Low Environmental Impact Research Articles

Mechanical Properties and Flammability Analysis of Wood Fiber Filled Polylactic Acid (PLA) Composites Using Additive Manufacturing

ABSTRACT Natural fibers, such as wood fibers, can substitute for synthetic fibers in various applications due to their low environmental impact, cost-effectiveness, and outstanding mechanical properties as rapid-growing materials and renewable resources. This paper aims to investigate the mechanical properties of 20% wood fiber as a reinforcement material in polylactic acid (PLA) using an additive manufacturing approach. The samples were fabricated using 3D printing techniques. The relevant parameters included the orientation of printing in X, Y, and Z directions, with the percentage of infill set to be 100%. The findings indicated that bio-composites and their adopted printing orientations confirmed the significant effects on the mechanical properties. Pure PLA possessed superior properties in all directions compared to wood/PLA. The highest values were 50.33 MPa for tensile strength and 94.36 MPa for flexural strength, both achieved in Y orientations. However, composites showed an improvement in tensile and flexural moduli in X orientation with 1395.40 MPa, and 2937.72 MPa for Young and flexural modulus, respectively. In the flammability test, wood/PLA bio-composites were ignited easily with reduced smoke production compared to the neat PLA. Wood/PLA bio-composites exhibited high stiffness, and their mechanical properties were influenced by many factors, such as percentage of weight fraction, wood type, and printing orientations.

Flexibility with low environmental impact

Flexibility with low environmental impact

Integrating life cycle assessment and multi criteria decision making analysis towards sustainable cocoa production system in Indonesia: An environmental, economic, and social impact perspective

Sustainable Cocoa production practices should be investigated comprehensively to address sustainability requirements and mitigate Cocoa production issues in Indonesia. This study aims to identify the sustainable Cocoa production system considering the environmental, economic, and social impacts. Life cycle framework and multicriteria decision-making (MCDM) were integrated to obtain the study's objectives by comparing Cocoa monocropping system (CM) and Cocoa intercropping systems (IC). The result indicated that in the environmental sustainability aspect, the monocropping system (CM) showed higher performance as indicated by the lower environmental impact in all indicators; for example, CM emitted a lower Global Warming Potential (GWP) that has a lower margin of 34.5–55.9 % compared to the intercropping system (IC-I and IC-II). In the economic aspect, both on the short-term and long-term analysis, the Cocoa intercropping system (IC-II) generated higher value-added and economic feasibility, with a higher profit margin of 150–205 % compared to CM and IC-1. Along with the increase of economic benefits in IC II, this system also significantly provides social benefits, as presented by the higher social index margin of 4.9–23.7 % compared to other systems. Furthermore, by applying decision-making analysis, the result determines the highest index on the Cocoa intercropping system II (IC-II). These findings highlight that applying the intercropping system II is recommended to overcome the cocoa issue at the farmer and decision-maker levels. Additionally, the proposed method that combined LCA-MCDM can be applied to another agricultural commodity to achieve sustainable agriculture production.

Effect of Annealing Time on Various PtNi/C Binary Alloy Catalysts for ORR in PEFCs

Polymer electrolyte fuel cells (PEFCs) are used in automotive power supplies due to their advantages of low environmental impact and high energy conversion efficiency. However, Pt used for electrocatalysts is expensive and its activity and durability are problematic. In this study, the PtNi/C catalysts were prepared with different annealing times and the oxygen reduction reaction activity was evaluated. The linear sweep voltammograms and current-voltage curves showed that the PtNi/C catalysts annealing time for 60 min performed better than the commercial catalyst. This would be attributed to the internal alloying of Ni and better electronic structure due to the longer annealing time.

Morphological, Thermal, and Mechanical Assessment of Polypropylene and Ammonium Phosphate Composites Enhanced with Lignosulfonate and Zirconium.

Polypropylene and ammonium phosphate (AP) composites were synthesized at a 25 wt% concentration. The changes in the morphological, thermal, and physical behavior of the composites were analyzed with the addition of lignosulfonate (LG) and zirconium phosphate (ZrP). Additionally, metallic zirconium was deposited onto lignosulfonate using the magnetron sputtering technique to develop polypropylene and zirconium-modified lignosulfonate (LGMod) composites. Thus, composites of PP/25AP, PP/25AP/8LG/5ZrP, and PP/25AP/8LGMod were synthesized. The synthesis involved mixing the materials in a Hake mixer, followed by compression molding. The composites were characterized by field emission scanning electron microscopy (SEM-EDS), a thermogravimetric analysis (TGA) with combustion parameters, a vertical burn test (UL-94), a thermal camera, and mechanical properties. All composites achieved a V2 rating according to UL-94 standards. The PP/25AP extinguishes flames more quickly compared to other materials, approximately 99.2% faster than PP and showed the lowest temperature variation and mass loss after burning. The PP/25AP/8LG/5ZrP composite exhibited a 7% higher rigidity and 84.5% better flame retardancy compared to pure PP. Additionally, substituting ZrP with LGMod led to a lower environmental impact and improved thermal properties, despite some mechanical disadvantages.

The impact of health and environmental messaging with and without product filtering in complex retail markets: the case of pulses.

Multiple barriers exist to healthy and environmentally sustainable food choices. Limited consumer understanding of the health and environmental implications of food choices complicates their abilities to make choices that lead to desired outcomes. The complexity of the retail environment itself may crowd out less immediate motivations to address health or environment. Even if consumers understand general impacts of food choices on health and environmental outcomes, there may be non-negligible time and search costs to identifying the products that meet consumers' needs. In many food categories, the foods containing attributes that help achieve health and sustainability outcomes may represent a small percentage of available products. In this research, we examine the case of pulses-beans, chickpeas, lentils, and dry peas. Pulses are nutritious and have a low environmental impact. However, consumption of pulses in the US is quite low, which may be attributable to low consumer knowledge of pulse benefits, as well as difficulty of identifying pulse products in retail environments. In this research, we examine the choice of pulse-based foods in three conditions: (1) a control condition, (2) a messaging condition communicating the health and environmental benefits of pulse products, and (3) a paired messaging condition with a choice environment intervention that allows respondents to choose to filter products to those that contain pulses. Participants selected a food item from each of six food categories. We find slight, but significant, increases in pulse choice in the messaging only condition relative to the control condition, but dramatic and highly significant increases when participants can filter the products to easily view pulse products. We also find evidence for knowledge being a barrier to healthy/sustainable food choice. Participants exposed to the messaging were more likely to view pulses as environmentally beneficial, and less likely to report that they did not know the health or environmental impacts of pulse foods. We find that paired messaging and filtering interventions significantly increase the choice of pulse-based foods, which offer both human health and sustainability benefits.

Utilization of CoSe2-loaded carbon nanofibers for enhancing separator performance in lithium-sulfur batteries: Polysulfide immobilization and redox conversion enhancement

Lithium‑sulfur batteries (LSBs) are recognized as promising candidates for the next generation of secondary batteries due to their high energy density, high theoretical capacity, and low environmental impact. However, the poor electrical conductivity of sulfur and Li2S, the “shuttle effect” of polysulfides, and the slow kinetics of redox reactions have significantly hindered the practical application of LSBs. In this work, CoSe2-loaded carbon nanofibers (CoSe2@CNF) derived from metal-organic frameworks were successfully prepared by electrospinning and used as a functional coating on the polypropylene separator. The three-dimensional network structure of CNFs not only improves the electrical conductivity of the material but also provides channels to facilitate ion and electron transport, while the CoSe2 particles distributed on the surface effectively act as adsorption and catalytic active sites for lithium polysulfides. Under the synergistic effect, the CoSe2@CNF-modified separator suppressed the shuttle effect and significantly enhanced the kinetics of redox reactions. The LSBs assembled with CoSe2@CNF-modified separator exhibited excellent electrochemical performance, achieving an initial capacity of 1445.6 mAh g−1 at 0.5C and maintaining a discharge specific capacity of 849.5 mAh g−1 after 275 cycles.

Enhancing bio-composite performance: mechanical properties of Diss fibre-reinforced epoxy

As industries increasingly adopt composites for their superior stress resistance, the high cost and environmental challenges associated with their disposal remain significant concerns. Bio-composites offer a sustainable alternative by addressing these issues with better recyclability and lower environmental impact. This study explores the mechanical performance of a bio-composite featuring Diss fibres embedded in an epoxy matrix. We conducted tensile and Charpy impact tests to measure Young's modulus and impact energy, respectively. Different weight percentages of Diss fibres (wtD%) were used to prepare the specimens. The findings indicate that the Young's modulus of the bio-composite peaked at 1.30GPa with 20wtD%, after which it declined. The incorporation of Diss fibres notably enhanced the tensile strength of the samples compared to the pure epoxy matrix. Additionally, impact energy increased with higher wtD%, reaching a maximum of 3.5J at 30wtD%. These results suggest that Diss fibres are a viable reinforcement material for developing greener composites.

Sustainability analysis of apple orchards: Integrating environmental and economic perspectives

The agricultural sector faces numerous challenges today, including the protection of biodiversity and the mitigation of environmental impact. Addressing these challenges require ensuring the stability of farmers' income, thus facilitating effective land management.The present study aims to evaluate the environmental and economic sustainability of apple orchards under two distinct systems (integrated versus organic) and a scab-resistant variety. The Life Cycle Assessment method (LCA) was employed to evaluate environmental impact, while financial and economic aspects were analysed using metrics such as Net Present Value (NPV), Equivalent Annual Value (EAV), Benefit-Cost Ratio (B/C) and Discounted Payback Period (DPP).Results analysis reveals that both inorganic fertilisation and pesticides usage have the greatest impacts in both integrated cultivation and scab-resistant orchards. In organic orchards, diesel usage emerges as a primary factor due to the substitution of chemical interventions with mechanical methods. For the same reason, labour constitutes 45 % of the organic production costs. Despite the lower environmental impact, organic treatments still contribute 22 % of the total production cost. Regarding the investment evaluation, the scab-resistant variety offers marginally lower costs than conventional varieties due to the reduction of required treatments; however, organic farming shows superior economic performance despite higher production costs, mainly attributed to higher market prices. This highlights the influence of market dynamics on business decisions in the apple sector, where farmers often have no direct control.

What is a sustainable diet in the Norwegian context?

Introduction: Sustainable diets promote health and wellbeing and have low environmental impact. They should be accessible, affordable, safe, equitable and culturally acceptable. Translating these general principles into Norwegian-specific dietary recommendations is essential, as foods beneficial for health tend to also be environmentally sustainable. Following the dietary recommendations is an important step towards sustainability. Aim: To identify challenges and potential solutions for transitioning towards more sustainable diets in Norway. Methods: We used scientific articles, reports, policy documents, and statistics on Norwegian food production and consumption to discuss a sustainable diet in a Norwegian context. Results and discussion: There is a large gap between dietary guidelines and actual consumption. More than 60% of the calories in the Norwegian diet are based on imported foods and feed. Changing people’s diet is identified as central in transforming the food system to become more sustainable, as is prioritizing the use of local resources. Good animal health and welfare are also fundamental premises for a sustainable food system. Conclusions: Transitioning to a more sustainable diet requires comprehensive efforts at multiple levels. There is considerable room for action to increase the use of Norwegian resources in a sustainable and responsible way. Potential strategies include reducing meat intake in favour of plant-based foods and fish, consuming more local products, decreasing food waste and supporting agricultural practices that promote environmental and social sustainability. A more sustainable diet may also lead to significantly increased self-sufficiency and food security in Norway.

Calibration Methods for Large-Scale and High-Precision Globalization of Local Point Cloud Data Based on iGPS.

The point cloud is one of the measurement results of local measurement and is widely used because of its high measurement accuracy, high data density, and low environmental impact. However, since point cloud data from a single measurement are generally small in spatial extent, it is necessary to accurately globalize the local point cloud to measure large components. In this paper, the method of using an iGPS (indoor Global Positioning System) as an external measurement device to realize high-accuracy globalization of local point cloud data is proposed. Two calibration models are also discussed for different application scenarios. Verification experiments prove that the average calibration errors of these two calibration models are 0.12 mm and 0.17 mm, respectively. The proposed method can maintain calibration precision in a large spatial range (about 10 m × 10 m × 5 m), which is of high value for engineering applications.

Multifunctional properties of peptides derived from black cricket (Gryllus assimilis) and effects of in vitro digestion simulation on their bioactivities

Insects are a rich source of proteins and are produced in systems that have lower environmental impact. As an alternative protein source, they can be consumed directly or used as an ingredient in other formulations. Recently, there has been growing interest in utilizing insect proteins as a substrate to obtain bioactive peptides as well as in investigating the maintenance of their biological properties under physiological conditions. This study aimed to evaluate the impact of simulated digestion on the bioactive properties of protein hydrolysates from black crickets (Gryllus assimilis). Following simulated digestion of the hydrolysate obtained through the application of Flavourzyme, the scavenging activities of ABTS and DPPH radicals, and ferric reducing antioxidant power (FRAP) increased by approximately 17 %, 246 %, and 173 %, respectively. For the hydrolysate obtained using the binary combination of Flavourzyme/Neutrase, the inhibitory activities of α-amylase and α-glucosidase after digestion were 47.87 % and 12.73 %, respectively, not significantly (p > 0.05) different from non-digested hydrolysates. The angiotensin-converting enzyme (ACE) inhibitory activity of the sample hydrolyzed with Flavourzyme/Alcalase proteases was 42.22 %, but this property was completely lost after in vitro digestion. Untargeted proteomic analysis allowed the identification of 22 peptides in the <3 kDa fraction of the digested black cricket protein. The LPPLP sequence was considered potentially bioactive for all activities tested in silico.

Optimization of microwave-assisted drying of scallions (Allium fistulosum L.): A comprehensive study on drying kinetics, energy consumption, CO2 emissions, and thermodynamic properties

This study explores the effectiveness of microwave-assisted drying for scallions (Allium fistulosum L.), focusing on drying kinetics, energy consumption, CO2 emissions, and thermodynamic properties. Scallion samples were subjected to different microwave power levels (136 W and 264 W) and varying sample masses (5 g, 10 g, and 20 g) to assess the drying process. The Page model was identified as the most suitable for describing the drying kinetics, providing a precise fit to the experimental data. The study revealed that higher microwave power levels significantly enhanced the drying efficiency by increasing moisture diffusivity, thereby reducing drying time. The thermodynamic analysis indicated that the drying process is endothermic, requiring external energy for moisture removal, with positive enthalpy and Gibbs free energy values confirming the non-spontaneous nature of the process. Entropy analysis suggested a decrease in molecular disorder during drying. In terms of energy consumption and CO2 emissions, the results highlighted that microwave-assisted drying offers a lower environmental impact, with specific energy consumption (SEC) values demonstrating efficient energy use during the drying process. This study supports the viability of microwave-assisted drying as a sustainable and efficient method for processing scallions. The findings provide valuable insights for optimizing drying processes in the food industry, emphasizing the potential for microwave drying technologies to improve energy efficiency and reduce environmental impact.

Life cycle assessment of polysilicon photovoltaic modules with green recycling based on the ReCiPe method

Polysilicon photovoltaic (PV) modules are about to enter the end-of-life (EOL) stage on a large scale, and making the exploration of effective recycling methods and comprehensive evaluations their environmental impact through life cycle assessment (LCA) are key issues that need to be urgently tackled. In this study, we innovatively propose a recycling method utilising the green organic solvents 1,3-dimethyl-2-imidazolidinone (DMI) and deep eutectic solvent (DES). Additionally, an LCA of 1 m2 polysilicon PV modules - from industrial silicon production to waste recycling - was conducted using the ReCiPe 2016 method. The results indicate that the recycling process of polysilicon has the lowest environmental impact (1.02 Pt), whilst the production process has the highest environmental impact (4.22 Pt), leading to greater uncertainty. Sensitivity analyses showed that the sensitivity of the whole process was higher for electricity consumption and global warming (GW). Comparing the green organic solvent recycling to downcycling and landfill further demonstrates that environmental impact can be significantly reduced by employing this green organic solvent recycling approach, providing an important theoretical and practical pathway to promote the circular economy and sustainable development of the PV industry.

The Environmental Impact of Low-Pressure Anhydrous Dyeing Technology for Polyester: Carbon Footprint Quantification and Evaluation

Many emerging dyeing technologies have recently entered laboratory research or industrial production phases. However, only a few studies have evaluated and compared the environmental impact of different dyeing systems. This study calculated the carbon footprint of low-pressure anhydrous dyeing for polyester and compared with conventional water bath dyeing. The results showed that the carbon footprint of the anhydrous dyeing process was 1670 kgCO2 eq/1000 kg polyester. Steam occupied the most significant proportion, accounting for 55.5%, followed by electricity at 35.5%. The waste has the lowest environmental impact, with 0.55%. Uncertainty analyses showed that the data and results in this article were reliable. The results of the sensitivity analyses indicated that more attention should be paid to the data quality of steam and electricity. Compared with the traditional water bath dyeing process, the low-pressure anhydrous dyeing system can reduce greenhouse gas emissions by more than 30% and, more importantly, can avoid almost all the consumption of clean water. This anhydrous dyeing system can save water and reduce carbon emissions, which is of positive significance to the sustainable development of the textile and fashion industry. Further studies could use the water footprint as an indicator to evaluate this dyeing system in terms of water consumption and potential environmental impact.

Preliminary Study of Stone Sawing Sludges-based Alkali Activated Materials (AAMs) for the Conservation of Archaeological Ceramics

This paper presents research into the feasibility of using stone sawing sludge-based Alkali Activated Materials (AAMs) for conservation of Cultural Heritage. Sawing sludges are a stone processing waste product resulting from the mixing of rock powder with the water used to cool down the cutting blades. The chemical composition of the sawing sludges, when aluminosilicatic, is suitable for acting as a precursor to produce AAMs. AAMs are known for their low environmental impact and versatility since their existence is drawn from recycling waste materials. One of their possible applications is in the conservation of Cultural Heritage objects. This work presents a preliminary investigation into three sawing sludge-based AAMs with different mineralogical compositions and contributes to formulating guidelines for applying them as fillers on modern and archaeological ceramic pottery based on the evaluation of their workability, appearance and physical properties over time from the moment of application and up to 30 days. Dynamic Vapor Sorption and X-Ray Diffraction results provided an overview of the structural and mineralogical changes under high RH conditions, where the tested AAMs showed a type II isotherm curve, as expected for concrete-like materials, as well as disappearance of thermonatrite after one isothermal cycle. Ultrasonic Pulse Velocity test demonstrated the general homogeneity of the AAMs despite the lower velocity exhibited by one of the formulations, probably due to its internal pore distribution and possible presence of microstratification. The Oddy tests, application tests and colourimetric measurements evidenced the advantages and weaknesses of the AAMs, with overall encouraging results ensuing investment in further in-depth studies of these innovative conservation materials in view of their future use in the field of conservation of Cultural Heritage as a result of a circular economy model.

Gross to gourmet: A social media analysis of Naked Clams as a sustainable delicacy

AbstractAmidst a global food crisis, securing sustainable food sources is vital. Bivalves such as Naked Clams, historically known as shipworms, offer a promising solution due to their low environmental impact, high nutritional value, and rapid growth rates. Contrary to their image as pests, Naked Clams are the fastest growing bivalves and have various health benefits. Believed to be the world's first aquaculture species, cultivated by Aboriginal Australians 8000 years ago, they are a delicacy in Southeast Asia. Public perception of Naked Clams remains largely unexplored, hindered by their association as pests and worm‐like appearance. This study assesses the perception of Naked Clams through social media, analyzing 40 posts across Facebook, Instagram, TikTok, and YouTube, with millions of views and likes. Analysis of nearly 8000 comments revealed that public perception was split, though generally more positive than negative. Concerns included appearance, potential religious dietary conflicts, and the risk of parasites, which can be addressed with educational campaigns. Importantly, 84% of commenters who tried Naked Clams reported liking them. Naked Clams are noted for their high protein content, nutrient density, and health benefits, and are enjoyed in diverse culinary forms, from traditional raw dishes, to battered calamari‐style street foods, to innovative recipes like Naked Clam ice cream. This study highlights the untapped potential of Naked Clams in global diets and calls for further exploration into moving Naked Clams from “gross to gourmet.”

Behind the scenes: metagenomic analysis of bacterial communities in sustainable depilation of sheepskin.

The leather industry is embracing eco-friendly technologies for both regulatory compliance and sustainable growth. While enzymatic depilation provides a greener alternative to traditional beamhouse methods, its complexity often leads to higher costs. To address this, we examined the performance of sheepskins' native bacterial flora in acetic acid conditions with low-environmental impact. Utilizing metagenomic techniques, we analyzed the bacterial community dynamics during the depilation process. This investigation revealed a notable increase in microbial diversity and richness in acetic acid treatments compared to water treatments. At the class level, a post-processing decrease in Gammaproteobacteria dominance was observed, while Actinomycetia numbers surged in the acetic acid group. In contrast, the water group showed an increase in Bacteroidia. Order-level analysis indicated reductions in Pseudomonadales and increases in Actinomycetales with acetic acid treatment, whereas Flavobacteriales was more prevalent in water-treated liquors. At the family level, Moraxellaceae decreased and Micrococcaceae increased in the acetic acid group, in contrast to the marked rise of Weeksellaceae in the water group. Temporal analyses further highlighted the evolving bacterial landscapes under different treatments. Moreover, acetic acid treatment fostered a stable microbial community, beneficial for sustainable leather processing. Functional pathways were predicted using PICRUSt2. It showed that significantly enriched degradation pathways in the water group were less abundant in the acetic acid group, potentially preventing substrate matrix damage during depilation. The study underscores the transformative potential of acetic acid for the leather industry, offering a pathway to reduce pollution while maintaining economic viability. By enhancing our understanding of microbial interactions during depilation, this study opens avenues for refining these eco-friendly techniques. Our findings advocate for a shift towards greener depilation methods and contribute to the broader dialogue on sustainable manufacturing practices, emphasizing the importance of leveraging indigenous microbial communities for environmental and economic gains.

Damage and fracture studies of continuous flax fiber-reinforced composites 3D printed by in-nozzle impregnation additive manufacturing

Additive manufacturing (AM) of continuous yarn-reinforced biobased composites presents multi-functional properties and low environmental impact of this technology. Few studies focused on the mechanical damage mechanisms of continuous biobased composites obtained by AM processes, while it is a topic of high interest for the mastery of mechanical behaviors and optimization of the materials for high requirement applications. This study aims to assess the damage and fracture modes of continuous flax yarn-reinforced PLA manufactured by AM, with different yarn orientations. The additively manufactured biobased composites were characterized by tensile test, 3D microscopy and micro-tomography to link the process-structure-properties relationships regarding the damage and fracture modes. The results showed that the 0° manufactured composite had a significant enhancement of tensile properties compared to other configurations. The damage mechanism presented fiber rupture with polymer transverse cracks at 0°, while the 45° and 90°-oriented composites showed premature fiber/matrix interface debonding. This study aims to find the relationship between damage mechanisms, deposition strategy, and anisotropy of the additively manufactured long vegetal fibers-reinforced biobased composite materials. The results bring a new understanding of the anisotropy and defects in printed composite materials regarding their mechanical behaviors during damage.

Fabrication of Bi‐Functional Samarium Oxide/Copper Oxide Nanocuboid Electrocatalyst for Electrochemical Water Splitting

The development of low‐cost, high‐performance electrocatalysts for the oxygen evolution reaction (OER) is essential for a vast array of chemical and energy transformation applications. Using non‐platinum metals as electrocatalysts in a key process such as OER has become increasingly attractive given their relatively low cost, high electrocatalytic activity, and low environmental impact. Herein, to achieve a better catalytic material with high permeability and mass charge transfer in a catalytic framework, a novel, oxygen‐defective Sm2O3/CuO nanohybrid with nanocuboid architecture is developed. The creation of a new composite material which consist of samarium oxide and copper oxide, demonstrates high effectiveness in the process of electrochemical water splitting. The combined use of samarium oxide and copper oxide improves the electrocatalytic performance, stability, and durability due to it synergistic effect. In alkaline media, the Sm2O3/CuO nanocomposite exhibits an astonishing overpotential of 248 mV along with a lower Tafel value of 46 mVdec−1 for OER and nanocomposite also exhibits acceptable hydrogen evolution reaction (HER) performance. Due to the unprecedented porous nanocuboid morphology and the strong synergistic effect between the two materials, the oxygen‐defective Sm2O3/CuO composite exhibits impressive electrical properties and performs exceptionally well as an electrocatalyst for intrinsic water splitting. At an operational potential of 0.5 V, porous Sm2O3/CuO displays outstanding reactivity, Sm2O3/CuO exhibits remarkable results during electrochemical operation.