Low Expansion Research Articles

Green synthesis of SiOx/C-TiO2 with continuous conductive network towards enhancing lithium storage performance

High-capacity SiOx anodes face significant challenges in practical applications due to their low conductivity and high expansion rate. The combination of nanoengineering and carbon capping processes has been proven to address these issues. However, most carbon capping techniques cannot ensure uniform capping and fail to form a continuous conductive phase between active materials. This work proposes a green (solvent-free) and facile method for constructing SiOx/C-TiO2 (SCT@CN) nanocomposites by creating a three-dimensional carbon conductive network from gelatin-derived carbon and doping with titanium dioxide nanoparticles (TiO2 NPs). Comparison of TiO2 NPs with varying doping levels reveals that the synergistic effect between the conductive carbon network and TiO2 NPs enhances both the structural stability of batteries during charge/discharge cycles and the efficiency of active material utilization and lithium-ion diffusion. With the increase of TiO2 NPs, the capacity retention and ICE of the electrode improved, while the initial discharge capacity decreased. Notably, the SCT-2@CN electrode with 10 wt% TiO2 NPs exhibits the best electrochemical performance, with an initial coulombic efficiency (ICE) of 73.2 %. After 700 cycles at a high current density of 2.0 A g−1, it maintained a capacity of 503 mAh g−1, with a capacity retention rate of 81.86 %. The optimized carbon capping process and introduction of novel elements have the potential to enhance a range of energy storage materials.

Advancing Water Security and Agricultural Productivity: A Case Study of Transboundary Cooperation Opportunities in the Kabul River Basin

The Kabul River Basin (KRB) is witnessing frequent flood and drought events that influence food production and distribution. The KRB is one of the world’s poorest regions regarding food security. Food security issues in the KRB include shifts in short-term climate cycles with significant river flow variations that result in inadequate water distribution. Due to the lack of hydro-infrastructure, low irrigation efficiency, and continuing wars, the Afghanistan portion of the KRB has experienced low agricultural land expansion opportunities for food production. This research assesses the relationship between flood mitigation, flow balances, and food production and, cumulatively, assesses the social and economic well-being of the population of the KRB. SWAT modeling and climate change (CCSM4) implications are utilized to assess how these relationships impact the social and economic well-being of the population in the KRB. The intricacies of transboundary exchange and cooperation indicate that the conservation of ~38% of the water volume would nearly double the low flows in the dry season and result in the retention of ~2B m3/y of water for agricultural developmental use. Results show that the peak flood flow routing in reservoirs on the Afghanistan side of the KRB would have a substantial positive impact on agricultural products and, therefore, food security. Water volume conservation has the potential to provide ~44% more arable land with water, allowing a ~51% increase in crop yield, provided that improved irrigation efficiency techniques are utilized.

Hybrid 2D/3D carbon framework confined Si with optimized reaction kinetics for highly stable Li-Ion storage

Three-dimensional (3D) conductive skeletons can optimize electron/Li-ion migration kinetics and alleviate stress accumulation for silicon (Si)-based electrodes. In this study, the modified carbon nanotubes (MCNs) are used as a stress-buffering and high-speed conducting framework, and a hierarchical structure of 3D MCNs interspersed with flour-derived 2D N-doped C layer is designed for Si anode via molecular self-assembly and in-situ carbonization strategies. Experimental and theoretical calculations show that the charge redistribution occurred in the fabricated SiOx and N-doped C interfaces, which induced an electric field response and increased the interfacial electron/Li-ion transfer rate. Multiphysics simulations show that the 2D/3D hierarchical structures of carbon can optimize the physicochemical properties, such as a favorable local electronic environment, flexible stress dissipation mechanisms and good thermal stability. The prepared electrode with 77.1 wt% Si@SiOx shows a low volume expansion rate of 23 % and has an excellent Li-ion storage capability (972.1 mAh g−1 at 4000 mA g−1). Moreover, the structural stability of fabricated Si-based electrodes is enhanced, achieving 0.04 % per cycle capacity decay for 500 cycles at 2000 mA g−1. Such integrating the 2D/3D carbon framework to manipulate Si interfacial properties provides fundamental research for other electrodes plagued by significant volume expansion.

Carbonaceous C@FeS Flow Electrode for Electrochemcal Capacitive Deionization Application

FeS has attracted much attention in the field of capacitive deionisation of flow electrodes due to its high theoretical specific capacity and wide range of sources. However, it usually exhibits frustrating performance due to its inherent low conductivity and volume expansion during charging and discharging. Herein, we successfully prepared calcium alginate-coated FeS carbon spheres (C@FeS) with a hollow nanosphere structure by a combination of sol-gel and solid-phase sintering using sodium alginate as a carbon source. This unique hollow structure provides enough space for the expansion of FeS and enhances the stability of the sulfide; meanwhile, the internal “surface-line-surface” structure not only facilitates the migration and charge transfer of ions inside, but also provides more active electrosorption sites. When assembled as the flow electrode of the flow electrode capacitive deionisation (FCDI) system, the desalination capacity of the electrode was improved from 25.32 mg g−1 to 53.12 mg g−1. Therefore, the C@FeS composite is expected to provide a new candidate electrode material for the FCDI system, which will make the future desalination process more cost-effective and efficient.

Performance analysis of air-cooled turbine based on source terms method

Abstract Investigating turbine blade cooling and blade tip clearance leakage is crucial for reducing turbine losses and enhancing overall engine performance. Therefore, this paper uses the E3 two-stage high-pressure turbine as a case and employs the source term method to model the film cooling configuration, validating its efficacy and examining the performance parameters and flow field characteristics of air-cooled turbines under varying blade tip clearances. The outcomes demonstrate that the source term approach accurately forecasts the comprehensive performance parameters of air-cooled turbines, with blade tip clearance height predominantly impacting turbine performance in high-velocity regions. For small blade tip clearance, air-cooled turbines exhibit diminished efficiency with a decreasing expansion ratio in high-velocity regions, but they demonstrate an inverse behavior in low-velocity regions. Conversely, under conditions of larger blade tip clearances, the cooling effectiveness of air-cooled turbines is more pronounced in regions characterized by low expansion ratios and low speeds.

Investigations on opportunities and challenges of brilliant high-power laser beam welding with 24 kW and adjustable power distribution for different materials

Solid-state laser beam sources offer the possibility of generating high-brilliance laser beams with low expansion and high usable intensity at the focal point. New approaches include beam shaping with the use of core and ring fiber and, therefore, variable power distribution in the laser beam focal point and material interaction area. Particularly, high-power laser beam welding benefits from beam shaping because of the stabilizing effect on the weld pool. Furthermore, the technical progress achieved with regard to beam quality also allows one to achieve high Rayleigh lengths and, therefore, a more uniform beam diameter over the whole material thickness. In this study, investigations on high-power laser beam welding with a 24 kW disk laser beam source are conducted for three different materials (mild steel, aluminum alloy, and copper), which are of high interest for welding in different sectors. The influence of power distribution between the core and the ring as well as welding speed on weld geometry (depth and width), weld pool stability, and the resulting weld seam quality is investigated. It is shown that the welding process cannot just be scaled up in comparison with welding with lower laser beam power but has its own challenges. It is possible that high welding depths (12 mm for copper, more than 12 mm is possible for aluminum, and 25 mm for mild steel) could be achieved in one pass. To achieve this, aluminum needs the lowest energy per unit length per mm of sheet thickness and copper the highest.

Puzzlingly Low Utilization of Solar Irrigation Pumps by Smallholders in Nepal Undermines Cost-Effectiveness

Abstract Solar Powered Irrigation Pumps (SIPs) hold substantial potential for low carbon irrigation expansion, particularly where affordable electricity is limited. In contrast to diesel-based irrigation, which carries steep fuel costs, irrigation by SIPs requires zero marginal costs, but high initial investments. This makes their competitiveness with diesel pumps highly dependent on the temporal frequency of their usage. Using unique and detailed data on SIP usage by smallholders in Nepal, we show SIP usage frequency is low, making it financially competitive with Diesel for only a small fraction of farmers. We analyze characteristics of farmers who make low/high usage of the SIP, and explore potential explanations for the puzzling low level of SIP use.

Preparation of high strength and rigidity carbon layer on SiO material surface by dynamic CVD method using gas carbon source C2H2

The main issue in the application of silicon-based negative electrode materials is the inevitable volume expansion, leading to negative electrode material fracture, which severely impacts the performance of batteries. This study employed Chemical Vapor Deposition (CVD) (C2H2@SiO), solid-phase coating method (Pitch@SiO), and liquid-phase coating method (RGFQ@SiO) to coat the surface of SiO materials with a dense amorphous carbon structure. Material property analysis revealed that C2H2@SiO has a relatively small specific surface area (1.8 m2 g−1) and surface carbon increment (2.4 %). It exhibited high reversible specific capacity (1563.4 mAh g−1), high initial Coulombic efficiency (81.45 %), and low volume expansion rate (9.3 %). Mechanical performance testing indicated that the surface carbon layer Young's modulus of C2H2@SiO was the highest (35 GPa), suggesting that using the CVD method to obtain a dense carbon layer can enhance the structural strength of the material. Based on the electrochemical-mechanical coupling theory simulation analysis of the stress during the charge-discharge process of electrode materials, the evolution of concentration and stress field during lithium insertion process was obtained, showing that the coating can further improve the electrochemical and mechanical performance of the negative electrode materials effectively. Additionally, the negative electrode sheets fabricated using sample C2H2@SiO were assembled into 18650 cylindrical batteries, exhibiting excellent cycling performance in 1000 cycles at 25 °C with a capacity retention rate of 85.7 %, along with good rate capability and high/low-temperature performance. The conclusions of this study provide certain guidance for the design and optimization of negative electrode materials for battery electrodes.

Enhancing lithium storage performance of Carbon/SiOx composite via coating edge-nitrogen-enriched carbon

Silicon oxide (SiOx) exhibits promising potential as a lithium-ion battery anode. However, its practical application is impeded by low electrical conductivity and significant volumetric expansion. To overcome these limitations, we developed a novel co-precipitation and selectively etching approach that leveraged the nitrogen-retaining effect of ZnNCN to prepare an edge-nitrogen-enriched carbon/SiOx composite (NEC@LC-SiOx). This NEC@LC-SiOx showed enhanced electrical conductivity and reduced volumetric expansion. Our innovative approach effectively prevented excessive decomposition of nitrogen species, resulting in a high nitrogen doping content of 21.67 at.% while maintaining a stable structure and mitigated volume expansion during charging and discharging. Consequently, the prepared NEC@LC-SiOx exhibited excellent performance as an anode material for lithium-ion batteries, demonstrating a high reversible specific capacity of 802 mAh/g and outstanding rate capability. This work presents a novel strategy for designing high-performance SiOx anode materials.

Study on Thermal Chamber Expansion of VH-SAGD Process Using CO2-Inducing Effect for Heavy Oil Reservoirs

In heavy oil thermal recovery processes, higher pressure usually leads to low dryness and expansion difficulty for the injected steam in thermal recovery processes, which will result in lower oil recovery and more carbon emissions. This paper proposed a new CO2-inducing method to accelerate the steam chamber expansion, based on a core flooding experiment and numerical simulation. First, the CO2 showed significant viscosity reduction at high pressure in the PVT test. In the core flooding experiment, the CO2 provided strong flow conductivity in porous media for the thermal flooding, as the CO2 pre-injection restrained the steam condensation. Using the CO2-inducing method, CO2 pre-injection before steam built a fast flow channel in a relatively higher permeability layer and reduced the thermal injection pressure by about 1.0~2.4 MPa. As a result, the steam overlap around the injection wells became slower and the gravity drainage process was able to heat and displace the heavy oil above the channel. Furthermore, the CO2 gas trapped at the top reduced heat loss by about 12.4%. The field numerical simulation showed that this new method improved thermal recovery by 7.5% and reduced CO2 emissions by about 18 million kg/unit for the whole process. This method changes the conventional thermal expansion direction by CO2 inducing effect and fundamentally reduces heat loss, which provides significant advantages in low-carbon EOR.

Sugar-rich foods exacerbate antibiotic-induced microbiome injury.

Intestinal microbiota composition is implicated in several diseases; understanding the factors that influence it are key to elucidating host-commensal interactions and to designing microbiome-targeted therapies. We quantified how diet influences microbiome dynamics in hospitalized patients. We recorded 9,419 meals consumed by 173 patients undergoing hematopoietic cell transplantation and profiled the microbiome in 1,009 longitudinally collected stool samples from 158 of them. Caloric intake was correlated with fecal microbiota diversity. Bayesian inference revealed associations between intake of sweets or sugars during antibiotic exposure with microbiome disruption, as assessed by low diversity or expansion of the pathobiont Enterococcus. We validated this observation experimentally, finding that sucrose exacerbated antibiotic-induced Enterococcus expansion in mice. Taken together, our results suggest that avoiding sugar-rich foods during antibiotic treatment may reduce microbiome injury.

Convenient synthesis of phthalonitrile‐containing mono‐benzoxazines with exceptional thermal stability and improved curing activity

AbstractSimple synthesis and high performance are eternal pursuit for polymers. To lower the curing temperature, lower the melt viscosity and improve the processability of high performance phthalonitrile resins, a solvent‐free method was applied to synthesize three from different phenols. Their chemical structure was confirmed by FTIR and NMR spectra, the curing behavior was investigated by DSC and rheology. It was found that the polymerization of phthalonitrile groups could be effectively promoted by benzoxazine moieties and the curing temperature of phthalonitrile groups dropped to around 240°C. Consequently, owing to the high curing reactivity, polymers obtained at relatively low curing temperature possessed high crosslinking density and extremely high thermal stability. P‐apn‐200, which was cured at 200°C, showed 5 wt% weightloss temperature (Td5) of 472°C and char yield (Yc) of 75.77% at 800°C. Moreover, the polymers obtained after curing at 280°C showed superior dimensional stability, CN‐apn‐280 showed extremely low linear expansion coefficient (CTE) of 10.7 ppm/°C. And mP‐apn‐280 showed HR capacity of 3.99 J/g‧K, peak HRR of 4.0 W/K and total HR of 0.8 kJ/g.

Geographical distance, cultural differences and digitalization

This study examines the impact of geographical distance,cultural differences, and digitalization on the internationalization ofCroatian franchise businesses, incorporating a thorough analysis basedon the 2022 Global Market Potential Index. Covering 97 countries, theresearch specifically focuses on 22 European Union nations, which areevaluated for their potential to expand franchising operations. Theanalysis delves into various dimensions, including market potentials,geographical proximity, and the degree of digitalization, withparticular emphasis on access to digital public services.Notable findings highlight those countries like Ireland, Germany,Switzerland, and the Netherlands, with their robust market sizes,significant trade volumes, and high economic growth, rank amongthe top ten on the global index. This underscores the substantialimpact of the European market on the franchising internationalizationprocesses, with ten EU countries featuring prominently among the toptwenty positions.The study also discusses the positioning of Germany, Ireland, andBelgium at the top of the list, contrasting with countries such asBulgaria, Greece, and Latvia, which exhibit lower potential forfranchising expansion. The proximity of markets like Serbia, Bosniaand Herzegovina, and North Macedonia is recognized; however,these countries are not extensively analyzed due to their geographicalcloseness and presumed familiarity to Croatian entrepreneurs, whichposes fewer challenges in market expansion decisions.To facilitate informed decision-making in the internationalizationprocess, this paper extends the analysis to include cultural factors,geographical distances, and the level of digitalization in target markets.

High-volume recycled glass cementitious and geopolymer composites incorporating graphene oxide

This study presents the development of high-volume recycled glass construction materials using recycled glass aggregate (RGA) as a 100 % sand replacement, recycled glass powder (RGP) as 40 wt% of the binder, and 0.1 wt% graphene oxide (GO) as nano-reinforcement. The research investigates the individual and their combined effects on the engineering performance, reaction kinetics (using calorimetry, X-ray diffraction-XRD, Fourier Transform Infrared-FTIR and Thermogravimetric analysis-TGA), and microstructure (Scanning Electron Microscopy/ Energy Dispersive X-ray Spectroscopy-SEM/EDS) for both cementitious and geopolymer systems. The results indicate that while RGA reduces strength and exacerbates alkali-silica reaction (ASR), the presence of 40 wt% RGP significantly mitigates ASR despite a lower strength gain in both systems. Geopolymers exhibit significantly lower ASR expansion compared to cementitious matrices owing to their superior alkali-binding capacity and denser microstructure, which restricts water and alkali ion mobility. 0.1 wt% GO was found to accelerate geopolymerisation, enhancing the strength of geopolymer mixes, but it decreased compressive strength in cement-based mixes due to self-desiccation-induced micro-cracking under ambient curing condition. The study also highlights that cement and metasilicate, as well as slag, are the main contributors to cost and CO2 emissions in cementitious and geopolymer systems, respectively. Overall, geopolymers exhibit a significantly lower global warming potential (< 180 kg CO2-eq/m3) compared to cement-based mixes (> 365 kg CO2-eq/m3) with a comparable cost (190–230 AUD/m3). The results indicate the potential for sustainable construction applications using high volumes of recycled glass, incorporating over 70 % of the mixture by weight.

Supramolecular-driven construction of multilayered structure by modified hummers method for robust silicon anode

Rational design of nano-structured silicon (Si)-based composites to enhance the structural stability and electrical conductivity is key to developing high-performance lithium-ion batteries. Here, a supramolecular self-assembly strategy is first adopted to prepare Si@rGO composites with multilayered structure through the modified Hummers method. Experimental results demonstrate that Si@SiOx NPs are uniformly distributed in rGO interlayers by supramolecular interaction. In situ Raman results suggest that the multilayer embedded structure can effectively confine the Si NPs and preserve the integrity of the electrode. Theoretical calculations indicate that the imbalanced charge distribution in inner interface shows enhanced dual-interfacial bonding and charge interactions in the Si@SiOx⊂rGO composite, resulting in an interfacial electric-field between Si NPs and rGO for fast ionic and charge migration. The fabricated MSi@SiOx⊂rGO anode with high Si contents (> 60 wt.% Si) exhibits superior Li-ion reaction kinetics (882.4 mAh g−1 at 8 A g−1), durable structural stability (0.031% per cycle capacity attenuation with an average Coulombic efficiency > 99.7%), and low expansion rate. High-mass-loading electrodes show great potential for commercial applications. Full cells assembled with LiCoO2 cathodes also demonstrate outstanding Li-ion storage properties. This work provides insights into the interfacial design of Si@C anodes for advanced Li-ion battery.

Hierarchical design of carbon nanofibers wrapped antimony selenide nanorods with heteroatom-doped carbon quantum dots as efficient anode material of high-performance sodium-ion batteries

Researchers have focused on sodium-ion batteries (SIBs) due to low precursor costs and abundant reserves. However, low efficiency of anode materials hinders SIB commercialization, mainly due to large ionic radius and slow kinetics of Na+. Metal selenides such as Sb2Se3 have regarded as promising anode materials of SIBs due to high theoretical capacities. Despite this, the practical application has been limited by the poor rate capability, conductivity, and stability. In this study, one-dimensional Sb2Se3 nanorods and nitrogen-doped carbon quantum dots (N-CQDs) combined with carbon nanofibers (CNFs) have been developed as an effective anode material of SIBs. The uniform distribution of N-CQDs in the Sb2Se3 coated CNFs (Sb2Se3/CNFs) anode results in the highest reversible capacity of 647.9 mAhg−1 at 0.05 Ag-1. Moreover, the Sb2Se3 and N-CQDs coated CNFs (Sb2Se3@N-CQDs/CNFs) anode presents a good rate performance and retains a high reversible capacity of 444.7 mAhg−1 at a high current density of 0.4 Ag-1. Additionally, the Sb2Se3@N-CQDs/CNFs anode demonstrates excellent stability, retaining 78.8% of the initial capacity after 100 cycles. The improved electrochemical performance is attributed to low volume expansion and good conductivity due to carbon coating and addition of N-CQDs. Galvanostatic intermittent titration technique is also used to examine Na+ diffusion coefficients.

Carbon-Based 3D Architectures as Anodes for Lithium-Ion Battery Systems.

Graphite, with its exceptional cyclic performance, continues to dominate as the preferred anode material for lithium-ion batteries. However as high-energy application gains momentum, there is growing demand for higher capacities that alloying/de alloying and conversion type anode materials can offer. Despite their potential, these materials are plagued by challenges such as volumetric fluctuations, low conductivities, and poor cyclic stability. Carbon nanostructures, on the other hand, show tremendous promise with their low volume expansion, high ion diffusion rates, and excellent conductivity. Nevertheless, their limited areal and volumetric densities restrict their widespread utilization. To address these limitations, various strategies such as doping, composite formation, and structural modification have been proposed. This article provides a succinct overview of carbon nanomaterials and their electrochemical performance as 3D carbon-based anodes, along with a comprehensive analysis of the strategies employed to overcome associated challenges while evaluating their potential prospects in the field.

Effect of calcium silicate on foaming and anti‐shrinkage behavior of thermoplastic polyamide elastomers: Revelation of the open‐cell mechanism

AbstractThermoplastic polyamide elastomer (TPAE)/calcium silicate (CaSiO3) open‐cell foam with low shrinkage and high expansion ratio was prepared by using supercritical CO2 as a blowing agent. Adding CaSiO3 led to increased melt viscoelasticity and reduced crystallinity of TPAE. The primary mechanism of CaSiO3 promoting TPAE foam to form the open‐cell structure was discussed. The interaction between CaSiO3 and TPAE is fragile, making CaSiO3 easy to fall off the cell wall and form the open‐cell structure during foaming process. The increasing CaSiO3 content leads to increased cell density and thinned cell walls, thus increasing the tensile stress on cell wall. On the other hand, the agglomeration of CaSiO3 increases particle size, making it easier to fall off from the adhesion of TPAE matrix. The two aspects work together to improve the open‐cell content of TPAE foam up to 93.28%. The open‐cell structure is conducive to increasing the gas exchange rate and significantly decreasing foam shrinkage ratio. Finally, TPAE foam with a shrinkage ratio of only 2.68% and an expansion ratio of 18.77 times was obtained. In addition, open‐cell structure improves the adsorption performance of TPAE/CaSiO3 foam by 500%.

Dual-active sites and reversible-structural covalent organic framework for highly stable alkali metal-ion batteries

Organic materials are promising candidates for energy storage due to their sustainability, environmental friendliness, and structural designability. However, their application is severely limited due to short lifespan and sluggish kinetics caused by low redox stability, solubility, and low electronic conductivity. Here, we designed a polyimide-conjugated covalent organic framework (NAA-COF). Its highly covalent framework cannot only endow the organic material with strong π–π interactions and robust network ensuring its structure stability, but also offer open channels for rapid ions/electrons transfer inside. Additionally, the introduction of multiple redox-active sites can significantly enhance ion-storage capacity. Consequently, when evaluated as a cathode for Li-ion batteries, NAA-COF exhibits large capacity of 220mAh/g, superb initial coulombic efficiency (90 %), good voltage platform, long lifespan (10000 cycles), and high-rate performance (110 mAh/g at 10 A/g). More importantly, even for Na-/K-ion batteries, the exceptional electrochemical performances can still be maintained. In situ transmission electron microscopy (TEM) and in/ex situ spectroscopy further elucidate the low volume expansion (12.2 %) during the lithiation process and 8-electron reaction mechanism for the NAA-COF cathode. This work provides a high-performance universal COF cathode material that can simultaneously satisfy the requirements of alkali metal-ion batteries.

Analysis of the morphology of Sus scrofa domesticus oocyte-cumulus complexes exposed to low and ultra-low temperatures

Relevance. The priority task of reproductive technologies in animal husbandry is the development of effective storage protocols for female gametes. One way to preserve gametes is vitrification, which reduces damage to intracellular organelles by increasing viscosity upon cooling and minimizing crystallization.Methods. Various additives to cryoprotectants are used for optimization. In our work, titanium tetrapolyethylene glycolate was used in a 10-fold molar excess of polyethylene glycol (TTPEG*10PEG), the nature of the effect of which on cells was studied during short-term storage at low (5 °С) and ultra-low temperatures (-196 °С).The purpose of the study is a comprehensive analysis of the morphology of gametes and somatic cells (cumulus) of ovarian follicles of pigs after exposure to low and ultra-low temperatures (vitrification) when included in the TTPEG*10PEG low-temperature storage and vitrification protocol.Results. Exposure to TTPEG*10PEG at 5 °С caused an increase in the level of oocytes with subsequent morphological degenerations in points with control (from 13% to 5%, р = 0.005). After vitrification with TTPEG*10PEG: the level of gametes with low cumulus cells expansion increased to 35% in terms of the proportion of control gametes (23%); the proportion of denudated gametes was reduced to 50% compared to the control 65% (р &lt; 0.05); the level of morphologically degenerated gametes corresponded to that of native oocytes (8% each) and was lower than in the control (17%), р &lt; 0.005. The obtained data indicate the protective and cryoprotective effects of TTPEG*10PEG at a concentration of 2%, which suggests the possibility of its use in the technology of intraovarian vitrification of female reproductive cells.