jurassic and three Cretaceous sedimentary units that were affected either by low-grade regional metamorphism or by Miocene contact metamorphism. The highest [MnO|SiO2,Al2O3,FeO,MgO] values are recorded in the upper Zapata Formation. The Punta Barrosa, Cerro Toro and Tobífera Formations show slightly lower [MnO|SiO2,Al2O3,FeO,MgO] values. Elevated [MnO|SiO2,Al2O3,FeO,MgO] values at the transition between Zapata and Punta Barrosa Formations record an oxygenated shallow marine environment that can be linked to the closure of the Rocas Verdes Basin and the onset of fold-and-thrust belt formation. Decreasing [MnO|SiO2,Al2O3,FeO,MgO] values from the Punta Barrosa towards the Cerro Toro Formation indicate gradually increasing water depths during the Upper Cretaceous that correlate well with the global sea level.

Detrital U-Pb and 40Ar/39Ar geochronology of the Connecticut Valley-Gaspé trough, southern Quebec and northern Vermont – Transitional tectonism from Salinic to Acadian orogenic cycles

Detrital ages constrain the timing of deposition, along-strike paleo-geographic variations and the nature of erosional sources in sedimentary basins and can be used to constrain the transition between orogenic cycles. The Connecticut Valley-Gaspé (CVG) trough is a major Upper Ordovician-to-Devonian sedimentary basin that extends for >1000 km in the Northern Appalachians and was deposited during the Salinic and Acadian orogeneses. In Quebec and northern New England, the CVG trough is host to the Gaspé Belt and correlative units of the Connecticut Valley sequence (CVS). In southern Quebec, the Gaspé belt sedimentation occurred during late Silurian-to-Early Devonian crustal extension related to the Salinic orogeny. This study reports detrital U/Pb zircon and 40Ar/39Ar muscovite ages from the Ayers Cliff and Compton formations, Quebec and the correlatives Waits River and Gile Mountain formations, Vermont. Detrital zircon ages suggest that proximal early Silurian-to-Devonian erosional sources were submerged during sedimentation, which is consistent with an extension-related marine transgression marked by the Ayers Cliff and Waits River formations. The lack of Ediacaran zircons in the Ayers Cliff Formation contrasts with the Waits River Formation, suggesting that the nature of erosional sources varied during deposition of the lowermost part of the basin. Stratigraphically higher Compton and Gile Mountain formations have similar detrital zircon provenance suggesting homogenization of detrital contributions. This is attributed to the encroachment of Avalonian terranes and ongoing erosion, probably during uplift of Laurentia and Avalonian terranes leading to foreland basin development and deposition of the uppermost part of the Compton and Gile Mountain formations which yielded youngest mean ages of ca. 413 Ma and ca. 401 Ma, respectively. Low-grade metamorphic conditions allow the preservation of detrital 40Ar/39Ar muscovite ages which highlight the contribution of erosional sources that experienced Grenvillian, Taconian and Salinic metamorphism.

Near-Infrared Spectroscopy of Hydrothermal versus Low-Grade Metamorphic Chlorites

Although the composition of chlorite group minerals represents a known proxy for conditions in various geological environments, few comparative studies of chlorites from different geological environments have been carried out. In this study, we compare chlorites from a hydrothermal system with those formed under low-grade metamorphic conditions. Both sets of samples were collected from the Pilbara Craton, Western Australia. Near-infrared (NIR) spectroscopy was used to determine if spectral differences record compositional differences between chlorites from the two geological environments. The spectra showed a significant difference in the Mg-OH absorption wavelength, near 2350 nm, with the hydrothermal group showing longer absorption wavelengths than the metamorphic one. A comparison of the spectral data with geochemical analyses showed a relation between the absorption wavelength and the magnesium-to-iron ratio (magnesium number) of chlorite, as well as the bulk rock composition. Metamorphic rocks have a higher magnesium-to-iron ratio than the hydrothermal ones, predominantly explained by differences in the degree of metasomatism. In the hydrothermal system, mass transfer changes the bulk rock composition while for the metamorphic samples the original bulk chemistry determines the current composition of the rock.

40Ar/39Ar chronological constraints on syn- and post-Variscan biotite porphyroblasts from the Iberian Chains, NE Spain

We perform a multidisciplinary study of biotite porphyroblasts and veinlet infills hosted in Cambrian strata of the hanging walls from the NW-SE-trending Datos, Jarque and Daroca thrusts (Iberian Chains). Stratigraphic and microstructural crosscutting features indicate that a biotite isograd runs parallel to the southeastern transects of the three thrusts. The metamorphic grade reached in the southeastern edge of the Iberian Chains is clearly distinct from both the Cadomian epizonal metamorphism, exclusively recorded in the Ediacaran–basal Cambrian Paracuellos Group, and the Variscan anchizone metamorphism recorded throughout Cambrian–Devonian strata. During post–Variscan negative inversion tectonics, renewed K-metasomatism along the same thrusts led to crystallisation of geochemically similar biotites in parallel fissures and veins. 40Ar/39Ar ages are (i) latest Westphalian–to–Guadalupian (285.82 ± 23.75 Ma) for metamorphic biotite porphyroblasts affected by diffusion loss of Ar, including the Carboniferous–Permian transition within error; and (ii) Early Triassic (246.87 ± 5.36 Ma) for biotite occlusion in post–Variscan veinlets. The Iberian Chains represent the southeastern prolongation of the Cantabrian and West Asturian-Leonese zones. The latter displays a uniform eastward decrease in metamorphic grade, whereas the Iberian Chains exhibits a heterogeneous distribution of low-grade metamorphic conditions (chlorite zone). The local presence of the biotite isograd is linked to the higher tectonic gradients associated with the Daroca, Jarque and Datos thrusts, quite similar to the metamorphic isogrades recognized both in the northeastern edge of the Demanda Massif and the Novellana-Pola de Allande-Degana Belt of the West Asturian-Leonese Zone. This distribution allows the identification of a broad NW-SE belt of biotite-in isograd-related synkinematic metamorphism, following the western contact of the Narcea Antiform, the Anguiano Thrust and the southeastern edges of the Daroca, Jarque and Datos Thrusts in the Iberian Chains. Based on Variscan structural style and metamorphic grades, the Datos Thrust links with the contact that separates the Cantabrian and West Asturian-Leonese zones of the Iberian Massif.